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1. 发明授权

US4613706A Isomer-directed process for producing asymmetric ketones using catalytic Claisen rearrangement of allylic ethers, intermediates, and uses of products and intermediates of process in perfumery 失效
公开(公告)号：US4613706A
公开(公告)日：1986-09-23
申请号：US765231
申请日：1985-08-13
申请人： Mark A. Sprecker , Robert P. Belko , William L. Schreiber , Michael Licciardello
发明人： Mark A. Sprecker , Robert P. Belko , William L. Schreiber , Michael Licciardello
IPC分类号： C07C43/305 , C07C45/51 , C07C49/203 , C07C49/217 , C07C403/00 , C11B9/00
CPC分类号： C07C403/16 , C07C43/305 , C07C45/515 , C11B9/0015 , C11B9/0034 , C11B9/0061 , C07C2101/14 , C07C2101/16
摘要： Described is an isomer-directed process for producing asymmetric ketones defined according to the generic structure: ##STR1## wherein one of Z.sub.1 or Z.sub.2 is the moiety: ##STR2## and the other of Z.sub.1 or Z.sub.2 is hydrogen; wherein R.sub.11 and R.sub.21 represent hydrogen or the same or different alkyl or alkenyl with the proviso that R.sub.11 and R.sub.21 are not both hydrogen or wherein R.sub.11 and R.sub.21 taken together:(i) complete a cycloalkyl, cycloalkenyl, bicycloalkyl, mono or polyalkyl cycloalkyl or mono or polyalkyl cycloalkenyl ring, or(ii) represent alkylidene, cycloalkenyl alkylidene, aralkylidene, mono or polyalkyl cycloalkenyl alkylidene or mono or polyalkyl aralkylidene;and wherein R.sub.6, R.sub.7 and R.sub.8 are the same or different and each represents hydrogen or methyl, using a catalytic Claisen rearrangement of allylic ethers previously formed by reacting substituted or unsubstituted allylic alcohols defined according to the structure: ##STR3## with dialkyl ketals defined according to the structure: ##STR4## wherein R.sub.4 and R.sub.5 represent the same or different C.sub.1 -C.sub.4 alkyl.Also described are compounds and processes for using same in perfumery defined according the structures: ##STR5## Also described are certain diallylic ethers defined according to the generic structure: ##STR6##

2. 发明授权

US4548743A Ketal and use in perfumery 失效
标题翻译：金属和用于香料
公开(公告)号：US4548743A
公开(公告)日：1985-10-22
申请号：US602646
申请日：1984-04-20
申请人： Mark A. Sprecker , Robert P. Belko , William L. Schreiber , Michael Licciardello
发明人： Mark A. Sprecker , Robert P. Belko , William L. Schreiber , Michael Licciardello
IPC分类号： A61K8/00 , A61K8/35 , A61Q13/00 , C07C43/30 , C07C43/305 , C07C45/00 , C07C45/51 , C07C49/20 , C07C49/203 , C07C49/217 , C07C49/557 , C07C67/00 , C07C401/00 , C07C403/00 , C07C403/14 , C07C403/16 , C11B9/00 , A61K7/46 , C07C43/32
CPC分类号： C07C403/16 , C07C43/305 , C07C45/515 , C07C49/203 , C07C49/217 , C07C49/557 , C11B9/0015 , C11B9/0034 , C11B9/0061 , C07C2101/14 , C07C2101/16
摘要： Described is the compound having the structure ##STR1## useful in perfumery.
摘要翻译：描述了具有用于香料的结构的化合物。

3. 发明授权

US4616095A Isomer-directed process for producing asymmetric ketones using catalytic claisen rearrangement of allylic ethers, intermediates, and uses of products and intermediates of process in perfumery 失效
标题翻译：使用烯丙基醚的催化裂化重排，中间体以及香料中的产品和中间体的产物和中间体来生产不对称酮的异构体定向方法
公开(公告)号：US4616095A
公开(公告)日：1986-10-07
申请号：US765342
申请日：1985-08-13
申请人： Mark A. Sprecker , Robert P. Belko , William L. Schreiber , Michael Licciardello
发明人： Mark A. Sprecker , Robert P. Belko , William L. Schreiber , Michael Licciardello
IPC分类号： C07C43/305 , C07C45/51 , C07C49/21 , C07C49/217 , C11B9/00
CPC分类号： C07C403/16 , C07C43/305 , C07C45/515 , C11B9/0015 , C11B9/0034 , C11B9/0061 , C07C2101/14 , C07C2101/16
摘要： Described is an isomer-directed process for producing asymmetric ketones defined according to the generic structure: ##STR1## wherein one of Z.sub.1 or Z.sub.2 is the moiety: ##STR2## and the other of Z.sub.1 or Z.sub.2 is hydrogen; wherein R.sub.11 and R.sub.21 represent hydrogen or the same or different alkyl or alkenyl with the proviso that R.sub.11 and R.sub.21 are not both hydrogen or wherein R.sub.11 and R.sub.21 taken together:(i) complete a cycloalkyl, cycloalkenyl, bicycloalkyl, mono or polyalkyl cycloakyl or mono or polyalkyl cycloalkenyl ring, or(ii) represent alkylidene, cycloalkenyl alkylidene, aralkylidene, mono or polyalkyl cycloalkenyl alkylidene or mono or polyalkyl aralkylidene;and wherein R.sub.6, R.sub.7 and R.sub.8 are the same or different and each represents hydrogen or methyl, using a catalytic Claisen rearrangement of allylic ethers previously formed by reacting substituted or unsubstituted allylic alcohols defined according to the structure: ##STR3## with dialkyl ketals defined according to the structure: ##STR4## wherein R.sub.4 and R.sub.5 represent the same or different C.sub.1 -C.sub.4 alkyl.Also described are compounds and processes for using same in perfumery defined according the structures: ##STR5## Also described are certain diallylic ethers defined according to the generic structure: ##STR6##
摘要翻译：描述了根据通用结构定义的不对称酮的异构体定向方法：其中Z1或Z2之一为部分：Z1和Z2中的另一个为氢; 其中R11和R21表示氢或相同或不同的烷基或烯基，条件是R11和R21不同时为氢或其中R11和R21一起组合：（i）完成环烷基，环烯基，双环烷基，单或多烷基环烷基或单或聚烷基环烯基环，或（ii）代表亚烷基，环烯基亚烷基，亚烷叉基，单或多烷基环烯基亚烷基或单或多烷基亚烷基; 并且其中R 6，R 7和R 8相同或不同，并且各自表示氢或甲基，使用以前通过使根据以下结构定义的取代或未取代的烯丙基醇反应形成的烯丙基醚的催化Claisen重排：＆lt; IMAGE＆gt; 结构：其中R 4和R 5表示相同或不同的C 1 -C 4烷基。还描述了在根据以下结构定义的香料中使用它们的化合物和方法：其中描述了根据以下结构定义的某些二烯丙基醚：到通用结构：

4. 发明授权

US4576741A Isomer-directed process for producing asymmetric ketones using catalytic Claisen rearrangement of allylic ethers, intermediates, and uses of products and intermediates of process in perfumery 失效
标题翻译：使用烯丙基醚的催化Claisen重排，中间体以及香料中产品和方法中间体的用途来生产不对称酮的异构体定向方法
公开(公告)号：US4576741A
公开(公告)日：1986-03-18
申请号：US671473
申请日：1984-11-14
申请人： Mark A. Sprecker , Robert P. Belko , William L. Schreiber , Michael Licciardello
发明人： Mark A. Sprecker , Robert P. Belko , William L. Schreiber , Michael Licciardello
IPC分类号： C07C43/305 , C07C45/51 , C11B9/00 , C11D3/50 , A61K7/46
CPC分类号： C07C403/16 , C07C43/305 , C07C45/515 , C11B9/0015 , C11B9/0034 , C11B9/0061 , C07C2101/14 , C07C2101/16
摘要： Described in an isomer-directed process for producing asymmetric ketones defined according to the generic structure: ##STR1## wherein one of Z.sub.1 or Z.sub.2 is the moiety: ##STR2## and the other of Z.sub.1 or Z.sub.2 is hydrogen; wherein R.sub.11 and R.sub.21 represent hydrogen or the same or different alkyl or alkenyl with the proviso that R.sub.11 and R.sub.21 are not both hydrogen or wherein R.sub.11 and R.sub.21 taken together:(i) complete a cycloalkyl, cycloalkenyl, bicycloalkyl, mono or polyalkyl cycloalkyl or mono or polyalkyl cycloalkenyl ring, or(ii) represent alkylidene, cycloalkenyl alkylidene, aralkylidene, mono or polyalkyl cycloalkenyl alkylidene or mono or polyalkyl aralkylidene;and wherein R.sub.6, R.sub.7 and R.sub.8 are the same or different and each represents hydrogen or methyl, using a catalytic Claisen rearrangement of allylic ethers previously formed by reacting substituted or unsubstituted allylic alcohols defined according to the structure: ##STR3## with dialkyl ketals defined according to the structure: ##STR4## wherein R.sub.4 and R.sub.5 represent the same or different C.sub.1 -C.sub.4 alkyl.Also described are compounds and processes for using same in perfumery defined according the structures: ##STR5## Also described are certain diallylic ethers defined according to the generic structure: ##STR6##
摘要翻译：描述于根据通用结构定义的用于制备不对称酮的异构体定向方法：其中Z1或Z2之一为部分：Z1或Z2中的另一个为氢; 其中R11和R21表示氢或相同或不同的烷基或烯基，条件是R11和R21不同时为氢或其中R11和R21一起组合：（i）完成环烷基，环烯基，双环烷基，单或多烷基环烷基或单或聚烷基环烯基环，或（ii）代表亚烷基，环烯基亚烷基，亚烷叉基，单或多烷基环烯基亚烷基或单或多烷基亚烷基; 并且其中R 6，R 7和R 8相同或不同，并且各自表示氢或甲基，使用以前通过使根据以下结构定义的取代或未取代的烯丙基醇反应形成的烯丙基醚的催化Claisen重排：＆lt; IMAGE＆gt; 结构：其中R 4和R 5表示相同或不同的C 1 -C 4烷基。还描述了在根据以下结构定义的香水中使用该化合物的化合物和方法：还描述了根据通用物质定义的某些二烯丙基醚结构：

5. 发明授权

US4933320A Isomer-directed process for producing asymmetric ketones using catalytic Claisen rearrangement of allylic ethers, intermediates, and uses of products and intermediates of process in perfumery 失效
标题翻译：使用烯丙基醚的催化Claisen重排，中间体以及香料中产品和方法中间体的用途来生产不对称酮的异构体定向方法
公开(公告)号：US4933320A
公开(公告)日：1990-06-12
申请号：US863983
申请日：1986-05-16
申请人： Mark A. Sprecker , Robert P. Belko , William L. Schreiber , Michael Licciardello
发明人： Mark A. Sprecker , Robert P. Belko , William L. Schreiber , Michael Licciardello
IPC分类号： C07C43/303 , C07C43/305 , C07C45/51 , C07C49/203 , C07C49/217 , C07C49/557 , C11B9/00
CPC分类号： C11B9/0034 , C07C403/10 , C07C403/16 , C07C43/303 , C07C43/305 , C07C45/515 , C07C49/203 , C07C49/217 , C07C49/557 , C07C2101/14 , C07C2101/16
摘要： Described is an isomer-directed process for producing asymmetric ketones defined according to the generic structure: ##STR1## wherein one of Z.sub.1 or Z.sub.2 is the moiety: ##STR2## and the other of Z.sub.1 or Z.sub.2 is hydrogen; wherein R.sub.11 and R.sub.21 represent hydrogen or the same or different alkyl or alkenyl with the proviso that R.sub.11 and R.sub.21 are not both hydrogen or wherein R.sub.11 and R.sub.21 taken together:(i) complete a cycloalkyl, cycloalkenyl, bicycloalkyl, mono or polyalkyl cycloalkyl or mono or polyalkyl cycloalkenyl ring, or(ii) represent alkylidene, cycloalkenyl alkylidene, aralkylidene, mono or polyalkyl cycloalkenyl alkylidene or mono or polyalkyl aralkylidene;and wherein R.sub.6, R.sub.7 and R.sub.8 are the same or different and each represents hydrogen or methyl, using a catalytic Claisen rearrangement of allylic ethers previously formed by reacting substituted or unsubstituted allylic alcohols defined according to the structure: ##STR3## with dialkyl ketals defined according to the structure: ##STR4## wherein R.sub.4 and R.sub.5 represent the same or different C.sub.1 -C.sub.4 alkyl.Also described are compounds and processes for using same in perfumery defined according the structures: ##STR5## Also described are certain diallylic ethers defined according to the generic structure: ##STR6##
摘要翻译：描述了根据通用结构定义的不对称酮的异构体定向方法：其中Z1或Z2之一为部分：Z1和Z2中的另一个为氢; 其中R11和R21表示氢或相同或不同的烷基或烯基，条件是R11和R21不同时为氢或其中R11和R21一起组合：（i）完成环烷基，环烯基，双环烷基，单或多烷基环烷基或单或聚烷基环烯基环，或（ii）代表亚烷基，环烯基亚烷基，亚烷叉基，单或多烷基环烯基亚烷基或单或多烷基亚烷基; 并且其中R 6，R 7和R 8相同或不同，并且各自表示氢或甲基，使用以前通过使根据以下结构定义的取代或未取代的烯丙基醇反应形成的烯丙基醚的催化Claisen重排：＆lt; IMAGE＆gt; 结构：其中R 4和R 5表示相同或不同的C 1 -C 4烷基。还描述了根据以下结构定义的香水中使用它们的化合物和方法： + TR 是根据通用结构定义的某些二烯丙基醚：

6. 发明授权

US4615830A Isomer-directed process for producing asymmetric ketones using catalytic Claisen rearrangement of allylic ethers, intermediates, and uses of products and intermediates of process in perfumery 失效
标题翻译：使用烯丙基醚的催化Claisen重排，中间体以及香料中产品和方法中间体的用途来生产不对称酮的异构体定向方法
公开(公告)号：US4615830A
公开(公告)日：1986-10-07
申请号：US765278
申请日：1985-08-13
申请人： Mark A. Sprecker , Robert P. Belko , William L. Schreiber , Michael Licciardello
发明人： Mark A. Sprecker , Robert P. Belko , William L. Schreiber , Michael Licciardello
IPC分类号： C07C43/305 , C07C45/51 , C11B9/00 , A61K7/46
CPC分类号： C07C403/16 , C07C43/305 , C07C45/515 , C11B9/0015 , C11B9/0034 , C11B9/0061 , C07C2101/14 , C07C2101/16
摘要： Described is an isomer-directed process for producing asymmetric ketones defined according to the generic structure: ##STR1## wherein one of Z.sub.1 or Z.sub.2 is the moiety: ##STR2## and the other of Z.sub.1 or Z.sub.2 is hydrogen; wherein R.sub.11 and R.sub.21 represent hydrogen or the same or different alkyl or alkenyl with the proviso that R.sub.11 and R.sub.21 are not both hydrogen or wherein R.sub.11 and R.sub.21 taken together:(i) complete a cycloalkyl, cycloalkenyl, bicycloalkyl, mono or polyalkyl cycloalkyl or mono or polyalkyl cycloalkenyl ring, or(ii) represent alkylidene, cycloalkenyl alkylidene, aralkylidene, mono or polyalkyl cycloalkenyl alkylidene or mono or polyalkyl aralkylidene;and wherein R.sub.6, R.sub.7 and R.sub.8 are the same or different and each represents hydrogen or methyl, using a catalytic Claisen rearrangement of allylic ethers previously formed by reacting substituted or unsubstituted allylic alcohols defined according to the structure: ##STR3## with dialkyl ketals defined according to the structure: ##STR4## wherein R.sub.4 and R.sub.5 represent the same or different C.sub.1 -C.sub.4 alkyl.Also described are compounds and processes for using same in perfumery defined according the structures: ##STR5## Also described are certain diallylic ethers defined according to the generic structure: ##STR6##
摘要翻译：描述了根据通用结构定义的不对称酮的异构体定向方法：其中Z1或Z2之一为部分：Z1和Z2中的另一个为氢; 其中R11和R21表示氢或相同或不同的烷基或烯基，条件是R11和R21不同时为氢或其中R11和R21一起组合：（i）完成环烷基，环烯基，双环烷基，单或多烷基环烷基或单或聚烷基环烯基环，或（ii）代表亚烷基，环烯基亚烷基，亚烷叉基，单或多烷基环烯基亚烷基或单或多烷基亚烷基; 并且其中R 6，R 7和R 8相同或不同，并且各自表示氢或甲基，使用以前通过使根据以下结构定义的取代或未取代的烯丙基醇反应形成的烯丙基醚的催化Claisen重排：＆lt; IMAGE＆gt; 结构：其中R 4和R 5表示相同或不同的C 1 -C 4烷基。还描述了在根据以下结构定义的香料中使用它们的化合物和方法：其中描述了根据以下结构定义的某些二烯丙基醚：到通用结构：

7. 发明授权

US4780564A Allyl 4-cyclooctenyl glycolate, organoleptic uses thereof, process for preparing same and intermediates useful in said process 失效
标题翻译： 4-环辛烯基乙醇酸烯丙酯，其感官用途，其制备方法以及在所述方法中有用的中间体
公开(公告)号：US4780564A
公开(公告)日：1988-10-25
申请号：US66965
申请日：1987-06-29
申请人： Mark A. Sprecker , William L. Schreiber , Robert P. Belko
发明人： Mark A. Sprecker , William L. Schreiber , Robert P. Belko
IPC分类号： C11B9/00 , C07C69/734 , C07C59/62
CPC分类号： C11B9/0038
摘要： Described is allyl 4-cyclooctenyl glycolate of our invention having the structure: ##STR1## and the perfumery use thereof in augmenting or enhancing the aroma of perfume compositions, colognes and perfumed articles including solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softener compositions, fabric softener articles, hair preparations and cosmetic powders. The genus defined according to the structure: ##STR2## wherein R represents hydrogen, allyl or alkali metal and:represents a covalent bond wherein R represents hydrogen or allyl and an ionic bond where R represents alkali metal defines all of the products of our invention including intermediates useful in the process for preparing the compound having the structure: ##STR3##
摘要翻译：描述了本发明的具有以下结构的4-环辛烯基乙醇酸烯丙酯：具有以下结构的香料及其香料用途，用于增强或增强香料组合物，古龙水和香料制品的香气，包括固体或液体阴离子，阳离子，非离子或两性离子洗涤剂，织物软化剂组合物，织物柔软剂制品，头发制剂和化妆品粉末。根据以下结构定义的属性：其中R表示氢，烯丙基或碱金属，和：表示共价键，其中R表示氢或烯丙基，其中R表示碱金属的离子键定义了本发明的所有产物，包括在制备具有以下结构的化合物的方法中有用的中间体：

8. 发明授权

US4755502A Allyl-4-cyclooctenyl glycolate, organoleptic uses thereof, process for preparing same and intermediates useful in said process 失效
标题翻译：烯丙基-4-环辛烯基乙醇酸酯，其感官用途，其制备方法和可用于所述方法的中间体
公开(公告)号：US4755502A
公开(公告)日：1988-07-05
申请号：US114426
申请日：1987-10-29
申请人： Mark A. Sprecker , William L. Schreiber , Robert P. Belko
发明人： Mark A. Sprecker , William L. Schreiber , Robert P. Belko
IPC分类号： C11B9/00 , A61K7/46 , C07C69/74
CPC分类号： C11B9/0038
摘要： Described is allyl-4-cyclooctenyl glycolate of our invention having the structure: ##STR1## and the perfumery use thereof in augmenting or enhancing the aroma of perfume compositions, colognes and perfumed articles including solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softener compositions, fabric softener articles, hair preparations and cosmetic powders. The genus defined according to the structure: ##STR2## wherein R represents hydrogen, allyl or alkali metal and: represents a covalent bond wherein R represents hydrogen or allyl and an ionic bond where R represents alkali metal defines all of the products of our invention including intermediates useful in the process for preparing the compound having the structure: ##STR3## .
摘要翻译：描述了本发明的具有以下结构的烯丙基-4-环辛烯基乙醇酸酯：具有以下结构的香料及其香料用途，用于增强或增强香料组合物，古龙水和香料制品的香气，包括固体或液体阴离子，阳离子，非离子或两性离子洗涤剂，织物柔软剂组合物，织物柔软剂制品，头发制剂和化妆粉末。根据以下结构定义的属性：其中R表示氢，烯丙基或碱金属，和：表示共价键，其中R表示氢或烯丙基，其中R表示碱金属的离子键定义了本发明的所有产物，包括在制备具有以下结构的化合物的方法中有用的中间体：。

9. 发明授权

US5023352A Alkyl-substituted tetra- or hexahydrobenzopyran derivatives, organoleptic uses thereof and process for preparing same 失效
标题翻译：烷基取代的四或六氢苯并吡喃衍生物，其感官用途及其制备方法
公开(公告)号：US5023352A
公开(公告)日：1991-06-11
申请号：US546356
申请日：1990-06-29
申请人： Mark A. Sprecker , Robert P. Belko , Marie R. Hanna , Charles E. J. Beck , Salvatore M. Brucato
发明人： Mark A. Sprecker , Robert P. Belko , Marie R. Hanna , Charles E. J. Beck , Salvatore M. Brucato
IPC分类号： C07D311/74 , C07D311/94 , C11B9/00 , C11D3/50
CPC分类号： C07D311/74 , C07D311/94 , C11B9/008 , C11D3/50
摘要： Described are alkyl-substituted tetra- or hexahydrobenzopyran derivatives defined according to one of the generic structures: ##STR1## wherein Z is a moiety in the alternative either ##STR2## wherein in the moiety having the structure: ##STR3## R' is methyl or ethyl and in the moiety having the structure: ##STR4## one of the dashed lines is a carbon-carbon double bond and each of the other of the dashed lines represent carbon-carbon single bonds; wherein R.sub.1 and R.sub.2 taken separately represent hydrogen or C.sub.1 -C.sub.3 lower alkyl (with the proviso that R.sub.1 and R.sub.2 are not both hydrogen) or R.sub.1 and R.sub.2 taken together complete a C.sub.5 or C.sub.6 cycloalkyl moiety; and uses thereof in augmenting or enhancing the aroma of perfume compositions, colognes and perfumed articles including but not limited to solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softener compositions, fabric softener articles, hair preparations, cosmetic powder and perfumed polymers. Also described are synthesis processes for preparing such alkyl-substituted tetra- or hexahydrobenzopyran derivatives by means of reacting isopulegol or an isomer thereof with an acetal or ketal.
摘要翻译：描述了根据以下通用结构之一定义的烷基取代的四或六氢苯并吡喃衍生物：其中Z是可选择的部分或其中的“IMAGE”或“IMAGE”，其中在具有以下结构的部分中： R'是甲基或乙基，并且在具有以下结构的部分中：虚线之一是碳 - 碳双键，虚线中的每一个代表碳 - 碳单键; 其中R1和R2分别代表氢或C1-C3低级烷基（前提是R1和R2不同时为氢）或R1和R2一起形成C5或C6环烷基部分; 包括但不限于固体或液体阴离子，阳离子，非离子或两性离子洗涤剂，织物柔软剂组合物，织物柔软剂制品，毛发制剂，化妆品粉末和加香聚合物的香料组合物，古龙水和香料制品的香气。。还描述了通过异丙醇或其异构体与缩醛或缩酮反应制备这种烷基取代的四或六氢苯并吡喃衍生物的合成方法。

10. 发明授权

US4902672A Polyalkyl indanyl n-propyl and allyl ethers and perfumery uses thereof 失效
标题翻译：聚烷基茚基丙基正丙基和烯丙基醚及其香料用途
公开(公告)号：US4902672A
公开(公告)日：1990-02-20
申请号：US371294
申请日：1989-06-26
申请人： Mark A. Sprecker , Robert P. Belko , Ronald S. Fenn
发明人： Mark A. Sprecker , Robert P. Belko , Ronald S. Fenn
IPC分类号： C07C43/188 , C11B9/00 , C11D3/50
CPC分类号： C11B9/0049 , C07C43/188 , C11D3/50 , C07C2102/24
摘要： Described are polyalkyl indanyl n-propyl and allyl ethers defined according to the structure: ##STR1## wherein R.sub.3 represents methyl or hydrogen; wherein R.sub.1, R.sub.2, R.sub.4 and R.sub.5 each represents methyl or ethyl and wherein the dashed line represents a carbon-carbon single bond or a carbon-carbon double bond with the provisos that:1. at least three of R.sub.1, R.sub.2, R.sub.4 and R.sub.5 represents methyl;2. when each of R.sub.1, R.sub.2, R.sub.4 and R.sub.5 is methyl, then R.sub.3 is methyl; and3. when the dashed line is a carbon-carbon double bond and R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are each methyland uses thereof in augmenting or enhancing the aroma of perfume compositions, colognes and perfumed articles including but not limited to perfumed polymers, solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softener compositions, fabric softener articles, cosmetic powders and hair preparations.
摘要翻译：描述了根据以下结构定义的聚烷基茚满基丙基和烯丙基醚：其中R 3表示甲基或氢; 其中R1，R2，R4和R5各自表示甲基或乙基，其中虚线表示碳 - 碳单键或碳 - 碳双键，条件是：1. R1，R2，R4和R5中的至少三个代表甲基; 当R1，R2，R4和R5各自为甲基时，则R3为甲基; 和3.当虚线是碳 - 碳双键时，R 1，R 2，R 3，R 4和R 5各自是甲基，并且其用途用于增强或增强香水组合物，古龙水和香料制品的香气，包括但不限于香料聚合物，固体或液体阴离子，阳离子，非离子或两性离子洗涤剂，织物柔软剂组合物，织物柔软剂制品，化妆粉和头发制剂。

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