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    • 60. 发明申请
    • Method for the production of maleic anhydride
    • 马来酸酐生产方法
    • US20060241309A1
    • 2006-10-26
    • US10565889
    • 2004-07-06
    • Mark DudaOtto MachhammerAlexander Weck
    • Mark DudaOtto MachhammerAlexander Weck
    • C07D307/34
    • C07C51/215C07C57/145
    • A process for preparing maleic anhydride by oxidizing n-butane in the gas phase under heterogeneous catalysis with oxygen-containing gases over a vanadium-, phosphorus- and oxygen-containing catalyst in a reactor unit at a temperature in the range from 350 to 500° C., removing the maleic anhydride formed to form a gas stream which comprises unconverted n-butane and water and recycling at least a portion of the unconverted n-butane to the reactor unit, by feeding to the reactor unit an inlet stream having an n-butane concentration of from 0.5 to 1.5% by volume and an oxygen concentration of from 5 to 21% by volume, establishing a pressure at the inlet to the reactor unit of from 0.4 to 2 MPa abs, and converting from 40 to 100% of the n-butane from the inlet stream per reactor pass.
    • 在反应器单元中的含钒,含磷和氧的催化剂中,在350〜500℃的温度范围内,用含氧气体在非均相催化下,在气相中氧化正丁烷,制备马来酸酐的方法 C.去除形成的马来酸酐以形成包含未转化的正丁烷和水的气流,并将未转化的正丁烷的至少一部分再循环到反应器单元,通过向反应器单元供给具有n - 丁烷浓度为0.5至1.5体积%,氧浓度为5至21体积%,在反应器单元入口处建立压力为0.4至2MPa abs,并将40至100% 来自每个反应器的入口流的正丁烷通过。