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    • 53. 发明授权
    • Flexible superabsorbent binder polymer composition
    • 柔性超吸收性粘合剂聚合物组合物
    • US07399813B2
    • 2008-07-15
    • US11829205
    • 2007-07-27
    • Angela Jones LangDave Allen SoerensIqbal AhmedScott J. Smith
    • Angela Jones LangDave Allen SoerensIqbal AhmedScott J. Smith
    • C08F4/04C08F20/06
    • C08F220/06C08F220/26C08F230/08
    • A flexible superabsorbent binder polymer composition including a monoethylenically unsaturated polymer, such as carboxylic acid, sulphonic acid, or phosphoric acid, or salts thereof, and an acrylate or methacrylate ester that contains an alkoxysilane functionality, or a monomer capable of co-polymerization with a compound containing a trialkoxysilane functional group and subsequent reaction with water to form a silanol group wherein the flexible superabsorbent binder polymer composition has a residual monoethylenically unsaturated monomer of less than about 1000 ppm. The flexible superabsorbent binder polymer composition is particularly suitable for use in manufacturing absorbent articles. A method of making the flexible superabsorbent binder polymer composition includes preparing a monomer solution, adding the monomer solution to an initiator system, and activating a polymerization initiator within the initiator system.
    • 包含单烯属不饱和聚合物如羧酸,磺酸或磷酸或其盐的柔性超吸收性粘合剂聚合物组合物和含有烷氧基硅烷官能团的丙烯酸酯或甲基丙烯酸酯或能够与 含有三烷氧基硅烷官能团的化合物,随后与水反应以形成硅烷醇基团,其中柔性超吸收性粘合剂聚合物组合物具有小于约1000ppm的残余单烯属不饱和单体。 柔性超吸收性粘合剂聚合物组合物特别适合用于制造吸收制品。 制备柔性超吸收性粘合剂聚合物组合物的方法包括制备单体溶液,将单体溶液加入引发剂体系中,并在引发剂体系内活化聚合引发剂。
    • 58. 发明授权
    • Grafted copolymers highly absorbent to aqueous electrolyte solutions
    • 接枝共聚物对水性电解质溶液具有高吸收性
    • US5439983A
    • 1995-08-08
    • US280955
    • 1994-07-27
    • Iqbal AhmedHenry L. Hsieh
    • Iqbal AhmedHenry L. Hsieh
    • A61L15/60C08F220/34C08F220/60C08F246/00C08F251/00C08F255/02A61L15/24A61L15/28D21H17/45
    • C08F255/02A61L15/60C08F220/34C08F220/60C08F246/00C08F251/00
    • The present invention provides graft copolymers that are highly absorbent to aqueous electrolyte solutions. The graft copolymer is formed by the graft polymerizing an effective amount of each of the following components together to provide a highly absorbent copolymer:(a) graft polymerizing onto a first polymer selected from the group consisting of polysaccharide, polypropylene, polyethylene and other polyolefins, and at least one comonomer selected from the group consisting of acrylamide, methacrylamide, acrylonitrile, acrylic acid, methacrylic acid, alkali salts of acrylic acid, alkali salts of methacrylic acid, 2-methacryloyloxyethyldiethylamine, 2-acrylamido-2-methylpropane sulfonic acid, alkali salts of 2-acrylamido-2-methylpropane sulfonic acid, 2-methacryloyloxyethane sulfonic acid, alkali salts of 2-methacryloyloxyethane sulfonic acid, and any combination of two or more thereof; and(b) graft polymerizing therewith an ampholytic ion pair monomer comprising(i) an ammonium cation 2-methacryloyloxyethyldiethylammonium and(ii) a sulfonate anion selected from the group consisting of 2-acrylamido-2-methylpropane sulfonate, 2-methacryloyloxyethane sulfonate, vinyl sulfonate, styrene sulfonate and any combination thereof.
    • 本发明提供对水性电解质溶液具有高吸收性的接枝共聚物。 接枝共聚物通过将有效量的以下各组分接枝聚合在一起形成,以提供高吸收性共聚物:(a)接枝聚合到选自多糖,聚丙烯,聚乙烯和其它聚烯烃的第一聚合物上, 和至少一种选自丙烯酰胺,甲基丙烯酰胺,丙烯腈,丙烯酸,甲基丙烯酸,丙烯酸的碱金属盐,甲基丙烯酸的碱金属盐,2-甲基丙烯酰氧基乙基二乙基胺,2-丙烯酰胺基-2-甲基丙磺酸,碱金属的共聚单体 2-丙烯酰氨基-2-甲基丙烷磺酸的盐,2-甲基丙烯酰氧基乙烷磺酸,2-甲基丙烯酰氧基乙烷磺酸的碱金属盐,以及其两种或多种的任意组合; 其包含(i)铵阳离子2-甲基丙烯酰氧基乙基二乙基铵和(ii)选自2-丙烯酰胺基-2-甲基丙磺酸盐,2-甲基丙烯酰氧基乙烷磺酸盐,乙烯基乙烯基醚的磺酸盐阴离子的两性离子对单体的接枝聚合 磺酸盐,苯乙烯磺酸盐及其任何组合。
    • 59. 发明授权
    • Grafted copolymers highly absorbent to aqueous electrolyte solutions
    • 接枝共聚物对水性电解质溶液具有高吸收性
    • US5376729A
    • 1994-12-27
    • US92309
    • 1993-07-15
    • Iqbal AhmedHenry L. Hsieh
    • Iqbal AhmedHenry L. Hsieh
    • C08F251/00C08F255/00C08F285/00C08F265/00D21F11/00D21H11/00D21H13/00
    • C08F255/00C08F251/00C08F285/00
    • The present invention provides graft copolymers that are highly absorbent to aqueous electrolyte solutions. The graft copolymer is formed by the graft polymerizing an effective amount of each of the following components together to provide a highly absorbent copolymer:(a) graft polymerizing onto a first polymer selected from the group consisting of polysaccharide, polypropylene, polyethylene and other polyolefins, and at least one comonomer selected from the group consisting of acrylamide, methacrylamide, acrylonitrile, acrylic acid, methacrylic acid, alkali salts of acrylic acid, alkali salts of methacrylic acid, 2-methacryloyloxyethyltrimethylamine, 2-acrylamido-2-methylpropane sulfonic acid, alkali salts of 2-acrylamido-2-methylpropane sulfonic acid, 2-methacryloyloxyethane sulfonic acid, alkali salts of 2-methacryloyloxyethane sulfonic acid, and any combination of two or more thereof; and(b) graft polymerizing therewith an ampholytic ion pair monomer comprising(i) an ammonium cation 2-methacryloyloxyethyltrimethylammonium and(ii) a sulfonate anion selected from the group consisting of 2-acrylamido-2-methylpropane sulfonate, 2-methacryloyloxyethane sulfonate, vinyl sulfonate, styrene sulfonate and any combination of thereof.
    • 本发明提供对水性电解质溶液具有高吸收性的接枝共聚物。 接枝共聚物通过将有效量的以下各组分接枝聚合在一起形成,以提供高吸收性共聚物:(a)接枝聚合到选自多糖,聚丙烯,聚乙烯和其它聚烯烃的第一聚合物上, 和至少一种选自丙烯酰胺,甲基丙烯酰胺,丙烯腈,丙烯酸,甲基丙烯酸,丙烯酸的碱金属盐,甲基丙烯酸的碱金属盐,2-甲基丙烯酰氧基乙基三甲基胺,2-丙烯酰胺基-2-甲基丙磺酸,碱金属的共聚单体 2-丙烯酰氨基-2-甲基丙烷磺酸的盐,2-甲基丙烯酰氧基乙烷磺酸,2-甲基丙烯酰氧基乙烷磺酸的碱金属盐,以及其两种或多种的任意组合; 其包括(i)铵阳离子2-甲基丙烯酰氧基乙基三甲基铵和(ii)选自2-丙烯酰胺基-2-甲基丙磺酸盐,2-甲基丙烯酰氧基乙烷磺酸盐,乙烯基乙烯基醚的磺酸盐阴离子的两性离子对单体的接枝聚合 磺酸盐,苯乙烯磺酸盐及其任何组合。
    • 60. 发明授权
    • Grafted copolymers highly absorbent to aqueous electrolyte solutions
    • 接枝共聚物对水性电解质溶液具有高吸收性
    • US5334685A
    • 1994-08-02
    • US943108
    • 1992-09-10
    • Iqbal AhmedHenry L. Hsieh
    • Iqbal AhmedHenry L. Hsieh
    • A61L15/24A61L15/62C08F8/44C08F285/00C08L1/00C08L3/00
    • C08F285/00A61L15/24A61L15/62C08F8/44
    • The present invention provides graft copolymers that are highly absorbent to aqueous electrolyte solutions. The graft copolymer is formed by the graft polymerizing an effective amount of each of the following components together to provide a highly absorbent copolymer:(a) graft polymerizing onto a first polymer selected from the group consisting of polysaccharide, polypropylene, polyethylene and other polyolefins, and at least one comonomer selected from the group consisting of acrylamide, methacrylamide, acrylonitrile, acrylic acid, methacrylic acid, alkali salts of acrylic acid, alkali salts of methacrylic acid, 3-methacrylamidopropyltrimethylamine, 2-acrylamido-2-methylpropane sulfonic acid, alkali salts of 2-acrylamido-2-methylpropane sulfonic acid, 2-methacryloyloxyethane sulfonic acid, alkali salts of 2-methacryloyloxyethane sulfonic acid, and any combination of two or more thereof; and(b) graft polymerizing therewith an ampholytic ion pair monomer comprising(i) an ammonium cation 3-methacrylamidopropyltrimethylammonium and(ii) a sulfonate anion selected from the group consisting of 2-acrylamido-2-methylpropane sulfonate, 2-methacryloyloxyethane sulfonate, vinyl sulfonate, styrene sulfonate and any combination of thereof.
    • 本发明提供对水性电解质溶液具有高吸收性的接枝共聚物。 接枝共聚物通过将有效量的以下各组分接枝聚合在一起形成,以提供高吸收性共聚物:(a)接枝聚合到选自多糖,聚丙烯,聚乙烯和其它聚烯烃的第一聚合物上, 和至少一种选自丙烯酰胺,甲基丙烯酰胺,丙烯腈,丙烯酸,甲基丙烯酸,丙烯酸的碱金属盐,甲基丙烯酸的碱金属盐,3-甲基丙烯酰胺基丙基三甲基胺,2-丙烯酰胺基-2-甲基丙磺酸,碱 2-丙烯酰氨基-2-甲基丙烷磺酸的盐,2-甲基丙烯酰氧基乙烷磺酸,2-甲基丙烯酰氧基乙烷磺酸的碱金属盐,以及其两种或多种的任意组合; 其包括(i)铵阳离子3-甲基丙烯酰胺基丙基三甲基铵和(ii)选自2-丙烯酰胺基-2-甲基丙磺酸盐,2-甲基丙烯酰氧基乙烷磺酸盐,乙烯基醚的磺酸盐阴离子的两性离子对单体的接枝聚合 磺酸盐,苯乙烯磺酸盐及其任何组合。