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    • 45. 发明申请
    • FORMULATIONS, METHODS, AND APPARATUS FOR REMOTE TRIGGERING OF FRONTALLY CURED POLYMERS
    • 用于远端固化聚合物远程触发的配方,方法和设备
    • US20150152215A1
    • 2015-06-04
    • US14556090
    • 2014-11-28
    • HRL Laboratories, LLC
    • Tao XIEAndrew P. NOWAKThomas BOUNDY
    • C08G59/02B01J19/08C09J5/06C09J163/00
    • C09J5/06C09J163/00
    • In some variations, the invention provides a curable adhesive formulation comprising a curable liquid precursor capable of frontal polymerization, wherein the liquid precursor comprises a monomer and a polymerization catalyst, and frontal-polymerization-triggering susceptors in contact with, or contained within, the liquid precursor. The susceptors may include conducting and/or magnetic solid particles capable of induction heating in the presence of a remotely applied electromagnetic field. Other variations provide a polymer-curing system comprising a curable liquid precursor, frontal-polymerization-triggering susceptors, and an apparatus configured to remotely produce an alternating electromagnetic field in line-of-sight with the susceptors (but not necessarily in line-of-sight with the liquid precursor), thereby generating induction heating to initiate the frontal polymerization. The susceptors may be about 0.1 wt % to about 50 wt % of the curable formulation. Other variations provide a method of curing an adhesive joint through an opaque barrier.
    • 在一些变型中,本发明提供了一种可固化粘合剂制剂,其包含能够正面聚合的可固化液体前体,其中液体前体包含单体和聚合催化剂,以及与液体接触或包含在液体中的前部聚合触发感受体 前体 感应器可以包括能够在存在远程施加的电磁场的情况下感应加热的导电和/或磁性固体颗粒。 其它变型提供了一种聚合物固化体系,其包括可固化液体前体,正面聚合触发感受体,以及被配置为远程产生与感受体的视线中的交变电磁场的装置(但不一定是线性的) 观察液体前体),从而产生感应加热以引发正面聚合。 感受体可以是可固化制剂的约0.1重量%至约50重量%。 其它变型提供了通过不透明屏障固化粘合剂接头的方法。