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41. 发明授权

US6114483A Polymerization of olefins 失效
标题翻译：烯烃聚合
公开(公告)号：US6114483A
公开(公告)日：2000-09-05
申请号：US140080
申请日：1998-08-25
申请人： Edward Bryan Coughlin , Samuel David Arthur , Steven Dale Ittel
发明人： Edward Bryan Coughlin , Samuel David Arthur , Steven Dale Ittel
IPC分类号： C08F4/26 , C08F4/6192 , C08F4/70 , C08F10/00 , C08F10/02 , C08F110/02 , C08L23/06
CPC分类号： C08F10/02 , C08F10/00 , C08F110/02 , C08F4/65912 , C08F4/65925 , Y10S526/943
摘要： Mixtures of different polyolefins or branched polyolefins may be made by direct, preferably simultaneous, polymerization of one or more polymerizable olefins using two or more transition metal containing active polymerization catalyst systems, one of which contains preferably late transition metals complexed to selected ligands. The polyolefin products may have polymers that vary in molecular weight, molecular weight distribution, crystallinity, or other factors, and are useful as molding resins and for films.
摘要翻译：不同聚烯烃或支链聚烯烃的混合物可以通过使用两种或更多种含过渡金属的活性聚合催化剂体系的一种或多种可聚合烯烃的直接，优选同时聚合来制备，其中一种含有优选与选定配体络合的后期过渡金属。聚烯烃产品可以具有分子量，分子量分布，结晶度等因素变化的聚合物，并且可用作模制树脂和薄膜。

42. 发明授权

US5916627A Conductive polymer using self-regenerating oxidant 失效
标题翻译：导电聚合物使用自再生氧化剂
公开(公告)号：US5916627A
公开(公告)日：1999-06-29
申请号：US2091
申请日：1997-12-31
申请人： Philip M. Lessner , John T. Kinard , Brian J. Melody
发明人： Philip M. Lessner , John T. Kinard , Brian J. Melody
IPC分类号： C08G73/20 , C08F4/26 , C08F4/40 , C08G61/12 , H01B1/12 , H01G9/02 , H01G9/025 , B05D1/36 , B05D5/12
CPC分类号： H01G9/025 , C08G61/124 , H01B1/127 , H01G11/48 , H01G11/56 , Y02E60/13
摘要： Conductive polymers are formed with a self-regenerating oxidant system made with a reversibly reducible metal salt at amounts sufficient to polymerize a cyclic monomer through oxidation and leave a reduced metal ion, and an oxidant in an amount sufficiently small and under conditions sufficient to oxidize the reduced metal ion but avoid oxidation or degradation of the polymer. The most preferred combination of agents includes ferric nitrate and a small amount of ammonium nitrate at a pH within the range of 2 to 7.
摘要翻译：导电聚合物由具有可逆还原金属盐的自再生氧化剂体系形成，其量足以通过氧化聚合环状单体并留下还原的金属离子，并且氧化剂的量足够小并且在足以氧化减少的金属离子，但避免聚合物的氧化或降解。最优选的试剂组合物包括硝酸铁和少量硝酸铵，pH在2-7范围内。

43. 发明授权

US5677405A Homopolymers and copolymers of cationically polymerizable monomers and method of their preparation 失效
标题翻译：阳离子聚合单体的均聚物和共聚物及其制备方法
公开(公告)号：US5677405A
公开(公告)日：1997-10-14
申请号：US448961
申请日：1995-05-24
申请人： Brian Leslie Goodall , Lester Howard McIntosh, III , Dennis Allen Barnes
发明人： Brian Leslie Goodall , Lester Howard McIntosh, III , Dennis Allen Barnes
IPC分类号： C08F4/26 , C08F4/42 , C08F4/70 , C08F10/10 , C08F210/00 , C08F216/12 , C08F226/12 , C08F232/00 , C08F236/10 , C08G61/08 , C08F232/02 , C08F4/82
CPC分类号： C08G61/08 , C08F10/00 , C08F10/10 , C08F210/00 , C08F212/08 , C08F216/12 , C08F226/12 , C08F232/00 , C08F236/10 , C08F110/10 , C08F210/12 , C08F212/12 , C08F2410/03 , C08F4/61925
摘要： The invention discloses methods of preparing copolymers from norbornene-type monomers and cationically polymerizable monomers or polymers from catalytically polymerizable monomers by employing Group VIII transition metal ion source in a solvent for said monomers at a temperature in the range from -100.degree. C. to 120.degree. C. Also disclosed are copolymers from norbornene-type monomers and catalytically polymerizable monomers.
摘要翻译：本发明公开了在-100℃至120℃的温度下，通过在所述单体的溶剂中使用VIII族过渡金属离子源，由降冰片烯型单体和可阳离子聚合的单体或聚合物制备共聚物的方法 DEG还公开了来自降冰片烯型单体和催化可聚合单体的共聚物。

44. 发明授权

US5602220A Free radical polymerisation process 失效
标题翻译：自由基聚合过程
公开(公告)号：US5602220A
公开(公告)日：1997-02-11
申请号：US596230
申请日：1996-02-09
申请人： David M. Haddleton , Andrew V. G. Muir
发明人： David M. Haddleton , Andrew V. G. Muir
IPC分类号： C08F2/38 , C08F4/26 , C08F10/00 , C08F4/04 , C08F12/08 , C08F20/10
CPC分类号： C08F10/00
摘要： Process for the free-radical polymerisation of olefinically unsaturated monomer(s) using a free-radical initiator, wherein said polymerisation is performed in the presence of a compound for effecting molecular weight control, said molecular weight control compound being selected from Cobalt II chelates of the following formulae I, II and III: ##STR1## wherein: x and y are independently 2 to 5;each R.sup.1, R.sup.2, R.sup.3 and R.sup.4 is independently selected from H, C1-C12 alkyl, optionally substituted aryl, OR.sup.5 where R.sup.5 is C1 to C12 alkyl or optionally substituted aryl, CO.sub.2 R.sup.5, SO.sub.3 H, C(.dbd.O)R.sup.5, CO.sub.2 H, NO.sub.2, OH, NR.sup.5.sub.2, NH.sub.2, NHR.sup.5, SR.sup.5, SH, CN, SO.sub.3 R.sup.5, halogen, 2-furyl and 3-furyl;each X is independently selected from (CR.sup.6.sub.2).sub.n, (CR.sup.6.sub.2 O).sub.n, optionally substituted o-phenylene, and optionally substituted 1,8-naphthylene, where each R.sup.6 is independently selected from H and C1 to C12 alkyl, and n is 1 to 10;and wherein said cobalt chelates of formulae I and II possess a positive charge of 2 and are associated with an anion or anions for balancing the positive charge, while that of formula III is neutral;and also Co III analogues of said cobalt II chelates of formulae I, II and III in which the Co atom is additionally covalently bonded, in a direction at right angles to the macrocyclic chelate ring system, to H, a halide ion or other anion, or a homolytically dissociatable organic group.
摘要翻译： PCT No.PCT / GB94 / 01693 Sec。 371日期1996年2月9日 102（e）日期1996年2月9日PCT 1994年8月2日PCT公布。公开号WO95 / 04759 日期1995年2月16日使用自由基引发剂自由基聚合烯属不饱和单体的方法，其中所述聚合在化合物存在下进行以进行分子量控制，所述分子量控制化合物被选择由下式I，II和III的钴II螯合物构成：x和y分别为2〜5; 每个R 1，R 2，R 3和R 4独立地选自H，C 1 -C 12烷基，任选取代的芳基，OR 5，其中R 5是C 1至C 12烷基或任选取代的芳基，CO 2 R 5，SO 3 H，C（= O）R 5，CO 2 H，，OH，NR 52，NH 2，NHR 5，SR 5，SH，CN，SO 3 R 5，卤素，2-呋喃基和3-呋喃基; 每个X独立地选自（CR 62）n，（CR 62 O）n，任选取代的邻亚苯基和任选取代的1,8-亚萘基，其中每个R 6独立地选自H和C 1至C 12烷基，并且n是1至 10; 并且其中所述式I和II的钴螯合物具有2的正电荷，并且与用于平衡正电荷的阴离子相关联，而式III的中性为阴离子。以及所述式I，II和III的所述钴II螯合物的Co III类似物，其中Co a

45. 发明授权

US5324879A Oligomerization process 失效
标题翻译：低聚过程
公开(公告)号：US5324879A
公开(公告)日：1994-06-28
申请号：US751631
申请日：1991-08-26
申请人： David G. Hawthorne
发明人： David G. Hawthorne
IPC分类号： C08F2/38 , C08F4/80 , C08F290/04 , C07C2/26 , C07C2/34 , C08F4/26
CPC分类号： C08F290/04 , C08F2/38
摘要： Oligomers are produced from unsaturated monomers. They contain terminal unsaturation and have a degree of polymerization of from 2 to 200. These oligomers are produced by the free radical polymerization of unsaturated monomers using as an initiator and/or chain transfer agent in the process a transition metal complex comprising a metal cation and at least one chelating agent, said transition metal complex being generally in accordance with formula (I), wherein M is a transition metal ion which can form hexa- or penta-coordinated structures and, when complexed in this manner, has two or more readily interconverted adjacent valence states, R is hydrogen or an organic group or a transition metal complex derived form formula (I) and L is a ligand or controlling the stability and electron transfer properties of the transition metal complex and consists of an electron pair donor (Lewis base) capable of coordination with the metal ion.
摘要翻译：低聚物由不饱和单体生产。它们含有末端不饱和度并且具有2至200的聚合度。这些低聚物通过在该方法中使用作为引发剂和/或链转移剂的不饱和单体的自由基聚合制备，所述过渡金属络合物包含金属阳离子和至少一种螯合剂，所述过渡金属络合物通常是根据式（I），其中M是可以形成六价或五配位结构的过渡金属离子，当以这种方式复合时，它具有两个或更多个容易相互转化的相邻价态，R是氢或衍生自式（I）的有机基团或过渡金属络合物，L是配体或控制过渡金属络合物的稳定性和电子转移性质，并由电子对供体（Lewis 碱）能够与金属离子配位。

46. 发明授权

US5272233A Platinum-based catalysts for the polymerization of vinyl ether monomers and polymers 失效
标题翻译：用于聚合乙烯基醚单体和聚合物的铂基催化剂
公开(公告)号：US5272233A
公开(公告)日：1993-12-21
申请号：US916283
申请日：1992-07-17
申请人： James V. Crivello , Mingxin Fan
发明人： James V. Crivello , Mingxin Fan
IPC分类号： C08F4/06 , C08F4/26 , C08F4/80 , C08F16/12 , C08F16/14 , C08F290/00 , C08F299/02 , C08F299/08 , C08L83/07 , C08F130/08 , C08F116/12
CPC分类号： C08F16/14 , C08F4/80
摘要： The present invention relates to a curable polyvinyl ether composition created using a novel catalyst system for the synthesis of polyethers from vinyl ether monomers or polymers. This catalyst system comprises a platinum complex catalyst and silicon hydride cocatalyst. The invention also relates to a method of producing polyethers from vinyl ether monomers or polymers using the above-mentioned catalyst system.

47. 发明授权

US5266665A Metathesis polymerization catalyst and method of polymerizing cyclic olefins therewith 失效
标题翻译：复分解聚合催化剂及其与环烯烃聚合的方法
公开(公告)号：US5266665A
公开(公告)日：1993-11-30
申请号：US531663
申请日：1990-06-01
申请人： Christopher J. Hardiman
发明人： Christopher J. Hardiman
IPC分类号： C08F4/26 , C08G61/06 , C08G61/08 , B32B33/00 , C08F32/04
CPC分类号： C08G61/08 , Y10S526/902 , Y10T428/2991
摘要： Cyclic olefin metathesis polymerization catalyst comprising metal compounds wherein said metals consist essentially of a minor amount of a transition metal which Will initiate ring-opening metathesis polymerization of a cyclic olefin and a major amount of at least one second metal which will propagate the polymerization, wherein said catalyst is essentially devoid of pyrophoric metal compounds, e.g. metal alkyls, and preformed metal carbenes. A preferred transition metal is ruthenium. Said second metal can comprise aluminum, copper, hafnium, iron (III), iridium, manganese, molybdenum, nickel, niobium, rhenium, rhodium, tantalum, titanium, tungsten, yttrium, a Lanthanide, zinc or zirconium or a mixture thereof. Using such catalyst cyclic olefin, e.g. norbornene derivatives, can be polymerized, e.g. in an extruder, even in the presence of water.
摘要翻译：包含金属化合物的环状烯烃易位聚合催化剂，其中所述金属基本上由少量的过渡金属组成，其将引发环烯烃的开环易位聚合和主要量的至少一种将使聚合反应的第二金属，其中所述催化剂基本上没有自燃金属化合物，例如金属烷基和预制金属卡宾。优选的过渡金属是钌。所述第二金属可以包括铝，铜，铪，铁（III），铱，锰，钼，镍，铌，铼，铑，钽，钛，钨，钇，镧系元素，锌或锆或它们的混合物。使用这种催化剂环烯烃，例如降冰片烯衍生物可以聚合，例如在挤出机中，甚至在水的存在下。

48. 发明授权

US5051286A Highly effective polarizers 失效
标题翻译：高效偏光片
公开(公告)号：US5051286A
公开(公告)日：1991-09-24
申请号：US446944
申请日：1989-12-06
申请人： Karl H. A. O. Starzewski
发明人： Karl H. A. O. Starzewski
IPC分类号： G02B5/28 , C08F2/44 , C08F4/06 , C08F4/26 , C08F4/80 , C08F38/00 , C08F38/02 , C08L29/04 , C08L49/00 , G02B1/04 , G02B1/08 , G02B5/30
CPC分类号： C08F38/00 , G02B1/08 , Y10S428/91 , Y10T428/31855
摘要： Highly effective polarizers are described having a degree of polarization P of at least 95% and a dichroic ratio Q.sub.E =quotient of the extinction in the blocking position to the extinction in the transmitting position, of 10 or more over almost the whole wavelength range of visible light between 400 and 800 nm, the said polarizers comprising polymer products containing polyacetylene, in whose matrix 70 to 90% of all comonomer units are vinyl alcohol units. The polarizers are used in the form of films with a stretch ratio ##EQU1## (1=length after stretching, l.sub.o =length before stretching) of more than 300%. They can be produced by polymerization of acetylene in the solution of a copolymer in which 70 to 90% of all comonomer units are vinyl alcohol units, in the presence of a nickel catalyst.
摘要翻译：描述了高效偏振器，其偏振度P至少为95％，二色性比QE =阻挡位置消光在发射位置消光的商数在可见光的几乎整个波长范围内为10以上 400至800nm之间的光，所述偏振器包含含有聚乙炔的聚合物产物，其中70-90％的所有共聚单体单元均为乙烯醇单元。偏振器以拉伸比（1 =拉伸后的长度，拉伸后的拉伸长度）超过300％的膜的形式使用。它们可以通过在镍催化剂存在下，在其中70-90％的所有共聚单体单元是乙烯醇单元的共聚物的溶液中聚合乙炔来制备。

49. 发明授权

US5026675A Polymerization catalyst, the process for its preparation and its use in ethylene homo and copolymerization 失效
标题翻译：聚合催化剂，其制备方法及其在乙烯均聚和共聚中的应用
公开(公告)号：US5026675A
公开(公告)日：1991-06-25
申请号：US506845
申请日：1990-04-10
申请人： Giuseppe Braca , Alessandro Ricci , Glauco Sbrana , Maurizio Brunelli , Aldo Giusti , Guglielmo Bertolini , Anna M. R. Galletii
发明人： Giuseppe Braca , Alessandro Ricci , Glauco Sbrana , Maurizio Brunelli , Aldo Giusti , Guglielmo Bertolini , Anna M. R. Galletii
IPC分类号： C08F4/26 , C08F4/42 , C08F4/80 , C08F8/42 , C08F10/00
CPC分类号： C08F10/00
摘要： A catalyst active in the polymerization of ethylene or the copolymerization of ethylene with unsaturated monomers consists of a nickel complex catalyst bonded to a polystyrene substrate, and definable by the general formula (I): ##STR1## where R, R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6 and R.sub.7 have the meanings given in the description.The preparation is described of the catalyst and its use in the polymerization of ethylene and the copolymerization of ethylene with other unsaturated monomers.

50. 发明授权

US4778864A Acid-stabilized metal drier 失效
标题翻译：酸稳定的金属干燥机
公开(公告)号：US4778864A
公开(公告)日：1988-10-18
申请号：US946740
申请日：1986-12-24
申请人： Christopher J. Hardiman
发明人： Christopher J. Hardiman
IPC分类号： C08J7/04 , C08F4/06 , C08F4/26 , C08F4/44 , C08F290/06 , C09D4/00 , C09F9/00 , C08F2/00 , C08F4/46 , C08F16/12
CPC分类号： C09F9/00 , C08F290/06 , C09D4/00
摘要： Coating compositions comprising (a) free-radical polymerizable compound, (b) metal drier reversibly inhibited to catalyzing free-radical polymerization by a fugitive acid and (c) an allyloxy compound exhibiting long pot life and rapid cure, e.g. at elevated temperature, to hard, tough coatings.
摘要翻译：包含（a）自由基可聚合化合物的涂料组合物，（b）金属干燥剂可逆地抑制催化由逸散酸引起的自由基聚合，和（c）具有长的适用期和快速固化的烯丙氧基化合物，例如，在升高的温度下，变成坚硬，坚韧的涂层。

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