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41. 发明申请

US20140107383A1 Selective Hydrogenation Catalyst and Methods of Making and Using Same 有权
标题翻译：选择性氢化催化剂及其制备和使用方法
公开(公告)号：US20140107383A1
公开(公告)日：2014-04-17
申请号：US14134282
申请日：2013-12-19
申请人： Chevron Phillips Chemical Company LP
发明人： Tin-Tack Peter Cheung , Zongxuan Hong
IPC分类号： B01J31/02 , C07C5/09
CPC分类号： C07C5/09 , B01J23/44 , B01J23/66 , B01J27/13 , B01J31/0271 , B01J31/1616 , B01J31/1845 , B01J31/185 , B01J31/1865 , B01J31/1875 , B01J31/24 , B01J31/2404 , B01J35/008 , B01J35/023 , B01J35/1009 , B01J35/1014 , B01J37/0203 , B01J37/024 , B01J37/28 , B01J2231/645 , B01J2531/824 , C07C5/05 , C07C2521/04 , C07C2531/26 , C10G45/40 , C10G2300/703
摘要： A composition comprising a supported hydrogenation catalyst comprising palladium and an organophosphorous compound, the supported hydrogenation catalyst being capable of selectively hydrogenating highly unsaturated hydrocarbons to unsaturated hydrocarbons. A method of making a selective hydrogenation catalyst comprising contacting a support with a palladium-containing compound to form a palladium supported composition, contacting the palladium supported composition with an organophosphorus compound to form a catalyst precursor, and reducing the catalyst precursor to form the catalyst. A method of selectively hydrogenating highly unsaturated hydrocarbons to an unsaturated hydrocarbon enriched composition comprising contacting a supported catalyst comprising palladium and an organophosphorous compound with a feed comprising highly unsaturated hydrocarbon under conditions suitable for hydrogenating at least a portion of the highly unsaturated hydrocarbon feed to form the unsaturated hydrocarbon enriched composition.
摘要翻译：一种包含负载氢化催化剂的组合物，其包含钯和有机磷化合物，所述负载氢化催化剂能够将高度不饱和烃选择性氢化为不饱和烃。一种制备选择性氢化催化剂的方法，包括使载体与含钯化合物接触以形成负载钯的组合物，使钯负载的组合物与有机磷化合物接触以形成催化剂前体，还原催化剂前体以形成催化剂。将高度不饱和烃选择性氢化为不饱和烃富集组合物的方法，包括在适于氢化至少一部分高度不饱和烃进料的条件下使包含钯和有机磷化合物的负载催化剂与包含高度不饱和烃的进料接触以形成不饱和烃富集组合物。

42. 发明授权

US08637695B2 Synthesis of organohalosilane monomers from conventionally uncleavable Direct Process Residue 有权
标题翻译：从常规不溶性直接工艺残留物合成有机卤代硅烷单体
公开(公告)号：US08637695B2
公开(公告)日：2014-01-28
申请号：US13340882
申请日：2011-12-30
申请人： Kenrick Martin Lewis , John David Neely
发明人： Kenrick Martin Lewis , John David Neely
IPC分类号： C07F7/14
CPC分类号： C07F7/125 , B01J31/24 , C07F7/12
摘要： Disclosed herein is a catalytic process for the synthesis of organohalosilane monomers from tetraorganodihalodisilanes and other compounds that are not cleaved during the conventional hydrochlorination of Direct Process Residue. The process is characterized by the use of a catalyst containing (1) one or more heterocyclic amines and/or one or more heterocyclic ammonium halides, and (2) one or more quaternary Group 15 onium compounds.
摘要翻译：本文公开了一种用于从四有机二卤代二硅烷和其它化合物合成有机卤代硅烷单体的催化方法，该化合物在常规氢化直接工艺残余物期间不被裂解。该方法的特征在于使用含有（1）一种或多种杂环胺和/或一种或多种杂环卤化铵的催化剂，和（2）一种或多种季铵鎓鎓化合物。

43. 发明授权

US08604249B2 Process for producing phosphonium borate compound, novel phosphonium borate compound, and method of using the same 有权
标题翻译：硼酸鏻化合物的制造方法，新型硼酸鏻化合物及其使用方法
公开(公告)号：US08604249B2
公开(公告)日：2013-12-10
申请号：US12947311
申请日：2010-11-16
申请人： Shin Masaoka , Hideyuki Iwazaki
发明人： Shin Masaoka , Hideyuki Iwazaki
IPC分类号： C07F9/28 , C07F9/54
CPC分类号： B01J31/32 , B01J31/0268 , B01J31/04 , B01J31/146 , B01J31/2234 , B01J31/24 , B01J31/2404 , B01J31/26 , B01J31/28 , B01J2231/4205 , B01J2231/4283 , B01J2531/72 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/828 , B01J2531/84 , C07C1/325 , C07C1/326 , C07C29/32 , C07C41/16 , C07C45/68 , C07C67/343 , C07C209/10 , C07C213/08 , C07C227/08 , C07C253/30 , C07F9/54 , C07C49/782 , C07C49/796 , C07C69/612 , C07C69/618 , C07C211/54 , C07C215/68 , C07C229/44 , C07C255/41 , C07C255/49 , C07C33/483 , C07C33/30 , C07C43/263 , C07C43/275
摘要： The invention relates to novel phosphonium borate compounds represented by the Formula: (R1)(R2)(R3)PH.BAr4, wherein R1, R2, R3 and Ar4 are as defined herein, and compositions including such phosphonium borate compounds in combination with a transition metal, transition metal salt, transition metal oxide or transition metal complex for use in carbon-carbon bond forming reactions, carbon-nitrogen bond forming reactions and carbon-oxygen bond forming reactions.
摘要翻译：本发明涉及由式（R1）（R2）（R3）PH.BAr4表示的新的硼酸鏻化合物，其中R1，R2，R3和Ar4如本文所定义，组合物包括这种硼酸鏻化合物与过渡金属，过渡金属盐，用于碳 - 碳键形成反应的过渡金属氧化物或过渡金属络合物，碳 - 氮键形成反应和碳 - 氧键形成反应。

44. 发明申请

US20130244865A1 Metal Complex Compound, Hydrogen Production Catalyst and Hydrogenation Reaction Catalyst Each Comprising the Metal Complex Compound, and Hydrogen Production Method and Hydrogenation Method Each Using the Catalyst 有权
标题翻译：金属配位化合物，氢生产催化剂和氢化反应催化剂，各自包含金属络合物，氢气生产方法和氢化方法各自使用催化剂
公开(公告)号：US20130244865A1
公开(公告)日：2013-09-19
申请号：US13989229
申请日：2011-11-24
申请人： Makoto Muranaka , Toshiyuki Oshiki
发明人： Makoto Muranaka , Toshiyuki Oshiki
IPC分类号： C07F15/00 , C07C5/09 , B01J31/20 , C01B3/22 , B01J31/24
CPC分类号： C07F15/0033 , B01J31/0237 , B01J31/20 , B01J31/2208 , B01J31/24 , B01J31/2404 , B01J31/2409 , B01J31/2414 , B01J2231/76 , B01J2531/821 , B01J2531/822 , B01J2531/827 , B01J2531/842 , C01B3/22 , C01B2203/0277 , C01B2203/1064 , C07C5/03 , C07C5/09 , C07C2531/24 , C07F9/5045 , C07F15/004 , C07F15/0053 , C07F15/008 , C07F15/025 , H01M8/0606 , Y02E60/50 , C07C15/52 , C07C9/00
摘要： Provided is a catalyst for producing hydrogen, which catalyst has higher performance than conventional catalysts since, for example, it exhibits a certain high level of activity in an aqueous formic acid solution at high concentration even without addition of a solvent, amine and/or the like. The metal phosphine complex is a metal phosphine complex represented by General Formula (1): MHm(CO)Ln, wherein M represents an iridium, iron, rhodium or ruthenium atom; in cases where M is an iridium or rhodium atom, m=3 and n=2, and in cases where M is an iron or ruthenium atom, m=2 and n=3; and the number n of Ls each independently represent a tri-substituted phosphine represented by General Formula (2): PR1R2R3. The catalyst for producing hydrogen comprises the metal phosphine complex as a constituent component.
摘要翻译：提供了一种用于生产氢的催化剂，该催化剂具有比常规催化剂更高的性能，因为例如即使不加入溶剂，也可以在高浓度的甲酸水溶液中表现出一定的高水平的活性，胺和/或喜欢。金属膦配合物是由通式（1）表示的金属膦络合物：MHm（CO）Ln，其中M表示铱，铁，铑或钌原子; 在M为铱或铑原子的情况下，m = 3且n = 2，在M为铁或钌原子的情况下，m = 2且n = 3; L的数n各自独立地表示由通式（2）表示的三取代膦：PR1R2R3。用于生产氢的催化剂包括作为组成成分的金属膦络合物。

45. 发明授权

US08524930B2 Class of olefin metathesis catalysts, methods of preparation, and processes for the use thereof 有权
标题翻译：烯烃复分解催化剂类，制备方法及其使用方法
公开(公告)号：US08524930B2
公开(公告)日：2013-09-03
申请号：US13149012
申请日：2011-05-31
申请人： Matthew W. Holtcamp , Matthew S. Bedoya
发明人： Matthew W. Holtcamp , Matthew S. Bedoya
IPC分类号： C07F15/00 , C07C2/04 , C08F4/80
CPC分类号： C07F15/0046 , B01J31/2265 , B01J31/24 , B01J2231/543 , B01J2531/821 , B01J2531/825 , C07C6/06 , C07C2531/22 , C07C2531/24 , C07C13/44 , C07C13/68
摘要： This invention relates to a metathesis catalyst comprising a Group 8 metal complex represented by the formula: wherein: M is a Group 8 metal; each X is independently an anionic ligand; R1 and R2 are independently selected from the group consisting of hydrogen, a C1 to C30 hydrocarbyl, and a C1 to C30 substituted hydrocarbyl; R3 and R4 are independently selected from the group consisting of hydrogen, C1 to C12 hydrocarbyl groups, substituted C1 to C12 hydrocarbyl groups, and halides; and L is a neutral donor ligand. This invention also relates to processes for performing a metathesis reaction, in particular ring opening cross metathesis reactions and ring opening metathesis polymerization reactions, using the Group 8 metal complexes.
摘要翻译：本发明涉及包含由下式表示的第8族金属络合物的复分解催化剂：其中：M是第8族金属; 每个X独立地是阴离子配体; R 1和R 2独立地选自氢，C 1至C 30烃基和C 1至C 30取代的烃基; R3和R4独立地选自氢，C1至C12烃基，取代的C1至C12烃基和卤化物; L是中性供体配体。本发明还涉及使用第8族金属络合物进行复分解反应，特别是开环交叉复分解反应和开环易位聚合反应的方法。

46. 发明申请

US20120101321A1 Ethylene oligomerization 审中-公开
标题翻译：乙烯低聚
公开(公告)号：US20120101321A1
公开(公告)日：2012-04-26
申请号：US13200287
申请日：2011-09-22
申请人： Stephen John Brown , Charles Ashton Garret Carter , P. Scott Chisholm , Isam Jaber
发明人： Stephen John Brown , Charles Ashton Garret Carter , P. Scott Chisholm , Isam Jaber
IPC分类号： C07C2/36
CPC分类号： C07C2/36 , B01J31/143 , B01J31/24 , B01J2231/20 , B01J2531/0238 , B01J2531/62 , C07C2531/14 , C07C2531/24 , C07C11/02
摘要： The oligomerization of ethylene using a chromium catalyst having a bridged diphosphine ligand can produce a selective product distribution (to predominantly hexene or predominantly octene/hexene) when activated with an aluminoxane. The oligomerization reaction also produces polymer by product—particularly when the aluminoxane is provided in a non-aromatic solvent. The present invention mitigates this problem.
摘要翻译：当用铝氧烷活化时，使用具有桥连二膦配体的铬催化剂的乙烯的低聚可以产生选择性产物分布（主要是己烯或主要是辛烯/己烯）。低聚反应还通过产物产生聚合物，特别是当在非芳族溶剂中提供铝氧烷时。本发明减轻了这个问题。

47. 发明授权

US08133464B2 Hydrogen production from formic acid 有权
标题翻译：从甲酸生产氢气
公开(公告)号：US08133464B2
公开(公告)日：2012-03-13
申请号：US12311954
申请日：2007-10-17
申请人： Gabor Laurenczy , Céline Fellay , Paul Dyson
发明人： Gabor Laurenczy , Céline Fellay , Paul Dyson
IPC分类号： C01B31/20 , C01B3/22
CPC分类号： C01B3/22 , B01J31/0215 , B01J31/0225 , B01J31/24 , B01J2531/821 , C01B32/50 , Y02P20/128
摘要： The present invention relates to a method of producing hydrogen gas and carbon dioxide in a catalytic reaction from formic acid, said reaction being conducted in an aqueous solution over a wide temperature range and already at room temperature (25° C.). The reaction is advantageous because it can be tuned to take place at very high rates, up to about 90 liter H2/minute/liter reactor volume. The gas produced is free of carbon monoxide. The method of the present invention is particularly suitable for providing hydrogen for a motor, fuel cell or chemical synthesis.
摘要翻译：本发明涉及一种在甲酸催化反应中生产氢气和二氧化碳的方法，所述反应在宽温度范围内已经在室温（25℃）下在水溶液中进行。该反应是有利的，因为它可以调节以非常高的速率进行，高达约90升H 2 /分升/升反应器体积。产生的气体不含一氧化碳。本发明的方法特别适用于为电动机，燃料电池或化学合成提供氢。

48. 发明授权

US08053605B2 Phosphorus-containing catalyst composition and hydroformylation process using the same 有权
标题翻译：含磷催化剂组合物和使用其的加氢甲酰化方法
公开(公告)号：US08053605B2
公开(公告)日：2011-11-08
申请号：US12677496
申请日：2008-06-05
申请人： Jae-Hui Choi , Dong-Hyun Ko , Sung-Shik Eom , Sang-Gi Lee , Moo-Ho Hong , O-Hark Kwon
发明人： Jae-Hui Choi , Dong-Hyun Ko , Sung-Shik Eom , Sang-Gi Lee , Moo-Ho Hong , O-Hark Kwon
IPC分类号： C07C45/50 , B01J31/12
CPC分类号： B01J31/24 , B01J31/1875 , B01J31/20 , B01J31/2208 , B01J31/2291 , B01J31/2295 , B01J2231/321 , B01J2531/822 , B01J2531/827 , B01J2531/845
摘要： The present invention relates to a catalyst composition that includes a triphenylphosphine ligand, a monodentate phosphine ligand, a monodentate phosphine oxide ligand, and a transition metal catalyst, and a hydroformylation process using the same. In the hydroformylation process using the catalyst composition according to the present invention, the high catalytic activity can be obtained, and the selectivity (N/I selectivity) in respects to normal- or iso-aldehyde can be desirably controlled.
摘要翻译：本发明涉及包含三苯基膦配体，单齿膦配位体，单齿氧化膦配体和过渡金属催化剂的催化剂组合物，以及使用该催化剂组合物的加氢甲酰化方法。在使用根据本发明的催化剂组合物的加氢甲酰化方法中，可以获得高催化活性，并且可以期望控制相对于正醛或异醛的选择性（N / I选择性）。

49. 发明申请

US20110175521A1 ORGANIC ELECTROLUMESCENCE DEVICE 审中-公开
标题翻译：有机电解装置
公开(公告)号：US20110175521A1
公开(公告)日：2011-07-21
申请号：US13079225
申请日：2011-04-04
申请人： Chishio Hosokawa , Masakazu Funahashi , Hisayuki Kawamura , Hiromasa Arai , Hidetoshi Koga , Hidetsugu Ikeda
发明人： Chishio Hosokawa , Masakazu Funahashi , Hisayuki Kawamura , Hiromasa Arai , Hidetoshi Koga , Hidetsugu Ikeda
IPC分类号： H01J1/63 , C07C211/54
CPC分类号： C09K11/06 , B01J31/24 , C07C211/54 , C07C211/58 , C07C211/61 , C07C2603/18 , C07C2603/24 , C07C2603/26 , C07C2603/44 , C07C2603/48 , C07C2603/52 , C09K2211/10 , C09K2211/1003 , C09K2211/1007 , C09K2211/1011 , C09K2211/1014 , C09K2211/1092 , H01L51/0042 , H01L51/005 , H01L51/0052 , H01L51/0054 , H01L51/0058 , H01L51/0059 , H01L51/006 , H01L51/0061 , H01L51/0068 , H01L51/007 , H01L51/0081 , H01L51/5012 , H01L51/5048 , H01L51/5088 , H01L2251/308 , H05B33/14 , Y10S428/917
摘要： Materials for organic electroluminescence devices are represented by following general formula [1]: wherein A represents a chrysene group, X1 to X4 each independently represent a substituted or unsubstituted arylene group having 6 to 30 carbon atoms, X1 and X2 may be bonded to each other, X3 and X4 may be bonded to each other, Y1 to Y4 each independently represent an organic group represented by general formula [2], a to d each represent an integer of 0 to 2 and, a+b+c+d≧0; general formula [2] being: wherein R1 to R4 each independently represent hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 20 carbon atoms, cyano group or form a triple bond by a linkage of R1 and R2 or R3 and R4, Z represents a substituted or unsubstituted aryl group having 6 to 20 carbon atoms and n represents 0 or 1.
摘要翻译：用于有机电致发光器件的材料由以下通式[1]表示：其中A表示一个基团，X 1至X 4各自独立地表示取代或未取代的具有6至30个碳原子的亚芳基，X 1和X 2可以彼此键合，X3和X4可以彼此键合，Y1至Y4各自独立地表示由通式[2]表示的有机基团，a至d各自表示0至2的整数，并且a + b + c +d≥0 ; 通式[2]是：其中，R 1〜R 4各自独立地表示氢原子，取代或未取代的碳原子数1〜20的烷基，取代或未取代的碳原子数6〜20的芳基，氰基或三键通过R 1和R 2或R 3和R 4的键合，Z表示取代或未取代的碳原子数6〜20的芳基，n表示0或1。

50. 发明申请

US20110160474A1 C2-SYMMETRICAL RUTHENOCENE DIPHOSPHINE LIGANDS ONLY WITH SURFACE CHIRALITY AND THEIR MANUFACTURE 失效
标题翻译： C2-对称二硫代磷酸酯配体仅具有表面光洁度及其制造
公开(公告)号：US20110160474A1
公开(公告)日：2011-06-30
申请号：US12303767
申请日：2007-06-08
申请人： Wanbin Zhang , Fang Xie , Delong Liu , Li Luo , Genghong Hua , Jian Shang
发明人： Wanbin Zhang , Fang Xie , Delong Liu , Li Luo , Genghong Hua , Jian Shang
IPC分类号： C07F17/02
CPC分类号： C07F17/02 , B01J31/2295 , B01J31/24 , B01J31/2409 , B01J2531/0205 , B01J2531/0263 , B01J2531/821
摘要： The invention affords C2-symmetrical ruthenocene diphosphine ligands with surface chirality and their manufacture. The present invention uses (S)—(S)-1,1′-2(diphenylphosphino)-2,2′-2[(S)-4-isopropyloxazolinyl]ruthenocene as raw material and the product is prepared through two or three steps of reaction. At the action of trifluoroacetic acid, (S)—(S)-1,1′-2(diphenylphosphino)-2,2′-2[(S)-4-isopropyloxazolinyl]ruthenocene first removes oxazoline and gets ester amides compound which then carries out ester exchange or reduction alkylation and gets the product of ruthenocene diphosphine ligand with surface chirality. The ligands prepared with the structure as follows from the invention can be used in all kinds of metallic catalysis asymmetric reaction and has good reaction activity and stereoselectivity, wherein R is methyl or ethyl, R1 is linear or branched alkyl, cycloalkyl, alkoxy, aryl, aralkyl and alkyl amino.
摘要翻译：本发明提供具有表面手性及其制造的C2对称的二茂铁二膦配体。本发明使用（S） - （S）-1,1'-2（二苯基膦基）-2,2'-2 [（S）-4-异丙唑恶唑啉基] rut烯为原料，通过2或3 反应步骤。在三氟乙酸的作用下，（S） - （S）-1,1'-2（二苯基膦基）-2,2'-2 [（S）-4-异丙基恶唑啉基] rut hen ene首先除去恶唑啉并得到酯酰胺化合物，然后进行酯交换或还原烷基化，得到具有表面手性的钌基二膦配体的产物。由本发明制备的具有如下结构的配位体可用于各种金属催化不对称反应，具有良好的反应活性和立体选择性，其中R为甲基或乙基，R 1为直链或支链烷基，环烷基，烷氧基，芳基，芳烷基和烷基氨基。

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