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1. 发明授权

US09181360B2 Polymers prepared by ring opening / cross metathesis 有权
标题翻译：通过开环/交叉复分解制备的聚合物
公开(公告)号：US09181360B2
公开(公告)日：2015-11-10
申请号：US13209242
申请日：2011-08-12
申请人： Matthew W. Holtcamp , John R. Hagadorn , Caol P. Huff , Matthew S. Bedoya , Catherine Anne Faler
发明人： Matthew W. Holtcamp , John R. Hagadorn , Caol P. Huff , Matthew S. Bedoya , Catherine Anne Faler
IPC分类号： C08G61/08 , C08F4/80 , C07C13/11 , C08F32/08 , C08F136/20 , C10M107/10 , C08F8/04
CPC分类号： C08F4/80 , C08F32/08 , C08F136/20 , C08G2261/1642 , C08G2261/3325 , C08G2261/418 , C10M107/10 , C10M2205/0285 , C10N2270/00
摘要： This invention relates to a process for producing a polymer of a cyclic olefin and a linear mono-olefin, the process comprising contacting at least one C5 based cyclic olefin with at least one linear mono-olefin having from two to twenty carbon atoms in the presence of an alkene metathesis catalyst, and the polymer so produced.
摘要翻译：本发明涉及一种制备环状烯烃和直链单烯烃聚合物的方法，该方法包括使至少一种C 5基环烯烃与至少一种具有2-20个碳原子的直链单烯烃在存在的烯烃复分解催化剂和如此制备的聚合物。

2. 发明申请

US20120077945A1 Novel Class Of Olefin Metathesis Catalysts, Methods Of Preparation, And Processes For The Use Thereof 有权
标题翻译：新型烯烃复分解催化剂，制备方法及其使用方法
公开(公告)号：US20120077945A1
公开(公告)日：2012-03-29
申请号：US12890315
申请日：2010-09-24
申请人： Matthew W. Holtcamp , Matthew S. Bedoya , Laughlin G. McCullough
发明人： Matthew W. Holtcamp , Matthew S. Bedoya , Laughlin G. McCullough
IPC分类号： C08F4/80 , C07F15/00
CPC分类号： C07F15/002 , B01J31/0231 , B01J31/2414 , B01J2231/543 , B01J2531/0213 , B01J2531/821 , B01J2531/825 , C07F15/0046
摘要： This invention relates to a metathesis catalyst comprising (i) a Group 8 metal hydride-dihydrogen complex represented by the formula: wherein M is a Group 8 metal; X is an anionic ligand; and L1 and L2 are neutral donor ligands; and (ii) a ligand exchange agent represented by the formula J-Y, wherein J is selected from the group consisting of hydrogen, a C1 to C30 hydrocarbyl, and a C1 to C30 substituted hydrocarbyl; and Y is selected from the group consisting of halides, alkoxides, aryloxides, and alkyl sulfonates.
摘要翻译：本发明涉及复分解催化剂，其包含（i）由下式表示的第8族金属氢化物 - 二氢配合物：其中M是第8族金属; X是阴离子配体; L1和L2是中性供体配体; 和（ii）由式J-Y表示的配体交换剂，其中J选自氢，C1至C30烃基和C1至C30取代的烃基; Y选自卤化物，醇盐，芳氧化物和烷基磺酸盐。

3. 发明授权

US09024034B2 Metathesis catalysts and processes for use thereof 有权
标题翻译：复分解催化剂及其使用方法
公开(公告)号：US09024034B2
公开(公告)日：2015-05-05
申请号：US12939024
申请日：2010-11-03
申请人： Matthew W. Holtcamp , Matthew S. Bedoya , Catherine A. Faler , Caol P. Huff , John R. Hagadorn , Ravindra Ganesh
发明人： Matthew W. Holtcamp , Matthew S. Bedoya , Catherine A. Faler , Caol P. Huff , John R. Hagadorn , Renuka N. Ganesh
IPC分类号： C07F15/00 , C07C6/04 , B01J31/22
CPC分类号： C07F15/0046 , B01J31/2208 , B01J31/2273 , B01J31/2278 , B01J2531/0261 , B01J2531/821 , B01J2531/825 , C07C6/04 , C07C2531/22 , C07C11/02
摘要： This invention relates to a metathesis catalyst compound comprising an asymmetrically substituted N-heterocyclic carbene (NHC) metathesis catalyst and a process to make linear alpha-olefins comprising contacting a feed material and an optional alkene (such as ethylene) with said catalyst, where the feed material is a triacylglyceride, fatty acid, fatty acid alkyl ester, and/or fatty acid ester, typically derived from biodiesel.
摘要翻译：本发明涉及包含不对称取代的N-杂环卡宾（NHC）复分解催化剂的复分解催化剂化合物和制备线性α-烯烃的方法，包括使进料和任选的烯烃（如乙烯）与所述催化剂接触，其中饲料是通常衍生自生物柴油的三酰基甘油酯，脂肪酸，脂肪酸烷基酯和/或脂肪酸酯。

4. 发明授权

US08691714B2 Processes for making multimodal molecular weight distribution polyolefins 失效
标题翻译：制备多峰分子量分布聚烯烃的方法
公开(公告)号：US08691714B2
公开(公告)日：2014-04-08
申请号：US13401147
申请日：2012-02-21
申请人： Matthew W. Holtcamp , Matthew S. Bedoya
发明人： Matthew W. Holtcamp , Matthew S. Bedoya
IPC分类号： C08F4/61 , C08F4/615 , C08F4/6592 , C08F4/69
CPC分类号： C08F10/00 , C08F4/63925 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F110/02 , C08F2500/05 , C08F4/63904
摘要： This invention relates to a process to make a multimodal polyolefin composition comprising: (i) contacting at least one first olefin monomer with a mixed catalyst system, under polymerization conditions, to produce at least a first polyolefin component having a Mw of 5,000 g/mol to 600,000 g/mol, wherein the mixed catalyst system comprises: (a) at least one polymerization catalyst comprising a Group 4 or Group 5 transition metal; (b) at least one organochromium polymerization catalyst; (c) an activator; and (d) a support material; (ii) thereafter, contacting the first polyolefin component/mixed catalyst system combination with a molecular switch; (iii) contacting the first polyolefin component/mixed catalyst system combination with at least one second olefin monomer, which may be the same or different, under polymerization conditions; and (iv) obtaining a multimodal polyolefin composition.
摘要翻译：本发明涉及一种制备多峰聚烯烃组合物的方法，其包括：（i）在聚合条件下使至少一种第一烯烃单体与混合催化剂体系接触，以产生至少一种Mw为5,000g / mol的第一聚烯烃组分至600,000g / mol，其中所述混合催化剂体系包含：（a）至少一种包含第4族或第5族过渡金属的聚合催化剂; （b）至少一种有机铬聚合催化剂; （c）活化剂; 和（d）支撑材料; （ii）之后，使第一聚烯烃组分/混合催化剂体系组合与分子开关接触; （iii）在聚合条件下使第一聚烯烃组分/混合催化剂体系组合与至少一种可以相同或不同的第二烯烃单体接触; 和（iv）获得多峰聚烯烃组合物。

5. 发明授权

US08237003B2 Metathesis catalyst and process for use thereof 有权
标题翻译：复分解催化剂及其使用方法
公开(公告)号：US08237003B2
公开(公告)日：2012-08-07
申请号：US12705136
申请日：2010-02-12
申请人： Matthew W. Holtcamp , Catherine Anne Faler , Caol P. Huff , Matthew S. Bedoya , John R. Hagadorn
发明人： Matthew W. Holtcamp , Catherine Anne Faler , Caol P. Huff , Matthew S. Bedoya , John R. Hagadorn
IPC分类号： C07C6/04 , C07C1/213 , C07F15/00
CPC分类号： C07F15/0046 , C07D207/06 , C10G3/00 , C10G2300/1014 , C10G2300/1088 , C10G2400/20 , C10G2400/22 , Y02E50/13
摘要： This invention relates to a catalyst compound for the metathesis of olefins represented by the formula: wherein M is a Group 8 metal; X and X1 are anionic ligands; L is a neutral two electron donor; L1 is N, O, P, or S, preferably N or O; R is a C1 to C30 hydrocarbyl or a C1 to C30 substituted hydrocarbyl; G* is selected from the group consisting of hydrogen, a C1 to C30 hydrocarbyl, and a C1 to C30 substituted hydrocarbyl; R1 is selected from the group consisting of hydrogen, a C1 to C30 hydrocarbyl, and a C1 to C30 substituted hydrocarbyl; and G is independently selected from the group consisting of hydrogen, halogen, C1 to C30 hydrocarbyls and C1 to C30 substituted hydrocarbyls. This invention also relates to process to make alphaolefins comprising contacting an olefin, such as ethylene, with a feed oil containing a triacylglyceride (typically a fatty acid ester (such as methyl oleate)) with the catalyst compound described above. The fatty acid ester may be a fatty acid methyl ester derived from biodiesel.
摘要翻译：本发明涉及一种用于由下式表示的烯烃复分解的催化剂化合物：其中M是第8族金属; X和X1是阴离子配体; L是中性二电子给体; L1是N，O，P或S，优选N或O; R是C1至C30烃基或C1至C30取代的烃基; G *选自氢，C1至C30烃基和C1至C30取代的烃基; R1选自氢，C1至C30烃基和C1至C30取代的烃基; 且G独立地选自氢，卤素，C 1至C 30烃基和C 1至C 30取代的烃基。本发明还涉及制备α-烯烃的方法，包括使烯烃如乙烯与含有三酰基甘油酯（通常为脂肪酸酯（如油酸甲酯））的进料油与上述催化剂化合物接触。脂肪酸酯可以是衍生自生物柴油的脂肪酸甲酯。

6. 发明申请

US20110112305A1 METATHESIS CATALYST AND PROCESS FOR USE THEREOF 有权
标题翻译： METATHESIS催化剂及其使用方法
公开(公告)号：US20110112305A1
公开(公告)日：2011-05-12
申请号：US12939054
申请日：2010-11-03
申请人： John R. Hagadorn , Matthew W. Holtcamp , Matthew S. Bedoya
发明人： John R. Hagadorn , Matthew W. Holtcamp , Matthew S. Bedoya
IPC分类号： C07F15/00 , C07C1/213 , C07C1/207
CPC分类号： C07F15/0046 , C07D207/06 , C10G3/00 , C10G2300/1014 , C10G2300/1088 , C10G2400/20 , C10G2400/22 , Y02E50/13
摘要： This invention relates to a catalyst compound comprising a combination of a cyclic alkyl amino carbene ligand and a benzylidene both attached to a Group 8 metal, preferably ruthenium atom.This invention also relates to a process to make linear alpha-olefins comprising contacting a feed material and an optional alkene (such as ethylene) with the catalyst described above, wherein the feed material is a triacylglyceride, fatty acid, fatty acid alkyl ester, and/or fatty acid ester, typically derived from seed oil (e.g., biodiesel).
摘要翻译：本发明涉及包含环烷基氨基卡宾配体和亚苄基的组合的催化剂化合物，它们都附着在第8族金属，优选钌原子上。本发明还涉及制备线性α-烯烃的方法，包括使进料和任选的烯烃（如乙烯）与上述催化剂接触，其中进料是甘油三酯，脂肪酸，脂肪酸烷基酯和 /或脂肪酸酯，通常衍生自种子油（例如，生物柴油）。

7. 发明授权

US08809563B2 Metathesis catalyst and process for use thereof 有权
标题翻译：复分解催化剂及其使用方法
公开(公告)号：US08809563B2
公开(公告)日：2014-08-19
申请号：US13535875
申请日：2012-06-28
申请人： Matthew W. Holtcamp , Catherine A. Faler , Caol P. Huff , Matthew S. Bedoya , John R. Hagadorn
发明人： Matthew W. Holtcamp , Catherine A. Faler , Caol P. Huff , Matthew S. Bedoya , John R. Hagadorn
IPC分类号： C07F15/00 , C07C1/22
CPC分类号： C07F15/0046 , B01J31/2226 , B01J31/2265 , B01J2231/543 , B01J2531/821 , C07C6/04 , C07C2531/26 , C07D207/06 , C10G3/47 , C10G2300/1014 , C10G2300/1018 , C10G2300/1088 , C10G2300/4025 , C10G2400/20 , C10G2400/22 , Y02E50/13 , C07C11/02
摘要： This invention relates to a Group 8 metal containing catalyst compound for the metathesis of olefins.This invention also relates to process to make alphaolefins comprising contacting an olefin, such as ethylene, with a feed oil containing a triacylglyceride (typically a fatty acid ester (such as methyl oleate)) with a Group 8 metal containing catalyst compound. The fatty acid ester may be a fatty acid methyl ester derived from biodiesel.
摘要翻译：本发明涉及用于烯烃复分解的含8族金属的催化剂化合物。本发明还涉及制备α-烯烃的方法，包括使烯烃如乙烯与含有三酰基甘油酯（通常为脂肪酸酯（如油酸甲酯））的原料油与含有第8族金属的催化剂化合物接触。脂肪酸酯可以是衍生自生物柴油的脂肪酸甲酯。

8. 发明授权

US08227371B2 Class of olefin metathesis catalysts, methods of preparation, and processes for the use thereof 有权
标题翻译：烯烃复分解催化剂类，制备方法及其使用方法
公开(公告)号：US08227371B2
公开(公告)日：2012-07-24
申请号：US12890315
申请日：2010-09-24
申请人： Matthew W. Holtcamp , Matthew S. Bedoya , Laughlin G. McCullough
发明人： Matthew W. Holtcamp , Matthew S. Bedoya , Laughlin G. McCullough
IPC分类号： C07F11/00 , C07F7/04 , B01J31/00
CPC分类号： C07F15/002 , B01J31/0231 , B01J31/2414 , B01J2231/543 , B01J2531/0213 , B01J2531/821 , B01J2531/825 , C07F15/0046
摘要： This invention relates to a metathesis catalyst comprising (i) a Group 8 metal hydride-dihydrogen complex represented by the formula: wherein M is a Group 8 metal; X is an anionic ligand; and L1 and L2 are neutral donor ligands; and (ii) a ligand exchange agent represented by the formula J-Y, wherein J is selected from the group consisting of hydrogen, a C1 to C30 hydrocarbyl, and a C1 to C30 substituted hydrocarbyl; and Y is selected from the group consisting of halides, alkoxides, aryloxides, and alkyl sulfonates.
摘要翻译：本发明涉及复分解催化剂，其包含（i）由下式表示的第8族金属氢化物 - 二氢配合物：其中M是第8族金属; X是阴离子配体; L1和L2是中性供体配体; 和（ii）由式J-Y表示的配体交换剂，其中J选自氢，C1至C30烃基和C1至C30取代的烃基; Y选自卤化物，醇盐，芳氧化物和烷基磺酸盐。

9. 发明申请

US20120053309A1 Functionalizable Synthetic Hydrocarbon Fluids and Integrated Method for Production Thereof 有权
标题翻译：可合成的合成烃类流体及其生产方法
公开(公告)号：US20120053309A1
公开(公告)日：2012-03-01
申请号：US13209215
申请日：2011-08-12
申请人： Matthew W. Holtcamp , John R. Hagadorn , Matthew S. Bedoya
发明人： Matthew W. Holtcamp , John R. Hagadorn , Matthew S. Bedoya
IPC分类号： C08F236/20 , B01J19/00 , C08F4/76
CPC分类号： C08F236/20 , C08C2019/09 , C08F4/65908 , C08F210/14 , C08F4/65927 , C08F2500/17
摘要： This invention relates to a process to produce a poly(alpha-olefin)(alpha, internally unsaturated, nonconjugated olefin) comprising: contacting at least one renewable feedstream with at least one lower olefin in the presence of a metathesis catalyst, wherein a mixture of at least one C4 to C40 linear alpha-olefin and at least one alpha, internally unsaturated, nonconjugated olefin is produced; and contacting the mixture with a metallocene catalyst system, wherein a poly(alpha-olefin)(alpha, internally unsaturated, nonconjugated olefin) is produced.
摘要翻译：本发明涉及一种生产聚（α-烯烃）（α，内部不饱和的非共轭烯烃）的方法，包括：在复分解催化剂存在下使至少一种可再生的原料流与至少一种低级烯烃接触，其中将产生至少一种C 4至C 40直链α-烯烃和至少一种α内部不饱和非共轭烯烃; 并使该混合物与金属茂催化剂体系接触，其中制备聚（α-烯烃）（α，内部不饱和的非共轭烯烃）。

10. 发明授权

US08524930B2 Class of olefin metathesis catalysts, methods of preparation, and processes for the use thereof 有权
标题翻译：烯烃复分解催化剂类，制备方法及其使用方法
公开(公告)号：US08524930B2
公开(公告)日：2013-09-03
申请号：US13149012
申请日：2011-05-31
申请人： Matthew W. Holtcamp , Matthew S. Bedoya
发明人： Matthew W. Holtcamp , Matthew S. Bedoya
IPC分类号： C07F15/00 , C07C2/04 , C08F4/80
CPC分类号： C07F15/0046 , B01J31/2265 , B01J31/24 , B01J2231/543 , B01J2531/821 , B01J2531/825 , C07C6/06 , C07C2531/22 , C07C2531/24 , C07C13/44 , C07C13/68
摘要： This invention relates to a metathesis catalyst comprising a Group 8 metal complex represented by the formula: wherein: M is a Group 8 metal; each X is independently an anionic ligand; R1 and R2 are independently selected from the group consisting of hydrogen, a C1 to C30 hydrocarbyl, and a C1 to C30 substituted hydrocarbyl; R3 and R4 are independently selected from the group consisting of hydrogen, C1 to C12 hydrocarbyl groups, substituted C1 to C12 hydrocarbyl groups, and halides; and L is a neutral donor ligand. This invention also relates to processes for performing a metathesis reaction, in particular ring opening cross metathesis reactions and ring opening metathesis polymerization reactions, using the Group 8 metal complexes.
摘要翻译：本发明涉及包含由下式表示的第8族金属络合物的复分解催化剂：其中：M是第8族金属; 每个X独立地是阴离子配体; R 1和R 2独立地选自氢，C 1至C 30烃基和C 1至C 30取代的烃基; R3和R4独立地选自氢，C1至C12烃基，取代的C1至C12烃基和卤化物; L是中性供体配体。本发明还涉及使用第8族金属络合物进行复分解反应，特别是开环交叉复分解反应和开环易位聚合反应的方法。

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