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    • 47. 发明申请
    • ETCHING SOLUTION FOR REMOVAL OF OXIDE FILM, METHOD FOR PREPARING THE SAME, AND METHOD OF FABRICATING SEMICONDUCTOR DEVICE
    • 用于除去氧化膜的蚀刻溶液,其制备方法和制备半导体器件的方法
    • US20090023265A1
    • 2009-01-22
    • US12243728
    • 2008-10-01
    • CHANG-SUP MUNHyung-Ho KoWoo-Gwan ShimChang-Ki HongSang-Jun Choi
    • CHANG-SUP MUNHyung-Ho KoWoo-Gwan ShimChang-Ki HongSang-Jun Choi
    • H01L21/762H01L21/306H01L21/02
    • H01L21/31111H01L21/76224H01L28/40
    • Provided are an anionic surfactant-containing etching solution for removal of an oxide film, preparation methods thereof, and methods of fabricating a semiconductor device using the etching solution. The etching solution includes a hydrofluoric acid (HF), deionized water, and an anionic surfactant. The anionic surfactant is a compound in which an anime salt is added as a counter ion, as represented by R1—OSO3−HA+, R1—CO2−HA+,R1—PO42—(HA+)2,(R1)2—PO4—HA+, or R1—SO3—HA+ where R1 is a straight or branched hydrocarbon group of C4 to C22 and A is ammonia or amine. The etching solution provides a high etching selectivity ratio of an oxide film to a nitride film or a polysilicon film. Therefore, in a semiconductor device fabrication process such as a STI device isolation process or a capacitor formation process, when an oxide film is exposed together with a nitride film or a polysilicon film, the etching solution can be efficiently used in selectively removing only the oxide film.
    • 提供了一种用于去除氧化膜的含阴离子表面活性剂的蚀刻溶液,其制备方法以及使用该蚀刻溶液制造半导体器件的方法。 蚀刻溶液包括氢氟酸(HF),去离子水和阴离子表面活性剂。 阴离子表面活性剂是其中以R1-OSO3-HA +,R1-CO2-HA +,R1-PO42-(HA +)2,(R1)2-PO4-HA + 或R1-SO3-HA +,其中R1是C4至C22的直链或支链烃基,A是氨或胺。 蚀刻溶液提供氧化膜与氮化物膜或多晶硅膜的高蚀刻选择性比。 因此,在诸如STI器件隔离处理或电容器形成工艺的半导体器件制造工艺中,当氧化物膜与氮化物膜或多晶硅膜一起暴露时,可以有效地使用蚀刻溶液来仅选择性地除去氧化物 电影。