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    • 42. 发明授权
    • Radiation-sensitive planographic printing plate
    • 辐射敏感平版印刷版
    • US06340554B1
    • 2002-01-22
    • US09596051
    • 2000-06-16
    • Koichi KawamuraKazuo MaemotoSumiaki YamasakiTadahiro SororiHiroshi TashiroKiyotaka Fukino
    • Koichi KawamuraKazuo MaemotoSumiaki YamasakiTadahiro SororiHiroshi TashiroKiyotaka Fukino
    • G03F7004
    • B41M5/368B41C1/1041
    • An object of the present invention is to provide excellent in terms of durability wherein development with water, or direct production of the plate from digital data through infrared laser recording in particular such that a special process is not necessary, is possible, by forming on a support a photosensitive layer containing a reaction product of a compound having in a molecule thereof a functional group X and a functional group Y and a compound represented by a formula (1) stated below, or alternatively, containing a polymerization product of a compound having the functional group X and a compound represented by the formula (1) stated below. Further by incorporating water-insoluble particles in this photosensitive layer, many voids are formed in the photosensitive layer, further improving sensitivity and discrimination. The functional group X is a group selected from among a sulfonic acid ester group, a disulfone group, a sulfonimide group, and an alkoxyalkyl ester group and the functional group Y is a group selected from among —OH, —NH2, —COOH, —NH—CO—R3, and —Si(OR4)3 [wherein R3 and R4 each represents an alkyl group or an aryl group]. (R1)n—X—(OR2)4−n  (1) (1) is (R1)n—X—(OR2)4−n wherein R1 and R2 each represents an alkyl group or an aryl group; X represents Si, Al, Ti, or Zr; and n represents an integer from 0 to 2.
    • 本发明的目的在于提供优异的耐久性,其特征在于,利用水的显影,或通过红外激光记录从数字数据直接制造板,使得不需要特殊的处理,可以通过在 支持含有分子中具有官能团X和官能团Y的化合物和由下式(1)表示的化合物的反应产物的感光层,或者包含具有下式的化合物的聚合产物: 官能团X和下述式(1)表示的化合物。 此外,通过在该感光层中引入水不溶性颗粒,在感光层中形成许多空隙,进一步提高了敏感性和鉴别性。 官能团X是选自磺酸酯基,二砜基,磺酰亚胺基和烷氧基烷基酯基的基团,官能团Y是选自-OH,-NH 2,-COOH, - NH-CO-R3和-Si(OR4)3 [其中R3和R4各自表示烷基或芳基](1)为(R1)nX-(OR2)4-n,其中R1和R2各自表示 烷基或芳基; X表示Si,Al,Ti或Zr; n表示0〜2的整数。
    • 45. 发明授权
    • Positive image forming composition
    • 正成像组合物
    • US5731123A
    • 1998-03-24
    • US791901
    • 1997-01-31
    • Koichi KawamuraKazuya Uenishi
    • Koichi KawamuraKazuya Uenishi
    • C07C311/48G03F7/004G03F7/039G03F7/021
    • G03F7/039G03F7/0045Y10S430/106Y10S430/111Y10S430/121Y10S430/122Y10S430/127
    • Provided is a positive image forming composition which comprises (a) a compound generating an acid when exposed to light or heat and (b) a sulfonimide compound represented by the following formula (I): L.sub.1 --(SO.sub.2 --NR.sub.2 --SO.sub.2 --R.sub.1).sub.n (I) wherein n is an integer from 1 to 6; R.sub.1 is an aromatic group or an alkyl group; L.sub.1 is an aromatic group or an alkyl group in the case of n=1, while it is a polyvalent organic linkage group in the case of n=2-6; and R.sub.2 is an alkoxymethyl group, an arylmethyl group, or an alicyclic alkyl group; or a polymer containing in side chains constitutional units represented by the following formula (I'): --L--SO.sub.2 --NR.sup.2 --SO.sub.2 --R.sup.1 (I') wherein R.sup.1 has the same meaning as R.sub.1 in formula (I); L is a polyvalent organic group for connecting the constitutional unit of formula (I') to the polymer skeleton; and R.sup.2 has the same meaning as R.sub.2 in formula (I).
    • 提供了一种正成像组合物,其包含(a)当暴露于光或热时产生酸的化合物和(b)由下式(I)表示的磺酰亚胺化合物:L1-(SO2-NR2-SO2-R1) n(I)其中n为1至6的整数; R1是芳基或烷基; 在n = 1的情况下,L 1为芳基或烷基,n = 2-6的情况下为多价有机连接基; R2是烷氧基甲基,芳基甲基或脂环族烷基; 或含有下式(I')表示的侧链结构单元的聚合物:-L-SO 2 -NR 2 -SO 2 -R 1(I')其中R 1与式(I)中的R 1相同; L是用于将式(I')的结构单元与聚合物骨架连接的多价有机基团; R2与式(I)中的R 2具有相同的含义。