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    • 46. 发明授权
    • Silver halide photographic light-sensitive material
    • 卤化银照相感光材料
    • US5459027A
    • 1995-10-17
    • US24915
    • 1993-03-02
    • Shunji TakadaHiroyuki MifuneTetsuro Kojima
    • Shunji TakadaHiroyuki MifuneTetsuro Kojima
    • G03C1/09
    • G03C1/09
    • Disclosed herein is a silver halide photographic light-sensitive material comprising at least one layer made of a silver halide emulsion comprising a dispersion medium and silver halide grains dispersed in the dispersion medium. Each of the silver halide grains contains a metal or metal ions other than silver. The emulsion has been chemically sensitized in the presence of a tellurium compound which has a pseudo-first order reaction rate constant k of 1.times.10.sup.-8 to 1.times.10.sup.-0 min.sup.-1. The metal is at least one polyvalent metal selected from the group consisting of Ir, Rh, Pd, Ru, Pt, Os, Fe, Ni and Co. The metal ions are ammonium salt, acetate, nitrate, sulfate, phosphate, hydroxide, or complex salt of the metal. Telluroketones or phosphinetellurides is used as the tellurium compound. It is desirable that the silver halide emulsion is a monodispersed emulsion having a variation coefficient of 22% or less. The silver halide photographic light-sensitive material has its photographic properties, particularly the gradation and the reciprocity, improved, with no reduction of its sensitivity.
    • 本文公开了一种卤化银照相感光材料,其包含由包含分散介质的卤化银乳剂和分散在分散介质中的卤化银颗粒组成的至少一层。 每个卤化银颗粒含有除银以外的金属或金属离子。 在碲化合物存在下,乳液已被化学增感,碲化合物的伪一级反应速率常数k为1×10 -8至1×10 -10分钟-1。 金属是选自Ir,Rh,Pd,Ru,Pt,Os,Fe,Ni和Co中的至少一种多价金属。金属离子是铵盐,乙酸盐,硝酸盐,硫酸盐,磷酸盐,氢氧化物或 复合盐的金属。 用碲化合物或碲化碲作为碲化合物。 优选卤化银乳剂是变分系数为22%以下的单分散乳液。 卤化银摄影感光材料具有其摄影性能,特别是渐变和互易性,改善了,其灵敏度没有降低。
    • 49. 发明授权
    • Method for processing silver halide photographic materials, and
developer and silver halide photographic material used therein
    • 用于处理银盐摄影材料的方法及其使用的开发商和银盐摄影材料
    • US5102779A
    • 1992-04-07
    • US596272
    • 1990-10-12
    • Tetsuro KojimaEiichi OkutsuKazunobu Katoh
    • Tetsuro KojimaEiichi OkutsuKazunobu Katoh
    • G03C5/29G03C1/043G03C1/06G03C5/30G03C5/305
    • G03C5/305G03C1/043
    • A method for processing silver halide photographic materials comprising the step of: processing imagewise exposed silver halide photographic material using a developer containing at least one compound represented by general formula (X): ##STR1## wherein R.sub.1 and R.sub.2 each represents a hydrogen atom, an alkyl group containing from 2 to 8 carbon atoms, an alkenyl group containing from 3 to 8 carbon atoms, or an aralkyl group containing from 7 to 12 carbon atoms; or R.sub.1 and R.sub.2 are combined to form a ring; R.sub.3, R.sub.4, R.sub.5, and R.sub.6 each represents a hydrogen atom, or an alkyl group containing from 1 to 4 carbon atoms: and n represents an integer from 3 to 20. A developer for processing silver halide photographic materials comprising at least one compound represented by general formula (X), described above. A silver halide photographic material comprising: at least one compound represented by general formula (X'): ##STR2## wherein R'.sub.1 and R'.sub.2 each represents a hydrogen atom, an alkyl group containing from 1 to 30 carbon atoms, an alkenyl group containing from 3 to 30 carbon atoms, or an aralkyl group containing from 7 to 30 carbon atoms; or R'.sub.1 and R'.sub.2 are combined to form a ring; R.sub.3, R.sub.4, R.sub.5, and R.sub.6 are the same as described above; and n' represents an integer from 2 to 50. A method for processing silver halide photographic materials comprising the step of: processing imagewise exposed silver halide photographic material comprising at least one compound represented by general formula (X'), described above.