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41. 发明授权

US08062508B2 Hydroprocessing using bulk bimetallic catalysts 有权
标题翻译：使用散装双金属催化剂的加氢处理
公开(公告)号：US08062508B2
公开(公告)日：2011-11-22
申请号：US11586398
申请日：2006-10-25
申请人： Stuart L. Soled , Sabato Miseo , Sonja Eijsbouts , Frans L. Plantenga
发明人： Stuart L. Soled , Sabato Miseo , Sonja Eijsbouts , Frans L. Plantenga
IPC分类号： C10G45/00
CPC分类号： B01J23/883 , B01J35/002 , B01J37/0009 , B01J37/03 , B01J37/08 , C10G45/04 , C10G45/08 , C10G65/04 , C10G65/12
摘要： The invention relates to a process for upgrading hydrocarbonaceous feedstreams by hydroprocessing using bulk bimetallic catalysts. More particularly, the invention relates to a catalytic hydrotreating process for the removal of sulfur and nitrogen from a hydrocarbon feed such as a fuel or a lubricating oil feed. The catalyst is a bulk catalyst containing a Group VIII metal and a Group VIB metal.
摘要翻译：本发明涉及通过使用大量双金属催化剂的加氢处理来改质含烃原料流的方法。更具体地说，本发明涉及一种用于从诸如燃料或润滑油进料的烃进料中除去硫和氮的催化加氢处理方法。催化剂是含有VIII族金属和VIB族金属的本体催化剂。

42. 发明授权

US07232934B2 Hydrogenation of oxo aldehydes to oxo alcohols in the presence of a nickel-molybdenum catalyst 失效
标题翻译：在镍 - 钼催化剂存在下，将羰基醛氢化成羰基合成醇
公开(公告)号：US07232934B2
公开(公告)日：2007-06-19
申请号：US10938252
申请日：2004-09-10
申请人： Ramzi Yanni Saleh , Stuart L. Soled , Sabato Miseo , Hyung S. Woo
发明人： Ramzi Yanni Saleh , Stuart L. Soled , Sabato Miseo , Hyung S. Woo
IPC分类号： C07C27/00
CPC分类号： C07C29/141 , C07C31/125
摘要： A reduced or partially reduced nickel-molybdenum catalyst prepared by a process having the steps of 1) reacting nickel carbonate and molybdenum oxide precursors to form nickel molybdate and 2) treating the nickel molybdate under reducing conditions to form the reduced or partially reduced nickel-molybdenum catalyst. There is also a process for making the catalyst. There is also a process for using the catalyst in the hydrogenation of an oxo aldehyde, thereby forming an oxo alcohol of high selectivity. There is also a process for forming an oxo alcohol from the hydroformylation/hydrogenation of an olefinic feedstream. There is also a process for forming an oxo alcohol by contacting formates, dimers, trimers, and organic acids with hydrogen in the presence of a reduced or partially reduced nickel-molybdenum catalyst. The foregoing processes are also useful with a catalyst having the general formula YxZ wherein Y is nickel and/or cobalt and Z is molybdenum and/or tungsten; and wherein x ranges between about 0.25 to about 4.0. There are also reduced or partially reduced catalysts of the general formula NixMo or YxZ wherein x ranges between about 0.25 to about 4.0 and wherein oxide precursors of the catalysts are substantially free of ammonium groups.
摘要翻译：通过具有以下步骤的方法制备的还原或部分还原的镍 - 钼催化剂：具有以下步骤：1）使碳酸镍和氧化钼前体反应形成钼酸镍，和2）在还原条件下处理钼酸镍以形成还原或部分还原的镍 - 钼催化剂。还有一种制备催化剂的方法。还有一种使用催化剂加氢羰基醛的方法，从而形成高选择性的羰基合成醇。还有从烯烃进料流的加氢甲酰化/氢化形成羰基合成醇的方法。还有一种通过在还原或部分还原的镍 - 钼催化剂存在下使甲酸盐，二聚体，三聚体和有机酸与氢接触来形成羰基合成醇的方法。上述方法对于具有通式Y x Z Z的催化剂也是有用的，其中Y是镍和/或钴，Z是钼和/或钨; 并且其中x在约0.25至约4.0之间。还有还原或部分还原的通式为Ni x Mo或Y x Z z的催化剂，其中x在约0.25至约4.0之间，其中催化剂的氧化物前体是基本上不含铵基团。

43. 发明授权

US07229548B2 Process for upgrading naphtha 有权
标题翻译：石脑油升级工艺
公开(公告)号：US07229548B2
公开(公告)日：2007-06-12
申请号：US10677697
申请日：2003-10-02
申请人： Kenneth L. Riley , Stuart L. Soled , Sabato Miseo , Frans L. Plantenga , Marinus Bruce Cerfontain , Sonja Eijsbouts , Eelko Brevoord
发明人： Kenneth L. Riley , Stuart L. Soled , Sabato Miseo , Frans L. Plantenga , Marinus Bruce Cerfontain , Sonja Eijsbouts , Eelko Brevoord
IPC分类号： C10G45/00 , C10G65/02
CPC分类号： C10G65/12 , B01J23/002 , B01J23/85 , B01J23/88 , B01J23/883 , B01J23/8878 , B01J23/888 , B01J23/8885 , B01J37/03 , B01J37/082 , C07C29/16 , C08F8/00 , C08F8/04 , C08F8/50 , C10G45/08 , C10G45/16 , C10G47/04 , C10G65/04 , C10G65/08 , C10G2400/10 , C10G2400/14 , C08F240/00
摘要： A method for upgrading a naphtha feed to a naphtha product containing less than about 10 wppm of nitrogen and less than about 15 wppm sulfur, the method comprising contacting said naphtha feed with hydrogen in the presence of a bulk multimetallic catalyst under effective reactor conditions to hydrodesulfurize and hydrodenitrogenize said naphtha feed to produce said naphtha product, wherein said bulk multimetallic catalyst comprises at least one Group VIII non-noble metal and at least two Group VIB metals.
摘要翻译：一种将石脑油进料升级成含有小于约10wppm氮和小于约15wppm硫的石脑油产品的方法，所述方法包括在有效反应器条件下在大量多金属催化剂存在下使所述石脑油进料与氢气接触以加氢脱硫并且对所述石脑油进料进行加氢脱氮以产生所述石脑油产品，其中所述本体多金属催化剂包含至少一种第VIII族非贵金属和至少两种VIB族金属。

44. 发明授权

US5254518A Group IVB oxide addition to noble metal on rare earth modified silica alumina as hydrocarbon conversion catalyst 失效
标题翻译：第IVB族氧化物添加到稀土改性二氧化硅氧化铝上的贵金属作为烃转化催化剂
公开(公告)号：US5254518A
公开(公告)日：1993-10-19
申请号：US916759
申请日：1992-07-22
申请人： Stuart L. Soled , Gary B. McVicker , William E. Gates , Sabato Miseo
发明人： Stuart L. Soled , Gary B. McVicker , William E. Gates , Sabato Miseo
IPC分类号： B01J21/12 , B01J23/10 , B01J23/62 , B01J23/63 , B01J23/656 , C10G35/09 , C10G45/10 , C10G45/12 , C10G45/62 , C10G45/64 , B01J23/12 , B01J23/16
CPC分类号： B01J23/10 , B01J23/626 , B01J23/63 , B01J23/6567 , C10G35/09
摘要： By this invention there is provided a catalyst composition comprising a Group IVB oxide, an amorphous silica-alumina support having dispersed thereon a rare earth oxide, which as herein used also includes yttrium oxide, and a metal(s) selected from the group consisting of Group VIII noble metal(s), mixtures of Group VIII noble metal(s) and tin, mixtures of Group VIII noble metal(s) and rhenium, and mixtures of Group VIII noble metal(s), tin and rhenium. The amorphous silica-alumina support contains at least about 50% silica by weight. The catalyst can function as a hydrocarbon conversion catalyst in reactions where platinum on halided (Cl,F)-alumina is typically used.

45. 发明授权

US5113034A Dimerization catalyst and process therefor 失效
标题翻译：二聚催化剂及其工艺
公开(公告)号：US5113034A
公开(公告)日：1992-05-12
申请号：US740251
申请日：1991-08-05
申请人： Stuart L. Soled , Nicholas C. Dispenziere, Jr. , Ramzi Y. Saleh , Sabato Miseo
发明人： Stuart L. Soled , Nicholas C. Dispenziere, Jr. , Ramzi Y. Saleh , Sabato Miseo
IPC分类号： B01J21/06 , B01J23/30 , B01J27/047 , B01J27/053 , C07B61/00 , C07C2/08 , C07C2/10 , C07C11/02 , C07C11/107
CPC分类号： B01J21/066 , B01J21/063 , B01J23/30 , B01J27/053 , C07C2/10 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/12
摘要： A solid, acid catalyst, supported or unsupported, comprised of an anion modified Group IVB oxide is used to dimerize C.sub.3 or C.sub.4 containing feedstreams.

46. 发明申请

US20110190557A1 HYDROPROCESSING CATALYSTS AND THEIR PRODUCTION 有权
标题翻译：氢化催化剂及其生产
公开(公告)号：US20110190557A1
公开(公告)日：2011-08-04
申请号：US12967354
申请日：2010-12-14
申请人： Chris E. Kliewer , Stuart L. Soled , Sabato Miseo , Jeffrey S. Beck
发明人： Chris E. Kliewer , Stuart L. Soled , Sabato Miseo , Jeffrey S. Beck
IPC分类号： C07C5/02 , B01J27/051 , B01J37/20 , B01J37/04
CPC分类号： C10G45/08 , B01J23/8885 , B01J27/0515 , B01J33/00 , B01J35/002 , B01J35/0046 , B01J37/04 , B01J37/10 , B01J37/14 , B01J37/20 , C10G45/10 , C10G49/04 , C10G49/06 , C10G2300/202 , C10G2300/70
摘要： In a process for producing a hydroprocessing catalyst, a particulate metal oxide composition comprising an oxide of at least one first metal selected from Group 6 of the Periodic Table of the Elements can be mixed with particles of a sulfide of at least one second metal selected from Groups 8 to 10 of the Periodic Table of the Elements to produce a particulate catalyst precursor. The particulate catalyst precursor can then be sulfided under conditions sufficient to at least partially convert the particulate catalyst precursor into a layered metal sulfide having defect sites associated with the second metal sulfide.
摘要翻译：在制备加氢处理催化剂的方法中，包含选自元素周期表第6族的至少一种第一金属的氧化物的颗粒状金属氧化物组合物可与选自以下的至少一种第二金属的硫化物颗粒混合：元素周期表第8至10族，以产生颗粒催化剂前体。然后可以在足以至少部分地将颗粒状催化剂前体转化成具有与第二金属硫化物相关的缺陷位点的层状金属硫化物的条件下将颗粒状催化剂前体硫化。

47. 发明授权

US07591942B2 Bulk bi-metallic catalysts made from precursors containing an organic agent 有权
标题翻译：由含有有机试剂的前体制成的块状双金属催化剂
公开(公告)号：US07591942B2
公开(公告)日：2009-09-22
申请号：US11227726
申请日：2005-09-14
申请人： Stuart L. Soled , Sabato Miseo , Zhiguo Hou
发明人： Stuart L. Soled , Sabato Miseo , Zhiguo Hou
IPC分类号： C10G45/04 , C10G45/44 , C10G47/02 , C10G45/60 , C07C5/02 , B01J27/00 , B01J27/043 , B01J31/00 , B01J23/00
CPC分类号： B01J35/002 , B01J23/88 , B01J23/883 , B01J23/888 , B01J27/188 , B01J27/24 , B01J35/1014 , B01J35/1038 , B01J37/0018 , B01J37/03 , B01J37/20 , B01J37/28 , C10G45/08 , C10G45/38 , C10G45/50 , C10G45/60 , C10G47/02 , C10G49/04 , C10G49/08 , C10G65/02 , C10G65/12
摘要： Bulk bi-metallic catalysts for use in the hydroprocessing of hydrocarbon feeds, as well as a method for preparing such catalysts. The catalysts are prepared from a catalyst precursor containing an organic agent.
摘要翻译：用于烃进料加氢处理的块状双金属催化剂，以及制备这种催化剂的方法。催化剂由含有有机试剂的催化剂前体制备。

48. 发明授权

US5457253A Oxide addition to noble metal on rare earth modified silica alumina as hydrocarbon conversion catalyst 失效
标题翻译：氧化物加入贵金属稀土改性二氧化硅作为烃转化催化剂
公开(公告)号：US5457253A
公开(公告)日：1995-10-10
申请号：US359764
申请日：1994-12-20
申请人： Stuart L. Soled , Gary B. McVicker , William E. Gates , Sabato Miseo
发明人： Stuart L. Soled , Gary B. McVicker , William E. Gates , Sabato Miseo
IPC分类号： B01J21/12 , B01J23/10 , B01J23/62 , B01J23/63 , B01J23/656 , C10G35/09 , C10G45/10 , C10G45/12 , C10G45/62 , C10G45/64 , C07C2/52 , C07C5/13 , C10G35/06 , C10G73/00
CPC分类号： B01J23/10 , B01J23/626 , B01J23/63 , B01J23/6567 , C10G35/09
摘要： By this invention there is provided a catalyst composition comprising a Group IVB oxide, an amorphous silica-alumina support having dispersed thereon a rare earth oxide, which as herein used also includes yttrium oxide, and a metal(s) selected from the group consisting of Group VIII noble metal(s), mixtures of Group VIII noble metal(s) and tin, mixtures of Group VIII noble metal(s) and rhenium, and mixtures of Group VIII noble metal(s), tin and rhenium. The amorphous silica-alumina support contains at least about 50% silica by weight. The catalyst can function as a hydrocarbon conversion catalyst in reactions where platinum on halided (Cl,F)-alumina is typically used.
摘要翻译：通过本发明，提供了一种催化剂组合物，其包含IVB族氧化物，其上分散有稀土氧化物的无定形二氧化硅 - 氧化铝载体，其在本文中还包括氧化钇和选自以下的金属： VIII族贵金属，第VIII族贵金属和锡的混合物，第VIII族贵金属和铼的混合物，以及第VIII族贵金属，锡和铼的混合物。无定形二氧化硅 - 氧化铝载体含有至少约50重量％的二氧化硅。在通常使用卤化（Cl，F） - 氧化铝上的铂的反应中，催化剂可以用作烃转化催化剂。

49. 发明授权

US5420092A Silica supported metal and heteropolyacid catalysts 失效
标题翻译：二氧化硅负载金属和杂多酸催化剂
公开(公告)号：US5420092A
公开(公告)日：1995-05-30
申请号：US58605
申请日：1993-05-06
申请人： Stuart L. Soled , Gary B. McVicker , Sabato Miseo , William E. Gates
发明人： Stuart L. Soled , Gary B. McVicker , Sabato Miseo , William E. Gates
IPC分类号： B01J23/63 , B01J23/652 , B01J23/888 , B01J27/185 , B01J27/186 , B01J27/188 , C07B61/00 , C07C5/27 , C07C9/16 , B01J27/18 , B01J21/08 , B01J23/30 , B01J27/182
CPC分类号： C07C5/2724 , B01J23/6527 , B01J23/888 , B01J27/185 , B01J27/188 , C07C5/2791
摘要： The present invention is directed to novel catalyst compositions, their preparation, and their use in a selective paraffin isomerization process. The solid acid catalyst compositions comprise a silica support, a Group VIII metal, and a heteropolyacid selected from the group consisting of 12-tungstophosphoric acid, 12-tungstosilicic acid, the exchanged aluminum salt of 12-tungstophosphoric acid, the exchanged aluminum salt of 12-tungstosilicic acid and mixtures thereof. The use of said catalysts in an isomerization process comprises contacting said catalysts with a feed comprising C.sub.n or C.sub.n + paraffins, wherein n=4.
摘要翻译：本发明涉及新型催化剂组合物及其制备方法及其在选择性石蜡异构化方法中的应用。固体酸催化剂组合物包含二氧化硅载体，第Ⅷ族金属和选自12-钨磷酸，12-钨硅酸，12-钨磷酸的交换的铝盐，12-交换的铝盐12 钨硅酸及其混合物。在异构化方法中使用所述催化剂包括使所述催化剂与包含C n或C n +链烷烃的进料接触，其中n = 4。

50. 发明授权

US5100856A Iron-zinc based catalysts for the conversion of synthesis gas to alpha-olefins 失效
标题翻译：用于将合成气转化成α-烯烃的基于铁 - 锌的催化剂
公开(公告)号：US5100856A
公开(公告)日：1992-03-31
申请号：US591304
申请日：1990-10-01
申请人： Stuart L. Soled , Sabato Miseo , Enrique Iglesia , Rocco A. Fiato
发明人： Stuart L. Soled , Sabato Miseo , Enrique Iglesia , Rocco A. Fiato
IPC分类号： B01J23/80 , C07C1/04
CPC分类号： C07C1/044 , B01J23/80 , C07C2523/04 , C07C2523/06 , C07C2523/72 , C07C2523/745 , C07C2523/80
摘要： New copper-potassium promoted iron-zinc catalysts wherein the iron:zinc atomic ratio is 5:1 or greater, exhibit improved activity, selectivity and stability in the synthesis of alpha-olefins from hydrogen and carbon monoxide.
摘要翻译：新的铜 - 钾促进的铁 - 锌催化剂，其中铁：锌原子比为5:1或更大，在氢和一氧化碳合成α-烯烃中表现出改进的活性，选择性和稳定性。

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