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41. 发明授权

US4400311A Substituted methyl isopropyl cyclohexenones, organoleptic uses thereof and process for preparing same 失效
公开(公告)号：US4400311A
公开(公告)日：1983-08-23
申请号：US343580
申请日：1982-01-28
申请人： Philip T. Klemarczyk , Lambert Dekker , Jacob Kiwala
发明人： Philip T. Klemarczyk , Lambert Dekker , Jacob Kiwala
IPC分类号： A24B15/34 , C07C45/72 , C07C45/74 , C11B9/00 , C11D3/50
CPC分类号： C11D3/50 , A24B15/34 , C07C45/72 , C07C45/74 , C11B9/0034
摘要： Described is the genus of compounds defined according to the structure: ##STR1## wherein one of the dashed lines represents a carbon-carbon double bond and the other of the dashed lines represents a carbon-carbon single bond; wherein R.sub.4 represents methyl or ethyl; wherein one of the R.sub.1, R.sub.2 and R.sub.3 represents 2-methyl-1-propenyl or 2-methyl-1-propylidenyl; and the other of R.sub.1, R.sub.2 and R.sub.3 represent hydrogen; with the provisos that:(i) when the dashed line at the 3-4 position is a double bond, then R.sub.3 is hydrogen or 2-methyl-1-propenyl;(ii) when the dashed line at the 2-3 position is a double bond, then R.sub.2 is hydrogen or 2-methyl-1-propenyl;(iii) when R.sub.4 is ethyl, then R.sub.2 is methyl and the double bond is at the 2-3 position; and(iv) when R.sub.4 is methyl, then R.sub.2 is hydrogen; 2-methyl-1-propenyl or 2-methyl-1-propylidenyl;with the members of said genus being novel compounds when R.sub.4 is ethyl or when R.sub.4 is methyl and the double bond is at the 3-4 position or when R.sub.4 is methyl and the double bond is at the 2-3 position with R.sub.3 being hydrogen.The compounds of the genus defined according to the structure: ##STR2## are useful in augmenting or enhancing the aroma or taste of consumable materials including smoking tobacco compositions, smoking tobacco articles, perfume compositions, colognes and perfumed articles (e.g. solid or liquid anionic, cationic, nonionic or zwitterionic detergents, cosmetic powder compositions, fabric softener compositions and fabric softener articles). Also described is the novel process for preparing compounds defined according to the genus having the structure: ##STR3## by either dimerizing unsaturated ketones defined according to the structure: ##STR4## wherein one of the dashed lines is a carbon-carbon double bond and the other of the dashed lines is a carbon-carbon single bond and wherein R.sub.4 ' represents hydrogen or methyl in the presence of an appropriate catalyst such as an alkali metal hydroxide or an alkaline earth metal hydroxide catalyst, aluminum chloride, sulfuric acid or the like or by reaction of isobutyraldehyde and acetone or methyl ethyl ketone in the presence of an appropriate catalyst such as an alkali metal hydroxide or an alkaline earth metal hydroxide or aluminum chloride or the like.

42. 发明授权

US4374746A Cyclohexyl phenethylether derivatives, process for preparing same and uses thereof in combatting tobacco beetles and in augmenting or enhancing the aroma of perfumes, colognes and perfumed articles 失效
标题翻译：环己基苯乙醚衍生物，其制备方法及其在对付烟草甲虫中的用途，以及增强或增强香水，古龙水和香料的香气
公开(公告)号：US4374746A
公开(公告)日：1983-02-22
申请号：US305537
申请日：1981-09-25
申请人： Jacob Kiwala , Richard J. Tokarzewski , Frederick L. Schmitt , Mark A. Sprecker
发明人： Jacob Kiwala , Richard J. Tokarzewski , Frederick L. Schmitt , Mark A. Sprecker
IPC分类号： A01N31/06 , C07C43/168 , C11B9/00 , C11D3/50 , C11D9/44
CPC分类号： C11B9/0061 , A01N31/06 , C07C43/168 , C11B9/0038 , C11D3/50
摘要： Described is the genus of compounds defined according to the structure: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are the same or different and each represents methyl or hydrogen with the proviso that when one of R.sub.2, R.sub.3 and R.sub.4 is methyl, then the other two of R.sub.2, R.sub.3 and R.sub.4 are hydrogen which have been found to be useful in augmenting or enhancing the aroma of perfumes and perfumed articles as well as colognes and, in addition, in combatting tobacco beetles of the species Lasioderma serricorne (F.). Also described are novel processes for preparing such cyclohexyl phenethylether derivatives by reacting cyclohexene having the structure: ##STR2## with a phenethyl alcohol derivative having the structure: ##STR3## in the presence of an acid catalyst.
摘要翻译：描述了根据以下结构定义的化合物属：其中R 1，R 2，R 3和R 4相同或不同，并且各自表示甲基或氢，条件是当R 2，R 3和R 4中的一个为甲基时，则已经发现R2，R3和R4中的另外两个是氢，其可用于增强或增强香料和香料制品以及古龙水的香气，并且另外还用于对抗Lasioderma serricorne（F）的烟草甲虫。）。还描述了通过在酸催化剂存在下使具有以下结构的环己烯与具有以下结构的苯乙醇衍生物反应来制备这种环己基苯乙醚衍生物的新方法：

43. 发明授权

US4374055A Alkyl esters of 1-alkanoyl cycloalkanols and organoleptic uses thereof 失效
标题翻译： 1-烷酰基环烷醇的烷基酯及其感官用途
公开(公告)号：US4374055A
公开(公告)日：1983-02-15
申请号：US314002
申请日：1981-10-22
申请人： Ronald P. Schreck , Kenneth K. Light , John B. Hall , Frederick L. Schmitt , Manfred H. Vock , William L. Schreiber , Joaquin F. Vinals , Jacob Kiwala
发明人： Ronald P. Schreck , Kenneth K. Light , John B. Hall , Frederick L. Schmitt , Manfred H. Vock , William L. Schreiber , Joaquin F. Vinals , Jacob Kiwala
IPC分类号： A24B15/34 , C11B9/00 , C11D3/50 , A61K7/46
CPC分类号： A24B15/34 , C11B9/0026 , C11D3/50
摘要： Described is a process for preparing several substituted or unsubstituted cycloalkyl acyl alkanoates defined according to the generic structure: ##STR1## wherein R.sub.1 and R.sub.2 taken together complete a cycloalkyl moiety or methyl, dimethyl or trimethyl substituted cycloalkyl moiety containing five or six carbon atoms in the ring and wherein R.sub.3 is C.sub.1 -C.sub.3 lower alkyl and R.sub.4 is methyl or hydrogen by reacting a compound having the generic structure: ##STR2## in an aqueous silver-ion containing solution having a weakly acidic pH at elevated temperatures. The compounds so produced are useful for their organoleptic properties in consumable materials, such as foodstuffs, foodstuff flavorants, chewing gums, chewing gum flavorants, toothpastes, toothpaste flavorants, medicinal products, medicinal product flavorants, chewing tobaccos, chewing tobacco flavorants, smoking tobaccos, smoking tobacco flavorants, perfume compositions, perfumed articles, such as cationic, anionic, nonionic and zwitterionic detergents, fabric softener compositions, drier-added fabric softener articles, textile sizing agents and optical brighteners for textiles as well as colognes.
摘要翻译：描述了根据通用结构定义的若干取代或未取代的环烷基酰基链烷酸酯的方法：其中R 1和R 2一起完成环烷基部分或含有5或6个碳原子的甲基，二甲基或三甲基取代的环烷基部分环，其中R 3是C 1 -C 3低级烷基，R 4是甲基或氢，通过使具有通式结构的化合物：在高温下具有弱酸性pH的含水银离子溶液中。如此生产的化合物可用于消费材料如食品，食品香料，口香糖，口香糖调味剂，牙膏，牙膏调味剂，药用产品，药用香料，咀嚼烟草，咀嚼烟草香料，烟草烟草，吸烟烟草调味剂，香料组合物，香料制品，例如阳离子，阴离子，非离子和两性离子洗涤剂，织物柔软剂组合物，干燥剂添加的织物柔软剂制品，纺织品上浆剂和用于纺织品的荧光增白剂以及古龙水。

44. 发明授权

US4371715A Process for preparing cyclohexyl phenethylether derivatives 失效
标题翻译：制备环己基苯乙醚衍生物的方法
公开(公告)号：US4371715A
公开(公告)日：1983-02-01
申请号：US305535
申请日：1981-09-25
申请人： Jacob Kiwala , Richard J. Tokarzewski , Frederick L. Schmitt , Mark A. Sprecker
发明人： Jacob Kiwala , Richard J. Tokarzewski , Frederick L. Schmitt , Mark A. Sprecker
IPC分类号： A01N31/06 , C07C43/168 , C11B9/00 , C07C41/06
CPC分类号： A01N31/06 , C07C43/168 , C11B9/0038 , C11B9/0061
摘要： Described is the genus of compounds defined according to the structure: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are the same or different and each represents methyl or hydrogen with the proviso that one of R.sub.2, R.sub.3 and R.sub.4 is methyl and the other two of R.sub.2, R.sub.3 and R.sub.4 are hydrogen which have been found to be useful in augmenting or enhancing the aroma of perfumes and perfumed articles as well as colognes and, in addition, in combatting tobacco beetles of the species Lasioderma serricorne (F.). Also described are novel processes for preparing such cyclohexyl phenethylether derivatives by reacting cyclohexene having the structure: ##STR2## with a phenethyl alcohol derivative having the structure: ##STR3## in the presence of an acid catalyst.
摘要翻译：描述了根据以下结构定义的化合物属：其中R 1，R 2，R 3和R 4相同或不同，并且各自表示甲基或氢，条件是R 2，R 3和R 4中的一个为甲基，另一个为已经发现R2，R3和R4中的两个是氢，其可用于增强或增强香料和香料制品以及古龙水的香气，并且另外用于对抗Lasioderma serricorne（F.）的烟草甲虫。还描述了通过在酸催化剂存在下使具有以下结构的环己烯与具有以下结构的苯乙醇衍生物反应来制备这种环己基苯乙醚衍生物的新方法：

45. 发明授权

US4343791A Cyclohexyl phenethylether derivatives for combatting tobacco beetles 失效
标题翻译：用于对付烟草甲虫的环己基苯乙醚衍生物
公开(公告)号：US4343791A
公开(公告)日：1982-08-10
申请号：US305539
申请日：1981-09-25
申请人： Jacob Kiwala , Richard J. Tokarzewski , Frederick L. Schmitt , Mark A. Sprecker
发明人： Jacob Kiwala , Richard J. Tokarzewski , Frederick L. Schmitt , Mark A. Sprecker
IPC分类号： A01N31/06 , C07C43/168 , C11B9/00 , A01N25/00 , A01N31/00
CPC分类号： C11B9/0061 , A01N31/06 , C07C43/168 , C11B9/0038
摘要： Described is the genus of compounds defined according to the structure: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are the same or different and each represents methyl or hydrogen with the proviso that one of R.sub.2, R.sub.3 and R.sub.4 is methyl and the other two of R.sub.2, R.sub.3 and R.sub.4 are hydrogen which have been found to be useful in augmenting or enhancing the aroma of perfumes and perfumed articles as well as colognes and, in addition, in combatting tobacco beetles of the species Lasioderma serricorne (F.). Also described are novel processes for preparing such cyclohexyl phenethylether derivatives by reacting cyclohexene having the structure: ##STR2## with a phenethyl alcohol derivative having the structure: ##STR3## in the presence of an acid catalyst.
摘要翻译：描述了根据以下结构定义的化合物属：其中R 1，R 2，R 3和R 4相同或不同，并且各自表示甲基或氢，条件是R 2，R 3和R 4中的一个为甲基，另一个为已经发现R2，R3和R4中的两个是氢，其可用于增强或增强香料和香料制品以及古龙水的香气，并且另外用于对抗Lasioderma serricorne（F.）的烟草甲虫。还描述了通过在酸催化剂存在下使具有以下结构的环己烯与具有以下结构的苯乙醇衍生物反应来制备这种环己基苯乙醚衍生物的新方法：

46. 发明授权

US4315953A Process for augmenting or enhancing the aroma or taste of raspberry flavored foodstuffs using 2,6,6-trimethylcyclohexene derivatives 失效
标题翻译：使用2,6,6-三甲基环己烯衍生物增强或增强覆盆子风味食品的香味或味道的方法
公开(公告)号：US4315953A
公开(公告)日：1982-02-16
申请号：US239048
申请日：1981-02-27
申请人： Robert W. Trenkle , Braja D. Mookherjee , Frederick L. Schmitt , Manfred H. Vock , Joaquin F. Vinals , Jacob Kiwala
发明人： Robert W. Trenkle , Braja D. Mookherjee , Frederick L. Schmitt , Manfred H. Vock , Joaquin F. Vinals , Jacob Kiwala
IPC分类号： A23L27/29 , A24B15/34 , C07C45/62 , C07C49/303 , C07C49/543 , C11B9/00 , C11D3/50 , A23L1/235
CPC分类号： C07C403/16 , A24B15/34 , C07C45/62 , C07C49/303 , C07C49/543 , C11B9/0034 , C11D3/50 , C07C2101/16
摘要： Described is a process for augmenting or enhancing the aroma or taste of raspberry flavored foodstuffs comprising the step of adding to a foodstuff, an aroma augmenting or enhancing quantity of certain 2,6,6-trimethylcyclohexene derivatives.
摘要翻译：描述了增加或增强覆盆子风味食品的香气或味道的方法，其包括向食品添加增强或增加某些2,6,6-三甲基环己烯衍生物的量的步骤。

47. 发明授权

US4312766A Derivatives of cis-3-hexenol and process for producing compositions of matter containing cis-3-hexenal and products produced thereby and organoleptic uses thereof 失效
标题翻译：顺式-3-己烯醇的衍生物及其制备含有顺式-3-己烯醛的物质组合物的方法及由此产生的产物及其感官用途
公开(公告)号：US4312766A
公开(公告)日：1982-01-26
申请号：US169813
申请日：1980-07-17
申请人： Cynthia J. Mussinan , Braja D. Mookherjee , Manfred H. Vock , Frederick L. Schmitt , Edward J. Granda , Joaquin F. Vinals , Jacob Kiwala
发明人： Cynthia J. Mussinan , Braja D. Mookherjee , Manfred H. Vock , Frederick L. Schmitt , Edward J. Granda , Joaquin F. Vinals , Jacob Kiwala
IPC分类号： A23L27/20 , A24B15/32 , D06M13/16 , A61K7/46 , D06M13/18 , D06M13/20
CPC分类号： A24B15/32 , A23L27/2024
摘要： Described are cis-3-hexenyl derivatives having the generic structure: ##STR1## wherein R is one of the moieties: ##STR2## which are useful in foodstuffs, flavorings, fragrances, perfumed articles (e.g. anionic, cationic or nonionic detergents, dryer-added fabric softener articles and cosmetic powders) and smoking tobacco flavorings; processes for producing such cis-3-hexenyl derivatives and products produced according to such processes which include chemical compounds in addition to said cis-3-hexenyl derivatives.
摘要翻译：描述了具有以下通用结构的顺式-3-己烯基衍生物：其中R是可用于食品，调味品，香料，加香制品（例如阴离子，阳离子或非离子洗涤剂，干燥剂 - 添加织物柔软剂制品和化妆粉）和吸烟烟草调味剂; 制备这种顺式-3-己烯基衍生物的方法和根据这些方法生产的产物，除了所述顺式-3-己烯基衍生物外，还包括化学化合物。

48. 发明授权

US4301024A Use of cyclic chemical compounds for augmenting or enhancing the aroma of optical brightener composition 失效
标题翻译：使用环状化合物来增强或增强荧光增白剂组合物的香气
公开(公告)号：US4301024A
公开(公告)日：1981-11-17
申请号：US113290
申请日：1980-01-18
申请人： Mark A. Sprecker , Frederick L. Schmitt , Manfred H. Vock , Joaquin F. Vinals , Jacob Kiwala
发明人： Mark A. Sprecker , Frederick L. Schmitt , Manfred H. Vock , Joaquin F. Vinals , Jacob Kiwala
IPC分类号： A24B15/40 , C07C29/40 , C07D493/08 , C11B9/00 , C09K11/00
CPC分类号： C07D493/08 , A24B15/403 , C07C29/40 , C11B9/0034 , C11B9/008 , C07C2101/16
摘要： Described are derivatives of 2-oxabicyclo[2.2.2]octanes and precursors therefor, cyclohexenemethanols as well as lower alkyl esters of said cyclohexenemethanols. The oxabicyclooctanes are useful in perfumery and foodstuff, medicinal product and tobacco flavors. The cyclohexenemethanols are useful as precursors for the oxabicyclooctanes and are, themselves, useful for their organoleptic properties in perfumery and flavors as are the esters of said cyclohexenemethanols.
摘要翻译：描述的是2-氧杂二环[2.2.2]辛烷及其前体，环己烯甲醇以及所述环己烯甲醇的低级烷基酯的衍生物。氧杂双环辛烷可用于香料和食品，药用产品和烟草香精。环己烯甲醇可用作氧杂双环辛烷的前体，它们本身可用于香料和香料中的感官特性，以及所述环己烯甲醇的酯类。

49. 发明授权

US4292447A Process for hydrogenation of 2,6,6-trimethyl cyclohexene derivatives, products produced thereby and organoleptic uses of said products 失效
标题翻译： 2,6,6-三甲基环己烯衍生物的氢化方法，由此生产的产品和所述产品的感官用途
公开(公告)号：US4292447A
公开(公告)日：1981-09-29
申请号：US969852
申请日：1978-12-15
申请人： Robert W. Trenkle , Braja D. Mookherjee , Frederick L. Schmitt , Manfred H. Vock , Joaquin F. Vinals , Jacob Kiwala
发明人： Robert W. Trenkle , Braja D. Mookherjee , Frederick L. Schmitt , Manfred H. Vock , Joaquin F. Vinals , Jacob Kiwala
IPC分类号： A24B15/34 , C07C45/62 , C07C49/303 , C07C49/543 , C07C403/00 , C11B9/00 , C11D3/50
CPC分类号： C07C403/16 , A24B15/34 , C07C45/62 , C07C49/303 , C07C49/543 , C11B9/0034 , C11D3/50 , C07C2101/16
摘要： Described is a process for preparing hydrogenated derivatives of 2,6,6-trimethyl cyclohexene derivatives by means of treating said derivatives with hydrogen in the presence of a supported palladium catalyst such as palladium-on-calcium carbonate or palladium-on-barium sulfate in the presence of a quinoline activator. The resulting products are useful for their organoleptic properties as foodstuff flavorants and flavor enhancers, perfume composition ingredients, perfumed article ingredients and tobacco flavorants and flavor enhancers.
摘要翻译：描述了通过在负载的钯催化剂如碳酸钯/钯/硫酸钡的存在下用氢处理所述衍生物来制备2,6,6-三甲基环己烯衍生物的氢化衍生物的方法，其中喹啉激活剂的存在。所得到的产品对于其感官特性可用作食品香料和风味增强剂，香料组合物成分，香料制品成分和烟草香料以及风味增强剂。

50. 发明授权

US4287133A 6-Hydroxy-2,6-dimethylheptanal, organoleptic uses thereof and processes for preparing the same 失效
标题翻译： 6-羟基-2,6-二甲基庚醛，其感官用途及其制备方法
公开(公告)号：US4287133A
公开(公告)日：1981-09-01
申请号：US169900
申请日：1980-07-17
申请人： Mark A. Sprecker , Robert W. Trenkle , Braja D. Mookherjee , Manfred H. Vock , Joaquin F. Vinals , Jacob Kiwala , Frederick L. Schmitt
发明人： Mark A. Sprecker , Robert W. Trenkle , Braja D. Mookherjee , Manfred H. Vock , Joaquin F. Vinals , Jacob Kiwala , Frederick L. Schmitt
IPC分类号： C07C45/54 , C07C45/56 , C07C45/64 , C07C47/19 , C11B9/00 , C07C141/10
CPC分类号： C11B9/0015 , C07C45/54 , C07C45/56 , C07C45/64 , C07C47/19
摘要： Described is the compound 6-hydroxy-2,6-dimethylheptanal and methods for preparing foodstuffs, flavoring compositions for foodstuffs, tobacco compositions, flavoring compositions for tobacco, perfume compositions, ingredients for perfume compositions, perfumed articles and ingredients for perfumed articles by including said 6-hydroxy-2,6-dimethylheptanal therein in order to produce:(a) In food flavorings, sweet, green, melon-like, tropical fruit-like, seedy and raspberry aromas and/or tastes;(b) In perfumes, sweet, green, melony, floral and muguet-like aromas; and(c) In tobaccos, sweet, fruity-melon-like, peach-like, and floral aromas prior to and on smoking in the main stream and in the sidestream in smoking tobaccos and the same aroma and taste nuances in the filter.Processes for synthesizing the 6-hydroxy-2,6-dimethylheptanal by hydrolysis of 2,6-dimethyl-5-heptenal are also described.
摘要翻译：描述了化合物6-羟基-2,6-二甲基庚醛以及制备食品的方法，用于食品的调味组合物，烟草组合物，烟草调味组合物，香料组合物，香料组合物成分，香料制品和用于香料制品的成分，包括所述 6-羟基-2,6-二甲基庚醛，以产生：（a）在食品香料中，甜味，绿色，瓜类，热带水果样，种子和覆盆子香气和/或口味; （b）香水，甜，绿，香，香，香，香; 和（c）在主烟道和吸烟烟草之间的吸烟之前和烟草中的烟草，甜味，水果瓜状，桃子状和花香味，以及过滤器中相同的香气和味道细微差别。还描述了通过2,6-二甲基-5-庚烯醛水解合成6-羟基-2,6-二甲基庚醛的方法。

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