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41. 发明授权

US4052525A Multi-layer structure acrylic polymer composition 失效
标题翻译：多层结构丙烯酸聚合物组合物
公开(公告)号：US4052525A
公开(公告)日：1977-10-04
申请号：US679712
申请日：1976-04-23
申请人： Fumio Ide , Kazuo Kishida , Akira Hasegawa
发明人： Fumio Ide , Kazuo Kishida , Akira Hasegawa
IPC分类号： C08F220/00 , B32B27/28 , B32B27/30 , C08F220/10 , C08F285/00 , C08L33/00 , C08L33/04 , C08L51/00 , C08L51/02 , B32B27/36 , B32B27/08
CPC分类号： B32B27/28 , C08F285/00 , Y10T428/31507 , Y10T428/3175 , Y10T428/31797 , Y10T428/31909 , Y10T428/31913 , Y10T428/31917 , Y10T428/3192 , Y10T428/31924 , Y10T428/31928 , Y10T428/31935
摘要： A multi-layer structure polymer composition composed of an innermost layer (A), an elastomeric layer (B), an outermost layer (C), and at least one intermediate layer, said layer (A) having a glass transition temperature (Tg) of 10.degree. C. or higher and consisting of the reaction product of 51 to 100 parts by weight of an alkyl methacrylate whose alkyl group has 4 or less carbon atoms, 0 to 49 parts by weight of a copolymerizable monomer, 0 to 10 parts by weight of a polyfunctional monomer, and 0.1 to 5 parts by weight of a graftlinking agent; said layer (B) having a glass transition temperature (Tg) of 0.degree. C. or lower and consisting of the reaction product of 80 to 100 parts by weight of an alkyl acrylate whose alkyl group has 8 or less carbon atoms, 0 to 20 parts by weight of a copolymerizable monomer, 0 to 10 parts by weight of a polyfunctional monomer, and 0.1 to 5 parts by weight of a graftlinking agent; said layer (C) having a glass transition temperature (Tg) of 50.degree. C. or higher and consisting of the reaction product of 51 to 100 parts by weight of an alkyl methacrylate whose alkyl group has 4 or less carbon atoms, and 0 to 49 parts by weight of a copolymerizable monomer; and said intermediate layer consisting of the reaction product of 10 to 90 parts by weight of an alkyl methacrylate whose alkyl group has 4 or less carbon atoms, 90 to 10 parts by weight of an alkyl acrylate whose alkyl group has 8 or less carbon atoms, 0 to 10 parts by weight of a polyfunctional monomer, and 0.1 to 5 parts by weight of a graftlinking agent. The said polymer composition is excellent in transparency, gloss, and resistance to stress whitening and has good resistance to weather and impact.

42. 发明授权

US4041106A Vinyl chloride polymer composition modified for transparency, impact and thermal resistance 失效
标题翻译：氯乙烯聚合物组合物改性为透明性，耐冲击性和耐热性
公开(公告)号：US4041106A
公开(公告)日：1977-08-09
申请号：US685145
申请日：1976-05-11
申请人： Fumio Ide , Kazuo Kishida , Norihisa Osaka
发明人： Fumio Ide , Kazuo Kishida , Norihisa Osaka
IPC分类号： C08L27/00 , C08F285/00 , C08L1/00 , C08L7/00 , C08L21/00 , C08L25/16 , C08L27/06 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L51/04 , A43B13/04 , C08F6/24 , C08L51/06
CPC分类号： C08L27/06 , C08L25/16 , C08L51/04
摘要： Provided are vinyl chloride polymer compositions having a composite elastomer modifier incorporated therein, whereby said polymers exhibit on excellent balance of the physical properties of thermal resistance, transparency, and impact resistance. The composite elastomer modifier is comprised of (A) 20 to 60% by weight of a graft copolymer prepared by grafting methyl methacrylate and styrene onto a butadiene rubber in a specified sequential multi-stage polymerization procedure of (B) 40 to 80% by weight of a copolymer comprised of .alpha.-methylstyrene, methyl methacrylate and acrylonitrile. The composite elastomer modifier may be prepared by either blending graft copolymer (A) with copolymer (B) or by polymerizing a monomer charge of copolymer (B) in the presence of graft copolymer (A).
摘要翻译：所提供的是具有并入其中的复合弹性体改性剂的氯乙烯聚合物组合物，由此所述聚合物在耐热性，透明性和耐冲击性的物理性能方面表现出优异的平衡。复合弹性体改性剂由（A）20〜60重量％的接枝共聚物组成，接枝共聚物是通过以（B）40〜80重量％的指定的顺序多阶段聚合方法将甲基丙烯酸甲酯和苯乙烯接枝到丁二烯橡胶上而成的由α-甲基苯乙烯，甲基丙烯酸甲酯和丙烯腈组成的共聚物。复合弹性体改性剂可以通过将接枝共聚物（A）与共聚物（B）共混或通过在接枝共聚物（A）的存在下聚合共聚物（B）的单体电荷来制备。

43. 发明授权

US08372227B2 Method for producing multilayer ceramic substrate 有权
标题翻译：多层陶瓷基板的制造方法
公开(公告)号：US08372227B2
公开(公告)日：2013-02-12
申请号：US13274519
申请日：2011-10-17
申请人： Kazuo Kishida , Takahiro Takada
发明人： Kazuo Kishida , Takahiro Takada
IPC分类号： C03B29/00 , B29C65/00
CPC分类号： B32B18/00 , C04B2237/343 , C04B2237/562 , C04B2237/62 , C04B2237/66 , C04B2237/68 , C04B2237/704 , H05K1/167 , H05K3/4629 , H05K3/4688 , H05K2203/308 , Y10T156/10
摘要： In a method for producing a multilayer ceramic substrate by a non-shrinkage process, even when a total area of surface electrodes on a first principal surface side is smaller than that on a second principal surface side, a favorable balance in terms of a time period from softening to crystallization of glass is achieved between the first principal surface side and the second principal surface side, thereby allowing all base material layers to be densified and prevented from causing cracks or warpage, even when the crystallization temperature is lowered to prevent production of a reaction layer. The crystallization temperature of a glass material included in a second base material layer defining a second principal surface with a larger total area of surface electrodes is less than that of a glass material included in a first base material layer defining a first principal surface.
摘要翻译：在通过非收缩工艺制造多层陶瓷基板的方法中，即使在第一主表面侧的表面电极的总面积比第二主面侧的表面电极的总面积小的情况下，在时间段在第一主表面侧和第二主表面侧之间实现从玻璃的软化到结晶化，从而即使结晶温度降低，也可以使所有基材层致密化并防止其引起裂纹或翘曲，从而防止产生反应层。包含在限定具有较大表面电极总面积的第二主表面的第二基材层中的玻璃材料的结晶温度小于包含在限定第一主表面的第一基材层中的玻璃材料的结晶温度。

44. 发明授权

US07082852B2 Cable and/or the like supporting and guiding device 失效
标题翻译：电缆和/或类似的支撑和引导装置
公开(公告)号：US07082852B2
公开(公告)日：2006-08-01
申请号：US10689502
申请日：2003-10-18
申请人： Masaaki Ikeda , Shoichiro Komiya , Takayuki Matsuda , Hideaki Minami , Kazuo Kishida
发明人： Masaaki Ikeda , Shoichiro Komiya , Takayuki Matsuda , Hideaki Minami , Kazuo Kishida
IPC分类号： F16C1/26
CPC分类号： F16G13/16 , H02G11/006 , Y10T74/20462
摘要： To provide a cable and/or the like supporting and guiding device, by which a cable and/or the like can be easily incorporated into a chain and damage of the cable and/or the like and an accident of break in a cable can be minimized. A cable and/or the like supporting and guiding device comprises a chain (CH), a cable and/or the like (CB) disposed along the chain, and a support (20), which intersects the chain to support the cable and/or the like disposed on the chain. The support is composed of a material, which is flexed in the longitudinal direction of the cable and/or the like. In a curved section of the chain, when force is applied to the cable and/or the like, the support is flexed or bent in a direction of an action of force to ensure a length of the cable and/or the like, which is required for bending.
摘要翻译：为了提供电缆和/或类似的支撑和引导装置，通过该电缆和/或类似的支撑和引导装置可以容易地将电缆和/或类似物结合到链条中，并且电缆等的损坏和电缆中的断裂事故可以是最小化。电缆和/或类似的支撑和引导装置包括沿着链条设置的链条（CH），电缆和/或类似物（CB）以及支撑件（20），其与链条相交以支撑电缆和/ 或类似物。支撑体由在电缆的纵向方向上弯曲的材料和/或类似物构成。在链条的弯曲部分中，当力施加到电缆和/或类似物时，支撑件在力的作用方向上弯曲或弯曲，以确保电缆的长度等，弯曲所需。

45. 发明授权

US06376055B1 Composition for ceramic substrate and ceramic circuit component 有权
公开(公告)号：US06376055B1
公开(公告)日：2002-04-23
申请号：US09550826
申请日：2000-04-18
申请人： Kazuo Kishida , Akira Shiratori , Osamu Yokokura , Hiroshi Takagi
发明人： Kazuo Kishida , Akira Shiratori , Osamu Yokokura , Hiroshi Takagi
IPC分类号： B32B300
CPC分类号： C04B35/111 , C03C8/14 , C03C14/004 , H01L23/15 , H01L2924/0002 , H01L2924/09701 , H05K1/0306 , Y10S428/901 , Y10T428/24917 , Y10T428/24926 , H01L2924/00
摘要： There is disclosed a composition for a ceramic substrate comprising a mixture of: powdered borosilicate-based glass comprising about 5% to 17.5% by weight of B2O3, about 28% to 44% by weight of SiO2, 0% to about 20% by weight of Al2O3, and about 36% to 50% by weight of MO (where MO is at least one selected from the group consisting of CaO, MgO, and BaO), and a powdered ceramic; in which the amount of the powdered borosilicate-based glass is about 40% to 49% by weight based on the total amount of the composition for a ceramic substrate, and the amount of the powdered ceramic is about 60% to 51% by weight based on the total amount of the composition for a ceramic substrate.

46. 发明授权

US06372676B1 Ceramic substrate composition and ceramic circuit component 有权
标题翻译：陶瓷基板组成和陶瓷电路元件
公开(公告)号：US06372676B1
公开(公告)日：2002-04-16
申请号：US09317500
申请日：1999-05-24
申请人： Kazuo Kishida , Hirofumi Sunahara , Mitsuyoshi Nishide , Hiroshi Takagi
发明人： Kazuo Kishida , Hirofumi Sunahara , Mitsuyoshi Nishide , Hiroshi Takagi
IPC分类号： C03C1004
CPC分类号： C04B35/16 , C03C14/004 , H05K1/0306 , H05K3/4629
摘要： A ceramic substrate composition includes about 26 to 48% by weight of a CaO—Al2O3—B2O3—SiO2 type glass, about 35 to 68% by weight of at least one of alumina, mullite, cordierite and forsterite, and about 3 to 24% by weight of quartz, said glass being capable of being crystallized to wollastonite by firing of the composition at a temperature of about 800 to 1000° C. A ceramic circuit component contains a circuit formed on the ceramic substrate obtained by firing the composition.
摘要翻译：陶瓷基材组合物包含约26至48重量％的CaO-Al 2 O 3 -B 2 O 3 -SiO 2型玻璃，约35至68重量％的氧化铝，莫来石，堇青石和镁橄榄石中的至少一种，和约3至24重量％的石英，所述玻璃能够通过在约800〜1000℃的温度下焙烧组合物而结晶成硅灰石。陶瓷电路部件包含通过焙烧组合物而获得的陶瓷基板上形成的电路。

47. 发明授权

US4912162A Thermoplastic resin compositions having excellent impact resistance, weather resistance and moldability, and process for preparing the same 失效
标题翻译：耐冲击性，耐候性和成型性优异的热塑性树脂组合物及其制备方法
公开(公告)号：US4912162A
公开(公告)日：1990-03-27
申请号：US10426
申请日：1987-02-03
申请人： Kazuo Kishida , Yutaka Toyooka , Haruyoshi Kitahara
发明人： Kazuo Kishida , Yutaka Toyooka , Haruyoshi Kitahara
IPC分类号： C08F285/00 , C08L51/00
CPC分类号： C08L51/00 , Y10S525/902
摘要： Disclosed is a graft copolymer resin prepared by graft polymerizing a vinyl compound onto a composite-structured acrylic rubber whose particles are composed of a core consisting of a diene rubber enlarged by treatment with an acid group-containing copolymer latex, and an outer layer consisting of an acrylate polymer having a crosslinked structure formed by the combined use of a graft-linking agent and a cross-linking agent. This graft copolymer resin may be blended with a rigid thermoplastic resin in a specific proportion. This resin composition imparts a good gloss to the molded articles formed therefrom, while retaining excellent impact resistance and weather resistance.
摘要翻译：公开了通过将乙烯基化合物接枝聚合到复合结构的丙烯酸橡胶上而制备的接枝共聚物树脂，该复合结构的丙烯酸橡胶的颗粒由通过用含酸基的共聚物胶乳处理而扩大的二烯橡胶组成的芯和由具有通过组合使用接枝交联剂和交联剂形成的交联结构的丙烯酸酯聚合物。该接枝共聚物树脂可以与特定比例的刚性热塑性树脂共混。该树脂组合物对由其形成的模塑制品赋予良好的光泽，同时保持优异的耐冲击性和耐候性。

48. 发明授权

US4804706A Process for the preparation of maleimide copolymers and thermoplastic resin composition using the same 失效
标题翻译：用于制备马来酰亚胺共聚物和使用其的热塑性树脂组合物的方法
公开(公告)号：US4804706A
公开(公告)日：1989-02-14
申请号：US25628
申请日：1987-03-02
申请人： Kazuo Kishida , Yutaka Toyooka , Atsushi Kimura
发明人： Kazuo Kishida , Yutaka Toyooka , Atsushi Kimura
IPC分类号： C08F212/04 , C08F222/40 , C08L25/02 , C08L51/04 , C08L77/00 , C08L51/00
CPC分类号： C08F222/40
摘要： The present invention provides a process for the preparation of maleimide copolymers by emulsion polymerization of an aromatic vinyl monomer, a vinyl cyanide monomer and a maleimide monomer in specific proportions wherein the polymerization is carried out by charging not less than a specific proportion of the aromatic vinyl monomer and optionally not more than a specific proportion of the vinyl cyanide monomer into the polymerization system before initiation of the polymerization; adding, continuously or dividedly, a mixture composed of the total amount of the maleimide monomer and the remainder of the other monomers to the polymerization system after initiation of the polymerization; maintaining the pH of the aqueous phase of the polymerization system in the range of 3 to 9 at the initiation of said polymerization; and using a redox catalyst containing an oil-soluble organic peroxide. According to this polymerization process, maleimide copolymers having excellent thermal resistance and resistance to thermal decomposition can be prepared in high yield.The present invention also provides a resin composition having excellent thermal resistance, resistance to thermal decomposition, and impact resistance which is formed by blending, in a specific proportion, a maleimide copolymer prepared by the aforesaid process with a rubber-reinforced resin obtained by grafting a vinyl cyanide monomer or the like onto a specific elastomer; and optionally blending the resulting thermoplastic resin composition with a thermoplastic resin that is hard at room temperature.
摘要翻译：本发明提供了一种通过芳香族乙烯基单体，乙烯基氰单体和马来酰亚胺单体以特定比例的乳液聚合制备马来酰亚胺共聚物的方法，其中聚合通过将不少于特定比例的芳族乙烯基单体，并且任选地不超过特定比例的乙烯基氰单体在聚合开始之前进入聚合体系; 在聚合开始后，向马来酰亚胺单体和剩余的其它单体组成的混合物连续地或分开地加入到聚合体系中; 在所述聚合开始时，将聚合体系的水相的pH保持在3〜9的范围内; 并使用含有油溶性有机过氧化物的氧化还原催化剂。根据该聚合方法，可以高产率制备具有优异的耐热性和耐热分解性的马来酰亚胺共聚物。本发明还提供一种具有优异的耐热性，耐热分解性和耐冲击性的树脂组合物，其通过以特定比例将通过上述方法制备的马来酰亚胺共聚物与通过将上述方法获得的橡胶增强树脂乙烯基氰单体等涂覆在特定的弹性体上; 任选地将得到的热塑性树脂组合物与在室温下硬的热塑性树脂共混。

49. 发明授权

US4435540A Novel polymer composition 失效
标题翻译：新型聚合物组成
公开(公告)号：US4435540A
公开(公告)日：1984-03-06
申请号：US336460
申请日：1981-12-31
申请人： Kazuo Kishida , Isao Sasaki , Nobuhiro Mukai
发明人： Kazuo Kishida , Isao Sasaki , Nobuhiro Mukai
IPC分类号： C08F2/44 , C08K3/04 , C08K3/00 , C08K3/08 , C08K3/26
CPC分类号： C08F2/44
摘要： A polymer composition wherein an inorganic substance and an organic polymer are firmly consolidated, which is characterized by being produced by polymerizing a vinyl monomer susceptible to radical polymerization in a polymerization system containing a dispersed inorganic substance in the presence of at least one monomer selected from sulfonic acid monomers, sulfonate monomers, or carboxylic acid monomers represented by the general formula [I] ##STR1## wherein R.sub.1 is a hydrogen atom, alkyl group having 1 to 20 carbon atoms, phenyl group, derivative of phenyl group, or halogen atom, X is CONH, ##STR2## COO(CH.sub.2).sub.m or (CH.sub.2).sub.n (wherein R.sub.2 and R.sub.3 are each a hydrogen atom or alkyl group having 1 to 15 carbon atoms, R.sub.4 is an alkylene group having 1 to 15 carbon atoms, m is an integer of 1 to 20, and n is an integer of 0 to 20), and Y is a hydrogen atom, ammonium radical, or an alkali metal atom, or by the general formula [II] ##STR3## wherein R.sub.5 is a hydrogen atom, alkyl group having 1 to 15 carbon atoms, COOZ, halogen atom, phenyl group, or derivative of phenyl group, R.sub.6 is a hydrogen atom, alkyl group having 1 to 15 carbon atoms, COOZ, halogen atom, phenyl group, or derivative of phenyl group, R.sub.7 is a hydrogen atom, alkyl group having 1 to 15 carbon atoms, halogen atom, phenyl group, or derivative of phenyl group, and Z is a hydrogen atom, ammonium radical, or alkali metal atom, or by the general formula [III] ##STR4## wherein R.sub.8 and R.sub.9 are each a hydrogen atom, alkyl group having 1 to 15 carbon atoms, halogen atom, phenyl group, or derivative of phenyl group.
摘要翻译：一种聚合物组合物，其中无机物质和有机聚合物被牢固地固化，其特征在于通过在含有分散的无机物质的聚合体系中聚合具有自由基聚合的乙烯基单体在至少一种选自以下的单体由通式[I]表示的酸单体，磺酸酯单体或羧酸单体其中R1是氢原子，具有1-20个碳原子的烷基，苯基，苯基衍生物或卤素原子，X为CONH，COO（CH 2）m或（CH 2）n（其中R 2和R 3各自为氢原子或具有1至15个碳原子的烷基，R 4为具有1至15个碳原子的亚烷基 m为1〜20的整数，n为0〜20的整数，Y为氢原子，铵基或碱金属原子，通式[II]表示。[II] ]其中R5是氢原子，具有1至1的烷基 5个碳原子，COOZ，卤素原子，苯基或苯基的衍生物，R6是氢原子，具有1至15个碳原子的烷基，COOZ，卤素原子，苯基或苯基的衍生物，R7是氢原子，碳原子数1〜15的烷基，卤素原子，苯基或苯基的衍生物，Z为氢原子，铵基或碱金属原子，或通式[III] [III]其中R8和R9各自为氢原子，具有1至15个碳原子的烷基，卤素原子，苯基或苯基的衍生物。

50. 发明授权

US4339474A Coating composition and process for preparing synthetic resin shaped articles by using same 失效
标题翻译：涂料组合物及其制备方法
公开(公告)号：US4339474A
公开(公告)日：1982-07-13
申请号：US239202
申请日：1981-03-03
申请人： Kazuo Kishida , Isao Sasaki , Kenji Kushi , Misao Tamura
发明人： Kazuo Kishida , Isao Sasaki , Kenji Kushi , Misao Tamura
IPC分类号： C08F2/48 , C09D4/06 , B05D3/06 , C08F8/00
CPC分类号： C09D4/06
摘要： A coating composition for the preparation of synthetic resin shaped articles excellent in abrasion resistance and weatherability is described. This composition comprises (a) a polyfunctional monomer composition comprising (i) 40-100 wt. % of a polyfunctional monomer containing at least three methacryloyloxy or acryloyloxy groups in the molecule and having a MW of not higher than about 900 and (ii) 0-60 wt. % of a mono- or bi-functional monomer having one or two methacryloyloxy or acryloyloxy groups in the molecule and having a MW of not higher than about 300 per methacryloyloxy or acryloyloxy group, (b) 5-35 parts by wt., based on 100 wt. parts of the monomer composition, of at least one ultraviolet absorber, (c) 0.5-8 wt. parts, based on 100 parts by wt. of the monomer composition, of at least one polymeric material selected from polymers of alkyl methacrylates and alkyl acrylates, and (d) 0.01-6 parts by wt., based on 100 parts by wt. of the monomer composition, of a photosensitizer. The coating composition is coated on a synthetic resin shaped article and then, irradiated with ultraviolet rays in an inert gas or air to form a crosslinked coating film having a thickness of 1 to 30 microns.
摘要翻译：描述了用于制备耐磨性和耐候性优异的合成树脂成型制品的涂料组合物。该组合物包含（a）多官能单体组合物，其包含（i）40-100wt。％的分子中含有至少三个甲基丙烯酰氧基或丙烯酰氧基并具有不高于约900的MW的多官能单体和（ii）0-60重量％％的分子中具有1个或2个甲基丙烯酰氧基或丙烯酰氧基的单功能或双官能单体，每个甲基丙烯酰氧基或丙烯酰氧基具有不高于约300的MW，（b）5-35重量份，基于 100重量单体组合物的部分，至少一种紫外线吸收剂，（c）0.5-8wt。部分，基于100重量份。至少一种选自甲基丙烯酸烷基酯和丙烯酸烷基酯的聚合物的聚合物材料，和（d）基于100重量份的重量比为0.01-6重量份。的单体组合物。将涂料组合物涂布在合成树脂成形制品上，然后在惰性气体或空气中用紫外线照射，形成厚度为1至30微米的交联涂膜。

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