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    • 9. 发明授权
    • Thermoplastic resin composition of a polycarbonate and vinyl
aromatic-vinyl cyanide comonomers/diene rubber graft copolymer
    • 聚碳酸酯和乙烯基芳族乙烯基氰化物共聚单体/二烯橡胶接枝共聚物的热塑性树脂组合物
    • US4665125A
    • 1987-05-12
    • US798431
    • 1985-11-15
    • Kazuo KishidaHiroshi KawasakiHideyuki Shigemitsu
    • Kazuo KishidaHiroshi KawasakiHideyuki Shigemitsu
    • C08L25/12C08L51/00C08L69/00
    • C08L51/00C08L25/12C08L69/00
    • A thermoplastic resin composition having excellent heat resistance, impact resistance, moldability and platability, which comprises:(i) from 10 to 90% by weight of a thermoplastic polycarbonate;(ii) from 10 to 90% by weight of a graft copolymer obtained by firstly polymerizing a monomer mixture comprising more than 30 and not more than 50% by weight of acrylonitrile and at least 50 and less than 70% by weight of styrene, as monomers for the first stage of graft polymerization, in the presence of a rubber-like polymer, and then polymerizing a monomer mixture comprising from 15 to 40% by weight of acrylonitrile and from 60 to 85% by weight of .alpha.-methylstyrene, as monomers for the second stage of graft polymerization, in the presence of the polymer obtained in the first stage; and(iii) from 0 to 60% by weight of a copolymer obtained by co-polymerizing from 50 to 80% by weight of an aromatic vinyl monomer and from 20 to 50% by weight of a vinyl cyanide monomer;the total amount of components (i), (ii) and (iii) being 100% by weight. The composition is useful for making molded products having excellent heat resistance, impact resistance and platability.
    • 具有优异的耐热性,耐冲击性,成型性和可镀性的热塑性树脂组合物,其包含:(i)10〜90重量%的热塑性聚碳酸酯; (ii)10至90重量%的接枝共聚物,其通过首先将包含大于30重量%至50重量%的丙烯腈和至少50重量%且小于70重量%的苯乙烯的单体混合物聚合而获得,其为 在第一阶段接枝聚合的单体中,在橡胶状聚合物的存在下,然后将包含15-40%(重量)丙烯腈和60-85%(重量)α-甲基苯乙烯的单体混合物聚合成单体 在第一阶段获得的聚合物存在下进行接枝聚合的第二阶段; 和(iii)0至60重量%的通过共聚合50-80重量%的芳族乙烯基单体和20至50重量%的乙烯基氰单体得到的共聚物; 组分(i),(ii)和(iii)的总量为100重量%。 该组合物可用于制备具有优异的耐热性,耐冲击性和可镀性的成型产品。
    • 10. 发明授权
    • Non-rigid vinyl chloride polymer resin composition
    • 非刚性氯乙烯聚合物树脂组合物
    • US4663382A
    • 1987-05-05
    • US795518
    • 1985-11-06
    • Kazuo KishidaKazuo UedaKiyokazu KitaiTsuruyoshi Matsumoto
    • Kazuo KishidaKazuo UedaKiyokazu KitaiTsuruyoshi Matsumoto
    • C08K5/00C08L1/00C08L7/00C08L21/00C08L23/00C08L27/00C08L27/06C08L33/00C08L33/02C08L51/00C08L51/02C08L51/06C08L67/00C08L101/00C08L13/00C08L51/04
    • C08K5/0016C08L27/06C08L51/003
    • Disclosed is a non-rigid vinyl chloride polymer composition comprising 100 weight parts of a vinyl chloride polymer resin, 5-50 weight parts of a graft copolymer modifier and 10-300 weight parts of a plasticizer. The graft copolymer modifier is obtained by graft-polymerizing 25-150 weight parts of an alkyl ester of methacrylic acid having 1 to 4 carbon atoms in the alkyl group or a monomer mixture composed of at least more than 50% by weight of said alkyl ester of methacrylic acid onto 100 weight parts of an acrylic elastomer having a swelling degree of 5 to 25 so that the grafting ratio is not larger than 50%. The acrylic elastomer is obtained by polymerizing a mixture comprising an alkyl ester of acrylic acid having 2 to 10 carbon atoms in the alkyl group or a monomer mixture composed of at least 50% by weight of said alkyl ester of acrylic acid, and a polyfunctional crosslinking agent. The non-rigid vinyl chloride polymer composition has excellent weatherability and impact resistance, and exhibits a good molding processability.
    • 公开了一种非刚性氯乙烯聚合物组合物,其包含100重量份的氯乙烯聚合物树脂,5-50重量份的接枝共聚物改性剂和10-300重量份的增塑剂。 接枝共聚物改性剂通过在烷基中接枝聚合25-150重量份的具有1至4个碳原子的甲基丙烯酸的烷基酯或由至少大于50重量%的所述烷基酯组成的单体混合物 的甲基丙烯酸加入到100重量份的溶胀度为5〜25的丙烯酸类弹性体中,使得接枝率不大于50%。 丙烯酸弹性体是通过在烷基中聚合含有2-10个碳原子的丙烯酸烷基酯的混合物或由至少50重量%的所述丙烯酸烷基酯组成的单体混合物和多官能交联 代理商 非刚性氯乙烯聚合物组合物具有优异的耐候性和耐冲击性,并且表现出良好的成型加工性。