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41. 发明授权

US5227481A Cationic polysaccharides and reagents for their preparation 失效
标题翻译：阳离子多糖及其制剂的试剂
公开(公告)号：US5227481A
公开(公告)日：1993-07-13
申请号：US683483
申请日：1991-04-09
申请人： John J. Tsai , Peter T. Trzasko , Michael T. Philbin , Robert L. Billmers , Martin M. Tessler , Joseph A. Van Gompel , Morton W. Rutenberg
发明人： John J. Tsai , Peter T. Trzasko , Michael T. Philbin , Robert L. Billmers , Martin M. Tessler , Joseph A. Van Gompel , Morton W. Rutenberg
IPC分类号： C08B11/145 , C08B31/12 , D21H17/24
CPC分类号： C08B11/145 , C08B31/125 , D21H17/24
摘要： Cationic polysaccharide derivatives are prepared by reacting a polysaccharide with a polycationic reagent having one polysaccharide reactive group and at least two cationic groups. Suitable reagents include polycationic alkyl, aryl, alkaryl, cycloaliphatic, or heterocyclic amines, some of which are novel compositions. The polycationic polysaccharide derivatives prepared from these reagents are useful in the manufacture of paper.
摘要翻译：阳离子多糖衍生物通过使多糖与具有一个多糖反应性基团和至少两个阳离子基团的聚阳离子试剂反应来制备。合适的试剂包括聚阳离子烷基，芳基，烷芳基，脂环族或杂环胺，其中一些是新的组合物。由这些试剂制备的聚阳离子多糖衍生物可用于纸的制造。

42. 发明授权

US4929670A Polysaccharides containing aromatic aldehydes and their derivatization via amine-aldehyde interactions 失效
标题翻译：含有芳香醛的多糖及其通过胺 - 醛相互作用的衍生化
公开(公告)号：US4929670A
公开(公告)日：1990-05-29
申请号：US338827
申请日：1989-04-14
申请人： Robert L. Billmers , David M. Del Giudice , Martin M. Tessler
发明人： Robert L. Billmers , David M. Del Giudice , Martin M. Tessler
IPC分类号： C03C25/26 , C08B11/08 , C08B31/04 , C08B31/12 , C08B37/00
CPC分类号： C08B31/125 , C03C25/26 , C08B11/08 , C08B31/04 , C08B37/0096 , Y10S530/813 , Y10S530/814
摘要： A polysaccharide derivative having the structure Sacch--O--Z--Ar--CH.dbd.N--Y or ##STR1## where Sacch--O-- represents a polysaccharide molecule; Z is --(CH.sub.2).sub.n -- or ##STR2## Ar is a divalent aromatic group; Y is (a) a monovalent group derived from a water-soluble substituted or unsubstituted aromatic compound containing only one free primary amine group, or (b) a monovalent group derived from a water-soluble substituted or unsubstituted aliphatic or cycloaliphatic compound containing only one primary amine group, or (c) a multivalent group derived from a water-soluble protein containing more than one primary amine group; n is one or greater; and m is zero or greater, is prepared by first modifying the polysaccharide with a reagent to introduce free aromatic aldehyde groups and then reacting with a suitable amine-containing reagent. The siloxane-containing starch derivatives are useful in glass forming size compositions.
摘要翻译：具有Sacch-O-Z-Ar-CH = N-Y或S IMA-O结构的多糖衍生物，其中Sacch-O-代表多糖分子; Z为 - （CH 2）n - 或Ar为二价芳基; Y是（a）衍生自仅含有一个游离伯胺基的水溶性取代或未取代的芳族化合物的单价基团，或（b）衍生自仅含有一个的水溶性取代或未取代的脂族或脂环族化合物的一价基团伯胺基，或（c）衍生自含有多于一个伯胺基的水溶性蛋白质的多价基团; n是一个或多个; 并且m为零或更大，通过首先用试剂修饰多糖以引入游离芳族醛基，然后与合适的含胺试剂反应来制备。含硅氧烷的淀粉衍生物可用于玻璃形成尺寸组合物。

43. 发明授权

US4788280A Polysaccharide derivatives containing aldehyde groups on an aromatic ring, their preparation from the corresponding acetals and use in paper 失效
标题翻译：在芳香环上含有醛基的多糖衍生物，由相应的缩醛制备并用于纸张中
公开(公告)号：US4788280A
公开(公告)日：1988-11-29
申请号：US93939
申请日：1987-09-08
申请人： Robert L. Billmers , Martin M. Tessler , David M. Del Giudice , Craig Leake
发明人： Robert L. Billmers , Martin M. Tessler , David M. Del Giudice , Craig Leake
IPC分类号： C08B11/08 , C08B11/04 , C08B31/12 , C08B37/00 , C08L1/00 , C08L1/02 , C08L3/00 , C08L3/04 , C08L5/00 , D21H17/24 , D21H21/18 , C08B31/02 , C08B31/08 , C08B37/14
CPC分类号： D21H17/24 , C08B11/04 , C08B31/12 , C08B37/0087 , D21H21/18
摘要： Polysaccharide aldehydes having the formula ##STR1## or Sacch--O--CH.sub.2 --Ar--CHO (II) such as starch, cellulose, and gum aldehydes, are useful as paper additives for imparting strength and as the granular or gelatinized portion of a corrugating adhesive. Those having formula I are prepared by a nonoxidative method which involves reacting the polysaccharide base, in the presence of alkali, with a derivatizing acetal reagent having the general structure ##STR2## and then hydrolyzing the acetal by adjusting the pH to less than 7, preferably 2-4. In the formula Ar is an aryl group, optionally containing an ether linkage, or an alkaryl group and A and A' are lower alkyls or together form at least a 5-membered cyclic acetal. The polysaccharide aldehydes are crosslinked by the addition of selected polyfunctional crosslinkers such as an aliphatic primary polyamine or polyketone.

44. 发明授权

US4703116A Polysaccharide derivatives containing aldehyde groups, their preparation from the corresponding acetals and use as paper additives 失效
标题翻译：含有醛基的多糖衍生物，由相应的缩醛制成，用作纸添加剂
公开(公告)号：US4703116A
公开(公告)日：1987-10-27
申请号：US829675
申请日：1986-02-14
申请人： Daniel B. Solarek , Patrick G. Jobe , Martin M. Tessler , Robert L. Billmers , Diane J. Lamb , John J. Tsai
发明人： Daniel B. Solarek , Patrick G. Jobe , Martin M. Tessler , Robert L. Billmers , Diane J. Lamb , John J. Tsai
IPC分类号： C07H15/04 , C07H15/12 , C08B11/04 , C08B11/08 , C08B11/14 , C08B31/12 , C08B37/00 , C08B37/14 , D21H17/24 , D21H17/25 , D21H17/28 , D21H17/31 , C08B31/02 , C08B31/08
CPC分类号： C08B11/14 , C08B11/04 , C08B31/12 , C08B31/125 , C08B37/0096 , D21H17/24 , D21H17/25 , D21H17/28 , D21H17/31
摘要： Polysaccharide aldehydes having the formula Sacch--O--CH.sub.2 --CH.dbd.CH--CHO, ##STR1## such as starch, cellulose, and gum aldehydes, are useful for imparting wet, dry, or temporary wet strength to paper. They are prepared by a non-oxidative method which involves reacting the polysaccharide base, in the presence of alkali, with a derivatizing acetal reagent having the general structure ##STR2## and then hydrolyzing the acetal by adjusting the pH to less than 7, preferably 2-4. In the formulas, n is 1-3; R.sup.11 and R.sup.12 are independently an alkyl, aryl, aralkyl, or alkaryl group when n is 1, R.sup.11 or R.sup.12 is one of the groups when n is 2, or R.sup.11 and R.sup.12 are not present when n is 3; R.sup.13 is an alkyl group, optionally containing an ether linkage, or an aralkyl group; R.sup.14 and R.sup.15 are individually a hydrogen or a methyl group; R.sup.16, R.sup.17, and R.sup.18 are individually an alkyl group; Y- is an anion; Z is an organic group capable of reacting with the polysaccharide base to form an ether derivative and selected from the group consisting of an epoxide, ethylenically unsaturated group, halohydrin, and halogen; R.sup.19, if present, is a divalent organic group containing no reactive substituents; and A and A'0 are lower alkyls or together form at least a 5-membered cyclic acetal.
摘要翻译：具有式Sacch-O-CH2-CH = CH-CHO，SaachOCH2CCCHO，图像，图像，图像，如淀粉，纤维素和醛醛的多糖醛是可用于赋予纸张湿，干或临时湿强度。它们通过非氧化方法制备，其包括在碱存在下使多糖碱与具有一般结构“IMAGE”的衍生化缩醛试剂反应，然后通过将pH调节至小于7，优选2来水解缩醛 -4。在式中，n为1-3; 当n为1时，R11和R12独立地为烷基，芳基，芳烷基或烷芳基，当n为2时，R11或R12为基团之一，当n为3时，R11和R12不存在; R13是任选含有醚键或芳烷基的烷基; R 14和R 15分别为氢或甲基; R16，R17和R18各自为烷基; Y-是阴离子; Z是能够与多糖基反应形成醚衍生物并选自环氧化物，烯属不饱和基，卤代醇和卤素的有机基团; R19如果存在，是不含反应性取代基的二价有机基团; A和A'0是低级烷基或一起形成至少5元环缩醛。

45. 发明授权

US4673707A Synthetic polymers with glycoside side chains 失效
标题翻译：具有糖苷侧链的合成聚合物
公开(公告)号：US4673707A
公开(公告)日：1987-06-16
申请号：US814131
申请日：1985-12-27
申请人： John J. Tsai , Martin M. Tessler
发明人： John J. Tsai , Martin M. Tessler
IPC分类号： C07H15/26 , C08F8/00 , C08H1/00 , C07H15/02
CPC分类号： C08F8/00 , C07H15/26 , C08H1/00
摘要： Derivatized polymers containing glycoside side chains linked to the polymer by ether, sulfide, or amine linkages are prepared by reacting a polymer containing alcohol, thiol, and/or amine groups with a glycidyl glycoside having the formula ##STR1## where (SAC).sub.n represents a saccharide residue with n being 1-20. Typical polymers include poly(vinyl) alcohol, poly(ethyleneimine), poly(dimethylaminopropyl methacrylamide), and proteins such as caseinate or gluten. Typical glycosides are glycoside of glucose and maltodextrin-10.
摘要翻译：通过使含有醇，硫醇和/或胺基团的聚合物与具有式（IMAGE）的缩水甘油基糖苷反应，其中（SAC）n表示（SAC）n表示，含有通过醚，硫醚或胺键与聚合物连接的糖苷侧链的衍生化聚合物 n为1-20的糖残基。典型的聚合物包括聚（乙烯基）醇，聚（乙烯亚胺），聚（二甲基氨基丙基甲基丙烯酰胺）和蛋白质如酪蛋白酸盐或面筋。典型的糖苷是葡萄糖和麦芽糖糊精-10的糖苷。

46. 发明授权

US4438047A Process for the preparation of an aqueous 3-chloro-2-sulfopropionic acid reagent 失效
标题翻译：制备3-氯-2-磺基丙酸水溶液的方法
公开(公告)号：US4438047A
公开(公告)日：1984-03-20
申请号：US306129
申请日：1981-09-28
申请人： Martin M. Tessler , Dennis V. Neigel
发明人： Martin M. Tessler , Dennis V. Neigel
IPC分类号： C07C20060101 , C07C309/06 , C07C143/02
CPC分类号： C07C309/00
摘要： An improved and novel process for the preparation of an aqueous 3-chloro-2-sulfopropionic acid reagent involves the formation of a reaction mixture by adding acrylic acid to chlorosulfonic acid maintained at about 45.degree. to 130.degree. C., maintaining the mixture at about 60.degree.-130.degree. C. for about 2-6 hours, and adding sufficient water to the resulting anhydrous reagent to decompose the unreacted chlorosulfonic acid and dilute the reagent to a solids content of about 50-95%, preferably 70-90%. The reagent may be vacuum stripped to remove residual hydrochloric acid. Crystalline 3-chloro-2-sulfopropionic acid may be isolated from the aqueous reagent at a solids content above 80% and below 95%, preferably at 85%.
摘要翻译：用于制备3-氯-2-磺基丙酸水溶液的改进和新颖的方法涉及通过将丙烯酸加入保持在约45℃至130℃的氯磺酸形成反应混合物，将混合物保持在约 60°-130℃下搅拌约2-6小时，向所得无水试剂中加入足够的水分解未反应的氯磺酸，并将试剂稀释至约50-95％，优选70-90％的固体含量。可以将试剂真空汽提以除去残留的盐酸。可以以高于80％且低于95％，优选85％的固体含量从水性试剂中分离出结晶的3-氯-2-磺基丙酸。

47. 发明授权

US4379919A Starch sulfomaleate half-esters, a method for their preparation and their use to prepare starch disulfosuccinate half-esters 失效
标题翻译：淀粉磺基马来酸酯半酯，其制备方法及其用于制备淀粉二磺基琥珀酸酯半酯
公开(公告)号：US4379919A
公开(公告)日：1983-04-12
申请号：US364376
申请日：1982-04-01
申请人： Martin M. Tessler , Otto B. Wurzburg , Teresa A. Dirscherl
发明人： Martin M. Tessler , Otto B. Wurzburg , Teresa A. Dirscherl
IPC分类号： C08B31/04 , C08B31/16
CPC分类号： C08B31/04
摘要： Novel starch sulfomaleate half-esters are prepared by reacting a starch base or a modified starch containing anionic, cationic, and/or nonionic substituent groups with about 0.1 to 100% by weight of sulfomaleic anhydride or its salts. The reaction is carried out at pH 5-9 and at 5.degree.-90.degree. C. for 0.5-20 hours or at pH 9-11 and at 5.degree.-30.degree. C. for about 0.5-3 hours. The starch sulfomaleates may be reacted with sulfurous acid or its acid salts (e.g. sodium bisulfite) to form the novel starch disulfosuccinate.
摘要翻译：通过使含有阴离子，阳离子和/或非离子取代基的淀粉基或改性淀粉与约0.1至100重量％的磺基马来酸酐或其盐反应来制备新型磺基马来酸淀粉半酯。反应在pH 5-9和5°-90℃进行0.5-20小时，或在pH9-11和5-30℃进行约0.5-3小时。淀粉磺基马来酸盐可以与亚硫酸或其酸式盐（例如亚硫酸氢钠）反应形成新的淀粉二磺基琥珀酸盐。

48. 发明授权

US4276414A Novel zwitterion polygalactomannan ether derivatives and a method for the preparation thereof 失效
标题翻译：新型两性离子聚半乳甘露聚糖醚衍生物及其制备方法
公开(公告)号：US4276414A
公开(公告)日：1981-06-30
申请号：US189397
申请日：1980-09-22
申请人： Martin M. Tessler
发明人： Martin M. Tessler
IPC分类号： C08B37/14 , C08B37/00 , C07G17/00
CPC分类号： C08L5/00
摘要： Zwitterion polygalactomannan ether derivatives are prepared by reacting a polygalactomannan gum, such as guar gum or locust bean gum, with N-(2-haloethyl)iminobis(methylene)diphosphonic acid or with a N-(alkyl)-N-(2-haloethyl)aminomethylphosphonic acid. The derivatives contain aminophosphonic acid groups (or their salts) as zwitterion substituents which consist of either one or two anionic methylene phosphonic acid groups bound to a cationic nitrogen. Modified derivatives containing non-ionic, anionic, cationic, or cationogenic substituents may also be prepared.
摘要翻译：两性离子聚半乳甘露聚糖醚衍生物通过使聚半乳甘露聚糖胶如瓜耳胶或刺槐豆胶与N-（2-卤代乙基）亚氨基双（亚甲基）二膦酸或与N-（烷基）-N-（2-卤乙基）氨基甲基膦酸。衍生物含有作为两性离子取代基的氨基膦酸基团（或它们的盐），其由与阳离子氮结合的一个或两个阴离子亚甲基膦酸基团组成。还可以制备含有非离子，阴离子，阳离子或阳离子生成取代基的修饰衍生物。

49. 发明授权

US4260738A Novel starch ether derivatives, a method for the preparation thereof 失效
标题翻译：新型淀粉醚衍生物，其制备方法
公开(公告)号：US4260738A
公开(公告)日：1981-04-07
申请号：US110926
申请日：1980-01-10
申请人： Martin M. Tessler
发明人： Martin M. Tessler
IPC分类号： C08B31/08 , C08B31/12 , D21H17/28 , C08B31/10 , C08B31/14 , D21H3/28
CPC分类号： D21H17/28 , C08B31/08 , C08B31/125
摘要： Starch ether derivatives are prepared by reacting a starch base with N-(2-haloethyl)iminobis(methylene)diphosphonic acid or with a N-(alkyl)-N-(2-haloethyl)aminomethylphosphonic acid. The derivatives contain aminophosphonic acid groups (or their salts) as zwitterion substituents which consist of either one or two anionic methylene phosphonic acid groups bound to a cationic nitrogen. Their cationic or anionic characteristics may be increased by introducing suitable cationic or anionic groups either by simultaneous reaction with the aminophosphonic acid reagent or by consecutive reaction either prior to or subsequent to the aminophosphonic acid reaction. They are especially useful as pigment retention aids in paper making processes.
摘要翻译：淀粉醚衍生物通过使淀粉碱与N-（2-卤代乙基）亚氨基双（亚甲基）二膦酸或N-（烷基）-N-（2-卤代乙基）氨基甲基膦酸反应来制备。衍生物含有作为两性离子取代基的氨基膦酸基团（或它们的盐），其由与阳离子氮结合的一个或两个阴离子亚甲基膦酸基团组成。通过与氨基膦酸试剂同时反应或在氨基膦酸反应之前或之后通过连续反应引入合适的阳离子或阴离子基团，它们的阳离子或阴离子特征可以增加。它们在造纸过程中特别适用于颜料助留剂。

50. 发明授权

US4167621A Method for preparing starch ether derivatives 失效
标题翻译：淀粉醚衍生物的制备方法
公开(公告)号：US4167621A
公开(公告)日：1979-09-11
申请号：US918709
申请日：1978-06-26
申请人： Martin M. Tessler
发明人： Martin M. Tessler
IPC分类号： C08B31/08 , C08B31/12 , C08B31/16 , C08B33/06
CPC分类号： C08B31/12
摘要： Starch ether derivatives are prepared by reacting a starch base with about 0.5-100% by weight of a neutralized alkyl ester of 3-chloro-2-sulfopropionic acid, based on dry starch, and then isolating the resultant starch derivative. The 2-sulfo-2-carboxyethyl starch ethers thus prepared may be utilized in many applications, and are particularly useful as wet-end additives in paper manufacturing at low pH.
摘要翻译：淀粉醚衍生物通过使淀粉碱与约0.5-100重量％的中和的3-氯-2-磺基丙酸烷基酯（基于干淀粉）反应制备，然后分离得到的淀粉衍生物。如此制备的2-磺基-2-羧乙基淀粉醚可用于许多应用，并且在低pH下在纸制造中特别适用于湿端添加剂。

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