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1. 发明授权

US4983748A Acetals useful for the preparation of polysaccharide derivatives 失效
标题翻译：用于制备多糖衍生物的缩醛
公开(公告)号：US4983748A
公开(公告)日：1991-01-08
申请号：US290934
申请日：1988-12-28
申请人： John J. Tsai , Patrick G. Jobe , Diane J. Lamb , Robert L. Billmrs , Martin M. Tessler
发明人： John J. Tsai , Patrick G. Jobe , Diane J. Lamb , Robert L. Billmrs , Martin M. Tessler
IPC分类号： C08B11/14 , C08B31/12 , C08B37/14 , D21H17/25 , D21H17/28 , D21H17/31
CPC分类号： C08B11/14 , C08B31/12 , D21H17/25 , D21H17/28 , D21H17/31
摘要： Polysaccharide aldehydes having the formula Sacch--O--CH.sub.2 --CH.dbd.CH--CHO, Saach--O--CH.sub.2 --C.tbd.C--CHO, ##STR1## starch, cellulose, and gum aldehydes, are useful for imparting wet, dry, or temporary wet strength to paper. They are prepared by a non-oxidative method which involves reacting the polysaccharide base, in the presence of alkali, with a derivatizing acetal reagent having the general structure ##STR2## and then hydrolyzing the acetal by adjusting the pH to less than 7, preferably 2-4. In the formulas, n is 1-3; R.sup.11 and R.sup.12 are independently an alkyl, aryl, aralkyl, or alkaryl group when n is 1, R.sup.11 or R.sup.12 is one of the groups when n is 2, or R.sup.11 and R.sup.12 are not present when n is 3; R.sup.13 is an alkyl group, optionally containing an ether linkage, or an aralkyl group; R.sup.14 and R.sup.15 are individually a hydrogen or a methyl group; R.sup.16, R.sup.17, and R.sup.18 are individually an alkyl group; Y.sup.- is an anion; Z is an organic group capable of reacting with the polysaccharide base to form an ether derivative and selected from the group consisting of an epoxide, ethylenically unsaturated group, halohydrin, and halogen; R.sup.19, if present, is a divalent organic group containing no reactive substiuents; and A and A' are lower alkyls or together form at least a 5-membered cyclic acetal.
摘要翻译：具有式Sacch-O-CH2-CH = CH-CHO，Saach-O-CH2-C 3BOND C-CHO的多糖醛，图像＆gt;＆lt; IMAGE＆gt;＆lt; IMAGE＆gt;＆gt;淀粉，纤维素和醛醛可用于赋予纸张湿，干或临时湿强度。它们通过非氧化方法制备，其包括在碱存在下使多糖碱与具有一般结构“IMAGE”的衍生化缩醛试剂反应，然后通过将pH调节至小于7，优选2来水解缩醛 -4。在式中，n为1-3; 当n为1时，R11和R12独立地为烷基，芳基，芳烷基或烷芳基，当n为2时，R11或R12为基团之一，当n为3时，R11和R12不存在; R13是任选含有醚键或芳烷基的烷基; R 14和R 15分别为氢或甲基; R16，R17和R18各自为烷基; Y-是阴离子; Z是能够与多糖基反应形成醚衍生物并选自环氧化物，烯属不饱和基，卤代醇和卤素的有机基团; R19如果存在，是不含反应性残基的二价有机基团; 并且A和A'是低级烷基或一起形成至少5元环缩醛。

2. 发明授权

US4719272A Monomeric cationic glycoside derivatives 失效
标题翻译：单体阳离子糖苷衍生物
公开(公告)号：US4719272A
公开(公告)日：1988-01-12
申请号：US11170
申请日：1987-02-05
申请人： John J. Tsai , Martin M. Tessler
发明人： John J. Tsai , Martin M. Tessler
IPC分类号： C07H15/04 , D21H17/24 , C08F10/00
CPC分类号： C07H15/04 , D21H17/24
摘要： Novel cationic unsaturated mono- and polysaccharide glycoside derivatives are prepared by reacting glycidyl, halohydrin or haloalkyl glycosides (e.g. 3-chloro-2-hydroxypropyl glucoglycoside) with unsaturated amines (e.g. N,N-dimethylaminopropyl methacrylamide). The novel monomers may be homo- or copolymerized in order to prepare novel cationic polymers with pendant saccharide side chains. The monomers may also be used in the preparation of cationic polysaccharide graft copolymers.
摘要翻译：通过使缩水甘油基，卤代醇或卤代烷基糖苷（例如3-氯-2-羟丙基糖苷）与不饱和胺（例如N，N-二甲基氨基丙基甲基丙烯酰胺）反应来制备新的阳离子不饱和单糖苷和多糖糖苷衍生物。新单体可以均聚或共聚以制备具有侧链侧链的新型阳离子聚合物。单体也可用于制备阳离子多糖接枝共聚物。

3. 发明授权

US4831128A Synthetic homo- and heteropolysaccharides and a method for the preparation thereof 失效
标题翻译：合成均聚和杂多糖及其制备方法
公开(公告)号：US4831128A
公开(公告)日：1989-05-16
申请号：US882130
申请日：1986-07-03
申请人： John J. Tsai , Martin M. Tessler
发明人： John J. Tsai , Martin M. Tessler
IPC分类号： C07H15/04 , C08B31/08 , C08B31/12 , C08B37/00
CPC分类号： C07H15/04 , C08B31/08 , C08B31/12 , C08B37/0096
摘要： Mono- and polysaccharides comprising one to about 20 saccharide units which also contain a reducing carbon atom are reacted with 3-halo-1,2-propandiol in the presence of a cation exchange resin to form 3-halo-2-hydroxypropyl glycosides or glycidyl glycosides. These glycosides react with natural polysaccharides such as starch and plant gums to form novel synthetic homo- and heteropolysaccharides with pendant saccharide side chains.
摘要翻译：在阳离子交换树脂存在下，将含有还原性碳原子的1〜约20个糖单元的单糖和多糖与3-卤代-1,2-丙二醇反应，形成3-卤代-2-羟丙基糖苷或缩水甘油基糖苷。这些糖苷与天然多糖例如淀粉和植物树胶反应形成具有侧链侧链的新的合成的均聚和杂多糖。

4. 发明授权

US4741804A Polysaccharide derivatives containing aldehyde groups, their preparation from the corresponding acetals and use as paper additives 失效
标题翻译：含有醛基的多糖衍生物，由相应的缩醛制成，用作纸添加剂
公开(公告)号：US4741804A
公开(公告)日：1988-05-03
申请号：US34133
申请日：1987-04-03
申请人： Daniel B. Solarek , Patrick G. Jobe , Martin M. Tessler , Robert L. Billmers , Diane J. Lamb , John J. Tsai
发明人： Daniel B. Solarek , Patrick G. Jobe , Martin M. Tessler , Robert L. Billmers , Diane J. Lamb , John J. Tsai
IPC分类号： C08B11/04 , C08B11/14 , C08B31/12 , C08B37/14 , D21H17/25 , D21H17/28 , D21H17/31 , D21H3/20
CPC分类号： C08B11/14 , C08B11/04 , C08B31/12 , C08B31/125 , C08B37/0087 , C08B37/0093 , C08B37/0096 , D21H17/25 , D21H17/28 , D21H17/31
摘要： Polysaccharide aldehydes having the formula ##STR1## starch, cellulose, and gum aldehydes, are useful for imparting wet, dry, or temporary wet strength to paper. They are prepared by a non-oxidative method which involves reacting the polysaccharide base, in the presence of alkali, with a derivatizing acetal reagent having the general structure ##STR2## and then hydrolyzing the acetal by adjusting the pH to less than 7, preferably 2-4. In the formula, n is 1-3; R.sup.11 and R.sup.12 are independently an alkyl, aryl, aralkyl, or alkaryl group when n is 1, R.sup.11 or R.sup.12 is one of the groups when n is 2, or R.sup.11 and R.sup.12 are not present when n is 3; R.sup.13 is an alkyl group, optionally containing an ether linkage, or an aryl, aralkyl, or alkaryl group; R.sup.14 and R.sup.15 are individually a hydrogen or a methyl group; R.sup.16, R.sup.17, and R.sup.18 are individually an alkyl group; Y.sup.- is an anion; Z is an organic group capable of reacting with the polysaccharide base to form an ether derivative and selected from the group consisting of an epoxide, ethylenically unsaturated group, halohydrin, and halogen; R.sup.19, if present, is a divalent organic group containing no reactive substituents; and A and A' are lower alkyls or together form at least a 5-membered cyclic acetal.
摘要翻译：具有式Sacch-OCH2CHCHCHO，Sacch-OCH2CCCHO，淀粉，纤维素和树胶醛的多糖醛可用于赋予湿，干或临时潮湿强度纸。它们通过非氧化方法制备，其包括在碱存在下使多糖碱与具有一般结构“IMAGE”的衍生化缩醛试剂反应，然后通过将pH调节至小于7，优选2来水解缩醛 -4。在该式中，n为1-3; 当n为1时，R11和R12独立地为烷基，芳基，芳烷基或烷芳基，当n为2时，R11或R12为基团之一，当n为3时，R11和R12不存在; R13是任选含有醚键的烷基，或芳基，芳烷基或烷芳基; R 14和R 15分别为氢或甲基; R16，R17和R18各自为烷基; Y-是阴离子; Z是能够与多糖基反应形成醚衍生物并选自环氧化物，烯属不饱和基，卤代醇和卤素的有机基团; R19如果存在，是不含反应性取代基的二价有机基团; 并且A和A'是低级烷基或一起形成至少5元环缩醛。

5. 发明授权

US4804769A Acetals useful for the preparation of polysaccharide derivatives 失效
标题翻译：用于制备多糖衍生物的缩醛
公开(公告)号：US4804769A
公开(公告)日：1989-02-14
申请号：US037282
申请日：1987-04-10
申请人： Daniel B. Solarek , Patrick G. Jobe , Martin M. Tessler , Robert L. Billmers , Diane J. Lamb , John J. Tsai
发明人： Daniel B. Solarek , Patrick G. Jobe , Martin M. Tessler , Robert L. Billmers , Diane J. Lamb , John J. Tsai
IPC分类号： C07H15/04 , C07H15/12 , C08B11/04 , C08B11/08 , C08B11/14 , C08B31/12 , C08B37/00 , C08B37/14 , D21H17/24 , D21H17/25 , D21H17/28 , D21H17/31 , C07D319/06
CPC分类号： C08B11/14 , C08B11/04 , C08B31/12 , C08B31/125 , C08B37/0096 , D21H17/24 , D21H17/25 , D21H17/28 , D21H17/31
摘要： Polysaccharide aldehydes having the formula Sacch-O-CH.sub.2 -CH.dbd.CH-CHO, Sacch-O-CH.sub.2 -C.tbd.C-CHO, ##STR1## such as starch, cellulose, and gum aldehydes, are useful for imparting wet, dry, or temporary wet strength to paper. They are prepared by a non-oxidative method which involves reacting the polysaccharide base, in the presence of alkali, with a derivatizing acetal reagent having the general structure ##STR2## and then hydrolyzing the acetal by adjusting the pH to less than 7, preferably 2-4. In the formulas, n is 1-3; R.sup.11 and R.sup.12 are independently an alkyl, aryl, aralkyl, or alkaryl group when n is 1, R.sup.11 or R.sup.12 is one of the groups when n is 2, or R.sup.11 and R.sup.12 are not present when n is 3; R.sup.13 is an alkyl group, optionally containing an ether linkage, or an aralkyl group; R.sup.14 and R.sup.15 are individually a hydrogen or a methyl group; R.sup.16, R.sup.17, and R.sup.18 are individually an alkyl group; Y.sup.- is an anion; Z is an organic group capable of reacting with the polysaccharide base to form an ether derivative and selected from the group consisting of an epoxide, ethylenically unsaturated group, halohydrin, and halogen; R.sup.19, if present, is a divalent organic group containing no reactive substiuents; and A and A' are lower alkyls or together form at least a 5-membered cyclic acetal.
摘要翻译：具有式Sacch -O-CH 2 -CH = CH-CHO，Sacch -O-CH 2 -C 3OND C-CHO，图像＆gt;＆lt; IMAGE＆gt;＆lt; IMAGE＆gt;和+ TR＆lt; IMAGE＆gt;的多糖醛例如淀粉，纤维素和醛醛可用于赋予纸张湿，干或临时湿强度。它们通过非氧化方法制备，其包括在碱存在下使多糖碱与具有一般结构“IMAGE”的衍生化缩醛试剂反应，然后通过将pH调节至小于7，优选2来水解缩醛 -4。在式中，n为1-3; 当n为1时，R11和R12独立地为烷基，芳基，芳烷基或烷芳基，当n为2时，R11或R12为基团之一，当n为3时，R11和R12不存在; R13是任选含有醚键或芳烷基的烷基; R 14和R 15分别为氢或甲基; R16，R17和R18各自为烷基; Y-是阴离子; Z是能够与多糖基反应形成醚衍生物并选自环氧化物，烯属不饱和基，卤代醇和卤素的有机基团; R19如果存在，是不含反应性残基的二价有机基团; 并且A和A'是低级烷基或一起形成至少5元环缩醛。

6. 发明授权

US5227481A Cationic polysaccharides and reagents for their preparation 失效
标题翻译：阳离子多糖及其制剂的试剂
公开(公告)号：US5227481A
公开(公告)日：1993-07-13
申请号：US683483
申请日：1991-04-09
申请人： John J. Tsai , Peter T. Trzasko , Michael T. Philbin , Robert L. Billmers , Martin M. Tessler , Joseph A. Van Gompel , Morton W. Rutenberg
发明人： John J. Tsai , Peter T. Trzasko , Michael T. Philbin , Robert L. Billmers , Martin M. Tessler , Joseph A. Van Gompel , Morton W. Rutenberg
IPC分类号： C08B11/145 , C08B31/12 , D21H17/24
CPC分类号： C08B11/145 , C08B31/125 , D21H17/24
摘要： Cationic polysaccharide derivatives are prepared by reacting a polysaccharide with a polycationic reagent having one polysaccharide reactive group and at least two cationic groups. Suitable reagents include polycationic alkyl, aryl, alkaryl, cycloaliphatic, or heterocyclic amines, some of which are novel compositions. The polycationic polysaccharide derivatives prepared from these reagents are useful in the manufacture of paper.
摘要翻译：阳离子多糖衍生物通过使多糖与具有一个多糖反应性基团和至少两个阳离子基团的聚阳离子试剂反应来制备。合适的试剂包括聚阳离子烷基，芳基，烷芳基，脂环族或杂环胺，其中一些是新的组合物。由这些试剂制备的聚阳离子多糖衍生物可用于纸的制造。

7. 发明授权

US4703116A Polysaccharide derivatives containing aldehyde groups, their preparation from the corresponding acetals and use as paper additives 失效
标题翻译：含有醛基的多糖衍生物，由相应的缩醛制成，用作纸添加剂
公开(公告)号：US4703116A
公开(公告)日：1987-10-27
申请号：US829675
申请日：1986-02-14
申请人： Daniel B. Solarek , Patrick G. Jobe , Martin M. Tessler , Robert L. Billmers , Diane J. Lamb , John J. Tsai
发明人： Daniel B. Solarek , Patrick G. Jobe , Martin M. Tessler , Robert L. Billmers , Diane J. Lamb , John J. Tsai
IPC分类号： C07H15/04 , C07H15/12 , C08B11/04 , C08B11/08 , C08B11/14 , C08B31/12 , C08B37/00 , C08B37/14 , D21H17/24 , D21H17/25 , D21H17/28 , D21H17/31 , C08B31/02 , C08B31/08
CPC分类号： C08B11/14 , C08B11/04 , C08B31/12 , C08B31/125 , C08B37/0096 , D21H17/24 , D21H17/25 , D21H17/28 , D21H17/31
摘要： Polysaccharide aldehydes having the formula Sacch--O--CH.sub.2 --CH.dbd.CH--CHO, ##STR1## such as starch, cellulose, and gum aldehydes, are useful for imparting wet, dry, or temporary wet strength to paper. They are prepared by a non-oxidative method which involves reacting the polysaccharide base, in the presence of alkali, with a derivatizing acetal reagent having the general structure ##STR2## and then hydrolyzing the acetal by adjusting the pH to less than 7, preferably 2-4. In the formulas, n is 1-3; R.sup.11 and R.sup.12 are independently an alkyl, aryl, aralkyl, or alkaryl group when n is 1, R.sup.11 or R.sup.12 is one of the groups when n is 2, or R.sup.11 and R.sup.12 are not present when n is 3; R.sup.13 is an alkyl group, optionally containing an ether linkage, or an aralkyl group; R.sup.14 and R.sup.15 are individually a hydrogen or a methyl group; R.sup.16, R.sup.17, and R.sup.18 are individually an alkyl group; Y- is an anion; Z is an organic group capable of reacting with the polysaccharide base to form an ether derivative and selected from the group consisting of an epoxide, ethylenically unsaturated group, halohydrin, and halogen; R.sup.19, if present, is a divalent organic group containing no reactive substituents; and A and A'0 are lower alkyls or together form at least a 5-membered cyclic acetal.
摘要翻译：具有式Sacch-O-CH2-CH = CH-CHO，SaachOCH2CCCHO，图像，图像，图像，如淀粉，纤维素和醛醛的多糖醛是可用于赋予纸张湿，干或临时湿强度。它们通过非氧化方法制备，其包括在碱存在下使多糖碱与具有一般结构“IMAGE”的衍生化缩醛试剂反应，然后通过将pH调节至小于7，优选2来水解缩醛 -4。在式中，n为1-3; 当n为1时，R11和R12独立地为烷基，芳基，芳烷基或烷芳基，当n为2时，R11或R12为基团之一，当n为3时，R11和R12不存在; R13是任选含有醚键或芳烷基的烷基; R 14和R 15分别为氢或甲基; R16，R17和R18各自为烷基; Y-是阴离子; Z是能够与多糖基反应形成醚衍生物并选自环氧化物，烯属不饱和基，卤代醇和卤素的有机基团; R19如果存在，是不含反应性取代基的二价有机基团; A和A'0是低级烷基或一起形成至少5元环缩醛。

8. 发明授权

US4673707A Synthetic polymers with glycoside side chains 失效
标题翻译：具有糖苷侧链的合成聚合物
公开(公告)号：US4673707A
公开(公告)日：1987-06-16
申请号：US814131
申请日：1985-12-27
申请人： John J. Tsai , Martin M. Tessler
发明人： John J. Tsai , Martin M. Tessler
IPC分类号： C07H15/26 , C08F8/00 , C08H1/00 , C07H15/02
CPC分类号： C08F8/00 , C07H15/26 , C08H1/00
摘要： Derivatized polymers containing glycoside side chains linked to the polymer by ether, sulfide, or amine linkages are prepared by reacting a polymer containing alcohol, thiol, and/or amine groups with a glycidyl glycoside having the formula ##STR1## where (SAC).sub.n represents a saccharide residue with n being 1-20. Typical polymers include poly(vinyl) alcohol, poly(ethyleneimine), poly(dimethylaminopropyl methacrylamide), and proteins such as caseinate or gluten. Typical glycosides are glycoside of glucose and maltodextrin-10.
摘要翻译：通过使含有醇，硫醇和/或胺基团的聚合物与具有式（IMAGE）的缩水甘油基糖苷反应，其中（SAC）n表示（SAC）n表示，含有通过醚，硫醚或胺键与聚合物连接的糖苷侧链的衍生化聚合物 n为1-20的糖残基。典型的聚合物包括聚（乙烯基）醇，聚（乙烯亚胺），聚（二甲基氨基丙基甲基丙烯酰胺）和蛋白质如酪蛋白酸盐或面筋。典型的糖苷是葡萄糖和麦芽糖糊精-10的糖苷。

9. 发明授权

US5466862A Low molecular weight polyacetals and polyaldehydes 失效
标题翻译：低分子量聚缩醛和多醛
公开(公告)号：US5466862A
公开(公告)日：1995-11-14
申请号：US310451
申请日：1994-09-22
申请人： Gary T. Martino , Martin M. Tessler
发明人： Gary T. Martino , Martin M. Tessler
IPC分类号： C07C235/08 , C07C237/08 , C07C37/00
CPC分类号： C07C237/08 , C07C235/08
摘要： Low molecular weight polyaldehydes are prepared by converting the acetal groups of the low molecular weight polyacetal to aldehyde groups or by reacting an aldehyde-containing reagent (e.g., glyoxal) with a polyamide.
摘要翻译：通过将低分子量聚缩醛的缩醛基转化为醛基或通过使含醛试剂（例如乙二醛）与聚酰胺反应来制备低分子量多醛。

10. 发明授权

US5386040A Low molecular weight polyacetals and polyaldehydes 失效
标题翻译：低分子量聚缩醛和多醛
公开(公告)号：US5386040A
公开(公告)日：1995-01-31
申请号：US74278
申请日：1993-06-08
申请人： Gary T. Martino , Martin M. Tessler
发明人： Gary T. Martino , Martin M. Tessler
IPC分类号： C07C235/08 , C07C237/08 , C07C45/45 , C07C47/12
CPC分类号： C07C237/08 , C07C235/08
摘要： Low molecular weight polyacetals are prepared by reacting an acetal-containing reagent with a polyalcohol (e.g., glycerol or sucrose), a polyamine (e.g., 3,3'-diamine-N-methyl dipropylamine or ethylene diamine), a polyester (e.g., triethyl citrate), or a polyhalide (e.g., pentaerythrityl tetrabromide). Low molecular weight polyaldehydes are prepared by converting the acetal groups of the low molecular weight polyacetal to aldehyde groups or by reacting an aldehyde-containing reagent (e.g., glyoxal) with a polyamide.
摘要翻译：低分子量聚缩醛通过使含缩醛试剂与多元醇（例如甘油或蔗糖），多胺（例如3,3'-二胺-N-甲基二丙胺或乙二胺），聚酯（例如，柠檬酸三乙酯）或多卤素（例如季戊四醇四溴化物）。通过将低分子量聚缩醛的缩醛基转化为醛基或通过使含醛试剂（例如乙二醛）与聚酰胺反应来制备低分子量多醛。

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