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1. 发明授权

US5466862A Low molecular weight polyacetals and polyaldehydes 失效
标题翻译：低分子量聚缩醛和多醛
公开(公告)号：US5466862A
公开(公告)日：1995-11-14
申请号：US310451
申请日：1994-09-22
申请人： Gary T. Martino , Martin M. Tessler
发明人： Gary T. Martino , Martin M. Tessler
IPC分类号： C07C235/08 , C07C237/08 , C07C37/00
CPC分类号： C07C237/08 , C07C235/08
摘要： Low molecular weight polyaldehydes are prepared by converting the acetal groups of the low molecular weight polyacetal to aldehyde groups or by reacting an aldehyde-containing reagent (e.g., glyoxal) with a polyamide.
摘要翻译：通过将低分子量聚缩醛的缩醛基转化为醛基或通过使含醛试剂（例如乙二醛）与聚酰胺反应来制备低分子量多醛。

2. 发明授权

US5386040A Low molecular weight polyacetals and polyaldehydes 失效
标题翻译：低分子量聚缩醛和多醛
公开(公告)号：US5386040A
公开(公告)日：1995-01-31
申请号：US74278
申请日：1993-06-08
申请人： Gary T. Martino , Martin M. Tessler
发明人： Gary T. Martino , Martin M. Tessler
IPC分类号： C07C235/08 , C07C237/08 , C07C45/45 , C07C47/12
CPC分类号： C07C237/08 , C07C235/08
摘要： Low molecular weight polyacetals are prepared by reacting an acetal-containing reagent with a polyalcohol (e.g., glycerol or sucrose), a polyamine (e.g., 3,3'-diamine-N-methyl dipropylamine or ethylene diamine), a polyester (e.g., triethyl citrate), or a polyhalide (e.g., pentaerythrityl tetrabromide). Low molecular weight polyaldehydes are prepared by converting the acetal groups of the low molecular weight polyacetal to aldehyde groups or by reacting an aldehyde-containing reagent (e.g., glyoxal) with a polyamide.
摘要翻译：低分子量聚缩醛通过使含缩醛试剂与多元醇（例如甘油或蔗糖），多胺（例如3,3'-二胺-N-甲基二丙胺或乙二胺），聚酯（例如，柠檬酸三乙酯）或多卤素（例如季戊四醇四溴化物）。通过将低分子量聚缩醛的缩醛基转化为醛基或通过使含醛试剂（例如乙二醛）与聚酰胺反应来制备低分子量多醛。

3. 发明授权

US5011918A Polysaccharides containing aromatic aldehydes and their derivatization via amine-aldehyde interactions 失效
标题翻译：含有芳香醛的多糖及其通过胺 - 醛相互作用的衍生化
公开(公告)号：US5011918A
公开(公告)日：1991-04-30
申请号：US470276
申请日：1990-01-25
申请人： Robert L. Bilimers , David M. Del Giudice , Martin M. Tessler
发明人： Robert L. Bilimers , David M. Del Giudice , Martin M. Tessler
IPC分类号： C03C25/26 , C08B11/08 , C08B31/04 , C08B31/12 , C08B37/00
CPC分类号： C03C25/26 , C08B11/08 , C08B31/04 , C08B31/125 , C08B37/0096
摘要： A polysaccharide derivative having the structure Sacch--O--Z--Ar--CH.dbd.N--Y or ##STR1## where Sacch--O-- represents a polysaccharide molecule; Z is --(CH.sub.2).sub.n -- or ##STR2## Ar is a divalent aromatic group; Y is (a) a monovalent group derived from a water-soluble substituted or unsubstituted aromatic compound containing only one free primary amine group, or (b) a monovalent group derived from a water-soluble substituted or unsubstituted aliphatic or cycloaliphatic compound containing only one primary amine group, or (c) a multivalent group derived from a water-soluble protein containing more than one primary amine group; n is one or greater; and m is zero or greater, is prepared by first modifying the polysaccharide with a reagent to introduce free aromatic aldehyde groups and then reacting with a suitable amine-containing reagent. The siloxane-containing starch derivaties are useful in glass forming size compositions.
摘要翻译：具有Sacch-O-Z-Ar-CH = N-Y或S IMA-O结构的多糖衍生物，其中Sacch-O-代表多糖分子; Z为 - （CH 2）n - 或Ar为二价芳基; Y是（a）衍生自仅含有一个游离伯胺基团的水溶性取代或未取代的芳族化合物的单价基团，或（b）衍生自仅含有一个的水溶性取代或未取代的脂族或脂环族化合物的一价基团伯胺基，或（c）衍生自含有多于一个伯胺基的水溶性蛋白质的多价基团; n是一个或多个; 并且m为零或更大，通过首先用试剂修饰多糖以引入游离芳族醛基，然后与合适的含胺试剂反应来制备。含硅氧烷的淀粉衍生物可用于玻璃形成尺寸组合物中。

4. 发明授权

US5011630A Emulsifiable triglyceride compositions 失效
标题翻译：乳化甘油三酯组合物
公开(公告)号：US5011630A
公开(公告)日：1991-04-30
申请号：US742664
申请日：1985-06-07
申请人： Gary T. Martino , Martin M. Tessler
发明人： Gary T. Martino , Martin M. Tessler
IPC分类号： C07C233/18 , C11C3/00
CPC分类号： C11C3/003 , C07C233/18
摘要： Water dispersible, self-emulsifiable triglyceride compositions are provided. The compositions comprise the reaction product of (a) a triglyceride oil/olefinic acid (or anhydride) addition product and (b) a water soluble monofunctional polyalkylene oxide.
摘要翻译：提供了水分散性，可自乳化的甘油三酯组合物。组合物包含（a）甘油三酯油/烯属酸（或酸酐）加成产物和（b）水溶性单官能聚环氧烷烃的反应产物。

5. 发明授权

US4540778A Sulfosuccinate, alkyl- and alkenyl sulfosuccinate, sulfomaleate, and disulfosuccinate half-esters of polygalactomannans 失效
标题翻译：磺基琥珀酸盐，磺基琥珀酸烷基酯和链烯基酯，磺基马来酸盐和聚半乳甘露聚糖的二磺基琥珀酸盐半酯
公开(公告)号：US4540778A
公开(公告)日：1985-09-10
申请号：US618854
申请日：1984-06-08
申请人： Martin M. Tessler , Teresa A. Dirscherl , Otto B. Wurzburg
发明人： Martin M. Tessler , Teresa A. Dirscherl , Otto B. Wurzburg
IPC分类号： C08B37/00 , C08B37/14
CPC分类号： C08B37/0087 , C08B37/0096
摘要： Sulfosuccinate polygalactomannan half-esters, as well as the alkyl- and alkenyl-sulfosuccinates thereof, are prepared by reacting the gum with sulfosuccinic anhydride or a C.sub.1 -C.sub.22 -alkyl- or C.sub.3 -C.sub.22 -alkenyl sulfosuccinic anhydride. The reactions are carried out at about pH 7.5 in a two-phase system of solid gum slurried in an aqueous medium containing a water-miscible solvent. Sulfomaleate half-esters are prepared in a similar manner using sulfomaleic anhydride. Disulfosuccinate half-esters are prepared by reacting the sulfomaleate gum half-ester with sulfurous acid or a bisulfite salt such as sodium bisulfite.
摘要翻译：磺基琥珀酸盐半乳甘露聚糖半酯及其烷基 - 和链烯基 - 磺基琥珀酸盐通过使该树胶与磺基琥珀酸酐或C 1 -C 22烷基 - 或C 3 -C 22链烯基磺基琥珀酸酐反应来制备。在含有水混溶性溶剂的水性介质中，在固体胶的两相体系中，在约pH7.5下进行反应。使用磺基马来酸酐以类似的方式制备磺基马来酸酯半酯。二磺酸琥珀酸酯半酯通过磺基马来酸酯半酯与亚硫酸或亚硫酸氢盐如亚硫酸氢钠反应来制备。

6. 发明授权

US4020272A Preparation of starch esters 失效
标题翻译：淀粉酯的制备
公开(公告)号：US4020272A
公开(公告)日：1977-04-26
申请号：US643321
申请日：1975-12-22
申请人： Martin M. Tessler
发明人： Martin M. Tessler
IPC分类号： C08B31/02
CPC分类号： C08B31/02
摘要： Aqueous slurries or dispersions of starch are reacted with N,N'-disubstituted imidazolium salts under controlled conditions to yield starch esters. The starch ester derivatives can also be prepared by a reaction in non-aqueous solvents.
摘要翻译：在控制条件下，淀粉的水性浆料或分散体与N，N'-二取代的咪唑鎓盐反应，得到淀粉酯。淀粉酯衍生物也可以通过在非水溶剂中的反应来制备。

7. 发明授权

US4017460A Novel starch ethers 失效
标题翻译：新型淀粉醚
公开(公告)号：US4017460A
公开(公告)日：1977-04-12
申请号：US639490
申请日：1975-12-10
申请人： Martin M. Tessler
发明人： Martin M. Tessler
IPC分类号： C08B31/08 , C08B31/12
CPC分类号： C08B31/08 , C08B31/125
摘要： A reagent useful for the chemical modification of starch is prepared by the reaction of a 2,3-dihalopropionic acid or alkyl ester thereof with a secondry amine. The reaction of the reagent with starch, carried out in an aqueous solution under controlled conditions, produces novel amino acid ether derivatives which are characterized by the presence of both a cationic and an anionic substituent group on the same reactive site. The resulting starch ethers are characterized by their stability, their ability to form cooked pastes which are more resistant to gelling upon cooling and their lowered gelatinization temperatues.
摘要翻译：通过2,3-二卤代丙酸或其烷基酯与仲胺反应制备可用于淀粉化学改性的试剂。在受控条件下在水溶液中进行的试剂与淀粉的反应产生新的氨基酸醚衍生物，其特征在于在同一反应位点上存在阳离子和阴离子取代基。所得淀粉醚的特征在于它们的稳定性，它们形成熟化糊的能力，其在冷却时更耐胶凝，并且降低了糊化温度。

8. 发明授权

US5554660A Water humidity resistant starch foams 失效
标题翻译：防水防水淀粉泡沫
公开(公告)号：US5554660A
公开(公告)日：1996-09-10
申请号：US414862
申请日：1995-03-31
申请人： Paul A. Altieri , Martin M. Tessler
发明人： Paul A. Altieri , Martin M. Tessler
IPC分类号： C08L3/06 , C08J9/12 , C08L3/00 , C08L3/08 , C08L101/16 , C08J9/00
CPC分类号： C08J9/125 , C08L3/08 , C08J2303/08 , C08L2201/06 , C08L3/06
摘要： An expanded foamed starch product with improved water/humidity resistance comprising the combination of a starch or flour modified with alkylene oxide and a starch ester having an intermediate DS of from about 1.0 to 1.8 or a flour ester having a DS of 0.3 to 1.1.
摘要翻译：具有改善的耐水/抗湿性的膨胀发泡淀粉产品包括与环氧烷改性的淀粉或粉末和具有约1.0至1.8的中间体DS或DS为0.3至1.1的面粉酯的组合的组合。

9. 发明授权

US4839449A Polysaccharides containing aromatic aldehydes and their derivatization via amine-aldehyde interactions 失效
标题翻译：含有芳香醛的多糖及其通过胺 - 醛相互作用的衍生化
公开(公告)号：US4839449A
公开(公告)日：1989-06-13
申请号：US112634
申请日：1987-10-26
申请人： Robert L. Billmers , David M. Del Giudice , Martin M. Tessler , Michael J. Hasuly
发明人： Robert L. Billmers , David M. Del Giudice , Martin M. Tessler , Michael J. Hasuly
IPC分类号： C03C25/26 , C08B11/08 , C08B31/04 , C08B31/12 , C08B37/00
CPC分类号： C08B31/125 , C03C25/26 , C08B11/08 , C08B31/04 , C08B37/0096 , Y10T428/2938 , Y10T428/2956
摘要： A polysaccharide derivative having the structure Sacch--O--Z--Ar--CH.dbd.N--Y or ##STR1## where Sacch-O- represents a polysaccharide molecule; Z is --(CH.sub.2).sub.n -- or ##STR2## Ar is a divalent aromatic group; Y is (a) a monovalent group derived from a water-soluble substituted or unsubstituted aromatic compound containing only one free primary amine group, or (b) a monovalent group derived from a water-soluble substituted or unsubstituted aliphatic or cycloaliphatic compound containing only one primary amine group, or (c) a multivalent group derived from a water-soluble protein containing more than one primary amine group; n is one or greater; and m is zero or greater, is prepared by first modifying the polysaccharide with a reagent to introduce free aromatic aldehyde groups and then reacting with a suitable amine-containing reagent. The siloxane-containing starch derivatives are useful in glass forming size compositions.

10. 发明授权

US4831128A Synthetic homo- and heteropolysaccharides and a method for the preparation thereof 失效
标题翻译：合成均聚和杂多糖及其制备方法
公开(公告)号：US4831128A
公开(公告)日：1989-05-16
申请号：US882130
申请日：1986-07-03
申请人： John J. Tsai , Martin M. Tessler
发明人： John J. Tsai , Martin M. Tessler
IPC分类号： C07H15/04 , C08B31/08 , C08B31/12 , C08B37/00
CPC分类号： C07H15/04 , C08B31/08 , C08B31/12 , C08B37/0096
摘要： Mono- and polysaccharides comprising one to about 20 saccharide units which also contain a reducing carbon atom are reacted with 3-halo-1,2-propandiol in the presence of a cation exchange resin to form 3-halo-2-hydroxypropyl glycosides or glycidyl glycosides. These glycosides react with natural polysaccharides such as starch and plant gums to form novel synthetic homo- and heteropolysaccharides with pendant saccharide side chains.
摘要翻译：在阳离子交换树脂存在下，将含有还原性碳原子的1〜约20个糖单元的单糖和多糖与3-卤代-1,2-丙二醇反应，形成3-卤代-2-羟丙基糖苷或缩水甘油基糖苷。这些糖苷与天然多糖例如淀粉和植物树胶反应形成具有侧链侧链的新的合成的均聚和杂多糖。

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