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    • 34. 发明申请
    • Method for producing allyl compound, and allyl compound produced thereby
    • 制备烯丙基化合物的方法和由此制备的烯丙基化合物
    • US20050075518A1
    • 2005-04-07
    • US10650697
    • 2003-08-29
    • Masaki TakaiYoshiyuki Tanaka
    • Masaki TakaiYoshiyuki Tanaka
    • C07C41/16C07C67/10C07C209/66C07C211/35C08G63/52C08G63/87C07C41/06
    • C08G63/52C07C41/16C07C67/10C07C209/66C07C2601/14C08G63/87C07C69/78C07C211/35C07C43/215C07C43/15
    • A method for producing an allyl compound having a compositional formula different from that of an allyl starting material compound, which comprises reacting the allyl starting material compound with a nucleophilic agent in the presence of a catalyst containing at least one transitional metal compound containing a transition metal selected from the group consisting of transition metals belonging to Group 8 to Group 10 of the Periodic Table and at least one bidentate coordinated phosphite compound selected from the group consisting of compounds having structures of the following formulae (I) to (III): wherein A1 to A3 are respectively independently a diarylene group having a branched alkyl group at the ortho-position, R1 to R6 are respectively independently an alkyl group which may have a substituent or an aryl group which may have a substituent (including a heterocyclic compound forming an aromatic 6π electron cloud on the upper and lower sides of the ring, hereinafter the same), and Z1 to Z3 are respectively independently an alkylene group which may have a substituent, an arylene group which may have a substituent, an alkylene-arylene group which may have a substituent or a diarylene group which may have a substituent.
    • 一种具有与烯丙基原料化合物不同的组成式的烯丙基化合物的制备方法,该方法包括在含有至少一种含有过渡金属的过渡金属化合物的催化剂存在下使烯丙基原料化合物与亲核剂反应 选自属于元素周期表第8族至第10族的过渡金属和至少一种选自下式(I)至(III)的结构的化合物的二齿配位的亚磷酸酯化合物:其中A A 1〜A 3分别独立地为在邻位具有支链烷基的二亚芳基,R 1〜R 6分别独立地为可以具有取代基的烷基或芳基, 可以具有取代基(包括在环的上侧和下侧形成芳香族6pi电子云的杂环化合物,以下相同 )和Z 1〜Z 3分别独立地为可以具有取代基的亚烷基,可以具有取代基的亚芳基,可以具有取代基的亚芳基 - 亚芳基或可具有取代基的二亚芳基 取代基。