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    • 2. 发明授权
    • Aqueous, modified epoxy resin dispersions
    • 水性改性环氧树脂分散体
    • US5612394A
    • 1997-03-18
    • US253077
    • 1994-06-02
    • Armin PfeilMichael HoenelPaul OberresslDieter DreischhoffStefan Petri
    • Armin PfeilMichael HoenelPaul OberresslDieter DreischhoffStefan Petri
    • C08L51/08C08F2/44C08F283/00C08F283/10C08G59/06C08L71/02C08K3/20C08L63/00
    • C08G59/066C08F283/10C08L71/02
    • Aqueous epoxy resin dispersion comprising (A) an epoxy resin which is a condensation product of (A-1) from 50 to 95% by weight, preferably from 55 to 85% by weight, of one or more epoxide compounds having at least two epoxide groups per molecule and an epoxide equivalent mass of from 100 to 2000 g/mol, (A-2) from 5 to 50% by weight, preferably from 15 to 45% by weight, of an aromatic polyol; and (A-3) from 0 to 25% by weight, preferably from 0 to 10% by weight, of modifying compounds containing at least two epoxide-reactive groups; (B) a dispersant comprising (B-1) a condensation product of a polyol having a weight-average molecular mass (M.sub.w) of from 200 to 20,000 g/mol and an epoxide compound having on average at least two epoxide groups per molecule and an epoxide equivalent mass of from 100 to 10,000 g/mol, and (B-2) if desired other surfactants, preferably nonionic surfactants; (C) a polymer, prepared in this dispersion, of ethylenically unsaturated monomers which are capable of free-radical polymerization or copolymerization; (D) a curing agent for the epoxy resin (A); and (E) if desired, conventional additives and catalysts. These aqueous epoxy resin dispersions are suitable for the production of coatings, in particular for interior coatings of cans for beverages and preserves.
    • 一种水性环氧树脂分散体,其包含(A)环氧树脂,其为(A-1)50至95重量%,优选55至85重量%的一种或多种具有至少两个环氧化物的环氧化合物的缩合产物 (A-2)为5〜50重量%,优选为15〜45重量%的芳香族多元醇的环氧当量为100〜2000克/摩尔, 和(A-3)0至25重量%,优选0至10重量%的包含至少两个环氧化物反应性基团的化合物; (B)分散剂,其包含(B-1)重均分子量(Mw)为200〜20,000g / mol的多元醇与每分子平均具有至少两个环氧基的环氧化合物的缩合物,和 环氧当量为100至10,000g / mol,和(B-2)如果需要其他表面活性剂,优选非离子表面活性剂; (C)在该分散体中制备的能够进行自由基聚合或共聚的烯属不饱和单体的聚合物; (D)环氧树脂(A)的固化剂; 和(E)如果需要,常规添加剂和催化剂。 这些水性环氧树脂分散体适用于制备涂料,特别是用于饮料和保鲜罐的罐的内部涂料。
    • 3. 发明授权
    • Aqueous epoxy resin dispersions
    • 水性环氧树脂分散体
    • US5424340A
    • 1995-06-13
    • US216664
    • 1994-03-23
    • Armin PfeilJoerg-Peter GeislerPaul OberresslDieter Dreischhoff
    • Armin PfeilJoerg-Peter GeislerPaul OberresslDieter Dreischhoff
    • C08G59/20C08G59/04C08G59/42C08L63/00C09D5/00C09D5/02C09D163/00C08K3/20C08L63/02
    • C08G59/04C08L63/00Y10T428/31511
    • Aqueous epoxy resin dispersions containing(A) an epoxy resin which is a condensation product of one or more epoxy compound(s), of an aromatic polyol and, if used, of a modifying compound having at least two groups which are reactive with epoxides,(B) a dispersing agent in the form of a condensation product of an aliphatic polyol and an epoxy compound, the equivalent ratio of the OH groups to the epoxy groups being 1:0.8 to 1:3.5,(C) a carboxyl-containing or -releasing curing agent for the epoxy resin comprising one or more carboxyl-containing compound(s), at least one of these compounds having a functionality of at least three carboxyl groups per molecule, and(D) if desired customary additives, components (A), (B) and (C) being used in such amounts by weight that the equivalent ratio of the epoxy groups of component (A) capable of reacting to the carboxyl groups of component (B) is at least 1:0.5.
    • 含有(A)环氧树脂的水性环氧树脂分散体,其是一种或多种环氧化合物与芳族多元醇的缩合产物,如果使用的话,具有至少两个与环氧化物反应的基团的改性化合物, (B)脂族多元醇与环氧化合物缩合产物形式的分散剂,OH基与环氧基的当量比为1:0.8至1:3.5,(C)含羧基或 对于包含一种或多种含羧基化合物的环氧树脂的可释放固化剂,每分子具有至少三个羧基官能度的这些化合物中的至少一种,和(D)如果需要,常规添加剂,组分(A ),(B)和(C)以按组分(B)能够与羧基反应的组分(A)的环氧基的当量比至少为1:0.5的重量使用。
    • 8. 发明授权
    • Acid-modified polyesters and their use in stoving enamels
    • 酸改性聚酯及其在烘烤搪瓷中的应用
    • US5576397A
    • 1996-11-19
    • US389324
    • 1995-02-16
    • Paul OberresslJoachim Zoeller
    • Paul OberresslJoachim Zoeller
    • C08G63/20B65D25/34C08G63/12C08G63/16C08G63/60C09D167/00C09D167/02
    • C09D167/00C08G63/60
    • Acid-modified polyesters obtained by reacting(a) from 20 to 60, preferably 30-50, mol % of at least one dicarboxylic acid,(b) from 3 to 30, preferably 5-20, mol % of a dihydroxyalkanecarboxylic acid,(c) from 10 to 60, preferably 20-50, mol % of a diol,(d) from 0 to 30 mol % of a polyalcohol having more than two OH groups or of a polycarboxylic acid, and(e) from 0 to 20, preferably up to 10, mol % of a monocarboxylic acid,the ratio of the sum of the hydroxyl equivalents to the sum of the carboxyl equivalents in the reactants being between 0.5 and 2.0, the quantities of free hydroxyl groups in the end product being between 30 and 350 mmol of hydroxyl groups per 100 g of solid resin, preferably between 100 and 250 mmol of hydroxyl groups per 100 g of solid resin, and the content of free, neutralized and/or neutralizable acid groups being between 5 and 350 mmol of acid groups per 100 g of solid resin, preferably between 9 and 120 mmol of acid groups per 100 g of solid resin.
    • 通过(a)20重量%至60重量%,优选30-50摩尔%的至少一种二羧酸,(b)3-30重量%,优选5-20摩尔%的二羟基烷烃羧酸反应获得的酸改性聚酯, c)10至60,优选20-50摩尔%的二醇,(d)0至30摩尔%的具有多于2个OH基团的多元醇或多元羧酸,和(e)0至20 ,优选至多10摩尔%的单羧酸,羟基当量的总和与反应物中的羧基当量之和的比率在0.5和2.0之间,最终产物中游离羟基的量介于 每100克固体树脂含有30至350毫摩尔羟基,每100克固体树脂优选为100至250毫摩尔羟基,游离,中和和/或可中和酸基团的含量为5- 350毫摩尔 酸固体树脂,每100g固体树脂优选为9至120mmol酸基。