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    • 34. 发明授权
    • Process for the preparation of cationically modified formaldehyde resins
of prolonged stability
    • 阳离子改性甲醛树脂的制备方法具有延长的稳定性
    • US4182839A
    • 1980-01-08
    • US921008
    • 1978-06-30
    • Gerard Tesson
    • Gerard Tesson
    • C08G12/34D21H17/51C08G12/32
    • D21H17/51C08G12/34
    • Cationic resins soluble in water and stable in solution, based upon melamine and formaldehyde, primary or secondary aliphatic amines, alkanolamines or a polyamine are prepared by reacting melamine with formaldehyde in a methylolation reaction in methanol in the presence of one or more of the aforementioned amines by heating for a period of fifteen minutes to two hours at an alkaline pH of 7.5 to 10 at a temperature of 60.degree. to 85.degree. C. The methylation-condensation reaction which follows is carried out at a pH of 5 to 6, preferably 5.4 to 5.7 until a viscosity is obtained which has a minimum of seventeen seconds measured at 20.degree. C. by an AFNOR No. 6 consistometric head. The methylation reaction is then terminated by the addition of aqueous formaldehyde and condensation is carried out for thirty minutes to two hours at 60.degree. to 90.degree. C. and a pH of 5.5 to 7, preferably a pH of 6 to 6.5. The product has longterm stability and can be used as a water-resisting or humidity-resistant coating or sizing for paper or as an adhesion promoting coating for solid supports to which a varnish is to be applied.
    • 基于三聚氰胺和甲醛,基于三聚氰胺和甲醛,初级或仲脂肪族胺,链烷醇胺或多胺,溶于水并稳定的阳离子树脂通过在甲醇中的甲氧基化反应中,在一种或多种上述胺 通过在温度为60〜85℃的碱性pH为7.5〜10的温度下加热15分钟〜2小时。以下的甲基化缩合反应在5〜6的pH下进行,优选为5.4 至5.7,直到获得在20℃下通过AFNOR 6号共识头测量的至少17秒的粘度。 然后通过加入甲醛终止甲基化反应,并在60-90℃下进行缩合30分钟至2小时,pH为5.5-7,优选pH6-6.5。 该产品具有长期的稳定性,可用作纸的防水或防湿涂料或施胶剂,或用作要施用清漆的固体支持物的增粘涂层。
    • 38. 发明授权
    • Capsule manufacture
    • 胶囊制造
    • US4100103A
    • 1978-07-11
    • US755830
    • 1976-12-30
    • Peter L. ForisRobert W. BrownPaul S. Phillips, Jr.
    • Peter L. ForisRobert W. BrownPaul S. Phillips, Jr.
    • B41M5/165B01J13/02B01J13/18C08G12/32
    • B01J13/18C08G12/32Y10S428/914Y10T428/2989
    • A process is disclosed for performing encapsulation, en masse, by an in situ polymerization reaction to yield capsule wall material. The polymerization comprises a reaction between melamine and formaldehyde and/or polycondensation of monomeric methylol melamine or etherified methylol melamine, or a low molecular weight polymer thereof, in an aqueous vehicle and the reaction is conducted in the presence of negatively-charged, carboxyl-substituted, linear aliphatic hydrocarbon polyelectrolyte material dissolved in the vehicle. Liquid-liquid phase separation is accomplished and maintained by increase in the molecular weight of the resulting condensation polymer without further dilution of the manufacturing vehicle. The negatively-charged polyelectrolyte material is required and has an apparent effect of controlling or modifying the polymerization reaction. The disclosed encapsulation process permits manufacture of micro-capsules in concentrations of capsule to capsule manufacturing vehicle higher than previously possible.
    • 公开了一种通过原位聚合反应进行包封以产生胶囊壁材料的方法。 聚合反应包括三聚氰胺和甲醛之间的反应和/或单体羟甲基三聚氰胺或醚化的羟甲基三聚氰胺或其低分子量聚合物在水性载体中的缩聚,并且反应在带负电荷的羧基取代的存在下进行 溶解在载体中的直链脂族烃聚电解质材料。 通过增加所得缩合聚合物的分子量而不进一步稀释制造车辆来实现和维持液 - 液相分离。 需要带负电荷的聚电解质材料,并具有控制或改性聚合反应的明显效果。 所公开的封装方法允许制造胶囊至胶囊制造车辆的浓度比以前更高的微胶囊。