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31. 发明授权

US09620295B2 Dye-sensitized solar cell and method for manufacturing same 有权
公开(公告)号：US09620295B2
公开(公告)日：2017-04-11
申请号：US14398646
申请日：2013-05-08
申请人： LG CHEM, LTD. , Soo Hee Jung
发明人： Tae-Sik Kang
IPC分类号： H01G9/20 , H01L51/44 , H01L51/48 , H01L51/00
CPC分类号： H01G9/2022 , H01G9/2031 , H01G9/2036 , H01G9/204 , H01G9/2059 , H01G9/2072 , H01G9/2077 , H01L51/0086 , Y02E10/542 , Y02P70/521
摘要： The present invention relates to a dye-sensitized solar cell and a fabrication method thereof. The dye-sensitized solar cell according to the present invention comprises: a transparent substrate; a porous semiconductor layer provided on the transparent substrate and comprising a dye sensitizer; a current collecting electrode provided on the porous semiconductor layer and deposited such that a structure having at least one through-hole on the porous semiconductor layer is formed; a catalyst electrode; and an electrolyte material provided between the transparent substrate and the catalyst electrode.

32. 发明申请

US20170092435A1 PHOTOELECTRIC CONVERSION ELEMENT, DYE-SENSITIZED SOLAR CELL, METAL COMPLEX DYE, DYE SOLUTION, AND TERPYRIDINE COMPOUND OR ESTERIFIED PRODUCT THEREOF 审中-公开
公开(公告)号：US20170092435A1
公开(公告)日：2017-03-30
申请号：US15372532
申请日：2016-12-08
申请人： FUJIFILM Corporation
发明人： Kazuhiro TSUNA , Hiroki SUGIURA , Tomoaki YOSHIOKA , Kousuke WATANABE , Katsumi KOBAYASHI
IPC分类号： H01G9/20 , C07D213/79 , H01L51/00 , C07F7/08 , C07D409/14 , C09B57/10 , C07D495/04
CPC分类号： H01G9/2059 , C07D213/79 , C07D409/14 , C07D495/04 , C07F7/0816 , C09B23/105 , C09B57/10 , C09B67/0083 , H01G9/2009 , H01G9/2031 , H01L51/0086 , H01L51/42 , Y02E10/542
摘要： A photoelectric conversion element having an electrically conductive support, a photoconductor layer including an electrolyte, a charge transfer layer including an electrolyte, and a counter electrode, in which the photoconductor layer has semiconductor fine particles carrying a metal complex dye represented by the following Formula (1), and a dye-sensitized solar cell; and a metal complex dye, a dye solution, and a terpyridine compound, or an esterified product thereof, each of which is used in the photoelectric conversion element and the dye-sensitized solar cell, ML1L2(X)n1.CImY Formula (1) in Formula (1), M represents a metal ion, L1 represents a tridentate ligand having a group L represented by the following Formula (LV-1) or (LV-2); L2 represents a bidentate or tridentate ligand which coordinates to M with an anion, in which a ring including a ring-constituting nitrogen atom which coordinates to M with an lone electron pair has an organic group RVL: -(RVL)nVL; X represents a monodentate ligand; n1 represents 0 or 1; CI represents a required counterion; and mY represents an integer of 0 to 3, -RV1=RV2-RV3 Formula (LV-1) —C≡C—RV3 Formula (LV-2) in the formulae, RV1 and RV2 each independently represent a nitrogen atom or CRV4, RV4 represents a hydrogen atom or a substituent, and RV3 represents an aryl group or a heteroaryl group; RVL represents a specific aromatic ring group or the like; and nVL represents an integer of 0 or more.

33. 发明申请

US20170077572A1 HYBRID SYSTEM FOR STORING SOLAR ENERGY AS HEAT AND ELECTRICITY 审中-公开
标题翻译：将太阳能作为热能和电力储存的混合系统
公开(公告)号：US20170077572A1
公开(公告)日：2017-03-16
申请号：US15250577
申请日：2016-08-29
申请人： University of Wyoming
发明人： Bruce A. Parkinson
IPC分类号： H01M14/00 , H01M8/20 , H01G9/20 , H01M8/18
CPC分类号： H01G9/20 , H01G9/2018 , H01G9/2031 , H01G9/2059 , H01G9/2068 , H01M8/18 , Y02E10/542 , Y02E60/528
摘要： A photoelectrochemical system and method utilizing the photons having energies above the bandgaps of a p-type semiconductor photocathode and an n-type semiconductor photoanode with redox couples having fast electron transfer kinetics to keep overpotentials under 0.15 volts, and redox potentials energetically located within the band gaps, for storing energy in photodriven oxidation and reduction reactions separated by less than 1.6 volts using a redox flow battery configuration, are described. The photoelectrochemical system can also store heat in the flow battery generated from the inefficiencies of the photoredox reactions and from impinging photons having energies below the band gaps. Redox flow batteries contain fluid electrolyte and tanks for storing the redox equivalents, which can be used to store the solar energy not used to drive the photoredox chemistry for hot water and space heating applications. The present hybrid photoelectrochemical/thermal system may be used store excess grid electricity when electrical demand is low, or as a conventional redox flow battery in a distributed energy system, if the redox electrolyte volume was increased above that needed for solar load leveling on a daily or weekly time scale. Heat generated from the discharge of the redox battery would also be captured and stored.
摘要翻译：光电化学系统和方法利用具有高于p型半导体光电阴极的带隙的光子和具有快速电子转移动力学的氧化还原对的n型半导体光电阳极以保持低于0.15伏的超电势的光子，以及能量位于带内的氧化还原电位描述了用于使用氧化还原液流电池配置将能量存储在分解为小于1.6伏的光电二极管氧化和还原反应中的间隙。光电化学体系还可以存储由于光氧化反应的低效产生的流动电池中的热量以及能量低于带隙的入射光子。氧化还原液流电池包含流体电解质和用于存储氧化还原当量的罐，其可用于存储未用于驱动光氧化学化学品用于热水和空间加热应用的太阳能。当电力需求低时，本发明的混合光电化学/热系统可以用于存储多余的电网电力，或者如果氧化还原电解质体积增加到高于日常负载均衡所需的氧化还原电解质体积或每周时间尺度。从氧化还原电池的放电产生的热也将被捕获并储存。

34. 发明授权

US09574271B2 Method for forming metal oxide film, metal oxide film and apparatus for forming metal oxide film 有权
标题翻译：用于形成金属氧化物膜的方法，金属氧化物膜和用于形成金属氧化物膜的装置
公开(公告)号：US09574271B2
公开(公告)日：2017-02-21
申请号：US13383766
申请日：2009-09-02
申请人： Hiroyuki Orita , Takahiro Shirahata , Akio Yoshida , Shizuo Fujita , Naoki Kameyama , Toshiyuki Kawaharamura
发明人： Hiroyuki Orita , Takahiro Shirahata , Akio Yoshida , Shizuo Fujita , Naoki Kameyama , Toshiyuki Kawaharamura
IPC分类号： C23C16/00 , C23C18/12 , H01L31/18 , H01G9/20 , H01L29/786
CPC分类号： C23C18/1216 , C23C18/1258 , C23C18/1291 , H01G9/2031 , H01L29/7869 , H01L31/1884 , Y02E10/50
摘要： The present method of forming a metal oxide film can increase production efficiency while maintaining the low resistance of the metal oxide film. The present method of forming a metal oxide film includes first misting a solution containing a metallic element and ethylenediamine; meanwhile, heating a substrate; and then, supplying the misted solution onto a first main surface of the substrate.
摘要翻译：本发明的形成金属氧化物膜的方法可以提高生产效率，同时保持金属氧化物膜的低电阻。本发明的形成金属氧化物膜的方法包括首先将含有金属元素和乙二胺的溶液雾化; 同时加热基材; 然后将雾化溶液供给到基板的第一主表面上。

35. 发明授权

US09570242B2 Flexible Ti—In—Zn—O transparent electrode for dye-sensitized solar cell, and metal-inserted three-layer transparent electrode with high conductivity using same and manufacturing method therefor 有权
标题翻译：用于染料敏化太阳能电池的柔性Ti-In-Zn-O透明电极和具有高导电性的金属插入三层透明电极及其制造方法
公开(公告)号：US09570242B2
公开(公告)日：2017-02-14
申请号：US13822700
申请日：2012-05-02
申请人： Gi Seok Heo , Tae Won Kim , Jae Cheol Park , Kwang Young Kim
发明人： Gi Seok Heo , Tae Won Kim , Jae Cheol Park , Kwang Young Kim
IPC分类号： C23C14/08 , H01G9/20 , H01L51/44 , C23C14/02 , C23C14/04 , C23C14/20 , C23C28/00 , H01B1/08
CPC分类号： H01G9/2036 , C23C14/022 , C23C14/042 , C23C14/08 , C23C14/086 , C23C14/205 , C23C14/352 , C23C28/32 , C23C28/322 , C23C28/345 , H01B1/08 , H01G9/2031 , H01G9/204 , H01L51/442 , Y02E10/542 , Y02E10/549 , Y02P70/521
摘要： The present invention relates to a flexible transparent electrode for a dye-sensitized solar cell and a manufacturing method for same, and more specifically, to a flexible Ti—In—Zn—O transparent electrode for a dye-sensitized solar cell and a manufacturing method for same, and to a metal-inserted three-layer transparent electrode with high conductivity using the flexible transparent electrode and a manufacturing method for same, wherein compared with the conventional fluorine-doped tin oxide (FTO) and indium-tin oxide (ITO) transparent electrodes with a high deposition temperature, the flexible transparent electrode, despite being deposited at room or low temperature, has low surface resistance, high conductivity and transmittance, superior resistance against external bending, improved surface characteristics and better surface roughness performance.
摘要翻译：本发明涉及一种用于染料敏化太阳能电池的柔性透明电极及其制造方法，更具体地涉及用于染料敏化太阳能电池的柔性Ti-In-Zn-O透明电极及其制造方法与使用柔性透明电极的具有高导电性的金属插入三层透明电极及其制造方法相比，其中与常规的氟掺杂氧化锡（FTO）和氧化铟锡（ITO）相比，具有高沉积温度的透明电极，尽管在室温或低温下沉积，柔性透明电极具有低表面电阻，高导电性和透光率，优异的抗外部弯曲性能，改进的表面特性和更好的表面粗糙度性能。

36. 发明授权

US09546278B2 Porphyrin photosensitive dye and photoelectric conversion device utilizing the same 有权
标题翻译：卟啉光敏染料及其光电转换装置
公开(公告)号：US09546278B2
公开(公告)日：2017-01-17
申请号：US14620715
申请日：2015-02-12
申请人： Industrial Technology Research Institute
发明人： Shu-Nung Chang , Chia-Hua Lee , Yung-Liang Tung
IPC分类号： C07D487/22 , C09B47/00 , H01L51/00 , H01G9/20 , H01L51/50
CPC分类号： C09B47/00 , H01G9/2031 , H01G9/2059 , H01L51/0092 , H01L51/5012 , Y02E10/542 , Y02E10/549
摘要： Disclosed is a porphyrin photosensitive dye, having the chemical formula: Each of L1 and L2 is independently R1 is C5-20 linear/branched alkyl group. R2 is C0-20 linear/branched alkyl group. R4 is C1-20 linear/branched alkyl group. Each of R3 and R5 is independently C1-20 linear/branched alkyl group or C1-20 linear/branched alkoxy group. Y1 is C3-20 cycloalkyl group. Each of a and b is independently an integer of 0 to 5. D is Each of R6 to R11 is independently C1-10 alkyl group. X1 is N, O, S, or Se. Each of c, d, and e is independently an integer of 0 to 5. A is Each of Z1 and Z2 is independently hydrogen, alkali metal, or quaternary ammonium salt —N(R12)4. R12 is C1-10 alkyl group. X2 is N, O, S, or Se.
摘要翻译：公开了具有以下化学式的卟啉感光性染料：L1和L2各自独立地为R 1为C 5-20直链/支链烷基。 R2为C0-20直链/支链烷基。 R4是C1-20直链或支链烷基。 R 3和R 5各自独立地为C 1-20直链/支链的烷基或C 1-20直链/支链烷氧基。 Y1是C3-20环烷基。 a和b各自独立地为0〜5的整数.D为R 6〜R 11各自独立地为C 1-10烷基。 X1是N，O，S或Se。 c，d和e中的每一个独立地为0至5的整数。A是Z 1和Z 2各自独立地为氢，碱金属或季铵盐-N（R 12）4。 R 12是C 1-10烷基。 X2是N，O，S或Se。

37. 发明授权

US09536676B2 Dye-sensitized solar cell module 有权
标题翻译：染料敏化太阳能电池模块
公开(公告)号：US09536676B2
公开(公告)日：2017-01-03
申请号：US14015143
申请日：2013-08-30
申请人： FUJIKURA LTD.
发明人： Kouki Shimohira , Kenichi Okada
IPC分类号： H01G9/20
CPC分类号： H01G9/2077 , H01G9/2031 , H01G9/2059 , H01G9/2081 , Y02E10/542
摘要： A dye-sensitized solar cell module includes a plurality of dye-sensitized solar cells electrically connected in series. The dye-sensitized solar cell includes a first electrode that comprises a transparent substrate, and a transparent conductive film provided on the transparent substrate, a second electrode that faces the first electrode, an oxide semiconductor layer that is provided on the first electrode or the second electrode, and an annular sealing section that joins the first electrode and the second electrode. The transparent substrate is composed of a transparent substrate that is common to the plurality of dye-sensitized solar cells. The second electrodes of two adjoining dye-sensitized solar cells are separated apart from each other. The sealing section includes an annular first sealing section that is provided between the first electrode and the second electrode, and the first sealing sections that are adjoining are integrated together.
摘要翻译：染料敏化太阳能电池模块包括串联电连接的多个染料敏化太阳能电池。染料敏化太阳能电池包括：第一电极，其包括透明基板;以及设置在透明基板上的透明导电膜，与第一电极相对的第二电极，设置在第一电极或第二电极上的氧化物半导体层电极，以及连接第一电极和第二电极的环形密封部。透明基板由多个染料敏化太阳能电池共同的透明基板构成。两个相邻的染料敏化太阳能电池的第二电极彼此分开。密封部分包括设置在第一电极和第二电极之间的环形第一密封部分，并且邻接的第一密封部分集成在一起。

38. 发明申请

US20160379763A1 SUBSTRATE AND ELECTRODE FOR SOLAR CELLS AND THE CORRESPONDING MANUFACTURING PROCESS 审中-公开
标题翻译：太阳能电池的基板和电极以及相应的制造工艺
公开(公告)号：US20160379763A1
公开(公告)日：2016-12-29
申请号：US15258647
申请日：2016-09-07
申请人： Adélio Miguel MAGALHÃES MENDES , Luisa Manuela MADUREIRA ANDRADE , Joaquim Gabriel MAGALHÃES MENDES , José Miguel LOPES MAÇAIRA NOGUEIRA , Fernando Manuel DA SILVA RIBEIRO
发明人： Adélio Miguel MAGALHÃES MENDES , Luisa Manuela MADUREIRA ANDRADE , Joaquim Gabriel MAGALHÃES MENDES , José Miguel LOPES MAÇAIRA NOGUEIRA , Fernando Manuel DA SILVA RIBEIRO
IPC分类号： H01G9/20
CPC分类号： H01G9/2077 , H01G9/0029 , H01G9/2022 , H01G9/2027 , H01G9/2031 , H01G9/2059 , H01G9/2068 , H01L51/445 , Y02E10/542 , Y02E10/549 , Y02P70/521
摘要： Solar cells use as substrates glass (23) coated with a transparent conductive layer (21), able to collect the electric power generated by the solar cell. This layer (21), normally a TCO, have limited conductivity, implying the use of current collector lines applied in a complex manner. The conductivity of the conductive layer (21) is increased by the application of a structure, in particular a grid, of thin conductive lines (22) inserted in grooves on the glass surface (23) or directly applied on this, followed by a TCO layer coating (21). This highly conductive grid (22) collects the electricity from the TCO layer (21) and directs it to the periphery of the cell.Both glass substrates are sealed by a process employing a precursor of glass surrounding the entire perimeter of the substrate. The glass precursor is heated to its melting point, by a laser, completely sealing the two substrates of the module.
摘要翻译：通过使用围绕衬底的整个周边的玻璃前体的方法来密封两个玻璃基板。通过激光将玻璃前体加热到其熔点，完全密封模块的两个基板。

39. 发明授权

US09527754B2 Crystalline mesoporous titanium dioxide and the use thereof in electrochemical devices 有权
公开(公告)号：US09527754B2
公开(公告)日：2016-12-27
申请号：US14595038
申请日：2015-01-12
申请人： National University of Singapore
发明人： Palani Balaya , Ananthanarayanan Krishnamoorthy , Saravanan Kuppan
IPC分类号： C01G23/08 , B01J21/06 , B01J35/00 , B01J35/02 , B01J35/10 , B01J37/03 , H01G9/20 , H01M4/133 , H01M4/1393 , H01M4/485 , H01M4/58 , H01M4/62 , H01M10/0525 , C01G23/053 , H01M4/02
CPC分类号： C01G23/08 , B01J21/063 , B01J35/0013 , B01J35/0026 , B01J35/004 , B01J35/023 , B01J35/1019 , B01J35/1061 , B01J37/036 , C01G23/053 , C01P2002/60 , C01P2002/72 , C01P2002/78 , C01P2004/03 , C01P2004/04 , C01P2004/62 , C01P2006/11 , C01P2006/12 , C01P2006/16 , C01P2006/40 , H01G9/2031 , H01M4/133 , H01M4/1393 , H01M4/485 , H01M4/5825 , H01M4/624 , H01M10/0525 , H01M2004/021 , Y02E10/542 , Y02E60/122
摘要： The present invention relates to the preparation of a mesoporous substantially pure anatase titanium oxide (meso-TiO2) and its use in electrochemical devices, in particular lithium-ion batteries.

40. 发明授权

US09520512B2 Titanate interfacial layers in perovskite material devices 有权
标题翻译：钙钛矿材料器件中的钛酸盐界面层
公开(公告)号：US09520512B2
公开(公告)日：2016-12-13
申请号：US14711430
申请日：2015-05-13
申请人： Hunt Energy Enterprises, L.L.C.
发明人： Michael D. Irwin , Jerred A. Chute , Vivek V. Dhas
IPC分类号： H01L31/032 , H01L31/0256 , H01G9/20 , H01L51/00
CPC分类号： H01L31/0324 , H01G9/2031 , H01G9/2036 , H01G9/2059 , H01L31/032 , H01L51/006 , H01L51/0061 , H01L2031/0344 , Y02E10/542
摘要： Photovoltaic devices such as solar cells, hybrid solar cell-batteries, and other such devices may include an active layer disposed between two electrodes. The active layer may have perovskite material and other material such as mesoporous material, interfacial layers, thin-coat interfacial layers, and combinations thereof. The perovskite material may be photoactive. The active layer may include a titanate. The perovskite material may be disposed between two or more other materials in the photovoltaic device. Inclusion of these materials in various arrangements within an active layer of a photovoltaic device may improve device performance. Other materials may be included to further improve device performance, such as, for example: additional perovskites, and additional interfacial layers.
摘要翻译：诸如太阳能电池，混合太阳能电池和其它这样的器件的光伏器件可以包括设置在两个电极之间的有源层。活性层可以具有钙钛矿材料和其它材料，例如介孔材料，界面层，薄膜界面层及其组合。钙钛矿材料可以是光活性的。有源层可以包括钛酸盐。钙钛矿材料可以设置在光伏器件中的两种或更多种其它材料之间。将这些材料包含在光伏器件的有源层内的各种布置中可以提高器件性能。可以包括其它材料以进一步提高装置性能，例如：额外的钙钛矿和另外的界面层。

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