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    • 31. 发明授权
    • Process for producing clean liquid fuels from coal waste
    • 从废煤中生产清洁液体燃料的工艺
    • US07988754B1
    • 2011-08-02
    • US11969336
    • 2008-01-04
    • John W. Rich, Jr.
    • John W. Rich, Jr.
    • C10K3/06C10J3/16C10J3/46
    • C10G2/32C10J3/466C10J3/506C10J3/86C10J2300/0903C10J2300/093C10J2300/0943C10J2300/0959C10J2300/0973C10J2300/0993C10J2300/1634C10J2300/1659C10J2300/1678C10K1/004C10K1/026
    • The present invention is directed to a process for producing ultra clean liquid fuel from abandoned mine waste. A feedstock is prepared from water and coal mine waste having relatively high ash (non-carbonaceous matter) content. Foundry slag is added to the feedstock as a fluxant to adjust the melting behavior of the ash in the feedstock. Preferably, the fluxant is blast furnace slag provided in a particle size of less than about 150 μm and is provided in an amount sufficient to lower the melting point of the ash in the feedstock by at least about 200° F. The feedstock is admitted with a flow of oxygen into a pressurized chamber of an entrained flow gasifier in which the feedstock and oxygen are heated to produce a synthetic gas from a coal component of the feedstock and molten slag from the ash and fluxant components of the feedstock. The molten slag is of a viscosity to freely flow out of the gasifier through an exit port in the bottom of the gasifier. The synthetic gas can be used to produce paraffin from which ultra clean liquid fuel can be produced.
    • 本发明涉及从废弃矿山废料生产超清洁液体燃料的方法。 从具有相对高的灰分(非碳质物质)含量的水和煤矿废料制备原料。 将铸造渣作为助剂添加到原料中,以调节原料中灰分的熔融行为。 优选地,助熔剂是提供的粒度小于约150μm的高炉矿渣,其用量足以将原料中灰分的熔点降至至少约200°F。原料被允许用 氧气流入夹带流气化器的加压室中,其中原料和氧被加热以从原料的煤组分和来自原料的灰分和助熔剂组分的熔融渣中产生合成气。 熔渣具有通过气化器底部的出口自由流出气化器的粘度。 合成气可用于生产可以生产超清洁液体燃料的石蜡。
    • 35. 发明申请
    • METHOD AND APPARATUS TO PRODUCE SYNTHESIS GAS VIA FLASH PYROLYSIS AND GASIFICATION IN A MOLTEN LIQUID
    • 生产合成气的方法和装置通过液体中的闪蒸和气化
    • US20110088320A1
    • 2011-04-21
    • US12964036
    • 2010-12-09
    • Mark A. DietenbergerMark H. Anderson
    • Mark A. DietenbergerMark H. Anderson
    • C10J3/48C10J3/46
    • C10J3/57C10J3/463C10J3/66C10J2300/0909C10J2300/0916C10J2300/092C10J2300/0946C10J2300/0973C10J2300/0989C10J2300/1659C10J2300/1823C10K1/026Y02E20/18Y02E50/32Y02P20/145
    • Disclosed are a method and a corresponding apparatus for converting a biomass reactant into synthesis gas. The method includes the steps of (1) heating biomass in a first molten liquid bath at a first temperature, wherein the first temperature is at least about 100° C., but less than the decomposition temperature of the biomass, wherein gas comprising water is evaporated and air is pressed from the biomass, thereby yielding dried biomass with minimal air content. (2) Recapturing the moisture evaporated from the biomass in step 1 for use in the process gas. (3) Heating the dried biomass in a second molten liquid bath at a second temperature, wherein the second temperature is sufficiently high to cause flash pyrolysis of the dried biomass, thereby yielding product gases, tar, and char. (4) Inserting recaptured steam into the process gas, which may optionally include external natural gas or hydrogen gas or recycled syngas for mixing and reforming with tar and non-condensable gases. (5) Further reacting the product gases, tar, and char with the process gas within a third molten liquid bath at a third temperature which is equal to or greater than the second temperature within the second molten liquid bath, thereby yielding high quality and relatively clean synthesis gas after a relatively long residence time needed for char gasification. A portion of the synthesis gas so formed is combusted to heat the first, second, and third molten liquid baths, unless external natural or hydrogen gas is available for this use.
    • 公开了一种用于将生物质反应物转化成合成气的方法和相应的装置。 该方法包括以下步骤:(1)在第一温度下在第一熔融液浴中加热生物质,其中第一温度为至少约100℃,但小于生物质的分解温度,其中包含水的气体为 蒸发并从生物质中压制空气,从而产生具有最小空气含量的干燥生物质。 (2)在步骤1中回收从生物质蒸发的水分,用于工艺气体。 (3)在第二温度下在第二熔融液体浴中加热干燥的生物质,其中第二温度足够高以引起干燥的生物质的快速热解,从而产生产物气体,焦油和焦炭。 (4)将再吸收的蒸汽插入工艺气体中,其可任选地包括外部天然气或氢气或再循环的合成气,用于与焦油和不可冷凝气体混合和重整。 (5)使产物气体,焦油和焦炭与第三熔融液槽内的处理气体在第二熔融液浴中的第三温度等于或大于第二温度的第三温度下反应,从而产生高品质和相对的 洁净的合成气在焦化气化所需的较长停留时间后。 如此形成的合成气的一部分被燃烧以加热第一,第二和第三熔融液体浴,除非可用于该用途的外部天然或氢气。
    • 40. 发明申请
    • METHOD AND APPARATUS TO PROTECT SYNTHESIS GAS VIA FLASH PYROLYSIS AND GASIFICATION IN A MOLTEN LIQUID
    • 生产合成气的方法和装置通过液体中的闪蒸和气化
    • US20080307703A1
    • 2008-12-18
    • US12108747
    • 2008-04-24
    • Mark A. DietenbergerMark H. Anderson
    • Mark A. DietenbergerMark H. Anderson
    • C10J3/68C10J3/00
    • C10J3/57C10J3/463C10J3/66C10J2300/0909C10J2300/0916C10J2300/092C10J2300/0946C10J2300/0973C10J2300/0989C10J2300/1659C10J2300/1823C10K1/026Y02E20/18Y02E50/32Y02P20/145
    • Disclosed are a method and a corresponding apparatus for converting a biomass reactant into synthesis gas. The method includes the steps of (1) heating biomass in a first molten liquid bath at a first temperature, wherein the first temperature is at least about 100° C., but less than the decomposition temperature of the biomass, wherein gas comprising water is evaporated and air is pressed from the biomass, thereby yielding dried biomass with minimal air content. (2) Recapturing the moisture evaporated from the biomass in step 1 for use in the process gas. (3) Heating the dried biomass in a second molten liquid bath at a second temperature, wherein the second temperature is sufficiently high to cause flash pyrolysis of the dried biomass, thereby yielding product gases, tar, and char. (4) Inserting recaptured steam into the process gas, which may optionally include external natural gas or hydrogen gas or recycled syngas for mixing and reforming with tar and non-condensable gases. (5) Further reacting the product gases, tar, and char with the process gas within a third molten liquid bath at a third temperature which is equal to or greater than the second temperature within the second molten liquid bath, thereby yielding high quality and relatively clean synthesis gas after a relatively long residence time needed for char gasification. A portion of the synthesis gas so formed is combusted to heat the first, second, and third molten liquid baths, unless external natural or hydrogen gas is available for this use.
    • 公开了一种用于将生物质反应物转化成合成气的方法和相应的装置。 该方法包括以下步骤:(1)在第一温度下在第一熔融液浴中加热生物质,其中第一温度为至少约100℃,但小于生物质的分解温度,其中包含水的气体为 蒸发并从生物质中压制空气,从而产生具有最小空气含量的干燥生物质。 (2)在步骤1中回收从生物质蒸发的水分,用于工艺气体。 (3)在第二温度下在第二熔融液体浴中加热干燥的生物质,其中第二温度足够高以引起干燥的生物质的快速热解,从而产生产物气体,焦油和焦炭。 (4)将再吸收的蒸汽插入工艺气体中,其可任选地包括外部天然气或氢气或再循环的合成气,用于与焦油和不可冷凝气体混合和重整。 (5)使产物气体,焦油和焦炭与第三熔融液槽内的处理气体在第二熔融液浴中的第三温度等于或大于第二温度的第三温度下反应,从而产生高品质和相对的 洁净的合成气在焦化气化所需的较长停留时间后。 如此形成的合成气的一部分被燃烧以加热第一,第二和第三熔融液体浴,除非可用于该用途的外部天然或氢气。