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31. 发明授权

US07732052B2 Compositions of ethylene/alpha-olefin multi-block interpolymer for elastic films and laminates 有权
标题翻译：用于弹性膜和层压板的乙烯/α-烯烃多嵌段互聚物的组合物
公开(公告)号：US07732052B2
公开(公告)日：2010-06-08
申请号：US12032474
申请日：2008-02-15
申请人： Andy C. Chang , Ronald J. Weeks , Hong Peng , Antonios K. Doufas , Yunwa Wilson Cheung
发明人： Andy C. Chang , Ronald J. Weeks , Hong Peng , Antonios K. Doufas , Yunwa Wilson Cheung
IPC分类号： B32B27/40 , B32B7/02
CPC分类号： C08L23/0815 , C08F4/65908 , C08F4/65912 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08F110/02 , C08F210/16 , C08F297/08 , C08F2420/02 , C08L23/06 , C08L23/0853 , Y10T428/24942 , Y10T428/24992 , Y10T428/2826 , Y10T428/31573 , Y10T428/31587 , Y10T428/31913 , Y10T428/31917 , Y10T428/31924 , Y10T428/31931 , Y10T442/674 , C08L2666/06 , C08F210/14 , C08F2500/08 , C08F2500/03 , C08F2/38 , C08F4/65904 , C08F2500/09 , C08F4/64048 , C08F4/6411 , C08F4/64193 , C08F4/64113 , C08F4/64144 , C08F4/64148
摘要： This invention relates to polyolefin compositions. In particular, the invention pertains to elastic polymer compositions that can be more easily processed on cast film lines, extrusion lamination or coating lines due to improved resistance to draw resonance. The compositions of the present invention preferably comprise an elastomeric polyolefin resin and a high pressure low density type resin.
摘要翻译：本发明涉及聚烯烃组合物。特别地，本发明涉及弹性聚合物组合物，其可以由于提高的拉伸共振抗性而更容易地在流延膜线，挤出层压或涂布线上加工。本发明的组合物优选包含弹性体聚烯烃树脂和高压低密度树脂。

32. 发明申请

US20100093959A1 SUPPORTED CATALYST FOR OLEFIN POLLYMERIZATION USING TRANSITION METAL COMPOUND HAVING THENYLENE-BRIDGE, METHOD FOR PREPARING THE SAME, AND METHOD FOR PREPARING POLYOLEFINGUSINGTHED SAME 有权
标题翻译：使用具有亚戊基桥的过渡金属化合物的烯烃聚合的支持催化剂，其制备方法和制备聚烯烃的方法
公开(公告)号：US20100093959A1
公开(公告)日：2010-04-15
申请号：US12312823
申请日：2007-11-15
申请人： Dae-Sik Hong , Ki-Soo Lee , Yong-Gyu Han , Heon-Yong Kwon , Jong-Sang Park , Joon-Hee Cho , Seon-Kyoung Kim , Choong-Hoon Lee , Eun-Jung Lee , Seung-Whan Jung , Ki-Su Ro
发明人： Dae-Sik Hong , Ki-Soo Lee , Yong-Gyu Han , Heon-Yong Kwon , Jong-Sang Park , Joon-Hee Cho , Seon-Kyoung Kim , Choong-Hoon Lee , Eun-Jung Lee , Seung-Whan Jung , Ki-Su Ro
IPC分类号： C08F4/6592 , B01J31/14 , B01J37/00
CPC分类号： C08F210/16 , C08F4/65904 , C08F4/65912 , C08F2420/02 , Y10S526/943 , C08F4/6592 , C08F4/65916 , C08F210/14 , C08F2500/12 , C08F2500/03
摘要： The present invention provides a new supported catalyst for olefin polymerization prepared by reacting a novel transition metal compound on a cocatalyst-supported support, in which the transition metal compound is coordinated with a monocyclopentadienyl ligand to which an amido-quinoline group is introduced, a method for preparing the same, and a method for preparing a polyolefin using the same. The transition metal catalyst compound used in the present invention is configured such that an amido group is linked in a cyclic form via a phenylene bridge. Thus, a pentagon ring structure of the transition metal compound is stably maintained, so that monomers easily approach the transition metal compound and the reactivity is also high. Accordingly, if the supported catalyst for olefin polymerization prepared according to the present invention is applied to the copolymerization of ethylene and monomers having large steric hindrance in a slurry or a gas phase process, a linear, a linear, high molecular weight polyolefin having a very low density of 0.900 to 0.970 g/cc or less can be obtained.
摘要翻译：本发明提供了一种用于烯烃聚合的新型负载催化剂，其通过使新型过渡金属化合物在助催化剂负载的载体上反应制备，其中过渡金属化合物与引入酰胺基 - 喹啉基团的单环戊二烯基配体配位，以及制备使用该聚烯烃的聚烯烃的方法。本发明中使用的过渡金属催化剂化合物被配置成使得酰胺基通过亚苯基桥连接成环状。因此，稳定地维持过渡金属化合物的五角环结构，使得单体容易接近过渡金属化合物，反应性也高。因此，如果将根据本发明制备的用于烯烃聚合的负载型催化剂用于在浆料或气相方法中乙烯与具有大的空间位阻的单体的共聚合，则具有极性的直链，直链，高分子量的聚烯烃可以得到0.900〜0.970g / cc以下的低密度。

33. 发明申请

US20100062927A1 METHOD FOR PREPARING TRANSITION METAL COMPLEXES, TRANSITION METAL COMPLEXES PREPARE USING THE METHOD, CATALYTS COMPOSITION CONTAINING THE COMPLEXES 有权
标题翻译：制备过渡金属络合物的方法，使用该方法的过渡金属络合物的制备，包含复合物的催化剂组合物
公开(公告)号：US20100062927A1
公开(公告)日：2010-03-11
申请号：US12448825
申请日：2007-12-28
申请人： Choong-Hoon Lee , Eun-Jung Lee , Seung-Whan Jung , Jung-A Lee , Bo-Ram Lee , Bun-Yeoul Lee
发明人： Choong-Hoon Lee , Eun-Jung Lee , Seung-Whan Jung , Jung-A Lee , Bo-Ram Lee , Bun-Yeoul Lee
IPC分类号： B01J31/18 , C07F7/28 , C07F7/00
CPC分类号： C07F17/00 , C08F4/65908 , C08F2420/02 , Y02P20/55 , C08F210/16 , C08F210/08 , C08F2500/08 , C08F2500/12 , C08F4/6592
摘要： The present invention provides a novel transition metal complex where a monocy-clopentadienyl ligand to which an amido group is introduced is coordinated, a method for synthesizing the complex, and olefin polymerization using the same. The method for preparing a transition metal complex according to the present invention comprises a step of blocking a by-reaction of a nitrogen atom using a compound containing a protecting group, and thus it is possible to prepare a transition metal complex in a simpler manner in a high yield. Further, the transition metal complex according to the present invention has a pentagon ring structure having an amido group connected by a phenylene bridge in which a stable bond is formed in the vicinity of a metal site, and thus, sterically monomers can easily approach the transition metal complex. When a catalyst composition comprising the transition metal complex is applied in copoly-merization of ethylene and monomers having large steric hindrance, a very low density polyolefin copolymer having a density of less than 0.910 g/cc, in addition to a polyolefin having a high molecular weight and a linear low density, can be prepared. Furthermore, the reactivity is also very high.
摘要翻译：本发明提供了一种新型的过渡金属配合物，其中引入了酰氨基的单环氯苯二酮配体被配位，合成络合物的方法和使用它的烯烃聚合。本发明的过渡金属络合物的制造方法包括使用含有保护基的化合物阻断氮原子的副反应的工序，因此可以简单地制备过渡金属络合物高产量。此外，根据本发明的过渡金属络合物具有通过在金属部位附近形成稳定的键的亚苯基连接的酰胺基的五
元环结构，因此空间单体容易接近转变金属复合体。当包含过渡金属络合物的催化剂组合物被应用于乙烯和具有大的空间位阻的单体的共聚时，除了具有高分子量的聚烯烃之外，密度小于0.910g / cc的非常低密度的聚烯烃共聚物重量和线性低密度，可以制备。此外，反应性也非常高。

34. 发明授权

US07652159B2 Process for producing metallocene compound 失效
标题翻译：金属茂化合物的制备方法
公开(公告)号：US07652159B2
公开(公告)日：2010-01-26
申请号：US11660933
申请日：2005-07-11
申请人： Taichi Senda , Noriyuki Hida , Hidenori Hanaoka
发明人： Taichi Senda , Noriyuki Hida , Hidenori Hanaoka
IPC分类号： C07F7/00
CPC分类号： C07F17/00 , C08F10/00 , C08F2420/02 , C08F4/6592
摘要： The invention provides a process for producing a metallocene compound of formula (3) wherein R1 to R9 independently denote a hydrogen atom, a halogen atom, an alkyl, or the like; R10 denotes a halogen atom, an alkyl, an alkoxy, or the like; X5 and X6 independently denote a hydrogen atom, a halogen atom, or the like; and M denotes a transition metal atom of Group 4 of the Periodic Table, which process is characterized by reacting a silicon-substituted cyclopentadiene compound of formula (1) wherein R1 to R10 independently denote the same as described above; R11 denotes a hydrocarbon group or a tri-substituted silyl; and R12 to R14 independently denote a halogen atom or a hydrocarbon group, with a transition metal compound of the following formula (2) wherein M denotes the same as described above; X1, X2, X3, and X4 independently denotes a hydrogen atom, a halogen atom, an alkyl, or the like, in a solvent containing an aromatic hydrocarbon.
摘要翻译：本发明提供一种制备式（3）的茂金属化合物的方法，其中R 1至R 9独立地表示氢原子，卤素原子，烷基等; R 10表示卤素原子，烷基，烷氧基等; X 5和X 6独立地表示氢原子，卤素原子等; 并且M表示周期表第4族的过渡金属原子，该方法的特征在于使式（1）的硅取代的环戊二烯化合物（其中R 1至R 10独立地表示与上述相同的基团） R 11表示烃基或三取代甲硅烷基; 和R 12至R 14独立地表示卤素原子或烃基，与下式（2）的过渡金属化合物，其中M表示与上述相同的基团; X 1，X 2，X 3和X 4独立地表示在含有芳香族烃的溶剂中的氢原子，卤素原子，烷基等。

35. 发明申请

US20090286943A1 Process For Preparation Of Olefin Polymers 有权
标题翻译：烯烃聚合物的制备方法
公开(公告)号：US20090286943A1
公开(公告)日：2009-11-19
申请号：US12465055
申请日：2009-05-13
申请人： Don-Ho Kum , Eun-Jung Lee , Dong-Kyu Park , Choong-Hoon Lee , Jong-Joo Ha , Seung-Whan Jung , Jung-A Lee , Seong-Jin Kim
发明人： Don-Ho Kum , Eun-Jung Lee , Dong-Kyu Park , Choong-Hoon Lee , Jong-Joo Ha , Seung-Whan Jung , Jung-A Lee , Seong-Jin Kim
IPC分类号： C08F4/52 , C08F4/76
CPC分类号： C08F10/00 , C08F4/65908 , C08F4/65912 , C08F210/16 , C08F2420/02 , C08F4/6592 , C08F2/005 , C08F2/002 , C08F210/08 , C08F2500/08 , C08F2500/12
摘要： The present invention relates to a preparation method of olefin polymers using a catalyst composition containing a transition metal compound. In detail, the present invention provides a preparation method of olefin polymer using a catalyst composition comprising a transition metal compound, wherein the preparation method comprises introducing a scavenger to a continuous solution polymerization reactor in a specific range of amount to give the olefin polymer with good productivity.
摘要翻译：本发明涉及使用含有过渡金属化合物的催化剂组合物的烯烃聚合物的制备方法。详细地说，本发明提供了使用包含过渡金属化合物的催化剂组合物的烯烃聚合物的制备方法，其中所述制备方法包括在特定范围内将清除剂引入到连续溶液聚合反应器中以使烯烃聚合物具有良好的生产率。

36. 发明授权

US07579416B2 Catalyst system for olefin polymerization 有权
标题翻译：用于烯烃聚合的催化剂体系
公开(公告)号：US07579416B2
公开(公告)日：2009-08-25
申请号：US10583065
申请日：2004-12-22
申请人： Shahram Mihan
发明人： Shahram Mihan
IPC分类号： C08F4/22 , C08F4/69 , B01J31/34
CPC分类号： C08F10/00 , C08F4/6392 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F110/02 , C08F2420/02 , C08F4/025 , C08F4/69224 , C08F2500/17 , C08F2500/10 , C08F4/7042
摘要： The present invention relates to a catalyst system for olefin polymerization comprising an organic transition metal compound and, as cocatalyst, an ionic compound made up of anions of the formula (Ia), [Al(OR1)4]− (Ia) where the radicals R1 are identical or different and are each, independently of one another, a radical R2R3(CF3)2, R2 is a carbon or silicon atom and R3 is hydrogen, C1-C20-alkyl, C1-C20-fluoroalkyl, C6-C20-aryl, C6-C20-fluoroaryl, C7-C40-arylalkyl, C7-C40-fluoroarylalkyl, C7-C40-alkylaryl, C7-C40-fluoroalkylaryl or an SiR43 group, where R4 may be identical or different and is each C1-C20-alkyl, C1-C20-fluoroalkyl, C6-C20-aryl, C6-C20-fluoroaryl, C7-C40-arylalkyl, C7-C40-fluoroarylalkyl, C7-C40-alkylaryl or C7-C40-fluoroalkylaryl, and Lewis-acid cations or Brönsted acids as cations. In addition, the invention relates to the process for preparing such a catalyst system and to a process for the polymerization of olefins in which this catalyst system is used.
摘要翻译：本发明涉及一种用于烯烃聚合的催化剂体系，其包括有机过渡金属化合物和作为助催化剂的由式（Ia）的阴离子组成的离子化合物，<？在线配方描述=“在线式 “end =”lead“？> [Al（OR1）4] - （Ia）<？in-line-formula description =”In-line Formulas“end =”tail“？>其中基团R1相同或不同，各自独立地为基团R 2 R 3（CF 3）2，R 2为碳原子或硅原子，R 3为氢，C 1 -C 20 - 烷基，C 1 -C 20 - 氟代烷基，C 6 -C 20 - 芳基，C 6 -C 20 - 氟代芳基，C 7 -C 40 - 芳基烷基，C 7 -C 40 - 氟芳基烷基，C 7 -C 40 - 烷基芳基，C 7 -C 40 - 氟烷基芳基或SiR 43基团，其中R 4可以相同或不同，并且各自为C 1 -C 20烷基，氟代烷基，C 6 -C 20 - 芳基，C 6 -C 20 - 氟代芳基，C 7 -C 40 - 芳基烷基，C 7 -C 40 - 氟芳基烷基，C 7 -C 40 - 烷基芳基或C 7 -C 40 - 氟烷基芳基，和路易斯酸阳离子或布朗斯台德酸作为阳离子。此外，本发明涉及制备这种催化剂体系的方法以及使用该催化剂体系的烯烃聚合方法。

37. 发明授权

US07531608B2 Transition metal complexes, catalyst compositions containing the same, and olefin polymerization using the catalyst compositions 有权
标题翻译：过渡金属络合物，含有它们的催化剂组合物和使用催化剂组合物的烯烃聚合
公开(公告)号：US07531608B2
公开(公告)日：2009-05-12
申请号：US11483754
申请日：2006-07-10
申请人： Choong Hoon Lee , Eun Jung Lee , Seungwhan Jung , Jong Joo Ha , Beomdoo Seo , Bun Yeoul Lee , Ui Gab Joung , Dae June Joe
发明人： Choong Hoon Lee , Eun Jung Lee , Seungwhan Jung , Jong Joo Ha , Beomdoo Seo , Bun Yeoul Lee , Ui Gab Joung , Dae June Joe
IPC分类号： C08F4/42 , C07F7/28
CPC分类号： C07F17/00 , C08F2420/02 , Y10S526/943
摘要： Provided are a novel transition metal complex where a monocyclopentadienyl ligand to which an amine-based group is introduced is coordinated, a method of synthesizing the same, and olefin polymerization using the transition metal complex In the novel transition metal complex, an imino phenyl group is not cross-linked to a metal atom and directly introduced to a cyclopentadiene (Cp) ring. The catalyst composition including the transition metal compound is used to obtain a polyolefin copolymer having a very low density less than 0.910 g/cc.
摘要翻译：提供了一种新的过渡金属络合物，其中引入了胺基的单环戊二烯基配体被配位，其合成方法和使用过渡金属络合物的烯烃聚合在新的过渡金属络合物中，亚氨基苯基是不与金属原子交联并直接引入环戊二烯（Cp）环。包括过渡金属化合物的催化剂组合物用于获得密度小于0.910g / cc的非常低的聚烯烃共聚物。

38. 发明申请

US20080161514A1 Transition Metal Complex, Process For Producing Said Transition Metal Complex, Substituent-Carrying Fluorene Compound, Process For Producing Said Fluorene Compound, Catalyst Component For Olefin Polymerization, Catalyst For Olefin Polymerization, and Process For Producing Olefin Polymer 失效
公开(公告)号：US20080161514A1
公开(公告)日：2008-07-03
申请号：US11795967
申请日：2006-01-24
申请人： Taichi Senda , Hidenori Hanaoka , Shinya Nakahara , Kenji Sogoh
发明人： Taichi Senda , Hidenori Hanaoka , Shinya Nakahara , Kenji Sogoh
IPC分类号： C07F7/08 , C07F7/28 , C07F7/30 , C08F10/00 , B01J31/22
CPC分类号： C08F10/00 , B01J31/2295 , C07F17/00 , C08F4/65908 , C08F4/65912 , C08F10/02 , C08F210/02 , C08F210/16 , C08F2420/02 , Y10S526/941 , Y10S526/943 , C08F4/659 , C08F4/6592 , C08F232/00 , C08F2500/17 , C08F2500/25 , C08F210/14
摘要： A transition metal complex represented by the general formula [1]; a catalyst component for olefin polymerization comprising said transition metal complex; a catalyst for olefin polymerization using said transition metal complex as a catalyst component for olefin polymerization; a process for producing an olefin polymer comprising the step of polymerizing an olefin in the presence of said catalyst for olefin polymerization; a substituent-carrying fluorene compound; a process for producing said substituent-carrying fluorene compound; and a process for producing said transition metal complex using said substituent-carrying fluorene compound: wherein M is the group 4 transition metal atom in the periodic table of elements; A is the group 16 atom therein; J is the group 14 atom therein; R1, R2, R3, R4, R5, R6, X1 and X2 are independently of one another (1) a substituent selected from the group consisting of (1-1) an alkyl group having 1 to 20 carbon atoms, which may be substituted by a halogen atom, (1-2) an aralkyl group having 7 to 20 carbon atoms, which may be substituted by a halogen atom, (1-3) an aryl group having 6 to 20 carbon atoms, which may be substituted by a halogen atom, (1-4) a substituent-carrying silyl group having 1 to 20 carbon atoms, which substituent is a hydrocarbyl group, and said hydrocarbyl group may be substituted by a halogen atom, (1-5) a disubstituent-carrying amino group having 2 to 20 carbon atoms, which substituent is a hydrocarbyl group, and said hydrocarbyl group may be substituted by a halogen atom, (1-6) an alkoxy group having 1 to 20 carbon atoms, which may be substituted by a halogen atom, (1-7) an aralkyloxy group having 7 to 20 carbon atoms, which may be substituted by a halogen atom, and (1-8) an aryloxy group having 6 to 20 carbon atoms, which may be substituted by a halogen atom, (2) a halogen atom or (3) a hydrogen atom; R1 and R2, R2 and R3, and R3 and R4 may be linked to each other, respectively, to form respective rings; R5 and R6 may be linked to each other to form a ring; R7, R8, R9 and R10 are independently of one another (1) a substituent selected from the group consisting of (1-1) an alkyl group having 1 to 20 carbon atoms, which may be substituted by a halogen atom, (1-2) an aralkyl group having 7 to 20 carbon atoms, which may be substituted by a halogen atom, (1-3) an aryl group having 6 to 20 carbon atoms, which may be substituted by a halogen atom, (1-4) a substituent-carrying silyl group having 1 to 20 carbon atoms, which substituent is a hydrocarbyl group, and said hydrocarbyl group may be substituted by a halogen atom, (1-5) a disubstituent-carrying amino group having 2 to 20 carbon atoms, which substituent is a hydrocarbyl group, and said hydrocarbyl group may be substituted by a halogen atom, (1-6) an alkoxy group having 1 to 20 carbon atoms, which may be substituted by a halogen atom, (1-7) an aralkyloxy group having 7 to 20 carbon atoms, which may be substituted by a halogen atom, and (1-8) an aryloxy group having 6 to 20 carbon atoms, which may be substituted by a halogen atom, (2) a halogen atom or (3) a hydrogen atom; at least two of R7, R8, R9 and R10 are the substituent selected from the above-mentioned group or a halogen atom; R7 and R8 may be linked to each other to form a ring; and R9 and R10 may be linked to each other to form a ring.

39. 发明申请

US20070179046A1 CATALYST COMPOSITION INCLUDING TRANSITION METAL COMPLEXES AND OLEFIN POLYMERIZATION USING THE SAME 有权
标题翻译：催化剂组合物，包括过渡金属络合物和使用其的烯烃聚合
公开(公告)号：US20070179046A1
公开(公告)日：2007-08-02
申请号：US11670259
申请日：2007-02-01
申请人： Eunjung LEE , Choong Hoon LEE , Seungwhan JUNG , Jung A LEE , Boram LEE
发明人： Eunjung LEE , Choong Hoon LEE , Seungwhan JUNG , Jung A LEE , Boram LEE
IPC分类号： C08F4/02
CPC分类号： C08F10/00 , C08F4/65908 , C08F4/65912 , C08F210/16 , C08F2410/03 , C08F2420/02 , Y10S526/943 , C08F4/6592 , C08F4/65904 , C08F210/14 , C08F2500/12 , C08F2500/08
摘要： Provided is catalyst composition including a transition metal complex precatalyst represented by Formula 1; a first cocatalyst represented by Formula 2 which is an alkylaluminum compound; and a second cocatalyst represented by Formula 3 which is a salt compound comprising a Bronsted acid cation and a noncoordinating, compatible anion. Here, R1, R2, R3, R4, E, Q1, Q2 and M are defined in the specification. Al(R6)3 Formula 2 Here, R6 is defined in the specification. [L-H]+[ZA4]− Here, L, [L-H]+, Z and A are defined in the specification.A catalyst composition including binuclear transition metal complexes, an alkylaluminum compound, and a salt compound including a Bronsted acid cation, and a noncoordinating, compatible anion, and a method of preparing the catalyst composition are provided. The activity of the catalyst composition has been improved. The catalyst composition can be effectively used for copolymerization of ethylene with monomers having structural inherence, and a polyolefin copolymer having a very low density less than 0.910 g/cc can be obtained by using the catalyst composition.
摘要翻译：提供了包含式1表示的过渡金属络合物预催化剂的催化剂组合物; 由式2表示的作为烷基铝化合物的第一助催化剂; 和由式3表示的第二助催化剂，其是包含布朗斯台德酸阳离子和非配位的相容阴离子的盐化合物。这里，R 1，R 2，R 3，R 4，E，Q 1， / SUB>，Q 2和M在说明书中定义。 <？in-line-formula description =“In-line formula”end =“lead”？> Al（R 6）3式2 < 公式描述=“在线公式”end =“tail”？>这里，在说明书中定义了R 6。 <？in-line-formula description =“In-line Formulas”end =“lead”？> [LH] ^{+ [ZA SUP> <？in-line-formula description =“In-line Formulas”end =“tail”？>这里，L，[LH] +，Z和A在本说明书中定义。提供了包含双核过渡金属配合物，烷基铝化合物和包含布朗斯台德酸阳离子和非配位相容性阴离子的盐化合物的催化剂组合物和制备该催化剂组合物的方法。催化剂组合物的活性得到改善。催化剂组合物可以有效地用于乙烯与具有结构相干性的单体的共聚，并且通过使用催化剂组合物可以获得具有非常低的密度小于0.910g / cc的聚烯烃共聚物。}

40. 发明申请

US20070135623A1 Halogen substituted heteroatom-containing metallocene compounds for olefin polymerization 有权
标题翻译：用于烯烃聚合的卤素取代的含杂原子的茂金属化合物
公开(公告)号：US20070135623A1
公开(公告)日：2007-06-14
申请号：US11300240
申请日：2005-12-14
申请人： Alexander Voskoboynikov , Alexey Ryabov , Mikhail Nikulin , Alexander Lygin , Dmitry Uborsky , Catalina Coker , Jo Ann Canich
发明人： Alexander Voskoboynikov , Alexey Ryabov , Mikhail Nikulin , Alexander Lygin , Dmitry Uborsky , Catalina Coker , Jo Ann Canich
IPC分类号： C07F17/00
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65925 , C08F2420/02 , C08F2420/06 , Y10S526/943 , C08F4/65927 , C08F4/6592 , C08F110/06 , C08F2500/02 , C08F2500/03 , C08F210/16 , C08F210/14 , C08F110/02
摘要： Halogen substituted metallocene compounds are described and comprise one or more monocyclic or polycyclic ligands that are pi-bonded to the metal atom and include at least one halogen substituent directly bonded to an sp2 carbon atom at a bondable ring position of the ligand, wherein the or at least one ligand has one or more ring heteroatoms in its cyclic structure. When combined with a suitable activator, these compounds show activity in the polymerization of olefins, such as ethylene and propylene.
摘要翻译：描述了卤素取代的茂金属化合物，并且包含一个或多个单键或多环配位体，其与金属原子键合，并且包含至少一个与可结合环上的sp 2碳原子键合的卤素取代基配体的位置，其中所述或至少一个配体在其环状结构中具有一个或多个环杂原子。当与合适的活化剂组合时，这些化合物在烯烃如乙烯和丙烯的聚合中显示出活性。

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