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1. 发明申请

US20090286943A1 Process For Preparation Of Olefin Polymers 有权
标题翻译：烯烃聚合物的制备方法
公开(公告)号：US20090286943A1
公开(公告)日：2009-11-19
申请号：US12465055
申请日：2009-05-13
申请人： Don-Ho Kum , Eun-Jung Lee , Dong-Kyu Park , Choong-Hoon Lee , Jong-Joo Ha , Seung-Whan Jung , Jung-A Lee , Seong-Jin Kim
发明人： Don-Ho Kum , Eun-Jung Lee , Dong-Kyu Park , Choong-Hoon Lee , Jong-Joo Ha , Seung-Whan Jung , Jung-A Lee , Seong-Jin Kim
IPC分类号： C08F4/52 , C08F4/76
CPC分类号： C08F10/00 , C08F4/65908 , C08F4/65912 , C08F210/16 , C08F2420/02 , C08F4/6592 , C08F2/005 , C08F2/002 , C08F210/08 , C08F2500/08 , C08F2500/12
摘要： The present invention relates to a preparation method of olefin polymers using a catalyst composition containing a transition metal compound. In detail, the present invention provides a preparation method of olefin polymer using a catalyst composition comprising a transition metal compound, wherein the preparation method comprises introducing a scavenger to a continuous solution polymerization reactor in a specific range of amount to give the olefin polymer with good productivity.
摘要翻译：本发明涉及使用含有过渡金属化合物的催化剂组合物的烯烃聚合物的制备方法。详细地说，本发明提供了使用包含过渡金属化合物的催化剂组合物的烯烃聚合物的制备方法，其中所述制备方法包括在特定范围内将清除剂引入到连续溶液聚合反应器中以使烯烃聚合物具有良好的生产率。

2. 发明授权

US08946362B2 Process for preparation of olefin polymers 有权
标题翻译：制备烯烃聚合物的方法
公开(公告)号：US08946362B2
公开(公告)日：2015-02-03
申请号：US12465055
申请日：2009-05-13
申请人： Don-Ho Kum , Eun-Jung Lee , Dong-Kyu Park , Choong-Hoon Lee , Jong-Joo Ha , Seung-Whan Jung , Jung-A Lee , Seong-Jin Kim
发明人： Don-Ho Kum , Eun-Jung Lee , Dong-Kyu Park , Choong-Hoon Lee , Jong-Joo Ha , Seung-Whan Jung , Jung-A Lee , Seong-Jin Kim
IPC分类号： C08F4/52 , C08F4/64 , C08F4/76
CPC分类号： C08F10/00 , C08F4/65908 , C08F4/65912 , C08F210/16 , C08F2420/02 , C08F4/6592 , C08F2/005 , C08F2/002 , C08F210/08 , C08F2500/08 , C08F2500/12
摘要： The present invention relates to a preparation method of olefin polymers using a catalyst composition containing a transition metal compound. In detail, the present invention provides a preparation method of olefin polymer using a catalyst composition comprising a transition metal compound, wherein the preparation method comprises introducing a scavenger to a continuous solution polymerization reactor in a specific range of amount to give the olefin polymer with good productivity.
摘要翻译：本发明涉及使用含有过渡金属化合物的催化剂组合物的烯烃聚合物的制备方法。详细地说，本发明提供了使用包含过渡金属化合物的催化剂组合物的烯烃聚合物的制备方法，其中所述制备方法包括在特定范围内将清除剂引入到连续溶液聚合反应器中以使烯烃聚合物具有良好的生产率。

3. 发明授权

US08513369B2 Long chain-branched ethylene-alpha olefin copolymer 有权
标题翻译：长链支化乙烯-α-烯烃共聚物
公开(公告)号：US08513369B2
公开(公告)日：2013-08-20
申请号：US12600328
申请日：2008-05-16
申请人： Choong-Hoon Lee , Byung-Kwon Lim , Eun-Jung Lee , Jong-Joo Ha , Seung-Whan Jung , Jung-A Lee , Ki-Su Ro , Don-Ho Kum , Dong-Kyu Park
发明人： Choong-Hoon Lee , Byung-Kwon Lim , Eun-Jung Lee , Jong-Joo Ha , Seung-Whan Jung , Jung-A Lee , Ki-Su Ro , Don-Ho Kum , Dong-Kyu Park
IPC分类号： C08F210/08 , C08F210/02
CPC分类号： C08F4/76 , C08F4/65908 , C08F4/65912 , C08F210/16 , C08F2420/02 , C08F4/6592 , C08F2/06 , C08F210/08 , C08F2500/09 , C08F2500/03 , C08F2500/12 , C08F2500/08
摘要： The present invention relates to an ethylene-alpha olefin copolymer comprising long chain branches (LCB), while having a narrow molecular weight distribution. The ethylene-alpha olefin copolymer can be prepared by a continuous solution polymerization process using an activated catalyst composition containing a Group 4 transition metal compound having a monocyclopentadienyl ligand, to which a quinoline amino group is introduced.
摘要翻译：本发明涉及包含长链分支（LCB）的乙烯-α烯烃共聚物，同时具有窄的分子量分布。乙烯-α-烯烃共聚物可以通过使用含有引入喹啉氨基的具有单环戊二烯基配体的第4族过渡金属化合物的活化催化剂组合物的连续溶液聚合方法制备。

4. 发明申请

US20100179291A1 LONG CHAIN-BRANCHED ETHYLENE-ALPHA OLEFIN COPOLYMER 有权
标题翻译：长链分支乙烯 - 丙烯烯烃共聚物
公开(公告)号：US20100179291A1
公开(公告)日：2010-07-15
申请号：US12600328
申请日：2008-05-16
申请人： Choong-Hoon Lee , Byung-Kwon Lim , Eun-Jung Lee , Jong-Joo Ha , Seung-Whan Jung , Jung-A Lee , Ki-Su Ro , Don-Ho Kum , Dong-Kyu Park
发明人： Choong-Hoon Lee , Byung-Kwon Lim , Eun-Jung Lee , Jong-Joo Ha , Seung-Whan Jung , Jung-A Lee , Ki-Su Ro , Don-Ho Kum , Dong-Kyu Park
IPC分类号： C08F4/78 , C08F210/02
CPC分类号： C08F4/76 , C08F4/65908 , C08F4/65912 , C08F210/16 , C08F2420/02 , C08F4/6592 , C08F2/06 , C08F210/08 , C08F2500/09 , C08F2500/03 , C08F2500/12 , C08F2500/08
摘要： The present invention relates to an ethylene-alpha olefin copolymer comprising long chain branches (LCB), while having a narrow molecular weight distribution. The ethylene-alpha olefin copolymer can be prepared by a continuous solution polymerization process using an activated catalyst composition containing a Group 4 transition metal compound having a monocyclopentadienyl ligand, to which a quinoline amino group is introduced.
摘要翻译：本发明涉及包含长链分支（LCB）的乙烯-α烯烃共聚物，同时具有窄的分子量分布。乙烯-α-烯烃共聚物可以通过使用含有引入喹啉氨基的具有单环戊二烯基配体的第4族过渡金属化合物的活化催化剂组合物的连续溶液聚合方法制备。

5. 发明申请

US20100062927A1 METHOD FOR PREPARING TRANSITION METAL COMPLEXES, TRANSITION METAL COMPLEXES PREPARE USING THE METHOD, CATALYTS COMPOSITION CONTAINING THE COMPLEXES 有权
标题翻译：制备过渡金属络合物的方法，使用该方法的过渡金属络合物的制备，包含复合物的催化剂组合物
公开(公告)号：US20100062927A1
公开(公告)日：2010-03-11
申请号：US12448825
申请日：2007-12-28
申请人： Choong-Hoon Lee , Eun-Jung Lee , Seung-Whan Jung , Jung-A Lee , Bo-Ram Lee , Bun-Yeoul Lee
发明人： Choong-Hoon Lee , Eun-Jung Lee , Seung-Whan Jung , Jung-A Lee , Bo-Ram Lee , Bun-Yeoul Lee
IPC分类号： B01J31/18 , C07F7/28 , C07F7/00
CPC分类号： C07F17/00 , C08F4/65908 , C08F2420/02 , Y02P20/55 , C08F210/16 , C08F210/08 , C08F2500/08 , C08F2500/12 , C08F4/6592
摘要： The present invention provides a novel transition metal complex where a monocy-clopentadienyl ligand to which an amido group is introduced is coordinated, a method for synthesizing the complex, and olefin polymerization using the same. The method for preparing a transition metal complex according to the present invention comprises a step of blocking a by-reaction of a nitrogen atom using a compound containing a protecting group, and thus it is possible to prepare a transition metal complex in a simpler manner in a high yield. Further, the transition metal complex according to the present invention has a pentagon ring structure having an amido group connected by a phenylene bridge in which a stable bond is formed in the vicinity of a metal site, and thus, sterically monomers can easily approach the transition metal complex. When a catalyst composition comprising the transition metal complex is applied in copoly-merization of ethylene and monomers having large steric hindrance, a very low density polyolefin copolymer having a density of less than 0.910 g/cc, in addition to a polyolefin having a high molecular weight and a linear low density, can be prepared. Furthermore, the reactivity is also very high.
摘要翻译：本发明提供了一种新型的过渡金属配合物，其中引入了酰氨基的单环氯苯二酮配体被配位，合成络合物的方法和使用它的烯烃聚合。本发明的过渡金属络合物的制造方法包括使用含有保护基的化合物阻断氮原子的副反应的工序，因此可以简单地制备过渡金属络合物高产量。此外，根据本发明的过渡金属络合物具有通过在金属部位附近形成稳定的键的亚苯基连接的酰胺基的五
元环结构，因此空间单体容易接近转变金属复合体。当包含过渡金属络合物的催化剂组合物被应用于乙烯和具有大的空间位阻的单体的共聚时，除了具有高分子量的聚烯烃之外，密度小于0.910g / cc的非常低密度的聚烯烃共聚物重量和线性低密度，可以制备。此外，反应性也非常高。

6. 发明授权

US07932207B2 Method for preparing transition metal complexes, transition metal complexes prepared using the method, catalyst composition containing the complexes 有权
标题翻译：制备过渡金属络合物的方法，使用该方法制备的过渡金属络合物，含有络合物的催化剂组合物
公开(公告)号：US07932207B2
公开(公告)日：2011-04-26
申请号：US12448825
申请日：2007-12-28
申请人： Choong-Hoon Lee , Eun-Jung Lee , Seung-Whan Jung , Jung-A Lee , Bo-Ram Lee , Bun-Yeoul Lee
发明人： Choong-Hoon Lee , Eun-Jung Lee , Seung-Whan Jung , Jung-A Lee , Bo-Ram Lee , Bun-Yeoul Lee
IPC分类号： B01J31/18 , C07F7/28 , C07F7/00
CPC分类号： C07F17/00 , C08F4/65908 , C08F2420/02 , Y02P20/55 , C08F210/16 , C08F210/08 , C08F2500/08 , C08F2500/12 , C08F4/6592
摘要： The present invention provides a novel transition metal complex where a monocyclopentadienyl ligand to which an amido group is introduced is coordinated, a method for synthesizing the complex, and olefin polymerization using the same. The method for preparing a transition metal complex according to the present invention comprises a step of blocking a by-reaction of a nitrogen atom using a compound containing a protecting group, and thus it is possible to prepare a transition metal complex in a simpler manner in a high yield. Further, the transition metal complex according to the present invention has a pentagon ring structure having an amido group connected by a phenylene bridge in which a stable bond is formed in the vicinity of a metal site, and thus, sterically monomers can easily approach the transition metal complex.
摘要翻译：本发明提供了一种新的过渡金属配合物，其中引入了酰胺基的单环戊二烯基配位体，合成络合物的方法和使用其的烯烃聚合。本发明的过渡金属络合物的制造方法包括使用含有保护基的化合物阻断氮原子的副反应的工序，因此可以简单地制备过渡金属络合物高产量。此外，根据本发明的过渡金属络合物具有通过在金属部位附近形成稳定的键的亚苯基连接的酰胺基的五
元环结构，因此空间单体容易接近转变金属复合体。

7. 发明授权

US07678933B2 Transition metal complexes and preparation methods thereof 有权
标题翻译：过渡金属络合物及其制备方法
公开(公告)号：US07678933B2
公开(公告)日：2010-03-16
申请号：US12087215
申请日：2006-12-29
申请人： Choong-Hoon Lee , Eun-Jung Lee , Seung-Whan Jung , Jung-A Lee , Bo-Ram Lee , Bun-Yeoul Lee
发明人： Choong-Hoon Lee , Eun-Jung Lee , Seung-Whan Jung , Jung-A Lee , Bo-Ram Lee , Bun-Yeoul Lee
IPC分类号： C07F7/00 , C07C211/00 , C07C49/00
CPC分类号： C07F17/00 , C08F4/65908 , C08F210/16 , C08F2410/03 , C08F2420/02 , Y10S526/943 , C08F4/6592 , C08F210/14
摘要： The present invention provides a novel mononuclear transition metal compound, a novel binuclear transition metal compound, a novel organic amine or phosphorous compound, and a method for preparing the same. The mononuclear transition metal compound according to the present invention is configured such that a cyclopentadienyl group and an amido or phosphorous group are bridged via a phenylene bridge. The binuclear transition metal compound according to the present invention is configured such that the two bridged mononuclear transition metal compounds configured such that a cyclopentadienyl group and an amido or phosphorous group are bridged via a phenylene bridge are linked via a bridging group located at the phenylene bridge. According to the present invention, the mononuclear transition metal compound, the binuclear transition metal compound, the organic amine or phosphorous compound can be prepared in a simple manner by using suzuki-coupling reaction with a high yield.
摘要翻译：本发明提供新颖的单核过渡金属化合物，新型双核过渡金属化合物，新型有机胺或磷化合物及其制备方法。根据本发明的单核过渡金属化合物被配置为使得环戊二烯基和酰氨基或磷基通过亚苯桥桥连。根据本发明的双核过渡金属化合物被配置为使得配置成使得环戊二烯基和酰氨基或磷基经由亚苯桥桥连的两个桥连单核过渡金属化合物通过位于亚苯桥的桥连基团连接。根据本发明，单体过渡金属化合物，双核过渡金属化合物，有机胺或磷化合物可以通过以高产率使用Suzuki偶联反应简单地制备。

8. 发明申请

US20090030221A1 Transition Metal Complexes and Preparation Methods Thereof 有权
标题翻译：过渡金属络合物及其制备方法
公开(公告)号：US20090030221A1
公开(公告)日：2009-01-29
申请号：US12087215
申请日：2006-12-29
申请人： Choong-Hoon Lee , Eun-Jung Lee , Seung-Whan Jung , Jung-A Lee , Bo-Ram Lee , Bun-Yeoul Lee
发明人： Choong-Hoon Lee , Eun-Jung Lee , Seung-Whan Jung , Jung-A Lee , Bo-Ram Lee , Bun-Yeoul Lee
IPC分类号： C07F7/28 , C07C49/00 , C07C211/44
CPC分类号： C07F17/00 , C08F4/65908 , C08F210/16 , C08F2410/03 , C08F2420/02 , Y10S526/943 , C08F4/6592 , C08F210/14
摘要： The present invention provides a novel mononuclear transition metal compound, a novel binuclear transition metal compound, a novel organic amine or phosphorous compound, and a method for preparing the same. The mononuclear transition metal compound according to the present invention is configured such that a cyclopentadienyl group and an amido or phosphorous group are bridged via a phenylene bridge. The binuclear transition metal compound according to the present invention is configured such that the two bridged mononuclear transition metal compounds configured such that a cyclopentadienyl group and an amido or phosphorous group are bridged via a phenylene bridge are linked via a bridging group located at the phenylene bridge. According to the present invention, the mononuclear transition metal compound, the binuclear transition metal compound, the organic amine or phosphorous compound can be prepared in a simple manner by using suzuki-coupling reaction with a high yield.
摘要翻译：本发明提供新颖的单核过渡金属化合物，新型双核过渡金属化合物，新型有机胺或磷化合物及其制备方法。根据本发明的单核过渡金属化合物被配置为使得环戊二烯基和酰氨基或磷基通过亚苯桥桥连。根据本发明的双核过渡金属化合物被配置为使得配置成使得环戊二烯基和酰氨基或磷基经由亚苯桥桥连的两个桥连单核过渡金属化合物通过位于亚苯桥的桥连基团连接。根据本发明，单体过渡金属化合物，双核过渡金属化合物，有机胺或磷化合物可以通过以高产率使用偶联偶联反应以简单的方式制备。

9. 发明授权

US07972987B2 Fourth group transition metal compound having cyclopentadienyl ligand, method of preparing compound, and method of preparing olefin polymer using compound 有权
标题翻译：具有环戊二烯基配体的第四组过渡金属化合物，制备化合物的方法，以及使用化合物制备烯烃聚合物的方法
公开(公告)号：US07972987B2
公开(公告)日：2011-07-05
申请号：US12527091
申请日：2008-02-13
申请人： Jung-A Lee , Bo-Ram Lee , Eun-Jung Lee , Seung-Whan Jung , Choong-Hoon Lee
发明人： Jung-A Lee , Bo-Ram Lee , Eun-Jung Lee , Seung-Whan Jung , Choong-Hoon Lee
IPC分类号： C07F17/00 , B01J31/18 , B01J31/22 , C08F4/6592
CPC分类号： C07F17/00 , C08F4/65908 , C08F2420/03 , Y10S526/943 , C08F210/16 , C08F210/08 , C08F2500/08 , C08F2500/12 , C08F4/6592
摘要： The present invention relates to a novel cyclopentadienyl compound, a fourth group transition metal compound having the cyclopentadienyl compound, a method of preparing the fourth group transition metal compound, a method of preparing an olefin polymer by using the fourth group transition metal compound, and an olefin polymer prepared by using the method.
摘要翻译：本发明涉及新的环戊二烯基化合物，具有环戊二烯基化合物的第四组过渡金属化合物，制备第四组过渡金属化合物的方法，使用第四族过渡金属化合物制备烯烃聚合物的方法，以及烯烃聚合物通过使用该方法制备。

10. 发明授权

US07807762B2 Catalyst composition comprising Group 4 transition metal complexes and method for preparing polyolefins using the same 有权
标题翻译：包含第4族过渡金属络合物的催化剂组合物和使用其制备聚烯烃的方法
公开(公告)号：US07807762B2
公开(公告)日：2010-10-05
申请号：US12087216
申请日：2006-12-29
申请人： Choong-Hoon Lee , Eun-Jung Lee , Seung-Whan Jung , Jung-A Lee , Bo-Ram Lee , Bun-Yeoul Lee
发明人： Choong-Hoon Lee , Eun-Jung Lee , Seung-Whan Jung , Jung-A Lee , Bo-Ram Lee , Bun-Yeoul Lee
IPC分类号： C08F4/64 , C08F4/6592 , B01J31/22
CPC分类号： C07F17/00 , C08F4/65908 , C08F210/16 , C08F2410/03 , C08F2420/02 , Y10S526/943 , C08F4/6592 , C08F210/14
摘要： The present invention relates to a catalyst composition comprising a novel structure of a Group 4 transition metal compound, to a method for preparing the same, and to a method for preparing a polyolefin using the catalyst composition. The method for preparing a polyolefin according to the present invention can be used for preparing a polyolefin having a high molecular weight and high copolymerizability with a high activity even at a high polymerization temperature and for preparing a polyolefin having a double composition distribution.
摘要翻译：本发明涉及包含第4族过渡金属化合物的新结构的催化剂组合物及其制备方法，以及使用该催化剂组合物制备聚烯烃的方法。根据本发明的聚烯烃的制备方法可以用于制备具有高分子量和高共聚性的聚烯烃，即使在高聚合温度下也具有高活性，并且用于制备具有双组分分布的聚烯烃。

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