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31. 发明申请

US20070185290A1 Norbornene ring-opened polymer hydrogenated product and process for producing same 有权
标题翻译：降冰片烯开环聚合物氢化产物及其制备方法
公开(公告)号：US20070185290A1
公开(公告)日：2007-08-09
申请号：US10567964
申请日：2004-08-12
申请人： Shigetaka Hayano , Yasuo Tsunogae
发明人： Shigetaka Hayano , Yasuo Tsunogae
IPC分类号： C08F4/06
CPC分类号： C08G61/06 , C08G61/08 , C08G2261/3324 , C08G2261/3325 , C08G2261/418
摘要： A norbornene ring-opened polymer hydrogenated product having a syndiotactic structure and a process for producing the same are disclosed. The ring-opened polymer hydrogenated product contains a repeating unit originating from a polycyclic norbornene monomer with three or more rings in the polymer repeating units, having a weight average molecular weight of 500 to 1,000,000, and having a racemo diad proportion of 51% or more. The process comprises a step of polymerizing a polycyclic norbornene monomer having three or more rings by solution polymerization using a group 6 transition metal compound with a hydroxyl group-containing aryloxy group or the like bonded thereto as a polymerization catalyst to obtain a ring-opened polymer and a step of hydrogenating double bonds in the main chain of the ring-opened polymer.
摘要翻译：公开了具有间同立构结构的降冰片烯开环聚合物氢化物及其制造方法。开环聚合物氢化物含有在聚合物重复单元中具有三个以上环的多环降冰片烯单体的重复单元，其重均分子量为500〜1,000,000，并且具有51％以上的摩尔二烯比例。该方法包括通过溶液聚合将具有三个或更多个环的多环降冰片烯单体用作为聚合催化剂的含有含羟基的芳氧基等的第六族过渡金属化合物聚合，得到开环聚合物以及在开环聚合物的主链中氢化双键的步骤。

32. 发明授权

US07037993B2 Norbornene-based ring-opening polymerization polymer, product of hydrogenation of norbornene-based ring-opening polymerization polymer, and processes for producing these 有权
标题翻译：基于降冰片烯的开环聚合聚合物，降冰片烯类开环聚合聚合物的氢化产物及其制备方法
公开(公告)号：US07037993B2
公开(公告)日：2006-05-02
申请号：US10510513
申请日：2003-04-07
申请人： Kazunori Taguchi , Seiji Okada , Yasuo Tsunogae
发明人： Kazunori Taguchi , Seiji Okada , Yasuo Tsunogae
IPC分类号： C08G61/06
CPC分类号： C08G61/08 , C08G61/06
摘要： A norbornene ring-opened polymer which in the molecule has repeating units represented by the formula (1): wherein R1 represents Q, R2 represents Q or C(═O)R5, R3 represents Q or C(═O)R6, and R4 represents Q or X—C(═O)R7 (wherein Q represents hydrogen, a C1-10 hydrocarbon group, etc.; R5, R6 and R7 each represents hydroxyl, C1-10 alkoxyl, etc., provided that R6 and R7 may be bonded to each other to constitute oxygen, NH, etc.; X represents methylene, etc., provided that when R2 is Q, then R3 is C(═O)R6 and R4 is X—C(═O)R7 and that when R4 is Q, then R2 is C(═O)R5, R3 is C(═O)R6, and the configuration of R2 and R3 is trans, and m is 0 or 1), the polymer having a weight-average molecular weight as determined by gel permeation chromatography of 1,000 to 1,000,000. Also provided is a hydrogenation product of the norbornene ring-opened polymer. The norbornene ring-opened polymer and the hydrogenation product are excellent in heat resistance, electrical properties, etc.
摘要翻译：分子中具有由式（1）表示的重复单元的降冰片烯开环聚合物：其中R 1表示Q，R 2表示Q或C（-O ）R 5，R 3表示Q或C（-O）R 6，R 4表示Q 或XC（-O）R 7（其中Q表示氢，C 1-10烃基等; R 5，R R 6和R 7各自表示羟基，C 1-10烷氧基等，条件是R 6和 R 7可以彼此键合以构成氧，NH等; X表示亚甲基等，条件是当R 2为Q时，则R 0 > 3 是C（-O）R 6和R 4是XC（-O）R 7，当R 4是Q，则R 2是C（-O）R 5，R 3是C（ - O）R 6，R 2和R 3的构型为反式，m为0或1），所述聚合物具有重量平均分子量 d通过凝胶渗透色谱法为1,000至1,000,000。还提供了降冰片烯开环聚合物的氢化产物。降冰片烯开环聚合物和氢化产物的耐热性，电性能等优异。

33. 发明授权

US06995226B2 Open-ring copolymer, hydrogenated open-ring copolymer, process for production of both, and compositions 有权
标题翻译：开环共聚物，氢化开环共聚物，二者的生产方法和组合物
公开(公告)号：US06995226B2
公开(公告)日：2006-02-07
申请号：US10480002
申请日：2002-06-05
申请人： Kazunori Taguchi , Yasuo Tsunogae , Hitomi Takeuchi , Yasuhiro Wakisaka , Kei Sakamoto
发明人： Kazunori Taguchi , Yasuo Tsunogae , Hitomi Takeuchi , Yasuhiro Wakisaka , Kei Sakamoto
IPC分类号： C08G61/08
CPC分类号： C08G61/06
摘要： A ring-opened metathesis copolymer and its hydrogenated product having a desired monomer unit ratio and a high molecular weight and having hydroxyl groups or hydroxycarbonyl groups can be obtained by conducting a ring-opening metathesis copolymerization of a norbornene-type monomer having hydroxyl groups or hydroxycarbonyl groups with an unsubstituted norbornene-type monomer having at least three rings in the presence of a catalyst predominantly comprised of an organic ruthenium compound having coordinated therewith a neutral electron-donating ligand, and, if desired, hydrogenating the resulting copolymer. The thus-obtained ring-opened metathesis copolymer and its hydrogenation product are characterized by having a low water absorption, good adhesion to metal and other materials, good compatibility with a curing agent and other compounds, and high heat resistance, and exhibiting reduced signal retardation and signal noise.
摘要翻译：通过进行具有羟基或羟基羰基的降冰片烯型单体的开环易位共聚，可以获得具有所需单体单元比和高分子量并具有羟基或羟基羰基的开环复分解共聚物及其氢化产物具有至少三个环的未取代的降冰片烯型单体的基团在主要由与其配位有中性给电子配体的有机钌化合物组成的催化剂的存在下进行，并且如果需要，氢化所得共聚物。由此获得的开环复分解共聚物及其氢化产物的特征在于具有低吸水性，对金属和其他材料的良好粘附性，与固化剂和其它化合物的良好相容性，以及高耐热性，并且表现出降低的信号延迟和信号噪声。

34. 发明申请

US20050148746A1 Norbornene-based ring-opening polymerization polymer, product of hydrogenation of norbornene-based ring-opening polymerization polymer, and processes for producing these 有权
标题翻译：基于降冰片烯的开环聚合聚合物，降冰片烯类开环聚合聚合物的氢化产物及其制备方法
公开(公告)号：US20050148746A1
公开(公告)日：2005-07-07
申请号：US10510513
申请日：2003-04-07
申请人： Kazunori Taguchi , Seiji Okada , Yasuo Tsunogae
发明人： Kazunori Taguchi , Seiji Okada , Yasuo Tsunogae
IPC分类号： C08G61/06 , C08G61/08 , C08F10/00
CPC分类号： C08G61/08 , C08G61/06
摘要： A norbornene ring-opened polymer which in the molecule has repeating units represented by the formula (1): wherein R1 represents Q, R2 represents Q or C(═O)R5, R3 represents Q or C(═O)R6, and R4 represents Q or X—C(═O)R7 (wherein Q represents hydrogen, a C1-10 hydrocarbon group, etc.; R5, R6 and R7 each represents hydroxyl, C1-10 alkoxyl, etc., provided that R6 and R7 may be bonded to each other to constitute oxygen, NH, etc.; X represents methylene, etc., provided that when R2 is Q, then R3 is C(═O)R6 and R4 is X—C(═O)R7 and that when R4 is Q, then R2 is C(═O)R5, R3 is C(═O)R6, and the configuration of R2 and R3 is trans, and m is 0 or 1), the polymer having a weight-average molecular weight as determined by gel permeation chromatography of 1,000 to 1,000,000. Also provided is a hydrogenation product of the norbornene ring-opened polymer. The norbornene ring-opened polymer and the hydrogenation product are excellent in heat resistance, electrical properties, etc.
摘要翻译：分子中具有由式（1）表示的重复单元的降冰片烯开环聚合物：其中R 1表示Q，R 2表示Q或C（-O ）R 5，R 3表示Q或C（-O）R 6，R 4表示Q 或XC（-O）R 7（其中Q表示氢，C 1-10烃基等; R 5，R R 6和R 7各自表示羟基，C 1-10烷氧基等，条件是R 6和 R 7可以彼此键合以构成氧，NH等; X表示亚甲基等，条件是当R 2为Q时，则R 0 > 3 是C（-O）R 6和R 4是XC（-O）R 7，当R 4是Q，则R 2是C（-O）R 5，R 3是C（ - O）R 6，R 2和R 3的构型为反式，m为0或1），所述聚合物具有重量平均分子量 d通过凝胶渗透色谱法为1,000至1,000,000。还提供了降冰片烯开环聚合物的氢化产物。降冰片烯开环聚合物和氢化产物的耐热性，电性能等优异。

35. 发明授权

US06653424B1 Norbornene open-ring polymers, products of hydrogenation thereof and processes for the production of both 有权
标题翻译：降冰片烯开环聚合物，其氢化产物和两者的生产方法
公开(公告)号：US06653424B1
公开(公告)日：2003-11-25
申请号：US10049648
申请日：2002-02-25
申请人： Masato Sakamoto , Daisuke Uchida , Yasuo Tsunogae , Hiroshi Kurakata
发明人： Masato Sakamoto , Daisuke Uchida , Yasuo Tsunogae , Hiroshi Kurakata
IPC分类号： C08F3208
CPC分类号： C08G61/08
摘要： Using a polymerization catalyst comprising as a main ingredient a metal compound containing a transition metal of group 6 of the periodic table and having at least one imide group and at least two substituent (A) selected from the group consisting of an alkoxy group, an aryloxy group, an alkylamide group and an arylamide group, a polycyclic norbornene monomer is polymerized to give a ring-opened norbornene polymer having a weight average molecular weight of 500 to 1,000,000 as expressed in terms of polystyrene and a melting point of 140° C. or higher. This polymer is hydrogenated to give a hydrogenated product having a melting point of 140° C. or higher.
摘要翻译：使用包含作为主要成分的含有元素周期表第6族过渡金属并具有至少一个酰亚胺基团的金属化合物和至少两个选自烷氧基，芳氧基基团，烷基酰胺基和芳基酰胺基，多环降冰片烯单体聚合得到如聚苯乙烯和熔点为140℃表示的重均分子量为500至1,000,000的开环降冰片烯聚合物，或更高。将该聚合物氢化，得到熔点为140℃以上的氢化物。

36. 发明授权

US06486264B1 Process for producing hydrogenated ring-opening polymerization polymer of cycloolefin 有权
标题翻译：制备环烯烃氢化开环聚合聚合物的方法
公开(公告)号：US06486264B1
公开(公告)日：2002-11-26
申请号：US09980200
申请日：2001-11-30
申请人： Yasuo Tsunogae , Masato Sakamoto , Masaharu Tokoro , Kazunori Taguchi
发明人： Yasuo Tsunogae , Masato Sakamoto , Masaharu Tokoro , Kazunori Taguchi
IPC分类号： C08F804
CPC分类号： C08G61/08
摘要： A process for producing a hydrogenated product of a polymer prepared through ring-opening polymerization which comprises a polymerization step of polymerizing a cyclic olefin through ring-opening polymerization in the presence of a polymerization catalyst comprising an organoruthenium compound or an organoosmium compound to prepare a polymer, and a hydrogenation step of adding a hydrogenation catalyst and hydrogen into a polymerization system resulting from the polymerization step to hydrogenate the carbon-carbon double bonds of the polymer prepared through the ring-opening polymerization. When the organoruthenium compound- or organoosmium compound-containing catalyst further comprises a carbene compound, the catalyst exhibits a higher activity for the ring-opening polymerization.
摘要翻译：一种通过开环聚合制备的聚合物的氢化产物的制备方法，该方法包括在包含有机钌化合物或有机锇化合物的聚合催化剂存在下，通过开环聚合使环烯烃聚合的聚合步骤，以制备聚合物以及将氢化催化剂和氢气加入到由聚合步骤得到的聚合体系中氢化通过开环聚合制备的聚合物的碳 - 碳双键的氢化步骤。当含有机钌化合物或有机锇化合物的催化剂还包含卡宾化合物时，催化剂对开环聚合具有较高的活性。

37. 发明授权

US5905129A Ring-opening polymer hydrogenation products 失效
标题翻译：开环聚合物加氢产物
公开(公告)号：US5905129A
公开(公告)日：1999-05-18
申请号：US809298
申请日：1997-03-27
申请人： Toshihide Murakami , Mitsushi Tada , Yasuo Tsunogae
发明人： Toshihide Murakami , Mitsushi Tada , Yasuo Tsunogae
IPC分类号： C08G61/08 , C08L9/06 , C08L53/02 , C08L65/00 , H05K1/03 , C08F8/04 , C08F32/08
CPC分类号： C08L65/00 , C08G61/08 , C08L53/02 , C08L9/06 , H05K1/032
摘要： A thermoplastic norbornene resin having a number-average molecular weight (Mn) of 12,000 or more in terms of polyisoprene value measured by gel permeation chromatography and excellent in low birefringence property and resistance to deterioration with greases and oils is obtained by ring-opening polymerizing a polycyclic norbornene monomer containing at least 70% by weight of a norbornene monomer represented by the following formula I (for example, 1,4-methano-1,4,4a,9a-tetrahydrofluorene): ##STR1## (wherein the lower 6-membered ring structure may have a double bond) and hydrogenating the polymer so that the hydrogenation rate of double bond in the main chain is at least 98% and the hydrogenation rate of the 6-membered ring structure is at least 90%.
摘要翻译： PCT No.PCT / JP95 / 01992 Sec。 371日期1997年3月27日 102（e）1997年3月27日PCT PCT 1995年9月29日PCT公布。公开号WO96 / 10596 日期1996年4月11日按照通过凝胶渗透色谱法测定的以聚异戊二烯值计的数均分子量（Mn）为12000以上的热塑性降冰片烯系树脂，具有优异的低双折射性和耐油脂变质性，得到了开环聚合含有至少70重量％由下式I表示的降冰片烯单体的多环降冰片烯单体（例如，1,4-亚甲基-1,4,4a，9a-四氢芴）：（其中下部 6元环结构可以具有双键）和氢化聚合物，使得主链中双键的氢化率至少为98％，并且6元环结构的氢化率至少为90％。

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