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31. 发明授权

US5663379A Substituted phenyl ethers 失效
标题翻译：取代的苯基醚
公开(公告)号：US5663379A
公开(公告)日：1997-09-02
申请号：US366128
申请日：1994-12-29
申请人： Friedrich Karrer
发明人： Friedrich Karrer
IPC分类号： A01N39/00 , A01N43/28 , A01N43/30 , A01N43/40 , C07D317/22 , C07D317/54 , C07D317/72 , C07D405/04 , C07D317/00 , A61K31/335 , C07D307/77
CPC分类号： C07D405/04 , A01N43/28 , A01N43/30 , C07D317/22 , C07D317/72
摘要： Compounds of the formula ##STR1## in which R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 are as defined in claim 1 can be used as agrochemical active ingredients and can be prepared in a manner known per se.
摘要翻译：其中R 1，R 2，R 3，R 4，R 5和R 6如权利要求1中所定义的式（I）的化合物可用作农业化学活性成分，并且可以以本身已知的方式制备。

32. 发明授权

US5648494A Carbamic acid derivatives 失效
标题翻译：氨基甲酸衍生物
公开(公告)号：US5648494A
公开(公告)日：1997-07-15
申请号：US458926
申请日：1995-06-02
申请人： Friedrich Karrer
发明人： Friedrich Karrer
IPC分类号： A01N47/12 , A01N47/16 , A01N47/20 , A01N47/24 , C07C43/23 , C07C43/295 , C07C69/63 , C07C69/712 , C07C271/12 , C07C271/14 , C07C271/16 , C07C271/18 , C07C271/28 , C07C271/64 , C07C271/66 , C07C323/20 , C07C333/10 , C07C333/12 , C07D295/10 , C07D295/205 , C07D211/00 , C07C271/10 , C07D207/00
CPC分类号： C07D295/205 , A01N47/12 , A01N47/20 , A01N47/24 , C07C271/12 , C07C271/14 , C07C271/16 , C07C271/28 , C07C271/64 , C07C271/66 , C07C43/23 , C07C43/295
摘要： Compounds of the formula ##STR1## in which R.sub.1 is halogen, C.sub.1 -C.sub.3 alkyl, halo-C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 alkoxy, halo-C.sub.1 -C.sub.3 alkoxy or cyano and/or two substituents R.sub.1 which are bonded to adjacent C atoms of the phenyl ring together are --O--CH.sub.2 --O--; R.sub.2 is hydrogen, halogen or methyl;R.sub.3 is fluorine, chlorine, bromine or C.sub.1 -C.sub.3 alkyl; R.sub.4 is hydrogen or C.sub.1 -C.sub.3 alkyl; either R.sub.5 is hydrogen, C.sub.1 -C.sub.4 alkyl, ##STR2## --COCO--R.sub.8, --CO--R.sub.9 or S(O).sub.m --N(R.sub.10)--COO--R.sub.11 andR.sub.6 is C.sub.1 -C.sub.6 alkyl, halo-C.sub.1 -C.sub.4 alkyl, C.sub.2 -C.sub.6 alkenyl, halo-C.sub.3 -C.sub.4 alkenyl, C.sub.3 C.sub.5 alkynyl, halo-C.sub.3 -C.sub.5 alkynyl, C.sub.1 -C.sub.3 alkoxy-C.sub.1 -C.sub.3 alkyl, C.sub.3 -C.sub.6 cycloalkyl, unsubstituted or substituted phenyl; or R.sub.5 and R.sub.6 together are --(CH.sub.2).sub.4 -- or --(CH.sub.2).sub.5 --; R.sub.7 is hydrogen, halogen or C.sub.1 -C.sub.3 alkyl; R.sub.8 is C.sub.1 -C.sub.8 alkoxy or --N(R.sub.12).sub.2 ;R.sub.9 is C.sub.1 -C.sub.4 alkyl, C.sub.3 -C.sub.6 cycloalkyl, --N(R.sub.13).sub.2 or C.sub.1 -C.sub.4 alkoxy;R.sub.10 is C.sub.1 -C.sub.3 alkyl; R.sub.11 is C.sub.1 -C.sub.6 alkyl;R.sub.12 radicals independently of one another are C.sub.1 -C.sub.8 alkyl;R.sub.13 radicals independently of one another are C.sub.1 -C.sub.4 alkyl;m is the number 0, 1 or 2; n is the number 0, 1, 2 or 3 where, if n is 2 or 3, the radicals R.sub.1 can be identical or different; X is O, S, CH.sub.2, CO or --O--CH.sub.2 --;Y is O or S; and Z is O or S,with the exception of 1-(2-fluoro-4-phenoxyphenoxy)-2-ethylaminocarbonyloxyethane, in free form or in salt form, can be used as agrochemical active ingredients and can be prepared in a manner known per se.
摘要翻译：其中R 1是卤素，C 1 -C 3烷基，卤代-C 1 -C 3烷基，C 1 -C 3烷氧基，卤代-C 1 -C 3烷氧基或氰基和/或两个与相邻C原子键合的取代基R 1的化合物的苯环一起是-O-CH 2 -O-; R2是氢，卤素或甲基; R3是氟，氯，溴或C1-C3烷基; R4是氢或C1-C3烷基; R 5是氢，C 1 -C 4烷基，-COCO-R 8，-CO-R 9或S（O）m N（R 10）-COO-R 11，R 6是C 1 -C 6烷基，卤代C 1 -C 4烷基，C 2 -C 6烯基卤代C 3 -C 4烯基，C 3 -C 5炔基，卤代C 3 -C 5炔基，C 1 -C 3烷氧基-C 1 -C 3烷基，C 3 -C 6环烷基，未取代或取代的苯基; 或者R 5和R 6一起是 - （CH 2）4 - 或 - （CH 2）5 - R7是氢，卤素或C1-C3烷基; R8是C1-C8烷氧基或-N（R12）2; R9是C1-C4烷基，C3-C6环烷基，-N（R13）2或C1-C4烷氧基; R10是C1-C3烷基; R11是C1-C6烷基; R 12基彼此独立地为C 1 -C 8烷基; R 13基彼此独立地为C 1 -C 4烷基; m是数字0，1或2; n是数字0,1,2或3，其中如果n是2或3，基团R 1可以相同或不同; X是O，S，CH 2，CO或-O-CH 2 - ; Y为O或S; 和Z是O或S，除了1-（2-氟-4-苯氧基苯氧基）-2-乙基氨基羰基氧基乙烷以游离形式或盐形式，可以用作农业化学活性成分，并且可以以已知的方式制备本身。

33. 发明授权

US5393885A Carbamic acid derivatives 失效
标题翻译：氨基甲酸衍生物
公开(公告)号：US5393885A
公开(公告)日：1995-02-28
申请号：US199917
申请日：1994-02-22
申请人： Friedrich Karrer
发明人： Friedrich Karrer
IPC分类号： A01N47/12 , A01N47/16 , A01N47/20 , A01N47/24 , C07C43/23 , C07C43/295 , C07C69/63 , C07C69/712 , C07C271/12 , C07C271/14 , C07C271/16 , C07C271/18 , C07C271/28 , C07C271/64 , C07C271/66 , C07C323/20 , C07C333/10 , C07C333/12 , C07D295/10 , C07D295/205 , C07C319/00 , C07C33/34 , C07C43/00 , C07D273/00
CPC分类号： C07D295/205 , A01N47/12 , A01N47/20 , A01N47/24 , C07C271/12 , C07C271/14 , C07C271/16 , C07C271/28 , C07C271/64 , C07C271/66 , C07C43/23 , C07C43/295
摘要： Compounds of the formula ##STR1## in which R.sub.1 is halogen, C.sub.1 -C.sub.3 alkyl, halo-C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 alkoxy, halo-C.sub.1 -C.sub.3 alkoxy or cyano and/or two substituents R.sub.1 which are bonded to adjacent C atoms of the phenyl ring together are --O--CH.sub.2 --O--; R.sub.2 is hydrogen, halogen or methyl;R.sub.3 is fluorine, chlorine, bromine or C.sub.1 -C.sub.3 alkyl; R.sub.4 is hydrogen or C.sub.1 -C.sub.3 alkyl;either R.sub.5 is hydrogen, C.sub.1 -C.sub.4 alkyl, ##STR2## --COCO--R.sub.8,--CO--R.sub.9 or S(O).sub.m --N(R.sub.10)--COO--R.sub.11 andR.sub.6 is C.sub.1 -C.sub.6 alkyl, halo-C.sub.1 -C.sub.4 alkyl, C.sub.2 -C.sub.6 alkenyl, halo-C.sub.3 -C.sub.4 alkenyl, C.sub.3 -C.sub.5 alkynyl, halo-C.sub.3 -C.sub.5 alkynyl, C.sub.1 -C.sub.3 alkoxy-C.sub.1 -C.sub.3 alkyl, C.sub.3 -C.sub.6 cycloalkyl, unsubstituted or substituted phenyl; or R.sub.5 and R.sub.6 together are --(CH.sub.2).sub.4 -- or --(CH.sub.2).sub.5 --; R.sub.7 is hydrogen, halogen or C.sub.1 -C.sub.3 alkyl; R.sub.8 is C.sub.1 -C.sub.8 alkoxy or --N(R.sub.12).sub.2 ;R.sub.9 is C.sub.1 -C.sub.4 alkyl, C.sub.3 -C.sub.6 cycloalkyl, --N(R.sub.13).sub.2 or C.sub.1 -C.sub.4 alkoxy;R.sub.10 is C.sub.1 -C.sub.3 alkyl; R.sub.11 is C.sub.1 -C.sub.6 alkyl;R.sub.12 radicals independently of one another are C.sub.1 -C.sub.4 alkyl;R.sub.13 radicals independently of one another are C.sub.1 -C.sub.4 alkyl;m is the number 0, 1 or 2; n is the number 0, 1, 2 or 3 where, if n is 2 or 3, the radicals R.sub.1 can be identical or different; X is O, S, CH.sub.2, CO or --O--CH.sub.2 --;Y is O or S; and Z is O or S,with the exception of 1-(2-fluoro-4-phenoxyphenoxy)-2-ethylaminocarbonyloxyethane, in free form or in salt form, can be used as agrochemical active ingredients and can be prepared in a manner known per se.
摘要翻译：其中R 1是卤素，C 1 -C 3烷基，卤代-C 1 -C 3烷基，C 1 -C 3烷氧基，卤代-C 1 -C 3烷氧基或氰基和/或两个与相邻C原子键合的取代基R 1的化合物的苯环一起是-O-CH 2 -O-; R2是氢，卤素或甲基; R3是氟，氯，溴或C1-C3烷基; R4是氢或C1-C3烷基; R 5是氢，C 1 -C 4烷基，-COCO-R 8，-CO-R 9或S（O）m N（R 10）-COO-R 11，R 6是C 1 -C 6烷基，卤代C 1 -C 4烷基，C 2 -C 6烯基卤代C 3 -C 4烯基，C 3 -C 5炔基，卤代C 3 -C 5炔基，C 1 -C 3烷氧基-C 1 -C 3烷基，C 3 -C 6环烷基，未取代或取代的苯基; 或者R 5和R 6一起是 - （CH 2）4 - 或 - （CH 2）5 - R7是氢，卤素或C1-C3烷基; R8是C1-C8烷氧基或-N（R12）2; R9是C1-C4烷基，C3-C6环烷基，-N（R13）2或C1-C4烷氧基; R10是C1-C3烷基; R11是C1-C6烷基; R 12基彼此独立地为C 1 -C 4烷基; R 13基彼此独立地为C 1 -C 4烷基; m是数字0，1或2; n是数字0,1,2或3，其中如果n是2或3，基团R 1可以相同或不同; X是O，S，CH 2，CO或-O-CH 2 - ; Y为O或S; 和Z是O或S，除了1-（2-氟-4-苯氧基苯氧基）-2-乙基氨基羰基氧基乙烷以游离形式或盐形式，可以用作农业化学活性成分，并且可以以已知的方式制备本身。

34. 发明授权

US5082860A Use of ethyl 2-[4-(3,5-difluorophenoxy)phenoxy]ethylcarbamate for controlling cicadas which damage rice crops 失效
标题翻译：乙烯2-（4-（3,5-二氟苯氧基）苯氧基）乙酰胺的控制用于控制损害米糠的芝加哥
公开(公告)号：US5082860A
公开(公告)日：1992-01-21
申请号：US568373
申请日：1990-08-16
申请人： Friedrich Karrer , Alfred Rindlisbacher
发明人： Friedrich Karrer , Alfred Rindlisbacher
IPC分类号： A01N47/10 , A01N47/12
CPC分类号： A01N47/12
摘要： Use of ethyl 2-[4-(3,5-difluorophenoxy)phenoxy]ethylcarbamate for controlling cicadas which damage rice crops.
摘要翻译：使用2- [4-（3,5-二氟苯氧基）苯氧基]乙基氨基甲酸乙酯来控制损害水稻作物的蝉。

35. 发明授权

US4731393A Process for chemically bonding stabilizers to polymers 失效
标题翻译：将稳定剂化学键合到聚合物的方法
公开(公告)号：US4731393A
公开(公告)日：1988-03-15
申请号：US873853
申请日：1986-06-11
申请人： Friedrich Karrer , Peter Hofmann
发明人： Friedrich Karrer , Peter Hofmann
IPC分类号： C07D401/12 , C07D211/00 , C07D251/00 , C07D259/00 , C07D401/14 , C07D487/18 , C08F26/00 , C08F226/06 , C08F255/00 , C08F291/00 , C08G73/02 , C08K5/3432 , C08K5/3435 , C08K5/3477 , C08K5/3492 , C08J3/28 , C08L23/36
CPC分类号： C08F255/00 , C08F291/00
摘要： s-Triazine compounds, the molecule of which contains at least one ethylenically unsaturated group and at least one 2,2,6,6-tetramethylpiperidine group can be grafted onto organic polymers, in particular onto polyolefines, in the presence of free-radical formers or by means of irradiation. Examples of free-radical formers are peroxy or azo compounds. If polyunsaturated piperidine-triazine compounds are used, it is also possible to achieve crosslinking of the polymer, particularly in the case of polyethylene.
摘要翻译： s-三嗪化合物，其分子含有至少一个烯属不饱和基团和至少一个2,2,6,6-四甲基哌啶基团可以在自由基形成剂存在下接枝到有机聚合物，特别是聚烯烃上或通过照射。自由基形成剂的实例是过氧或偶氮化合物。如果使用多不饱和哌啶 - 三嗪化合物，也可以实现聚合物的交联，特别是在聚乙烯的情况下。

36. 发明授权

US4412021A Novel polyalkylpiperidyl-ureas and their use as stabilizers 失效
标题翻译：新型聚烷基哌啶基脲及其作为稳定剂的用途
公开(公告)号：US4412021A
公开(公告)日：1983-10-25
申请号：US351577
申请日：1982-02-23
申请人： Friedrich Karrer
发明人： Friedrich Karrer
IPC分类号： C08K5/00 , C07D211/58 , C08K5/34 , C08K5/3412 , C08K5/3435 , C08L23/00 , C08L101/00 , C07D211/56 , C07D211/92
CPC分类号： C07D211/58 , C08K5/3435
摘要： Polyalkylpiperidyl-ureas of the formula I ##STR1## in which m is 1-4, X, R.sup.2 and R.sup.3 are monovalent substituents and R.sup.1 is a m-valent radical, can be prepared from the corresponding 4-aminopiperidines by reaction with carbamoyl chlorides. They are outstanding stabilizers for plastics, and especially for polyolefins, to protect them against degradation by the action of light.
摘要翻译：其中m为1-4，X，R2和R3的式I的多烷基哌啶基脲是一价取代基，R 1为m价基团，可以通过与氨基甲酰氯反应制备自相应的4-氨基哌啶。它们是塑料，特别是聚烯烃的突出稳定剂，可以通过光的作用来保护它们免受降解。

37. 发明授权

US4317911A Piperidine containing cyanuric acid derivatives 失效
标题翻译：哌啶含氰尿酸衍生物
公开(公告)号：US4317911A
公开(公告)日：1982-03-02
申请号：US812295
申请日：1977-07-01
申请人： Michael Rasberger , Friedrich Karrer
发明人： Michael Rasberger , Friedrich Karrer
IPC分类号： C08L23/00 , C07D211/58 , C07D251/34 , C07D401/12 , C08K5/34 , C08K5/3477 , C08L7/00 , C08L21/00 , C08L51/00 , C08L51/02 , C08L101/00
CPC分类号： C07D251/34 , C07D211/58 , C08K5/3477
摘要： New cyanuric acid derivatives containing at least one hindered phenolic moiety and at least one hindered amine moiety are effectful light stabilizers and antioxidants for polymeric materials.
摘要翻译：含有至少一个受阻酚部分和至少一个受阻胺部分的新的氰尿酸衍生物是聚合材料的有效的光稳定剂和抗氧化剂。

38. 发明授权

US4234734A 2,2,6,6-Tetramethylpiperidine derivatives 失效
标题翻译： 2,2,6,6-四甲基哌啶衍生物
公开(公告)号：US4234734A
公开(公告)日：1980-11-18
申请号：US057628
申请日：1979-07-16
申请人： Friedrich Karrer
发明人： Friedrich Karrer
IPC分类号： C08K5/00 , C07D211/46 , C07D471/10 , C07D519/00 , C08K5/34 , C08K5/3442 , C08L7/00 , C08L21/00 , C08L23/00 , C08L51/00 , C08L51/02 , C08L101/00 , C07D401/10 , C07D401/06
CPC分类号： C07D471/10 , C07D211/46 , C08K5/34
摘要： 2,2,6,6-Tetramethylpiperidine derivatives of the formula I ##STR1## in which A is a radical of the formula II, III or IV, and in formula II B is bonded to the N atom, ##STR2## B is C.sub.2 -C.sub.12 alkylene, C.sub.4 -C.sub.10 alkenylene, C.sub.6 alkynylene, xylylene or bitolylene, R.sub.1 is H or C.sub.1 -C.sub.12 alkyl, R.sub.2 is hydrogen, methyl, ethyl, phenyl or phenoxymethyl and n is 0, 1 or 2, for use as stabilizers for synthetic organic polymer.
摘要翻译：其中A是式II，III或IV的基团，并且在式IIB中的式I的2,2,6,6-四甲基哌啶衍生物结合到N原子上，（IV）B是C 2 -C 12亚烷基，C 4 -C 10亚烯基，C 6亚炔基，亚二甲苯基或比特罗烯，R 1是H或C 1 -C 12烷基， R2是氢，甲基，乙基，苯基或苯氧基甲基，n是0,1或2，用作合成有机聚合物的稳定剂。

39. 发明授权

US4172146A Substituted phenyl derivatives 失效
标题翻译：取代的苯基衍生物
公开(公告)号：US4172146A
公开(公告)日：1979-10-23
申请号：US667006
申请日：1976-03-15
申请人： Friedrich Karrer
发明人： Friedrich Karrer
IPC分类号： C07C59/68 , C07C69/76
CPC分类号： C07C45/515 , C07C59/68
摘要： Compounds of the formula ##STR1## wherein R.sub.1 represents cyclohexyl, cyclohexyloxy or the group ##STR2## in which Y represents ##STR3## or the direct bond, Z represents ##STR4## BEING BONDED TO THE PHENYL NUCLEUS, R.sub.2 represents hydrogen, C.sub.1 -C.sub.3 -alkyl, R.sub.3 represents --COOH, (C.sub.1 -C.sub.5 -alkoxy)carbonyl, (C.sub.3 -C.sub.5 -alkenyloxy)carbonyl, (C.sub.3 -C.sub.5 -alkinyloxy)carbonyl, cyclohexyloxycarbonyl, phenoxycarbonyl, (C.sub.3 -C.sub.5 -haloalkenyloxy)carbonyl, the cyano group, a carbamoyl group which is mono- or disubstituted by C.sub.1 -C.sub.5 -alkyl, C.sub.3 -C.sub.5 -alkenyl or C.sub.3 -C.sub.5 -alkinyl, it being possible for the substituents of the carbamoyl group together with the nitrogen atom to which they are bonded to form a saturated 5- or 6-membered heterocyclic ring which can contain in addition an oxygen, a sulphur, or a further nitrogen atom, R.sub.4 represents hydrogen, methyl, or ethyl, R.sub.5 represents C.sub.1 -C.sub.3 -alkyl, formyl, or acetyl, R.sub.6 represents hydrogen or C.sub.1 -C.sub.3 -alkyl, R.sub.7 represents hydrogen, halogen, C.sub.1 -C.sub.5 -alkoxy or C.sub.1 -C.sub.5 -alkyl, and R.sub.8 represents hydrogen, halogen, methyl, or ethyl, and their use in pest control are disclosed.
摘要翻译：式（I）的化合物，其中R 1表示环己基，环己基氧基或其中Y表示直接键的基团，其中Z表示O，NH，R 5 N，+ RF + R 3代表氢，C 1 -C 3 - 烷基，R 3表示-COOH，（C 1 -C 5 - 烷氧基）羰基，（C 3 -C 5 - 烯氧基）羰基，（C 3 -C 5 - 烷氧基））羰基，环己氧基羰基，苯氧基羰基，（C 3 -C 5 - 卤代烯氧基）羰基，氰基，被C 1 -C 5 - 烷基，C 3 -C 5 - 链烯基或C 3 -C 5 - 炔基单取代或二取代的氨基甲酰基，可能的氨基甲酰基的取代基与它们所键合的氮原子一起形成可以另外含有氧，硫或另外的氮原子的饱和的5-或6-元杂环，R 4表示氢，甲基或乙基，R5代表C1-C3-烷基，甲酰基或乙酰基，R6代表氢或C1-C3-烷基，R7代表氢，卤素，C1-C5-烷氧基或C1- C5-烷基，R8表示氢，卤素，甲基或乙基，并且它们在害虫防治中的用途被公开。

40. 发明授权

US4153731A Phenoxy (benzyloxy/benzylthio) benzene derivatives 失效
标题翻译：苯氧基（苄氧基/苄硫基）苯衍生物
公开(公告)号：US4153731A
公开(公告)日：1979-05-08
申请号：US885719
申请日：1978-03-13
申请人： Friedrich Karrer
发明人： Friedrich Karrer
IPC分类号： A01N37/24 , C07C43/275 , C07C205/34 , C07C205/35 , C07C205/37 , C07C205/38 , C07D317/54 , C07D317/56 , C07D317/58 , A01N9/12
CPC分类号： C07D317/58 , C07C205/34 , C07C255/00 , C07C43/275 , C07D317/54 , C07D317/56
摘要： Compounds of the formula ##STR1## wherein N REPRESENTS THE NUMBERS 0 OR 1,Z represents oxygen, ##STR2## or sulphur R.sub.1 represents the groups ##STR3## wherein R.sub.5 represents hydrogen, halogen, C.sub.1 -C.sub.5 -alkyl, ethynyl, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.5 -alkoxy, C.sub.3 -C.sub.5 -alkenyloxy, C.sub.3 -C.sub.5 -haloalkenyloxy, C.sub.3 -C.sub.5 -alkynyloxy, nitro, cyano, C.sub.2 -C.sub.5 -alkoxycarbonyl, C.sub.3 -C.sub.5 -alkenyloxycarbonyl, C.sub.3 -C.sub.5 -alkynyloxycarbonyl, C.sub.1 -C.sub.3 -alkanoyl, C.sub.1 -C.sub.4 -alkylcarbamoyl, (di-C.sub.1 -C.sub.4 -alkyl)carbamoyl,R.sub.6 represents hydrogen, halogen, methyl, ethyl, isopropyl or methoxy, andR.sub.8 represents hydrogen or n-propyl,R.sub.2 represents hydrogen, methyl or ethyl,R.sub.3 and R.sub.4 each represent hydrogen, methyl, ethyl, methoxy, ethoxy, nitro or halogen, andR.sub.7 represents hydrogen or C.sub.1 -C.sub.2 -alkanoyl,And their use for combating insects and members of the order acarina are disclosed.
摘要翻译：式（I）的化合物其中N表示数字0或1，Z表示氧，或者R 1表示基团，其中R 5表示氢，卤素，C 1 -C 5 - 烷基，乙炔基， C1-C4-烷硫基，C1-C5-烷氧基，C3-C5-烯氧基，C3-C5-卤代烯氧基，C3-C5-炔氧基，硝基，氰基，C2-C5-烷氧基羰基，C3-C5-烯氧基羰基，C3-C5- （C 1 -C 4） - 烷基氨基甲酰基，（C 1 -C 4 - 烷基）氨基甲酰基，R 6表示氢，卤素，甲基，乙基，异丙基或甲氧基，R 8表示氢或正丙基，R 2表示氢，甲基或乙基，R 3和R 4各自表示氢，甲基，乙基，甲氧基，乙氧基，硝基或卤素，并且R 7表示氢或C 1 -C 2 - 烷酰基，并且它们用于组合药物和订单ACARINA的成员的用途被公开。

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