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31. 发明授权

US06706834B2 Sulphonic fluorinated ionomers 失效
标题翻译：磺化氟化离聚物
公开(公告)号：US06706834B2
公开(公告)日：2004-03-16
申请号：US09922741
申请日：2001-08-07
申请人： Ivan Wlassics , Vito Tortelli
发明人： Ivan Wlassics , Vito Tortelli
IPC分类号： C08F11418
CPC分类号： H01M8/1053 , C08F8/18 , C08F214/26 , C08F214/265 , C08J5/2237 , C08J2327/18 , H01M8/1023 , H01M8/1025 , H01M8/1039 , H01M8/106 , H01M8/1072 , H01M8/1088 , H01M2300/0082 , Y02P70/56
摘要： Sulphonic fluorinated ionomers crosslinked by radical crosslinking of: A) crosslinkable sulphonic fluorinated ionomers, having equivalent weight 380-1300 g/eq and comprising: from 48% to 85% by moles of monomeric units deriving from tetrafluoroethylene (TFE); from 15% to 47% by moles of fluorinated monomeric units containing sulphonyl groups —SO2F; from 0.01% to 5% by moles of monomeric units deriving from a bis-olefin of formula: wherein: m=2-10, preferably 4-8; R1, R2, R5, R6, equal to or different from each other, are H or C1-C5 alkyl groups; B) a fluorinated compound as crosslinking radical initiator; C) a fluorinated bis-olefin of structure (I) as crosslinking agent; the radical crosslinking being carried out at a temperature in the range 250° C.-310° C., preferably 260° C.-300° C.
摘要翻译：通过自由基交联交联的磺化氟化离聚物：A）具有当量重量380-1300g / eq的可交联磺化氟化离聚物，并且包含：衍生自四氟乙烯（TFE）的48％至85％摩尔的单体单元; 15％至含有磺酰基-SO2F的氟化单体单元47％衍生自下式的双烯烃的单体单元的0.01％至5％摩尔：其中：m = 2-10，优选4-8; R 1，R 2，R 5，R 6等于或不同的是H或C 1 -C 5烷基; B）作为交联自由基引发剂的氟化化合物; C）结构（I）的氟化双烯烃作为交联剂自由基交联在250℃-310℃，优选260℃-300℃的温度下进行。

32. 发明授权

US5585449A Fluoroelastomers comprising monomeric units deriving from a bis-olefin 失效
标题翻译：包含衍生自双烯烃的单体单元的氟弹性体
公开(公告)号：US5585449A
公开(公告)日：1996-12-17
申请号：US361663
申请日：1994-12-22
申请人： Vincenzo Arcella , Giulio Brinati , Margherita Albano , Vito Tortelli
发明人： Vincenzo Arcella , Giulio Brinati , Margherita Albano , Vito Tortelli
IPC分类号： C08G65/26 , C08F14/18 , C08F16/14 , C08F16/32 , C08F36/04 , C08F214/18 , C08F214/22 , C08F214/26 , C08F216/12 , C08F216/14 , C08F236/20 , C08K5/00 , C08F16/24
CPC分类号： C08F214/184 , C08F214/18 , C08K5/0025
摘要： New fluoroelastomers are described, comprising monomeric units deriving from a bis-olefin having general formula: ##STR1## wherein: R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, equal or different from each other, are H or alkyls C.sub.1 -C.sub.5 ; Z is an alkylene or cycloalkylene radical C.sub.1 -C.sub.18, linear or branched, optionally containing oxygen atoms, preferably at least partially fluorinated, or a (per)fluoropolyoxyalkylene radical.Such products are endowed with improved processability, especially during calendering of the vulcanization mixture, along with superior mechanical and workability properties during extrusion and injection molding, with a very good mold release.
摘要翻译：描述了新的含氟弹性体，其包含衍生自具有以下通式的双烯烃的单体单元：其中：R1，R2，R3，R4，R5，R6彼此相同或不同的是H或烷基C1 -C5; Z是直链或支链的亚烷基或亚环烷基C1-C18，任选含有氧原子，优选至少部分氟化，或（全）氟聚氧亚烷基。这些产品具有改进的加工性，特别是在硫化混合物的压延过程中，以及在挤出和注射成型期间具有优异的机械和可加工性能，具有非常好的脱模性。

33. 发明授权

US5087776A New perfluoroalkanes obtained by photochemical fluorination and use thereof as polymerization initiators 失效
标题翻译：通过光化学荧光获得的新型全氟烷烃，作为聚合引发剂使用
公开(公告)号：US5087776A
公开(公告)日：1992-02-11
申请号：US651086
申请日：1991-02-06
申请人： Claudio Tonelli , Vito Tortelli
发明人： Claudio Tonelli , Vito Tortelli
IPC分类号： C07C17/04 , C07C19/08 , C08F2/00 , C08F4/00 , C08F214/26
CPC分类号： C08F4/00 , C07C17/04 , C07C19/08
摘要： The present invention relates to branched perfluoroalkanes which, having bonds between a quaternary carbon atom and a tertiary carbon atom, easily undergo a homolytic scission of the C--C bond thereby releasing (non-persistent) radicals which may be used as initiators of polymerization of ethylenically unsaturated monomers.A further object of the present invention are new perfluoroalkanes having at least 9 carbon atoms belonging to the above described group.

34. 发明授权

US5075397A Perfluoroalkanes obtained by photochemical fluorination and use thereof as polymerization initiators 失效
标题翻译：通过光化学荧光获得的全氟烷烃和作为聚合引发剂的用途
公开(公告)号：US5075397A
公开(公告)日：1991-12-24
申请号：US294557
申请日：1988-12-06
申请人： Claudio Tonelli , Vito Tortelli
发明人： Claudio Tonelli , Vito Tortelli
IPC分类号： C07C17/04 , C07C19/08 , C08F2/00 , C08F4/00 , C08F214/26
CPC分类号： C08F4/00 , C07C17/04 , C07C19/08
摘要： The present invention relates to branched perfluoroalkanes which, having bonds between a quaternary carbon atom and a tertiary carbon atom, easily undergo a homolytic scission of the C--C bond thereby releasing (non-persistent) radicals which may be used as initiators of polymerization of ethylenically unsaturated monomers.A further object of the present invention are new perfluoroalkanes having at least 9 carbon atoms belonging to the above described group.
摘要翻译： PCT No.PCT / EP88 / 00296 Sec。 371日期：1988年12月6日 102（e）日期1988年12月6日PCT提交1988年4月8日PCT公布。第WO88 / 08007号公报 1988年10月20日。本发明涉及具有季碳原子和叔碳原子之间的键的支化全氟烷烃容易发生CC键的均裂断裂，从而释放可以使用的（非持久）基团作为烯属不饱和单体的聚合引发剂。本发明的另一个目的是属于上述组的具有至少9个碳原子的新的全氟烷烃。

35. 发明授权

US08742142B2 Process for producing perfluorinated organic compounds 有权
标题翻译：生产全氟化有机化合物的方法
公开(公告)号：US08742142B2
公开(公告)日：2014-06-03
申请号：US13378887
申请日：2010-07-06
申请人： Vito Tortelli , Marco Galimberti , Guiseppe Marchionni
发明人： Vito Tortelli , Marco Galimberti , Guiseppe Marchionni
IPC分类号： C07D317/42
CPC分类号： C07D317/42
摘要： A process for producing a perfluorinated functional compound is disclosed, which comprises: A. converting an at least partially hydrogenated alcohol into an at least partially hydrogenated fluoroformate compound; B. reacting said at least partially hydrogenated fluoroformate compound with fluorine in the presence of at least one (per)haloolefin comprising at least one carbon-carbon double bond and having at least one fluorine or chlorine atom on either one of the carbon atoms of said double bond, to obtain a perfluorinated fluoroformate compound.
摘要翻译：公开了一种制备全氟化官能化合物的方法，其包括：A.将至少部分氢化的醇转化为至少部分氢化的氟甲酸酯化合物; B.在至少一种包含至少一个碳 - 碳双键的（全）卤代烯烃存在下，使所述至少部分氢化的氟甲酸酯化合物与氟反应，并在所述的碳 - 碳双键的碳原子上具有至少一个氟或氯原子双键，得到全氟化氟甲酸酯化合物。

36. 发明申请

US20130256588A1 Process for producing fluorinated organic compounds 有权
标题翻译：氟化有机化合物的制备方法
公开(公告)号：US20130256588A1
公开(公告)日：2013-10-03
申请号：US13993154
申请日：2011-12-16
申请人： Vito Tortelli , Marco Galimberti , Cristiano Monzani , Piero Gavezotti
发明人： Vito Tortelli , Marco Galimberti , Cristiano Monzani , Piero Gavezotti
IPC分类号： C07C41/22 , C09K5/00
CPC分类号： C07C41/22 , C07C41/48 , C08G65/007 , C08G65/3236 , C09K5/00 , C07C43/126 , C07C43/315
摘要： A process for fluorinating hydrocarbon compounds, which comprises: A. providing a compound selected from the group consisting of straight-chain, branched-chain and cyclic alkanes, straight-chain, branched-chain and cyclic ethers, said compound comprising at least one carbon-hydrogen bond and being free from C(O)— functional groups; B. reacting said compound with fluorine in the presence of at least one (per)haloolefin comprising at least one carbon-carbon double bond and having at least one fluorine or chlorine atom on either one of the carbon atoms of said double bond, to obtain a compound wherein at least one carbon-hydrogen bond has been replaced by a carbon-fluorine bond. Compositions of partially fluorinated compounds obtained with the process are also disclosed.
摘要翻译：一种氟化烃化合物的方法，其包括：A.提供选自直链，支链和环烷烃，直链，支链和环醚的化合物，所述化合物包含至少一个碳 - 氢键并且不含C（O） - 官能团; 在至少一种包含至少一个碳 - 碳双键并且在所述双键的碳原子上具有至少一个氟或氯原子的（全）卤代烯烃存在下，使所述化合物与氟反应，得到其中至少一个碳 - 氢键已被碳 - 氟键取代的化合物。还公开了通过该方法获得的部分氟化化合物的组合物。

37. 发明申请

US20130116483A1 Process for the fluorination of haloolefins 有权
标题翻译：卤代烯烃氟化方法
公开(公告)号：US20130116483A1
公开(公告)日：2013-05-09
申请号：US13809486
申请日：2011-07-05
申请人： Vito Tortelli , Marco Galimberti
发明人： Vito Tortelli , Marco Galimberti
IPC分类号： C07C17/04
CPC分类号： C07C17/04 , C07C41/22 , C07C19/12 , C07C43/123
摘要： A process for the fluorination of haloolefins with elemental fluorine in the presence of anhydrous HF proceeds with high yield and selectivity in the product deriving from the addition of fluorine to the carbon-carbon double bond.
摘要翻译：在无水HF存在下用元素氟氟化氟代烯烃的方法在从碳 - 碳双键中加入氟的产物中产生高产率和选择性。

38. 发明授权

US08268947B2 Addition reaction to fluoroallylfluorosulfate 有权
标题翻译：氟代氟代硫酸盐的加成反应
公开(公告)号：US08268947B2
公开(公告)日：2012-09-18
申请号：US12745869
申请日：2008-12-17
申请人： Giuseppe Marchionni , Vito Tortelli
发明人： Giuseppe Marchionni , Vito Tortelli
IPC分类号： C08F16/24
CPC分类号： C07D317/42 , C07C41/24 , C07C51/58 , C07C303/24 , C08F214/18 , C08F259/08 , C07C59/135 , C07C305/26 , C07C43/126
摘要： The invention pertains to a process for preparing compounds of formula (I-A) or (I-B) here below: by reaction of perfluoroallylfluorosulfate (FAFS) of formula (II): with at least one hypofluorite of formula (II-A) or (II-B): wherein: RF in formulae (I-A) and (II-A) is a monovalent fluorocarbon C1-C20 group, optionally comprising oxygen catenary atoms, optionally comprising functional groups comprising heteroatoms (e.g. —SO2F groups); R′F in formulae (I-B) and (II-B) is a divalent fluorocarbon C1-C6 group, preferably a group of formula wherein X1 and X2, equal to or different from each other, are independently a fluorine atom or a C1-C3 fluorocarbon group. The FAFS-hypofluorite adducts of formulae (I-A) and (I-B) can be produced with high selectivity so as to access useful intermediates which can further be reacted taking advantage of the un-modified fluorosulfate group chemistry.
摘要翻译：本发明涉及如下制备式（IA）或（IB）化合物的方法：通过式（II）的全氟代氟代硫酸盐（FAFS）与至少一种式（II-A）的次氟酸盐或（II- B）：其中：式（IA）和（II-A）中的RF是任选包含氧连接原子的任选包含杂原子的官能团（例如-SO 2 F基团）的单价碳氟化合物C1-C20基团; 式（IB）和（II-B）中的R'F是二价碳氟化合物C1-C6基团，优选下式的基团：其中X1和X2彼此相同或不同，分别为氟原子或C1- C3碳氟化合物。可以高选择性地制备式（I-A）和（I-B）的FAFS-次氟化物加合物，以便获得可利用未改性的氟硫酸盐基团化学进一步反应的有用的中间体。

39. 发明授权

US07208638B2 Process for preparing fluorohalogenethers 有权
标题翻译：制备氟卤醚的方法
公开(公告)号：US07208638B2
公开(公告)日：2007-04-24
申请号：US11044022
申请日：2005-01-28
申请人： Vito Tortelli , Stefano Millefanti , Pierangelo Calini
发明人： Vito Tortelli , Stefano Millefanti , Pierangelo Calini
IPC分类号： C07C41/18
CPC分类号： C07C41/48 , C07C43/313 , C07C43/315
摘要： A process for preparing (per)fluorohalogenethers having general formula: wherein: A and A′, equal to or different from each other, are selected among Cl, Br and H; m=1, 2; n=0, 1; R′ is a C1 to C3 (per)fluoroalkyl substituent; R is a (per)fluoropolyether substituent; z and z′ are 1 or zero, X1=F, CF3; by reaction of carbonyl compounds having formula: (R′)n—C(O)(F)q(CFX1(CF2)z(CH2)z′OR1) (II) wherein: R′ and n are as above; q=0, 1; X1=F or CF3; z=0 or 1; R1 is a (per)fluoropolyether substituent; in liquid phase, with elemental fluorine and with olefinic compounds of formula: CAF=CA′F2 (III) wherein A and A′ are as above, at temperatures from −120° C. to −20° C., preferably from −100° C. to −40° C.
摘要翻译：制备具有以下通式的（全）氟卤醚的方法：其中：A和A'彼此相同或不同，选自Cl，Br和H; m = 1,2; n = 0,1; R'是C 3〜C 3（全）氟烷基取代基的C 1〜C 3。 R是一个（全）氟聚醚取代基; z和z'为1或0，X 1 = F，CF 3 3; 通过具有下式的羰基化合物的反应：<？in-line-formula description =“In-line formula”end =“lead”→（R'）n -C（O）（F）（CF 2）（CF 2）2（CF 2）2（CF 2）（CH 2）_{其中：R'和n分别为以上; q = 0,1; X 1 = F或CF 3 N; z = 0或1; R 1是一个（全）氟聚醚取代基; 在液相中使用元素氟和具有下式的烯属化合物：<？in-line-formula description =“In-line Formulas”end =“lead”？> CAF = CA'F 2 III）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中A和A'如上所述，在-120℃至-20℃的温度下，优选地 -100°C至-40°C}

40. 发明申请

US20070004940A1 Process for preparing fluorohalogenethers 有权
标题翻译：制备氟卤醚的方法
公开(公告)号：US20070004940A1
公开(公告)日：2007-01-04
申请号：US11044021
申请日：2005-01-28
申请人： Vito Tortelli , Stefano Millefanti , Pierangelo Calini
发明人： Vito Tortelli , Stefano Millefanti , Pierangelo Calini
IPC分类号： C07C43/02 , C07C43/20
CPC分类号： C07C43/123 , C07C41/01 , C07C43/126
摘要： A process for preparing (per)fluorohalogenethers having general formula: wherein: A and A′, equal to our different from each other, are selected among Cl, Br, H; m=1, 2; n=0, 1; R1 is a fluorinated substituent, preferably perfluorinated, selected from the following groups: C1-C20 linear or branched alkylic; C3-C7 cycloalkylic; aromatic, C6-C10 arylalkyl; heterocyclic or C5-C10-alkylheterocyclic; preferably perfluoroalkyl; R′ is as defined in the application; by reaction of carbonyl compounds having formula: wherein: R1 and n are as above; u=0, 1; R′ is as defined in the application; in liquid phase, with elemental fluorine and with olefinic compounds of formula: CAF═CA′F2 (III) wherein A and A′ are as above, at temperatures from −120° C. to −20° C., preferably from −100° C. to −40° C., optionally in the presence of an inert solvent under the reaction conditions.
摘要翻译：制备具有以下通式的（全）氟卤醚的方法：其中：A和A'等于我们彼此不同，选自Cl，Br，H; m = 1,2; n = 0,1; R 1是优选全氟化的氟化取代基，其选自以下基团：C 1 -C 20直链或支链烷基; C 3 -C 7环烷基; 芳族C 6 -C 10芳基烷基; 杂环或C 5 -C 10 - 烷基杂环; 优选全氟烷基; R'如申请中所定义; 通过具有下式的羰基化合物的反应：其中：R 1和n如上所述; u = 0，1; R'如申请中所定义; 在液相中使用元素氟和具有下式的烯属化合物：<？in-line-formula description =“In-line Formulas”end =“lead”？> CAF-CA'F 2 III）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中A和A'如上所述，在-120℃至-20℃的温度下，优选地 -100℃至-40℃，任选在惰性溶剂存在下，在反应条件下进行。

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