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1. 发明授权

US06706834B2 Sulphonic fluorinated ionomers 失效
标题翻译：磺化氟化离聚物
公开(公告)号：US06706834B2
公开(公告)日：2004-03-16
申请号：US09922741
申请日：2001-08-07
申请人： Ivan Wlassics , Vito Tortelli
发明人： Ivan Wlassics , Vito Tortelli
IPC分类号： C08F11418
CPC分类号： H01M8/1053 , C08F8/18 , C08F214/26 , C08F214/265 , C08J5/2237 , C08J2327/18 , H01M8/1023 , H01M8/1025 , H01M8/1039 , H01M8/106 , H01M8/1072 , H01M8/1088 , H01M2300/0082 , Y02P70/56
摘要： Sulphonic fluorinated ionomers crosslinked by radical crosslinking of: A) crosslinkable sulphonic fluorinated ionomers, having equivalent weight 380-1300 g/eq and comprising: from 48% to 85% by moles of monomeric units deriving from tetrafluoroethylene (TFE); from 15% to 47% by moles of fluorinated monomeric units containing sulphonyl groups —SO2F; from 0.01% to 5% by moles of monomeric units deriving from a bis-olefin of formula: wherein: m=2-10, preferably 4-8; R1, R2, R5, R6, equal to or different from each other, are H or C1-C5 alkyl groups; B) a fluorinated compound as crosslinking radical initiator; C) a fluorinated bis-olefin of structure (I) as crosslinking agent; the radical crosslinking being carried out at a temperature in the range 250° C.-310° C., preferably 260° C.-300° C.
摘要翻译：通过自由基交联交联的磺化氟化离聚物：A）具有当量重量380-1300g / eq的可交联磺化氟化离聚物，并且包含：衍生自四氟乙烯（TFE）的48％至85％摩尔的单体单元; 15％至含有磺酰基-SO2F的氟化单体单元47％衍生自下式的双烯烃的单体单元的0.01％至5％摩尔：其中：m = 2-10，优选4-8; R 1，R 2，R 5，R 6等于或不同的是H或C 1 -C 5烷基; B）作为交联自由基引发剂的氟化化合物; C）结构（I）的氟化双烯烃作为交联剂自由基交联在250℃-310℃，优选260℃-300℃的温度下进行。

2. 发明授权

US08933268B2 Process for the preparation of difluroacetic acid 有权
标题翻译：制备二氟乙酸的方法
公开(公告)号：US08933268B2
公开(公告)日：2015-01-13
申请号：US13883182
申请日：2011-10-28
申请人： Vito Tortelli , Cristiano Monzani , Ivan Wlassics
发明人： Vito Tortelli , Cristiano Monzani , Ivan Wlassics
IPC分类号： C07C51/41 , C07C51/02 , C07C51/00
CPC分类号： C07C51/41 , C07C51/00 , C07C51/02 , C07C51/412 , C07C53/18
摘要： A process is provided for the preparation of difluoroacetic acid from tetrafluoroethylene. The process comprises reacting tetrafluoroethylene with an aqueous solution of an inorganic base, optionally in the presence of an organic solvent.
摘要翻译：提供了从四氟乙烯制备二氟乙酸的方法。该方法包括任选地在有机溶剂存在下使四氟乙烯与无机碱的水溶液反应。

3. 发明授权

US08703889B2 Method for manufacturing fluoropolymers 有权
标题翻译：氟聚合物的制造方法
公开(公告)号：US08703889B2
公开(公告)日：2014-04-22
申请号：US13002781
申请日：2009-07-06
申请人： Giuseppe Marchionni , Vito Tortelli , Ivan Wlassics , Valeri Kapeliouchko
发明人： Giuseppe Marchionni , Vito Tortelli , Ivan Wlassics , Valeri Kapeliouchko
IPC分类号： C08F14/26
CPC分类号： C07D317/34 , C07D317/42 , C08F14/18 , C08F114/26 , C08F2/24
摘要： A method for making a fluoropolymer comprising an aqueous emulsion polymerization of one or more fluorinated monomers wherein the aqueous emulsion polymerization is carried out in the presence of at least one cyclic fluorocompound of the following formula (I): wherein X1, X2, X3, equal to or different from each other are independently selected among H, F, and C1-6 (per)fluoroalkyl groups, optionally comprising one or more catenary or non-catenary oxygen atoms; L represents a bond or a divalent group; RF is a divalent fluorinated C1-3 bridging group; Y is a hydrophilic function selected among anionic functionalities, cationic functionalities and non-ionic functionalities.
摘要翻译：一种制备含氟聚合物的方法，其包含一种或多种氟化单体的水乳液聚合，其中所述水乳液聚合在至少一种下式（I）的环状氟化合物的存在下进行：其中X1，X2，X3等于彼此独立地选自H，F和C 1-6（全）氟烷基，任选地包含一个或多个悬链或非链状氧原子; L表示键或二价基团; RF是二价氟化C1-3桥联基团; Y是选自阴离子官能团，阳离子官能团和非离子官能团的亲水性功能。

4. 发明授权

US5902857A Fluoroelastomeric compositions 失效
标题翻译：氟弹性组合物
公开(公告)号：US5902857A
公开(公告)日：1999-05-11
申请号：US733938
申请日：1996-10-18
申请人： Ivan Wlassics , Vito Tortelli , Walter Navarrini , Margherita Albano
发明人： Ivan Wlassics , Vito Tortelli , Walter Navarrini , Margherita Albano
IPC分类号： C09K3/10 , C08F8/00 , C08K5/00 , C08K5/01 , C08K5/02 , C08K5/04 , C08K5/14 , C08K5/49 , C08K5/54 , C08K5/56 , C08K5/57 , C08L27/12
CPC分类号： C08K5/54 , C08K5/0025 , C08K5/14 , C08K5/57
摘要： Curing systems for fluoroelastomers curable by peroxidic route which comprise bromine, optionally iodine, the bromine always being higher than iodine, comprising as essential elements:(I) a curing agent comprising a bis-olefin having general formula: ##STR1## wherein: R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, equal to or different from each other, are H or alkyl C.sub.1 -C.sub.5 ; Z is a linear or branched alkylenic or cycloalkylenic radical C.sub.1 -C.sub.18, optionally containing oxygen atoms, or a (per)fluoropolyoxyalkylenic radical.(II) a metallorganic hydride of formula: ##STR2## wherein: M is selected from Sn, Si, Ge, Pb; x is an integer from 1 to 3; y, z are zero or integers from 1 to 3, with the proviso y+z=4-x; w is an integer from 1 to 3; the R groups, equal to or different from each other, are selected from: alkyls C.sub.1 -C.sub.4, aryls C.sub.6 -C.sub.12, arylalkyls and alkylaryls C.sub.7 -C.sub.14, optionally containing nitrile and/or hydroxyl groups.
摘要翻译：包含溴，任选碘，总是高于碘的溴可以固化的含氟弹性体的固化体系包含作为必需元素：（I）包含具有以下通式的双烯烃的固化剂：其中：R1，R2，R3 相同或不同的R 4，R 5，R 6为H或C 1 -C 5烷基; Z是任选含有氧原子的直链或支链亚烷基或环烷基C1-C18，或（全）氟聚氧亚烷基。（II）下式的金属有机氢化物：其中：M选自Sn，Si，Ge，Pb; x是1至3的整数; y，z为零或1至3的整数，条件是y + z = 4-x; w为1〜3的整数; R基彼此相同或不同，选自烷基C1-C4，芳基C6-C12，芳基烷基和烷基芳基C7-C14，任选地含有腈和/或羟基。

5. 发明申请

US20060252968A1 Dehalogenation process 有权
标题翻译：脱卤过程
公开(公告)号：US20060252968A1
公开(公告)日：2006-11-09
申请号：US11417159
申请日：2006-05-04
申请人： Ivan Wlassics , Vito Tortelli
发明人： Ivan Wlassics , Vito Tortelli
IPC分类号： C07C41/24
CPC分类号： C07C17/23 , C07C41/24 , C07C41/48 , C07C43/17 , C07D317/42 , C07C21/20 , C07C43/313
摘要： A process for obtaining vinyl compounds by dehalogenation of halofluorinated compounds having a linear, branched or cyclic structure, said halofluorinated compounds containing in the molecule at least one group: wherein Y1 and Y2, equal to or different from each other, are selected from Cl, Br, I; wherein the halofluorinated compounds are dehalogenated in the presence of a transition metal, or of transition metal couples, by operating in a biphasic system of solvents immiscible among each other, formed of a (per)fluorinated solvent and a dipolar aprotic or protic solvent (co-solvent), wherein the ratio moles co-solvent/equivalents of the halofluorinated compound ranges from 0.5 to 10, preferably from 0.5 to 5, still more preferably from 1 to 3.
摘要翻译：一种通过使具有直链，支链或环状结构的卤代氟化化合物脱卤获得乙烯基化合物的方法，所述卤代氟化物在分子中含有至少一个基团：其中Y 1和Y 2，彼此相同或不同，选自Cl，Br，I; 其中所述卤代氟化合物在过渡金属或过渡金属偶存在下通过在彼此不混溶的溶剂的双相体系中操作而脱卤，由（一个）氟化溶剂和偶极非质子或质子溶剂（共 - 溶剂），其中所述卤化氟化合物的共溶剂/当量的摩尔比为0.5至10，优选0.5至5，还更优选1至3。

6. 发明授权

US06979699B2 Sulphonic fluorinated ionomers 失效
标题翻译：磺化氟化离聚物
公开(公告)号：US06979699B2
公开(公告)日：2005-12-27
申请号：US10768690
申请日：2004-02-02
申请人： Ivan Wlassics , Vito Tortelli
发明人： Ivan Wlassics , Vito Tortelli
IPC分类号： C08J5/18 , C08F8/18 , C08F214/26 , C08J5/20 , C08J5/22 , C08J9/42 , H01B1/06 , H01M8/02
CPC分类号： H01M8/1053 , C08F8/18 , C08F214/26 , C08F214/265 , C08J5/2237 , C08J2327/18 , H01M8/1023 , H01M8/1025 , H01M8/1039 , H01M8/106 , H01M8/1072 , H01M8/1088 , H01M2300/0082 , Y02P70/56
摘要： Sulphonic fluorinated ionomers crosslinked by radical crosslinking of: A) crosslinkable sulphonic fluorinated ionomers, having equivalent weight 380-1300 g/eq and comprising: from 48% to 85% by moles of monomeric units deriving from tetrafluoroethylene (TFE); from 15% to 47% by moles of fluorinated monomeric units containing sulphonyl groups —SO2F; from 0.01% to 5% by moles of monomeric units deriving from a bis-olefin of formula: wherein: m=2-10, preferably 4-8; R1, R2, R5, R6, equal to or different from each other, are H or C1-C5 alkyl groups; B) a fluorinated compound as crosslinking radical initiator; C) a fluorinated bis-olefin of structure (I) as crosslinking agent; the radical crosslinking being carried out at a temperature in the range 250° C.-310° C., preferably 260° C.-300° C.
摘要翻译：通过自由基交联交联的磺化氟化离聚物：A）具有当量重量380-1300g / eq的可交联磺化氟化离聚物，并且包含：衍生自四氟乙烯（TFE）的48％至85％摩尔的单体单元; 含有磺酰基-SO 2 F的氟化单体单元的15％至47％衍生自下式的双烯烃的单体单元的0.01％至5％摩尔：其中：m = 2-10，优选4-8; R 1，R 2，R 5，R 6，彼此相同或不同，为H 或C 1 -C 5烷基; B）作为交联自由基引发剂的氟化化合物; C）结构（I）的氟化双烯烃作为交联剂; 自由基交联在250℃-310℃，优选260℃-300℃的温度下进行。

7. 发明申请

US20140350181A1 HYDRO-FLUOROCOMPOUNDS 审中-公开
标题翻译：氢氟化合物
公开(公告)号：US20140350181A1
公开(公告)日：2014-11-27
申请号：US14118312
申请日：2012-05-24
申请人： Vito Tortelli , Ivan Wlassics , Cristiano Monzani , Bradley Lane Kent , Alessandro Veneroni
发明人： Vito Tortelli , Ivan Wlassics , Cristiano Monzani , Bradley Lane Kent , Alessandro Veneroni
IPC分类号： C07C59/135 , C08K3/20 , C07C51/377
CPC分类号： C07C59/135 , C07C51/00 , C07C51/377 , C07C51/41 , C07C59/115 , C08K3/20
摘要： The invention pertains to certain hydro-fluorocompounds of the following formula (I): RfO—RH—O—(CH2)m-[CF(X)n]—COOXa wherein: —Xa is H, a monovalent metal (preferably an alkaline metal) or an ammonium group of formula —N(R′n)4, wherein each of R′n, equal to or different from each other, independently represents a hydrogen atom or a C1-6 hydrocarbon group (preferably an alkyl group); —Rf is a C1-C6 (per)fluoroalkyl optionally comprising one or more catenary oxygen atoms, preferably Rf is a group of formula Rf—CH2—, wherein R′f is a C1-C5 perfluorinated group, possibly comprising one or more ethereal oxygens, preferably a C1-C3 perfluorinated group, possibly comprising one or more ethereal oxygens; —RH is a fluorine-free hydrocarbon group optionally comprising one or more catenary oxygen atoms; —X is F or CF3, preferably X is F; -m is 0 or 1; -n is 1 to 3, to a process for the manufacture of said hydro-fluorocompounds, to a method of making fluoropolymers in the presence of said hydro-fluorocompounds, and to fluoropolymer dispersions comprising said hydro-fluorocompound.
摘要翻译：本发明涉及以下式（I）的某些含氟化合物：RfO-RH-O-（CH2）m- [CF（X）n] -COOXa其中：-Xa为H，一价金属（优选碱金属）或式-N（R'n）4的铵基，其中R'n彼此相同或不同，各自独立地表示氢原子或C1-6烃基（优选烷基） ; -R f是任选地包含一个或多个链状氧原子的C 1 -C 6（全）氟代烷基，优选Rf是式Rf-CH 2 - 的基团，其中R 1f是C 1 -C 5全氟化基团，可能包含一个或多个醚氧，优选C1-C3全氟化基团，可能包含一个或多个醚类氧; -RH是任选地包含一个或多个链状氧原子的无氟烃基; -X是F或CF 3，优选X是F; -m为0或1; -n为1至3，涉及一种制备所述含氟化合物的方法，涉及一种在所述含氟化合物存在下制备含氟聚合物的方法，以及含有所述氢氟化合物的含氟聚合物分散体。

8. 发明申请

US20130231502A1 Process for the Preparation of Difluroacetic Acid 有权
标题翻译：二氟乙酸的制备方法
公开(公告)号：US20130231502A1
公开(公告)日：2013-09-05
申请号：US13883182
申请日：2011-10-28
申请人： Vito Tortelli , Cristiano Monzani , Ivan Wlassics
发明人： Vito Tortelli , Cristiano Monzani , Ivan Wlassics
IPC分类号： C07C51/41 , C07C51/02
CPC分类号： C07C51/41 , C07C51/00 , C07C51/02 , C07C51/412 , C07C53/18
摘要： A process is provided for the preparation of difluoroacetic acid from tetrafluoroethylene. The process comprises reacting tetrafluoroethylene with an aqueous solution of an inorganic base, optionally in the presence of an organic solvent.
摘要翻译：提供了从四氟乙烯制备二氟乙酸的方法。该方法包括任选地在有机溶剂存在下使四氟乙烯与无机碱的水溶液反应。

9. 发明授权

US07622616B2 Dehalogenation process 有权
标题翻译：脱卤过程
公开(公告)号：US07622616B2
公开(公告)日：2009-11-24
申请号：US11417159
申请日：2006-05-04
申请人： Ivan Wlassics , Vito Tortelli
发明人： Ivan Wlassics , Vito Tortelli
IPC分类号： C07C41/24 , C07D317/10
CPC分类号： C07C17/23 , C07C41/24 , C07C41/48 , C07C43/17 , C07D317/42 , C07C21/20 , C07C43/313
摘要： A process for obtaining vinyl compounds by dehalogenation of halofluorinated compounds having a linear, branched or cyclic structure, said halofluorinated compounds containing in the molecule at least one group: wherein Y1 and Y2, equal to or different from each other, are selected from Cl, Br, I; wherein the halofluorinated compounds are dehalogenated in the presence of a transition metal, or of transition metal couples, by operating in a biphasic system of solvents immiscible among each other, formed of a (per)fluorinated solvent and a dipolar aprotic or protic solvent (co-solvent), wherein the ratio moles co-solvent/equivalents of the halofluorinated compound ranges from 0.5 to 10, preferably from 0.5 to 5, still more preferably from 1 to 3.
摘要翻译：一种通过使具有直链，支链或环状结构的卤代氟化化合物脱卤获得乙烯基化合物的方法，所述卤代氟化合物在分子中含有至少一个基团：其中Y1和Y2彼此相同或不同，选自Cl， Br，I 其中所述卤代氟化合物在过渡金属或过渡金属偶存在下通过在彼此不混溶的溶剂的双相体系中操作而脱卤，由（一个）氟化溶剂和偶极非质子或质子溶剂（共 - 溶剂），其中所述卤化氟化合物的共溶剂/当量的摩尔比为0.5至10，优选0.5至5，还更优选1至3。

10. 发明授权

US07358405B2 Dehalogenation process 有权
标题翻译：脱卤过程
公开(公告)号：US07358405B2
公开(公告)日：2008-04-15
申请号：US11416129
申请日：2006-05-03
申请人： Ivan Wlassics , Vito Tortelli
发明人： Ivan Wlassics , Vito Tortelli
IPC分类号： C07C17/00 , C07C17/25 , C07C19/08
CPC分类号： C07C41/24 , C07C43/225
摘要： A process for obtaining vinyl compounds by dehalogenation of halofluorinated compounds with aromatic substituents, having formula: T-Ar—(O)y—CFX′—CF2X″ (I) wherein: X′=F, Cl, Br, I; X″=Cl, Br, I; y=0,1; when y=0 X′≠F; T=H, —(O)y—CFX′—CF2X″, wherein y, X′ and X″ are as above; Ar is a monocyclic, bicyclic or tricyclic bivalent aromatic radical from 6 to 14 carbon atoms, optionally containing heteroatoms, or Ar is formed of two aromatic rings linked by a bivalent radical; said process characterized in that the halofluorinated compounds are dehalogenated in the presence of a transition metal, by operating in a biphasic system of solvents immiscible among each other, formed of a (per)fluorinated solvent and a dipolar aprotic or protic solvent (co-solvent), wherein the ratio moles co-solvent/equivalents of the halofluorinated compound with aromatic substituents ranges from 0.5 to 10.
摘要翻译：通过卤代氟化化合物与芳族取代基脱卤获得乙烯基化合物的方法，具有下式：<？in-line-formula description =“In-line formula”end =“lead”？> T-Ar-（O） y-X'“（I）<？in-line-formula description =”In-line Formulas“end =”tail“？>其中：X' = F，Cl，Br，I; X“= Cl，Br，I; y = 0,1; 当y = 0时X'<> F; T = H， - （O）y -CFX'-CF 2 X“，其中y，X'和X”如上所述; Ar是6至14个碳原子的单环，双环或三环二价芳族基团，任选地含有杂原子，或Ar由两价基团连接的两个芳环形成; 所述方法的特征在于，在过渡金属存在下，通过在相互不混溶的溶剂的双相体系中操作，卤代氟化化合物脱卤，由（全）氟化溶剂和偶极非质子或质子溶剂（共溶剂），其中卤代氟化化合物与芳族取代基的共溶剂/当量的摩尔比为0.5至10。

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