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    • 32. 发明授权
    • Forming ferroelectric Pb(Zr,Ti)O3 films
    • 形成铁电Pb(Zr,Ti)O3薄膜
    • US06730354B2
    • 2004-05-04
    • US09925223
    • 2001-08-08
    • Stephen R. GilbertKaushal SinghSanjeev AggarwalStevan Hunter
    • Stephen R. GilbertKaushal SinghSanjeev AggarwalStevan Hunter
    • C23C1640
    • C23C16/409H01L21/31691Y10S427/101
    • Improved methods of forming PZT thin films that are compatible with industry-standard chemical vapor deposition production techniques are described. These methods enable PZT thin films having thicknesses of 70 nm or less to be fabricated with high within-wafer uniformity, high throughput and at a relatively low deposition temperature. In one aspect, a source reagent solution comprising a mixture of a lead precursor, a titanium precursor and a zirconium precursor in a solvent medium is provided. The source reagent solution is vaporized to form a precursor vapor. The precursor vapor is introduced into a chemical vapor deposition chamber containing the substrate. In another aspect, before deposition, the substrate is preheated during a preheating period. After the preheating period, the substrate is disposed on a heated susceptor during a heating period, after which a PZT film is formed on the heated substrate.
    • 描述了与工业标准化学气相沉积生产技术相容的形成PZT薄膜的改进方法。 这些方法使得厚度为70nm以下的PZT薄膜能够制造成具有高的晶片内均匀性,高产量和较低的沉积温度。 一方面,提供了在溶剂介质中包含铅前体,钛前体和锆前体的混合物的源试剂溶液。 源试剂溶液蒸发以形成前体蒸气。 将前体蒸气引入含有基材的化学气相沉积室中。 另一方面,在沉积之前,在预热期间预热衬底。 在预热期间之后,在加热时间内将衬底设置在加热的基座上,之后在被加热的衬底上形成PZT膜。
    • 33. 发明授权
    • One step deposition process for the top electrode and hardmask in a ferroelectric memory cell
    • 在铁电存储器单元中的顶部电极和硬掩模的一步沉积工艺
    • US06576482B1
    • 2003-06-10
    • US10140481
    • 2002-05-07
    • Sanjeev AggarwalScott R. SummerfeltStevan G. Hunter
    • Sanjeev AggarwalScott R. SummerfeltStevan G. Hunter
    • H01L2100
    • H01L28/75H01L21/28568H01L21/3143H01L28/55
    • One aspect of the invention relates to a one-step process for forming a transition metal aluminum oxynitride layer over a transition metal aluminum nitride layer. The transition metal aluminum nitride layer is sputter deposited using a transition metal/aluminum target in an atmosphere containing nitrogen. Subsequently, the oxygen content of the atmosphere is increased, whereby the transition metal aluminum oxynitride layer can be deposited without interrupting the process or otherwise reconditioning the target. Another aspect of the invention relates to depositing a transition metal aluminum nitride layer over a transition metal aluminum oxynitride layer by reducing the oxygen content of the atmosphere. The invention provides a one-step process for depositing a hard mask layer and upper diffusion barrier layer for the capacitor stack of a FeRAM. A top electrode, such as an Ir/IrO electrode, can be deposited as part of the one-step process.
    • 本发明的一个方面涉及在过渡金属氮化铝层上形成过渡金属铝氧氮化物层的一步法。 使用过渡金属/铝靶在含氮的气氛中溅射沉积过渡金属氮化铝层。 随后,气氛的氧含量增加,从而可以沉积过渡金属铝氮氧化物层,而不会中断该工艺或以其他方式修复靶。 本发明的另一方面涉及通过降低大气中的氧含量在过渡金属铝氮氧化物层上沉积过渡金属氮化铝层。 本发明提供了一种用于沉积FeRAM的电容器堆叠的硬掩模层和上扩散阻挡层的一步法。 作为一步法的一部分,可以沉积上电极,例如Ir / IrO电极。
    • 37. 发明授权
    • Cycling to mitigate imprint in ferroelectric memories
    • 循环以减轻铁电记忆中的印记
    • US07729156B2
    • 2010-06-01
    • US11964223
    • 2007-12-26
    • John Anthony RodriguezSanjeev Aggarwal
    • John Anthony RodriguezSanjeev Aggarwal
    • G11C11/22
    • G11C11/22G11C29/50
    • The method includes storing a memory data state in the ferroelectric memory cell. An event will trigger the evaluation of signal margin on a memory cell. If the memory cell is identified to have a weak signal, the memory cell is exercised. Exercising includes either performing one or more data read/re-write events or performing one or more simulated data read and data write events of an alternating high data state and a low data state to the memory cell associated with the weak data bit. Both the lifetime retention testing and the memory data state exercising are performed in the background of normal memory operation.
    • 该方法包括将存储器数据状态存储在铁电存储单元中。 事件将触发对存储器单元的信号余量的评估。 如果存储器单元被识别为具有弱信号,则执行存储器单元。 执行包括执行一个或多个数据读取/重写事件,或者执行交替的高数据状态和低数据状态的一个或多个模拟数据读取和数据写入事件到与弱数据位相关联的存储器单元。 寿命保留测试和存储器数据状态行使都是在正常存储器操作的背景下执行的。
    • 39. 发明申请
    • Ferroelectric memory cells and methods for fabricating ferroelectric memory cells and ferroelectric capacitors thereof
    • 铁电存储单元及其制造铁电存储单元及其铁电电容器的方法
    • US20060073613A1
    • 2006-04-06
    • US10952987
    • 2004-09-29
    • Sanjeev AggarwalK. UdayakumarJames Martin
    • Sanjeev AggarwalK. UdayakumarJames Martin
    • H01L21/00H01L21/20H01L21/8242
    • H01L28/57H01L27/11502H01L27/11507
    • Methods (100) are provided for fabricating a ferroelectric capacitor in a semiconductor device wafer, comprising forming (118) a lower electrode, depositing (126) PZT ferroelectric material on the lower electrode at a temperature below 450 degrees C., and forming (128) an upper electrode on the PZT. Methods are also provided for fabricating a ferroelectric memory cell in a semiconductor device wafer, comprising forming (106) a transistor in the wafer, forming (108) a nickel silicide structure on the gate or a source/drain of the transistor, forming (110) a dielectric over the transistor, forming (112) a conductive contact extending through the dielectric to the silicide structure, forming (114, 116, 118, 120) a lower electrode on at least a portion of the conductive contact, forming (126) PZT ferroelectric material above and in contact with the lower electrode at a temperature below 450 degrees C., forming (128, 132) an upper electrode above and in contact with the PZT, and patterning (134) the upper electrode, the PZT, and the lower electrode to form a patterned ferroelectric capacitor.
    • 提供了用于在半导体器件晶片中制造铁电电容器的方法(100),包括在低于450℃的温度下形成(118)下电极,在下电极上沉积(126)PZT铁电材料,以及形成(128 )PZT上的上电极。 还提供了用于在半导体器件晶片中制造铁电存储单元的方法,包括在晶片中形成(106)晶体管,在晶体管的栅极或源极/漏极上形成(108)硅化镍结构,形成(110) )在所述晶体管上形成电介质,形成(112)延伸穿过所述电介质到所述硅化物结构的导电接触,在所述导电接触的至少一部分上形成(114,116,118,120)下电极, PZT铁电体材料在低于450℃的温度下方与下电极接触,在PZT上方形成(128,132)上电极并与PZT接触,并且(134)上电极,PZT和 下电极形成图案化的铁电电容器。