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31. 发明授权

US06331376B1 Organic-solvent-based photocurable resist composition and resist pattern-forming method 失效
标题翻译：有机溶剂型光固化抗蚀剂组合物和抗蚀剂图案形成方法
公开(公告)号：US06331376B1
公开(公告)日：2001-12-18
申请号：US09582846
申请日：2000-07-05
申请人： Daisuke Kojima , Genji Imai , Jun Akui , Hideo Kogure , Osamu Isozaki
发明人： Daisuke Kojima , Genji Imai , Jun Akui , Hideo Kogure , Osamu Isozaki
IPC分类号： G03F7029
CPC分类号： G03F7/027 , C08F290/067 , C08G18/672 , C08G18/7642 , G03F7/0388 , C08G18/48 , C08G18/0823
摘要： An organic solvent based photocurable resist composition containing a photopolymerizable polyurethane compound having a repeating unit represented by the following formula: B—[X]n[Y]m—B, where X is represented by the formula: and Y is represented by the formula: —OOCHN—A—NHCOO(R2)—, A is a structural unit derived from a polyisocyanate compound, B is same or different and a structural unit derived from a hydroxy compound having at least one photopolymerizable unsaturated group at molecular terminals respectively and optionally containing an ether linkage, R1 is a structural unit derived from a carboxyl group-containing polyol compound, R2 is a structural unit derived from a polyol compound, n is an integer of 1 to 10, m is an integer of 1 to 10, provided that one X and one Y are bonded to each other, or three or more of X and/or Y are bonded to each other.
摘要翻译：含有具有下式表示的重复单元的光聚合性聚氨酯化合物的有机溶剂型光固化抗蚀剂组合物：B- [X] n [Y] mB，其中X由下式表示：Y由下式表示： - OOCHN-A-NHCOO（R2） - ，A是衍生自多异氰酸酯化合物的结构单元，B相同或不同，并且衍生自在分子末端具有至少一个光聚合性不饱和基团的羟基化合物的结构单元，并且任选地含有醚键，R1是衍生自含羧基的多元醇化合物的结构单元，R2是衍生自多元醇化合物的结构单元，n是1〜10的整数，m是1〜10的整数，条件是一个 X和一个Y彼此键合，或者X和/或Y中的三个或更多个彼此键合。

32. 发明授权

US5578695A Crosslinking agent and curable composition 失效
标题翻译：交联剂和可固化组合物
公开(公告)号：US5578695A
公开(公告)日：1996-11-26
申请号：US357267
申请日：1994-12-13
申请人： Osamu Isozaki
发明人： Osamu Isozaki
IPC分类号： C08G59/42 , C08G67/04 , C08L63/00 , C08L73/02 , C09D133/06
CPC分类号： C08L63/00 , C08G59/42 , C08G67/04 , C08L73/02 , C09D133/068
摘要： The invention provides a crosslinking agent comprising a compound having at least two noncyclic acid anhydride groups and represented by the following formula ##STR1## wherein R is a monovalent hydrocarbon group having 2 to 50 carbon atoms, R' is a bivalent hydrocarbon group having 2 to 50 carbon atoms, the hydrocarbon groups R and R' containing or not containing an ether linkage, urethane linkage or ester linkage, and n is an integer of 1 to 500.The invention also provides a curable composition including (A) at least one resin selected from the group consisting of (i) a resin having at least one epoxy group and at least one hydroxyl group in the molecule, (ii) a resin mixture of a resin having at least two epoxy groups in the molecule and a resin having at least two hydroxyl groups in the molecule, and (iii) a resin having at least two epoxy groups in the molecule, and (B) the above-mentioned crosslinking agent.
摘要翻译：本发明提供了包含具有至少两个非环状酸酐基团并由下式表示的化合物的交联剂：其中R是具有2-50个碳原子的一价烃基，R'是二价烃基具有2-50个碳原子，含有或不含醚键的烃基R和R'，氨基甲酸酯键或酯键，n是1至500的整数。本发明还提供一种可固化组合物，其包含（A）至少一种树脂，其选自（i）分子中具有至少一个环氧基和至少一个羟基的树脂，（ii）分子中具有至少两个环氧基的树脂的树脂混合物和分子中具有至少两个羟基的树脂，和（iii）分子中具有至少两个环氧基的树脂和（B）上述交联剂。

33. 发明授权

US5426135A Composition for forming soil preventing coating 失效
标题翻译：防止涂层的成分
公开(公告)号：US5426135A
公开(公告)日：1995-06-20
申请号：US177934
申请日：1994-01-06
申请人： Osamu Isozaki , Kiyoshi Nanishi , Hisashi Isaka
发明人： Osamu Isozaki , Kiyoshi Nanishi , Hisashi Isaka
IPC分类号： C08F8/42 , C08F8/46 , C08G77/442 , C09D5/16 , C09D135/00 , C09D183/06 , C09D183/10 , C09D201/08 , C09D201/10
CPC分类号： C08G77/442 , C08F8/42 , C08F8/46 , C09D135/00 , C09D183/06 , C09D183/10 , C09D201/08 , C09D201/10 , C09D5/165
摘要： The present invention provides a soil preventing coating forming composition which consists essentially of a resin having at least two acid anhydride groups in the molecule on the average, the acid anhydride groups being represented by the formula ##STR1## wherein R is a C.sub.1-40 monovalent hydrocarbon group or a monovalent chain polysiloxane group represented by the formula ##STR2## wherein R.sub.1 and R.sub.2 are the same or different and are each alkyl, cycloalkyl, aryl, aralkyl or ##STR3## group, R.sub.3, R.sub.4, R.sub.5, R.sub.6 and R.sub.7 are the same or different and are each alkyl, cycloalkyl, aryl or aralkyl, n is an integer of 1 to 6, m is an integer of 0 or 1, p is an integer of 2 to 50, and q is an integer of 0 to 50.
摘要翻译：本发明提供一种防污涂层形成组合物，其基本上由分子中具有至少两个酸酐基团的树脂组成，平均酸酐基由式碳基团表示，或由式式（II）其中R 1和R 2相同或不同并且各自为烷基，环烷基，芳基，芳烷基或者基团，R 3，R 4，R 5，R 6和R 7相同或不同，各自为烷基，环烷基，芳基或芳烷基，n为1〜6的整数，m为0或1的整数，p为2〜50的整数，q为0〜50的整数。

34. 发明授权

US5093223A Method of forming a cured coating film 失效
标题翻译：形成固化涂膜的方法
公开(公告)号：US5093223A
公开(公告)日：1992-03-03
申请号：US278505
申请日：1988-12-01
申请人： Naozumi Iwasawa , Osamu Isozaki
发明人： Naozumi Iwasawa , Osamu Isozaki
IPC分类号： B05D3/06 , C08G59/14 , C08J3/28 , G03F7/038
CPC分类号： G03F7/038 , B05D3/068 , C08G59/1433 , C08J3/28 , G03F7/0388 , Y10S522/904
摘要： The invention provides a method of forming a cured coating film which comprises exposing a coating composition consisting of, or containing as a main component, a resin containing polymerizable unsaturated group and aprotic onium-containing group of the formula ##STR1## wherein R.sub.1 means a hydrogen atom or a hydrocarbon group of 1 to 8 carbon atoms which may optionally be substituted by a hydroxyl, alkoxy or ester group or a halogen atom; ##STR2## where Z means a nitrogen atom or phosphorus atom and Y means a sulfur atom; R.sub.2, R.sub.3 and R.sub.4 are the same or different and respectively mean an organic group of 1 to 14 carbon atoms, provided that R.sub.2 and R.sub.3, or R.sub.2, R.sub.3 and R.sub.4 may jointly form a heterocyclic group taken together with the adjacent nitrogen, phosphorus or sulfur atom, to actinic radiation or electron beams to thereby induce a crosslinking reaction and, then, subjecting the composition to heat treatment at a temperature not less than 80.degree. C.
摘要翻译：本发明提供一种形成固化涂膜的方法，该方法包括使包含可聚合不饱和基团的树脂和式（Ⅰ）所示的非质子含鎓基团组成或包含作为主要成分的涂料组合物，其中R 1 是指氢原子或可任选被羟基，烷氧基或酯基或卤素原子取代的1至8个碳原子的烃基; 其中Z表示氮原子或磷原子，Y表示硫原子; R 2，R 3和R 4相同或不同，分别表示1至14个碳原子的有机基团，条件是R 2和R 3或R 2，R 3和R 4可以与相邻的氮，磷或磷一起形成杂环基硫原子，光化辐射或电子束，从而引起交联反应，然后使组合物在不低于80℃的温度下进行热处理。

35. 发明授权

US5087286A Heat-curable resinous coating composition 失效
标题翻译：可固化树脂涂料组合物
公开(公告)号：US5087286A
公开(公告)日：1992-02-11
申请号：US496201
申请日：1990-03-19
申请人： Mitsuhiro Fukuda , Hirotoshi Inoue , Akira Kasari , Yuzo Miyamoto , Osamu Isozaki , Noboru Nakai
发明人： Mitsuhiro Fukuda , Hirotoshi Inoue , Akira Kasari , Yuzo Miyamoto , Osamu Isozaki , Noboru Nakai
IPC分类号： C09D133/08 , C09D163/00 , C09D167/00 , C09D183/04
CPC分类号： C09D167/00 , C09D133/08 , C09D163/00 , C09D183/04
摘要： A heat-curable resinous coating composition comprising as a binder component(A) 5 to 90% by weight of a hydroxyl-containing resin selected from hydroxyl-containing acrylic resins and hydroxyl-containing polyester resins,(B) 5 to 50% by weight of an amino resin, and(C) 1 to 90% by weight of a crosslinkable resin selected from (C-a) polyfunctional resins having a number average molecular weight of at least 1000 and containing at least two carboxyl groups and at least two epoxy groups on an average per molecule and (C-b) polyorganosiloxanes having a number average molecular weight of at least 500 and containing at least two silanol groups on an average per molecule and if required, further containing an epoxy group.

36. 发明授权

US5026793A Resin compositions and a method of curing the same 失效
标题翻译：树脂组合物及其固化方法
公开(公告)号：US5026793A
公开(公告)日：1991-06-25
申请号：US402408
申请日：1989-09-05
申请人： Noboru Nakai , Osamu Isozaki , Naozumi Iwasawa
发明人： Noboru Nakai , Osamu Isozaki , Naozumi Iwasawa
IPC分类号： C08G59/40 , C07F7/08 , C07F7/18 , C08G59/00 , C08G59/02 , C08G59/04 , C08G59/30 , C08G59/32 , C08G59/70 , C08K5/00 , C08K5/07 , C08K5/1515 , C08K5/5415 , C08L33/06 , C08L43/04 , C08L63/00 , C08L75/04 , C08L101/06 , C09D133/06 , C09D133/14 , C09D143/04 , C09D163/00
CPC分类号： C08L63/00 , C07F7/0836 , C07F7/0858 , C07F7/0859 , C07F7/182 , C07F7/1836 , C07F7/1844 , C07F7/1896 , C08G59/02 , C08G59/04 , C08G59/306 , C08G59/3254 , C08G59/70 , C08K5/00 , C08K5/0091 , C08K5/07 , C08K5/1515 , C08K5/5415 , C08L101/06 , C08L75/04 , C09D133/064 , C09D133/068 , C09D143/04 , C09D163/00 , C08L33/068 , C08L43/04
摘要： A resinous composition containing (A) a high molecular weight hydroxy compound having 2 or more hydroxy groups per molecule and having a number average molecular weight of 3,000 to 200,000, (B) a high molecule weight epoxy compound having 2 or more epoxy groups per molecule and having a number average molecular weight of 120 to 200,000, (C) a silane compound having one or more silicon-containing functional groups per molecule and (D) a chelate of aluminum, titanium or zirconium with a ligand exhibiting ketoenol tautomerism, can be cured at temperatures not exceeding 100.degree. C. and forms a desirable coating when cured.

37. 发明授权

US4972027A Composition curable at low temperature 失效
标题翻译：组合物在低温下可固化
公开(公告)号：US4972027A
公开(公告)日：1990-11-20
申请号：US271268
申请日：1988-11-15
申请人： Osamu Isozaki , Noboru Nakai , Shinji Sugiura , Satoru Ito , Seiji Takami
发明人： Osamu Isozaki , Noboru Nakai , Shinji Sugiura , Satoru Ito , Seiji Takami
IPC分类号： C08F2/08 , C08K5/00 , C09D143/04
CPC分类号： C08K5/0091 , C08F2/08 , C09D143/04
摘要： Disclosed is a composition curable at a low temperature and characterized in that the composition comprises:(a) a nonaqueous dispersion of a particulate polymer insoluble in an organic liquid and prepared by polymerizing a radical-polymerizable unsaturated monomer in the organic liquid in the presence of a dispersion stabilizer resin, the stabilizer resin being at least one of a copolymer comprising as its monomer components an oxirane-containing vinyl monomer and an alkoxysilane-containing vinyl monomer and a vinyl copolymer comprising as its monomer components a polysiloxane macromonomer and an oxirane-containing vinyl monomer,(b) a chelate compound admixed with a nonaqueous dispersion.
摘要翻译：本发明公开了一种可在低温下固化的组合物，其特征在于该组合物包括：（a）不溶于有机液体的颗粒状聚合物的非水分散体，其通过在有机液体存在下使可自由基聚合的不饱和单体聚合而制备分散稳定剂树脂，所述稳定剂树脂是包含作为其单体组分的含环氧乙烷的乙烯基单体和含烷氧基硅烷的乙烯基单体和乙烯基共聚物中的至少一种，其包含作为其单体组分的聚硅氧烷大分子单体和含环氧乙烷的乙烯基共聚物乙烯基单体，（b）与非水分散体混合的螯合化合物。

38. 发明授权

US4923945A Resin composition curable at low temperature 失效
标题翻译：树脂组合物在低温下可固化
公开(公告)号：US4923945A
公开(公告)日：1990-05-08
申请号：US268406
申请日：1988-11-08
申请人： Osamu Isozaki , Noboru Nakai , Satoru Ito , Seiji Takami
发明人： Osamu Isozaki , Noboru Nakai , Satoru Ito , Seiji Takami
IPC分类号： C08F283/12 , C08K5/00 , C08K5/1515 , C08K5/205 , C08L33/06 , C08L43/04 , C08L83/07
CPC分类号： C08K5/205 , C08F283/124 , C08K5/0091 , C08K5/1515 , C08L33/06 , C08L43/04
摘要： Disclosed is a resin composition curable at a low temperature and characterized in that the composition comprises:(a) at least one of a copolymer comprising as its monomer components an oxirane-containing vinyl monomer and an alkoxysilane-containing vinyl monomer and a vinyl copolymer comprising at its monomer components a polysiloxane macromonomer and an oxirane-containing vinyl monomer,(b) a chelate compound, and(c) a compound having a number average molecular weight of up to about 1,000 and containing at least two alicyclic oxirane groups in the molecule.
摘要翻译：公开了一种在低温下可固化的树脂组合物，其特征在于该组合物包含：（a）包含含环氧乙烷的乙烯基单体和含烷氧基硅烷的乙烯基单体作为其单体成分的共聚物和乙烯基共聚物中的至少一种，其单体组分为聚硅氧烷大分子单体和含环氧乙烷的乙烯基单体，（b）螯合化合物，和（c）数均分子量高达约1,000并且在分子中含有至少两个脂环族环氧基团的化合物。

39. 发明授权

US4895910A Resin composition curable at low temperature 失效
标题翻译：树脂组合物在低温下可固化
公开(公告)号：US4895910A
公开(公告)日：1990-01-23
申请号：US161822
申请日：1988-02-29
申请人： Osamu Isozaki , Noboru Nakai
发明人： Osamu Isozaki , Noboru Nakai
IPC分类号： C08G59/32 , C08F8/42 , C08G59/20 , C08G59/40 , C08G59/70 , C08J7/04 , C08L63/00 , C08L83/04 , C08L83/07 , C09D4/02 , C09D155/00 , C09D183/07
CPC分类号： C08F8/42 , C09D155/005
摘要： This invention provides a resin composition curable at a low temperature and characterized in that the composition comprises:(a) a copolymer prepared from a polysiloxane macromonomer and an epoxy-containing monomer both containing ethylenically unsaturated groups,the polysiloxane macromonomer being prepared by reacting 70 to 99.999 mole % of a compound (A) represented by the formula ##STR1## wherein R.sub.1 is an aliphatic hydrocarbon group having 1 to 8 carbon atoms or phenyl, and R.sub.2, R.sub.3 and R.sub.4 are each alkoxyl having 1 to 4 carbon atoms or hydroxyl with 30 to 0.001 mole % of a compound (B) represented by the formula ##STR2## wherein R.sub.5 is a hydrogen atom or methyl, R.sub.6, R.sub.7 and R.sub.8 are each hydroxyl, alkoxyl having 1 to 4 carbon atoms or an aliphatic hydrocarbon group having 1 to 8 carbon atoms, at least one of R.sub.6, R.sub.7 and R.sub.8 being hydroxyl or alkoxyl, and n is an integer of 1 to 6, the polysiloxane macromonomer having per molecule at least two functional groups selected from hydroxyl and the alkoxyl and being 400 to 100000 in number average molecular weight,the epoxy-containing monomer having at its terminal end the group ##STR3## wherein (Z) forms an alicyclic group with the C--C bond, and (b) a 6-coordinate organoaluminum chelate compound and/or an 8-coordinate organozirconium chelate compound.
摘要翻译：本发明提供了一种在低温下可固化的树脂组合物，其特征在于该组合物包括：（a）由聚硅氧烷大分子单体和含有烯键式不饱和基团的含环氧基的单体制备的共聚物，所述聚硅氧烷大分子单体通过使70与 99.999摩尔％的由式（I）表示的化合物（A），其中R1是具有1-8个碳原子的脂族烃基或苯基，R2，R3和R4分别是具有1至4个碳原子的烷氧基或具有30至0.001摩尔％的由式（II）表示的化合物（B）的羟基，其中R 5是氢原子或甲基，R 6，R 7和R 8各自是羟基，具有1至4个碳原子的烷氧基或具有1至8个碳原子的脂族烃基，R 6，R 7和R 8中的至少一个为羟基或烷氧基，n为1至6的整数，每分子至少两个选自羟基的官能团的聚硅氧烷大分子单体 1，烷氧基，数均分子量为400〜100000，含环氧基的单体末端为基团，其中（Z）与CC键形成脂环族基团，（b）6- 配位有机铝螯合物和/或8-配位有机锆螯合物。

40. 发明授权

US4514471A Process for the preparation of electron beam curing gypsum panel 失效
标题翻译：电子束固化石膏板的制备工艺
公开(公告)号：US4514471A
公开(公告)日：1985-04-30
申请号：US594434
申请日：1984-03-29
申请人： Kenji Sugimoto , Osamu Isozaki
发明人： Kenji Sugimoto , Osamu Isozaki
IPC分类号： B28B11/04 , C04B28/14 , C04B41/48 , C04B41/63 , B05D3/06
CPC分类号： C04B41/009 , C04B28/146 , C04B41/48 , C04B41/63
摘要： Disclosed is a process for the preparation of an electron beam curing gypsum panel which comprises subjecting a hydrated gypsum slurry containing or free of an additive, fibrous material, fine aggregates, water, etc. to defoaming, setting and drying to form a gypsum substrate, coating an electron beam curing resin composition on the surface of the gypsum substrate to form a coated film, and irradiating accelerated electron beam on the coated film thereby to be cured.
摘要翻译：公开了一种制备电子束固化石膏板的方法，该方法包括使含有或不含添加剂，纤维材料，细骨料，水等的水合石膏浆料脱泡，固化和干燥以形成石膏基材，在石膏基材的表面上涂布电子束固化树脂组合物以形成涂膜，并将加速的电子束照射在涂膜上，从而进行固化。

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