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31. 发明授权

US07537786B2 Complex of drug-carbon nanohorn and a process for producing the complex 有权
标题翻译：药物 - 碳纳米角复合物及其制备方法
公开(公告)号：US07537786B2
公开(公告)日：2009-05-26
申请号：US11212645
申请日：2005-08-29
申请人： Sumio Iijima , Masako Yudasaka , Kumiko Ajima , Tatsuya Murakami , Kiyotaka Shiba
发明人： Sumio Iijima , Masako Yudasaka , Kumiko Ajima , Tatsuya Murakami , Kiyotaka Shiba
IPC分类号： A61K9/14 , A61K33/24 , A61K38/16
CPC分类号： A61K9/167 , A61K9/1617 , A61K31/573 , A61K33/24 , Y10S977/734 , Y10S977/744 , Y10S977/906
摘要： The present invention provides a carbon nanohorn complex that is excellent in characteristics of adsorption or inclusion of drugs and release, in particular, a sustained release of drugs as a novel drug carrier in drug delivery systems, as well as a process for producing the complex. The complex of drug and carbon nanohorns comprises a steroidal or metal-containing drug being adsorbed onto the oxidized carbon nanohorns, or included in pores opened thereof.
摘要翻译：本发明提供一种碳纳米角复合物，其特征在于吸附或包裹药物，特别是药物递送系统中作为新型药物载体的药物的持续释放以及生产该复合物的方法。药物和碳纳米角的复合物包含吸附在氧化的碳纳米角上的甾体或含金属的药物，或包含在其中打开的孔中。

32. 发明授权

US07209341B2 Polarizing electrode, manufacturing method thereof, and electric double-layer capacitor 失效
标题翻译：极化电极，其制造方法和双电层电容器
公开(公告)号：US07209341B2
公开(公告)日：2007-04-24
申请号：US10815120
申请日：2004-03-26
申请人： Tsutomu Yoshitake , Sumio Iijima , Masako Yudasaka
发明人： Tsutomu Yoshitake , Sumio Iijima , Masako Yudasaka
IPC分类号： H01G9/00
CPC分类号： H01G9/155 , H01M4/364 , H01M4/583 , Y02E60/13
摘要： An electric double-layer capacitor includes a carbon composite electrode which serves as a polarizing electrode and made of a single-layer carbon nanohorn aggregate having a specific structure and a very large surface area. The single carbon nanohorn aggregate is mixed with a phenol resin, the mixture is formed and heated to produce a carbon composite electrode. The carbon composite electrode is impregnated with an electrolyte to become a polarizing electrode. An electric double-layer capacitor includes this polarizing electrode has a large capacitance and is capable of discharging with large current.
摘要翻译：电双层电容器包括用作极化电极并由具有特定结构和非常大的表面积的单层碳纳米角骨料制成的碳复合电极。将单碳纳米角骨料与酚醛树脂混合，形成并加热该混合物以产生碳复合电极。碳复合电极用电解质浸渍成为极化电极。电气双层电容器包括该极化电极具有大的电容并且能够以大的电流放电。

33. 发明申请

US20070027029A1 Catalyst support, gas storage body and method for producing these 审中-公开
标题翻译：催化剂载体，储气体及其制备方法
公开(公告)号：US20070027029A1
公开(公告)日：2007-02-01
申请号：US10558979
申请日：2004-05-26
申请人： Daisuke Kasuya , Masako Yudasaka , Takeshi Azami , Tsutomu Yoshitake , Yoshimi Kubo , Sumio Iijima
发明人： Daisuke Kasuya , Masako Yudasaka , Takeshi Azami , Tsutomu Yoshitake , Yoshimi Kubo , Sumio Iijima
IPC分类号： B01J21/18
CPC分类号： B82Y30/00 , B01J20/20 , B01J20/205 , B01J21/185 , B82Y40/00 , C01B3/0021 , C01B32/18 , Y02E60/325 , Y02E60/327 , Y02E60/328 , Y02P20/129
摘要： Plural carbon nanohorn aggregates are mechanically mixed, and catalysts are supported on surfaces of the mixed carbon nanohorn aggregates. Alternatively gas is adsorbed on the surfaces of the mixed carbon nanohorn aggregates.
摘要翻译：将多个碳纳米角骨料机械混合，并将催化剂负载在混合碳纳米角骨料的表面上。或者，气体吸附在混合碳纳米角骨料的表面上。

34. 发明申请

US20060210464A1 Carbon nanohorn assembly producing method 审中-公开
标题翻译：碳纳米角组件生产方法
公开(公告)号：US20060210464A1
公开(公告)日：2006-09-21
申请号：US10555287
申请日：2004-05-13
申请人： Takeshi Azami , Daisuke Kasuya , Tsutomu Yoshitake , Yoshimi Kubo , Sumio Iijima , Masako Yudasaka
发明人： Takeshi Azami , Daisuke Kasuya , Tsutomu Yoshitake , Yoshimi Kubo , Sumio Iijima , Masako Yudasaka
IPC分类号： C01B31/02
CPC分类号： B82Y30/00 , B82Y40/00 , C01B32/18
摘要： In a production chamber (107), a cylindrical graphite rod (101) is fixed to a rotation device (115), enabling the graphite rod (101) to rotate around its longitudinal axis and to move right and left along its longitudinal axis. The lateral surface of the graphite rod (101) is irradiated with laser light (103) from a laser light source (111), and a nanocarbon recovering chamber (119) is installed in the direction of generation of plume (109). The pulse width of the laser light (103) is from 0.5 sec. to 1.25 sec.
摘要翻译：在生产室（107）中，圆柱形石墨棒（101）固定到旋转装置（115）上，使得石墨棒（101）能够绕其纵向轴线旋转并沿其纵向轴线左右移动。从激光源（111）向激光（103）照射石墨棒（101）的侧表面，沿着羽流（109）的产生方向安装纳米碳回收室（119）。激光（103）的脉冲宽度为0.5秒。至1.25秒

35. 发明授权

US07067096B2 Carbon nanotube-carbon nanohorn complex and method for producing the same 有权
标题翻译：碳纳米管 - 碳纳米角复合物及其制备方法
公开(公告)号：US07067096B2
公开(公告)日：2006-06-27
申请号：US10499010
申请日：2002-09-17
申请人： Sumio Iijima , Masako Yudasaka , Akira Koshio
发明人： Sumio Iijima , Masako Yudasaka , Akira Koshio
IPC分类号： B82B3/00 , C01B31/02
CPC分类号： B82Y30/00 , B82Y40/00 , C01B32/168 , C01B32/18 , Y10S977/929
摘要： A novel carbon nanotube-carbon nanohorn complex produced by a method comprising step 1 for irradiating carbon nanotube placed in a liquid solvent with ultrasonic wave to disperse carbon nanotube into the liquid solvent, and step 2 for adding carbon nanohorn aggregate to the liquid solvent dispersed with carbon nanotube to thus remove the liquid solvent, whereby the surface of the carbon nanotube and the carbon nanohorn aggregate can be utilized more effectively and the availability can be enlarged.
摘要翻译：一种新型的碳纳米管 - 碳纳米角复合体，其特征在于包括步骤1，用于将放置在液体溶剂中的碳纳米管用超声波辐射以将碳纳米管分散到液体溶剂中;以及步骤2，将碳纳米角骨料加入到分散有碳纳米管，从而去除液体溶剂，由此可以更有效地利用碳纳米管和碳纳米角骨料的表面，并且可以扩大可用性。

36. 发明申请

US20060013758A1 Method of selecting structure of carbon nanotube through photoirradiation 有权
标题翻译：通过光照射选择碳纳米管结构的方法
公开(公告)号：US20060013758A1
公开(公告)日：2006-01-19
申请号：US10521575
申请日：2003-04-01
申请人： Sumio Iijima , Masako Yudasaka , Minfang Zhang
发明人： Sumio Iijima , Masako Yudasaka , Minfang Zhang
IPC分类号： D01F9/12
CPC分类号： B82Y30/00 , B82Y40/00 , C01B32/172 , C01B2202/02 , Y10S977/75
摘要： A method for selectively obtaining carbon nanotubes having specific structures by selectively obtaining carbon nanotubes having structures different from the structures of the carbon nanotubes to be vanished by irradiating carbon nanotubes with a light beam of single wavelength so as to have carbon nanotubes in specific electron states in the excited states, and oxidizing and combusting the carbon nanotubes in the excited states by an oxygen or an oxidizing agent so as to vanish the same.
摘要翻译：选择性地获得具有特定结构的碳纳米管的方法，通过用单波长的光束照射碳纳米管，以具有特定电子态的碳纳米管，通过选择性地获得具有不同于待消失的碳纳米管结构的结构的碳纳米管，激发态，并且通过氧或氧化剂氧化和燃烧处于激发态的碳纳米管，以消除它们。

37. 发明申请

US20050106093A1 Method for preparing monolayer carbon nanotube 审中-公开
标题翻译：单层碳纳米管制备方法
公开(公告)号：US20050106093A1
公开(公告)日：2005-05-19
申请号：US10509575
申请日：2003-03-27
申请人： Sumio Iijima , Masako Yudasaka , Hiroo Hongo
发明人： Sumio Iijima , Masako Yudasaka , Hiroo Hongo
IPC分类号： C01B31/02 , D01F9/12 , D01C5/00
CPC分类号： B82Y30/00 , B82Y40/00 , C01B32/162 , C01B2202/02 , C01B2202/36
摘要： A combination of a metal-based catalyst having a function as a catalyst for formation of graphite and a single-crystal substrate having a certain correspondence to the metal-based catalyst with respect to the crystal grain size and the crystal orientation thereof is used; the metal-based catalyst is dispersed on the single-crystal substrate; and a carbon material is fed to the substrate at any temperature not lower than 500° C. to thereby form single single-walled carbon nanotubes through vapor phase thermal decomposition growth on the substrate. More precisely, the invention of this application enables production of single-walled carbon nanotubes with controlled diameter, requiring neither a porous material nor catalyst particles for use as a catalyst carrier. One example of the combination of the metal-based catalyst and the single-crystal substrate is a combination of Fe and sapphire substrate.
摘要翻译：使用具有作为形成石墨的催化剂的功能的金属类催化剂和与金属类催化剂相对应的单晶基板相对于晶粒尺寸及其晶体取向的组合; 金属基催化剂分散在单晶基板上; 并且在不低于500℃的任何温度下将碳材料供给到基板，从而通过基板上的气相热分解生长形成单个单壁碳纳米管。更准确地说，本申请的发明使得能够生产具有受控直径的单壁碳纳米管，既不需要多孔材料也不需要用作催化剂载体的催化剂颗粒。金属基催化剂和单晶基板的组合的一个实例是Fe和蓝宝石衬底的组合。

38. 发明申请

US20050037150A1 Sharp end, multi-layer carbon nano-tube radial aggregate and method of manufacturing the aggregate 有权
标题翻译：尖端，多层碳纳米管径向骨料及其制造方法
公开(公告)号：US20050037150A1
公开(公告)日：2005-02-17
申请号：US10495459
申请日：2002-11-05
申请人： Sumio Iijima , Masako Yudasaka , Akira Koshio
发明人： Sumio Iijima , Masako Yudasaka , Akira Koshio
IPC分类号： B32B9/00 , C01B31/02 , G01Q30/12 , H01L51/00 , H01L51/30 , B05D1/08 , H05H1/26
CPC分类号： B82Y30/00 , B82Y10/00 , B82Y40/00 , C01B32/16 , C01B2202/06 , C01B2202/30 , C01B2202/36 , H01L51/0048 , H01L51/0052 , Y10S977/741 , Y10T428/30
摘要： A method of manufacturing a acute tip, multi-wall carbon nanotube radial aggregate, comprising the steps of leading a graphite rod into plasma flame generated in a hydrogen-added inert gas atmosphere to evaporate carbon from the graphite rod and stacking, on the surface of the graphite rod, the acute tip, multi-wall carbon nanotube radial aggregation of novel carbon nano-structure useful as field emission electron sources such as probes for STM and APM, display elements, and displays.
摘要翻译：一种制造急尖头多壁碳纳米管径向聚集体的方法，包括以下步骤：将石墨棒引入在加氢的惰性气体气氛中产生的等离子体火焰中，以从石墨棒中蒸发碳并将其堆叠在石墨棒，尖端，多壁碳纳米管径向聚集的新型碳纳米结构可用作场致发射电子源，如STM和APM探针，显示元件和显示器。

39. 发明申请

US20050031525A1 Carbon nanotube-carbon nanohorn complex and method for producing the same 有权
标题翻译：碳纳米管 - 碳纳米角复合物及其制备方法
公开(公告)号：US20050031525A1
公开(公告)日：2005-02-10
申请号：US10499010
申请日：2002-09-17
申请人： Sumio Iijima , Masako Yudasaka , Akira Koshio
发明人： Sumio Iijima , Masako Yudasaka , Akira Koshio
IPC分类号： C01B31/02 , C01B31/00
CPC分类号： B82Y30/00 , B82Y40/00 , C01B32/168 , C01B32/18 , Y10S977/929
摘要： A novel carbon nanotube-carbon nanohorn complex produced by a method comprising step 1 for irradiating carbon nanotube placed in a liquid solvent with ultrasonic wave to disperse carbon nanotube into the liquid solvent, and step 2 for adding carbon nanohorn aggregate to the liquid solvent dispersed with carbon nanotube to thus remove the liquid solvent, whereby the surface of the carbon nanotube and the carbon nanohorn aggregate can be utilized more effectively and the availability can be enlarged.
摘要翻译：一种新型的碳纳米管 - 碳纳米角复合体，其特征在于包括步骤1，用于将放置在液体溶剂中的碳纳米管用超声波辐射以将碳纳米管分散到液体溶剂中;以及步骤2，将碳纳米角骨料加入到分散有碳纳米管，从而去除液体溶剂，由此可以更有效地利用碳纳米管和碳纳米角骨料的表面，并且可以扩大可用性。

40. 发明授权

US06331690B1 Process for producing single-wall carbon nanotubes uniform in diameter and laser ablation apparatus used therein 有权
标题翻译：用于制造直径均匀的单壁碳纳米管的方法和其中使用的激光烧蚀装置
公开(公告)号：US06331690B1
公开(公告)日：2001-12-18
申请号：US09562959
申请日：2000-05-03
申请人： Masako Yudasaka , Sumio Iijima
发明人： Masako Yudasaka , Sumio Iijima
IPC分类号： B23K2600
CPC分类号： B82Y30/00 , B01J19/121 , B01J2219/0871 , B01J2219/0883 , B01J2219/0892 , B82Y40/00 , C01B32/162 , C01B2202/02 , C01B2202/36 , Y10S977/844
摘要： Single-wall carbon nanotubes are produced from carbon vapor in the presence of nickel-cobalt catalyst vapor, and the carbon vapor and the nickel-cobalt catalyst vapor are constantly generated from a carbon pellet and a nickel-cobalt pellet under radiation of YAG laser beams so that the single-wall carbon nanotubes are constant in diameter.
摘要翻译：单壁碳纳米管由镍 - 钴催化剂蒸气存在下由碳蒸气生成，碳蒸汽和镍 - 钴催化剂蒸气在YAG激光束辐射下由碳颗粒和镍 - 钴颗粒恒定地产生使得单壁碳纳米管的直径恒定。

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