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31. 再颁专利

USRE39720E1 Catalytic reduction of emissions from internal combustion engines 失效
标题翻译：催化还原内燃机的排放
公开(公告)号：USRE39720E1
公开(公告)日：2007-07-10
申请号：US10206157
申请日：2001-04-03
申请人： Oliver J. Murphy , Craig C. Andrews
发明人： Oliver J. Murphy , Craig C. Andrews
IPC分类号： F01N3/00
CPC分类号： F01N3/2046 , F01N3/2006 , F01N3/206 , F01N3/32 , F01N13/009 , F01N2610/04 , F01N2610/08 , F02M25/12 , Y02T10/121 , Y02T10/22 , Y02T10/26 , Y10S123/12
摘要： An apparatus for treating an exhaust gas stream from cold startup through continuous operating conditions of an internal combustion engine includes an oxidizing catalyst bed disposed in an exhaust pipe and a reducing catalyst bed disposed in the exhaust pipe downstream from the oxidizing catalyst bed. The oxidizing catalyst bed as one or more oxidizing catalysts and the reducing catalyst bed has one or more reducing catalysts. A method is provided for treating an exhaust gas stream both during cold start and during continuous operating conditions of an internal combustion engine by passing the stream through an oxidizing catalyst bed having one or more oxidizing catalysts at a light off temperature; a reducing catalyst bed having one or more reducing catalysts and providing hydrogen into the reducing catalyst bed to condition the reducing catalyst; and introducing hydrogen into the internal combustion engine during cold startup.
摘要翻译：一种用于处理来自冷起动的内燃机的连续运行状态的废气流的装置，包括设置在排气管中的氧化催化剂床和设置在氧化催化剂床下游的排气管内的还原催化剂床。作为一种或多种氧化催化剂和还原催化剂床的氧化催化剂床具有一种或多种还原催化剂。提供了一种用于在冷启动期间和在内燃机的连续运行条件下处理排气流的方法，该方法是使流经过具有一种或多种氧化催化剂的氧化催化剂床在轻度关闭温度下; 还原催化剂床，其具有一种或多种还原催化剂并向还原催化剂床提供氢以调节还原催化剂; 并在冷起动期间将氢气引入内燃机。

32. 发明授权

US06838205B2 Bifunctional catalytic electrode 有权
标题翻译：双功能催化电极
公开(公告)号：US06838205B2
公开(公告)日：2005-01-04
申请号：US09974190
申请日：2001-10-10
申请人： Alan Cisar , Oliver J. Murphy , Eric Clarke
发明人： Alan Cisar , Oliver J. Murphy , Eric Clarke
IPC分类号： H01M4/86 , H01M4/90 , H01M4/92 , H01M8/18 , H01M4/96
CPC分类号： C25B9/10 , C25B1/06 , H01M4/8615 , H01M4/9016 , H01M4/921 , H01M8/186 , Y02E60/366 , Y02E60/528
摘要： The present invention relates to an oxygen electrode for a unitized regenerative hydrogen-oxygen fuel cell and the unitized regenerative fuel cell having the oxygen electrode. The oxygen electrode contains components electrocatalytically active for the evolution of oxygen from water and the reduction of oxygen to water, and has a structure that supports the flow of both water and gases between the catalytically active surface and a flow field or electrode chamber for bulk flow of the fluids. The electrode has an electrocatalyst layer and a diffusion backing layer interspersed with hydrophilic and hydrophobic regions. The diffusion backing layer consists of a metal core having gas diffusion structures bonded to the metal core.

33. 发明授权

US06712950B2 Electrochemical synthesis of ammonia 失效
标题翻译：电化学合成氨
公开(公告)号：US06712950B2
公开(公告)日：2004-03-30
申请号：US10090443
申请日：2002-03-04
申请人： Adrian Denvir , Oliver J. Murphy , Alan Cisar , Priscilla Robertson , Kyle Uselton
发明人： Adrian Denvir , Oliver J. Murphy , Alan Cisar , Priscilla Robertson , Kyle Uselton
IPC分类号： C25B100
CPC分类号： C25B1/00
摘要： A method for electrochemical synthesis of ammonia gas comprising providing an electrolyte between an anode and a cathode, providing hydrogen gas to the anode, oxidizing negatively charged nitrogen-containing species present in the electrolyte at the anode to form an adsorbed nitrogen species, and reacting the hydrogen with the adsorbed nitrogen species to form ammonia. Preferably, the hydrogen gas is provided to the anode by passing the hydrogen gas through a porous anode substrate. It is also preferred to produce the negatively charged nitrogen-containing species in the electrolyte by reducing nitrogen gas at the cathode. However, the negatively charged nitrogen-containing species may also be provided by supplying a nitrogen-containing salt, such as lithium nitride, into the molten salt electrolyte mixture in a sufficient amount to provide some or all of the nitrogen consumed in the production of ammonia.
摘要翻译：一种用于电化学合成氨气的方法，包括在阳极和阴极之间提供电解质，向阳极提供氢气，在阳极处氧化存在于电解质中的带负电荷的含氮物质以形成吸附的氮物质，并使氢与吸附的氮物质形成氨。优选地，通过使氢气通过多孔阳极基板而将氢气提供给阳极。还优选通过还原阴极处的氮气来在电解质中产生带负电的含氮物质。然而，带负电的含氮物质也可以通过向熔融盐电解质混合物中提供足够量的含氮盐（例如氮化钠）来提供在氨生产中消耗的一部分或全部氮。

34. 发明授权

US06551490B2 Generation and delivery device for ozone gas and ozone dissolved in water 失效
公开(公告)号：US06551490B2
公开(公告)日：2003-04-22
申请号：US09951094
申请日：2001-09-13
申请人： Craig C. Andrews , Oliver J. Murphy
发明人： Craig C. Andrews , Oliver J. Murphy
IPC分类号： C25B102
CPC分类号： C25B9/10 , C01B13/10 , C02F1/46104 , C02F1/46109 , C02F1/4672 , C02F1/78 , C02F2001/46128 , C02F2001/46142 , C02F2001/46157 , C02F2201/46115 , C02F2201/4612 , C02F2201/46155 , C02F2201/4616 , C02F2201/4617 , C02F2303/18 , C25B1/13 , Y02W10/37
摘要： The present invention provides an ozone generation and delivery system that lends itself to small scale applications and requires very low maintenance. The system includes an anode reservoir and a cathode phase separator each having a hydrophobic membrane to allow phase separation of produced gases from water. The system may be configured to operate passively with no moving parts or in a self-pressurizing manner with the inclusion of a pressure controlling device or valve in the gas outlet of the anode reservoir. The hydrogen gas, ozone gas and water containing ozone may be delivered under pressure.

35. 发明授权

US06461487B1 Generation and delivery device for ozone gas 失效
标题翻译：臭氧气体生成和输送装置
公开(公告)号：US06461487B1
公开(公告)日：2002-10-08
申请号：US09431424
申请日：1999-11-01
申请人： Craig C. Andrews , Oliver J. Murphy
发明人： Craig C. Andrews , Oliver J. Murphy
IPC分类号： C25B900
CPC分类号： C25B9/10 , C01B13/10 , C02F1/46104 , C02F1/46109 , C02F1/4672 , C02F1/78 , C02F2001/46128 , C02F2001/46142 , C02F2001/46157 , C02F2201/46115 , C02F2201/4612 , C02F2201/46155 , C02F2201/4616 , C02F2201/4617 , C02F2303/18 , C25B1/13
摘要： The present invention provides an ozone generation and delivery system that lends itself to small scale applications and requires very low maintenance. The system preferably includes an anode reservoir and a cathode phase separator each having a hydrophobic membrane to allow phase separation of produced gases from water. The hydrogen gas, ozone gas and water containing ozone may be delivered under pressure.
摘要翻译：本发明提供一种适用于小规模应用的臭氧产生和输送系统，并且需要非常低的维护。该系统优选地包括阳极储存器和阴极相分离器，其各自具有疏水膜，以允许产生的气体与水相分离。氢气，臭氧气体和含臭氧的水可以在压力下输送。

36. 发明授权

US06427639B1 Method and apparatus for warming intake air to an internal combustion engine 失效
标题翻译：将内燃机的进气升温的方法和装置
公开(公告)号：US06427639B1
公开(公告)日：2002-08-06
申请号：US09206828
申请日：1998-12-07
申请人： Craig C. Andrews , Oliver J. Murphy
发明人： Craig C. Andrews , Oliver J. Murphy
IPC分类号： F02M2700
CPC分类号： B01D53/9454 , B60H1/00271 , B60H1/18 , B60H1/2203 , C25B1/10 , C25B9/20 , F01N3/2006 , F01N3/206 , F01N3/2889 , F01N3/32 , F01N3/34 , F01N5/02 , F01N2240/02 , F01N2610/04 , F01N2610/08 , F01P2060/00 , F01P2060/18 , F02B43/10 , F02B2043/106 , Y02A50/2324 , Y02A50/2325 , Y02E60/366 , Y02T10/16 , Y02T10/22 , Y02T10/24 , Y02T10/26 , Y02T10/32 , Y10S123/12
摘要： The present invention provides a method and apparatus for chemically heating one or more components of, or intake air flowing to, an internal combustion engine by feeding hydrogen to a catalyst. In accordance with the invention, condensation of fuels on cold engine cylinder walls during and after cold start-ups is prevented, thereby reducing wear on the engine. The invention also provides a method and apparatus for reducing pollutants commonly occurring during cold start-up of combustion engines by heating components of, or intake air flowing to, a combustion engine, in order to quickly warm the engine and its catalytic converter to operating temperatures.
摘要翻译：本发明提供一种用于通过将氢气输送到催化剂来化学加热流入内燃机的一个或多个组分或进气的方法和装置。根据本发明，防止在冷启动期间和之后在冷发动机气缸壁上的燃料冷凝，从而减少发动机的磨损。本发明还提供一种方法和装置，用于通过加热燃烧发动机的内燃部件或进气来减少内燃机的冷启动期间通常发生的污染物，以便将发动机及其催化转化器快速升温至工作温度。

37. 发明授权

US06410180B1 Fuel cell system for low pressure operation 有权
标题翻译：燃料电池系统用于低压运行
公开(公告)号：US06410180B1
公开(公告)日：2002-06-25
申请号：US09523910
申请日：2000-03-13
申请人： Alan J. Cisar , Dacong Weng , Oliver J. Murphy
发明人： Alan J. Cisar , Dacong Weng , Oliver J. Murphy
IPC分类号： H01M486
CPC分类号： H01M4/8807 , C25B9/066 , C25B9/18 , C25B11/035 , H01M4/8631 , H01M4/8828 , H01M4/92 , H01M4/96 , H01M8/04007 , H01M8/04089 , H01M8/04119 , H01M8/04156 , H01M8/04186 , H01M8/04194 , H01M8/04291 , H01M8/1004 , H01M8/1007 , H01M8/1009 , H01M8/241 , H01M8/247 , H01M8/249 , H01M2300/0082 , Y10T29/49108 , Y10T29/4911 , Y10T29/49112 , Y10T29/49114 , Y10T29/49115 , Y10T29/53204
摘要： This invention is an improved fuel cell design for use at low pressure. The invention has a reduced number of component parts to reduce fabrication costs, as well as a simpler design that permits the size of the system to be reduced at the same time as performance is being improved. In the present design, an adjacent anode and cathode pair are fabricated using a common conductive element, with that conductive element serving to conduct the current from one cell to the adjacent one. This produces a small and simple system suitable for operating with gas fuels or alternatively directly with liquid fuels, such as methanol, dimethoxymethane, or trimethoxymethane. The use of these liquid fuels permits the storage of more energy in less volume while at the same time eliminating the need for handling compressed gases which further simplifies the fuel cell system. The electrical power output of the design of this invention can be further increased by adding a passage for cooling the stack through contact with a coolant.
摘要翻译：本发明是在低压下使用的改进的燃料电池设计。本发明具有减少的部件数量以减少制造成本，以及更简单的设计，其允许在性能得到改善的同时减小系统的尺寸。在本设计中，使用公共导电元件制造相邻的阳极和阴极对，该导电元件用于将电流从一个电池传导到相邻电池。这产生适合于使用气体燃料或者直接与液体燃料如甲醇，二甲氧基甲烷或三甲氧基甲烷一起操作的小而简单的系统。这些液体燃料的使用允许以更少的体积储存更多的能量，同时消除了处理压缩气体的需要，这进一步简化了燃料电池系统。本发明设计的电力输出可以通过增加通过与冷却剂接触来冷却堆的通道进一步增加。

38. 发明授权

US06232010B1 Unitized barrier and flow control device for electrochemical reactors 有权
标题翻译：用于电化学反应器的单元化屏障和流量控制装置
公开(公告)号：US06232010B1
公开(公告)日：2001-05-15
申请号：US09307410
申请日：1999-05-08
申请人： Alan J. Cisar , Oliver J. Murphy , King-Tsai Jeng , Carlos Salinas , Stan Simpson , Dacong Weng , Homayoun Moaddel
发明人： Alan J. Cisar , Oliver J. Murphy , King-Tsai Jeng , Carlos Salinas , Stan Simpson , Dacong Weng , Homayoun Moaddel
IPC分类号： H01M486
CPC分类号： H01M8/0258 , H01M4/8605 , H01M4/9083 , H01M4/96 , H01M8/0202 , H01M8/0204 , H01M8/0206 , H01M8/0228 , H01M8/0232 , H01M8/0234 , H01M8/0239 , H01M8/0243 , H01M8/0245 , H01M8/0267 , H01M8/0297 , H01M8/241 , H01M2008/1095
摘要： The invention provides for reducing the number of parts and the number of interfaces found in certain types of chemical reactors, particularly in electrochemical reactors, and especially in the type or reactor known as a fuel cell or fuel cell stack. This reduction comes from the use of a unified structure that combines the functions normally carried out by several components in the unit, particularly by combining the functions of the gas distribution structure and the gas diffusion structure, the gas distribution structure and the gas barrier structure, or all three structures into a single, unitary, metallic part. This offers the advantages of simplified design, better performance, and lighter weight.
摘要翻译：本发明提供减少在某些类型的化学反应器中发现的部件数量和接头数量，特别是在电化学反应器中，特别是在称为燃料电池或燃料电池堆的型式或反应器中。这种减少来自使用将通常由单元中的几个部件执行的功能组合的统一结构，特别是通过组合气体分配结构和气体扩散结构，气体分配结构和气体阻隔结构的功能，或所有三种结构成为单一，单一的金属部分。这提供了简化设计，更好的性能和更轻的重量的优点。

39. 发明授权

US6122909A Catalytic reduction of emissions from internal combustion engines 有权
标题翻译：催化还原内燃机的排放
公开(公告)号：US6122909A
公开(公告)日：2000-09-26
申请号：US163068
申请日：1998-09-29
申请人： Oliver J. Murphy , Craig C. Andrews
发明人： Oliver J. Murphy , Craig C. Andrews
IPC分类号： F01N3/20 , F01N3/32 , F01N13/02 , F02M25/12 , F01N3/00
CPC分类号： F01N3/2046 , F01N13/009 , F01N3/2006 , F01N3/206 , F02M25/12 , F01N2610/04 , F01N2610/08 , F01N3/32 , Y02T10/121 , Y02T10/22 , Y02T10/26 , Y10S123/12
摘要： An apparatus for treating an exhaust gas stream from cold startup through continuous operating conditions of an internal combustion engine includes an oxidizing catalyst bed disposed in an exhaust pipe and a reducing catalyst bed disposed in the exhaust pipe downstream from the oxidizing catalyst bed. The oxidizing catalyst bed has one or more oxidizing catalysts and the reducing catalyst bed has one or more reducing catalysts. A method is provided for treating an exhaust gas stream both during cold start and during continuous operating conditions of an internal combustion engine by passing the stream through an oxidizing catalyst bed having one or more oxidizing catalysts at a light off temperature; a reducing catalyst bed having one or more reducing catalysts and providing hydrogen into the reducing catalyst bed to condition the reducing catalyst; and introducing hydrogen into the internal combustion engine during cold startup.
摘要翻译：一种用于处理来自冷起动的内燃机的连续运行状态的废气流的装置，包括设置在排气管中的氧化催化剂床和设置在氧化催化剂床下游的排气管内的还原催化剂床。氧化催化剂床具有一种或多种氧化催化剂，还原催化剂床具有一种或多种还原催化剂。提供了一种用于在冷启动期间和在内燃机的连续运行条件下处理排气流的方法，该方法是使流经过具有一种或多种氧化催化剂的氧化催化剂床在轻度关闭温度下; 还原催化剂床，其具有一种或多种还原催化剂并向还原催化剂床提供氢以调节还原催化剂; 并在冷起动期间将氢气引入内燃机。

40. 发明授权

US6103078A Methods for preparing membranes with fluid distribution passages 失效
标题翻译：用流体分配通道制备膜的方法
公开(公告)号：US6103078A
公开(公告)日：2000-08-15
申请号：US390740
申请日：1999-09-07
申请人： G. Duncan Hitchems , Harry Jabs , Craig C. Andrews , Oliver J. Murphy , William White , George W. Jackson , Charles L. C. Tennakoon
发明人： G. Duncan Hitchems , Harry Jabs , Craig C. Andrews , Oliver J. Murphy , William White , George W. Jackson , Charles L. C. Tennakoon
IPC分类号： B01D61/44 , B01D61/52 , C08J5/22 , H01M8/10 , C25B13/00
CPC分类号： H01M8/1088 , B01D61/445 , B01D61/52 , C08J5/2275 , H01M8/1023 , H01M8/1039 , H01M8/106 , H01M8/1072 , C08J2323/12 , H01M2300/0082 , Y02P70/56
摘要： The present invention provides improved ionically conducting membranes having internal passages therethrough and methods for making the improved membranes. The membranes may be formed from any ionically conducting material. In particular, the membranes may be formed of a single ionically conducting material, such as in a cation-conductive or anion-conductive membrane, or a plurality of ionically conducting material, such as in a bipolar membrane having a cation-selective region, an anion-selective region, and an interfacial region between the anion-selective region and the cation-selective region.
摘要翻译：本发明提供了具有内部通道的改进的离子导电膜及其制备方法。膜可以由任何离子导电材料形成。特别地，膜可以由单个离子导电材料形成，例如在阳离子导电或阴离子导电膜中，或多个离子导电材料，例如具有阳离子选择性区域的双极膜，阴离子选择性区域以及阴离子选择性区域和阳离子选择性区域之间的界面区域。

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