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1. 发明授权

US6103078A Methods for preparing membranes with fluid distribution passages 失效
标题翻译：用流体分配通道制备膜的方法
公开(公告)号：US6103078A
公开(公告)日：2000-08-15
申请号：US390740
申请日：1999-09-07
申请人： G. Duncan Hitchems , Harry Jabs , Craig C. Andrews , Oliver J. Murphy , William White , George W. Jackson , Charles L. C. Tennakoon
发明人： G. Duncan Hitchems , Harry Jabs , Craig C. Andrews , Oliver J. Murphy , William White , George W. Jackson , Charles L. C. Tennakoon
IPC分类号： B01D61/44 , B01D61/52 , C08J5/22 , H01M8/10 , C25B13/00
CPC分类号： H01M8/1088 , B01D61/445 , B01D61/52 , C08J5/2275 , H01M8/1023 , H01M8/1039 , H01M8/106 , H01M8/1072 , C08J2323/12 , H01M2300/0082 , Y02P70/56
摘要： The present invention provides improved ionically conducting membranes having internal passages therethrough and methods for making the improved membranes. The membranes may be formed from any ionically conducting material. In particular, the membranes may be formed of a single ionically conducting material, such as in a cation-conductive or anion-conductive membrane, or a plurality of ionically conducting material, such as in a bipolar membrane having a cation-selective region, an anion-selective region, and an interfacial region between the anion-selective region and the cation-selective region.
摘要翻译：本发明提供了具有内部通道的改进的离子导电膜及其制备方法。膜可以由任何离子导电材料形成。特别地，膜可以由单个离子导电材料形成，例如在阳离子导电或阴离子导电膜中，或多个离子导电材料，例如具有阳离子选择性区域的双极膜，阴离子选择性区域以及阴离子选择性区域和阳离子选择性区域之间的界面区域。

2. 发明授权

US07449090B2 Electrochemical apparatus with retractable electrode 失效
标题翻译：带可伸缩电极的电化学装置
公开(公告)号：US07449090B2
公开(公告)日：2008-11-11
申请号：US10947033
申请日：2004-09-22
申请人： Craig C. Andrews , Oliver J. Murphy , Brian Boyd
发明人： Craig C. Andrews , Oliver J. Murphy , Brian Boyd
IPC分类号： C25B9/02 , C25B1/13
CPC分类号： A61L2/186 , A61L2/183 , A61L2/202 , A61L2202/11 , C01B13/10 , C02F1/28 , C02F1/281 , C02F1/283 , C02F1/32 , C02F1/42 , C02F1/46104 , C02F1/46109 , C02F1/4672 , C02F1/78 , C02F9/00 , C02F2001/427 , C02F2001/46123 , C02F2001/46133 , C02F2001/46142 , C02F2001/46166 , C02F2001/46185 , C02F2101/20 , C02F2201/46115 , C02F2201/46195 , C02F2201/78 , C02F2201/782 , C02F2201/784 , C02F2209/006 , C02F2303/04 , C25B1/13 , C25B9/00 , C25B9/12 , C25B15/00
摘要： Electrochemical apparatus and methods that support periodic, non-steady state, or discontinuous operation without suffering degradation of materials or loss of efficiency. The invention provides a means for positioning one or more electrodes into contact with electrolyte and means for retracting the one or more electrodes out of contact with the electrolyte. The means for positioning and means for retracting may be the same device or different devices. The means for positioning and means for retracting may be designed to provide automatic, passive, or fail-safe retraction of the electrode upon a given shutdown condition, such as a voltage of less than one Volt being applied between the first and second electrodes, expiration of a time period, an ozone concentration greater than a setpoint ozone concentration, contact pressure of less than 5 psig, and combinations thereof.
摘要翻译：支持周期性，非稳态或不连续运行的电化学装置和方法，而不会降低材料或效率损失。本发明提供了一种用于将一个或多个电极定位成与电解质接触的装置，以及用于缩回与电解质接触的一个或多个电极的装置。用于定位的装置和用于缩回的装置可以是相同的装置或不同的装置。用于定位的装置和用于缩回的装置可以被设计成在给定的关闭条件下提供电极的自动，被动或故障安全的回缩，例如施加在第一和第二电极之间的小于一伏的电压，期满一个时间段，臭氧浓度大于设定点臭氧浓度，接触压力小于5psig，以及它们的组合。

3. 发明授权

US07125625B2 Electrochemical cell and bipolar assembly for an electrochemical cell 失效
公开(公告)号：US07125625B2
公开(公告)日：2006-10-24
申请号：US10448974
申请日：2003-05-30
申请人： Alan J. Cisar , Craig C. Andrews , Charles J. Greenwald , Oliver J. Murphy , Chris Boyer , Rattaya Chow Yalamanchili , Carlos E. Salinas
发明人： Alan J. Cisar , Craig C. Andrews , Charles J. Greenwald , Oliver J. Murphy , Chris Boyer , Rattaya Chow Yalamanchili , Carlos E. Salinas
IPC分类号： H01M2/02 , H01M2/08 , H01M8/12
CPC分类号： H01M8/0206 , H01M8/0213 , H01M8/0221 , H01M8/0223 , H01M8/023 , H01M8/0232 , H01M8/0241 , H01M8/0247 , H01M8/0256 , H01M8/026 , H01M8/0271
摘要： A bipolar assembly for use in electrochemical cell stacks, especially stacks operated at low pressure. The bipolar assembly is lightweight and provides a “post-type” flow field that operates with a low pressure drop. The bipolar assembly comprises a gas barrier having an array of electronically conducting posts disposed approximately perpendicular to the gas barrier. Each end of the posts is in electrical communication with the surface of an electrode. Because the bipolar assembly separates a cathode from an anode, the posts contact an anode electrode on one end and a cathode electrode on the other end. The posts provide current conduction through the stack as well as provide the flow fields for the electrochemical reactants. Optionally, the bipolar assembly may contain cooling fluid channels formed by adding additional gas barriers to the bipolar assembly. The space between the gas barriers form a channel through which cooling fluids may be circulated.

4. 发明授权

US06866806B2 Methods for assembling an electrochemical cell 有权
标题翻译：组装电化学电池的方法
公开(公告)号：US06866806B2
公开(公告)日：2005-03-15
申请号：US10262558
申请日：2002-09-30
申请人： Craig C. Andrews , Oliver J. Murphy , G. Duncan Hitchens
发明人： Craig C. Andrews , Oliver J. Murphy , G. Duncan Hitchens
IPC分类号： C02F1/28 , C02F1/44 , C02F1/461 , C02F1/467 , C02F1/78 , C25B1/13 , C25B9/08 , B29C45/14 , B29C65/56
CPC分类号： C02F1/78 , C02F1/283 , C02F1/44 , C02F1/4672 , C02F2001/46142 , C02F2201/46155 , C02F2201/782 , C02F2303/04 , C02F2303/18 , C25B1/13 , C25B9/08 , Y02W10/37
摘要： A method for securing an anode, a cathode and an ion exchange membrane disposed between the anode and the cathode within a premolded thermoplastic frame. The frame both secures the anode the cathode and the ion exchange membrane within the frame and further maintain the anode, cathode and membrane in intimate contact. Additionally, injection molding around the premolded thermoplastic frame may be performed or alternatively, injection molding around a plurality of thermoplastic frames.
摘要翻译：一种用于在预成型的热塑性框架内固定设置在阳极和阴极之间的阳极，阴极和离子交换膜的方法。框架将阳极固定在框架内的阴极和离子交换膜，并进一步保持阳极，阴极和膜的紧密接触。另外，可以对预成型的热塑性框架进行注塑，也可以在多个热塑性框架周围注塑。

5. 发明授权

US06804949B2 Water sources for automotive devices 失效
标题翻译：汽车设备用水源
公开(公告)号：US06804949B2
公开(公告)日：2004-10-19
申请号：US10226361
申请日：2002-08-22
申请人： Craig C. Andrews , Alan J. Cisar , Carlos Salinas , Oliver J. Murphy , A. John Appleby
发明人： Craig C. Andrews , Alan J. Cisar , Carlos Salinas , Oliver J. Murphy , A. John Appleby
IPC分类号： F01N300
CPC分类号： C25B15/08 , F01N2240/22 , F02B43/10 , F02B47/02 , F02B2043/106 , Y02T10/121 , Y02T10/32 , Y02T90/42
摘要： The present invention provides a self-replenishing liquid water source onboard an automobile for supplying liquid water to an electrolyzer, such as an on-board hydrogen generator useful for the suppression of unwanted emissions. While automobiles typically have water reservoirs resupplied by a person, the invention provides a passive means of water collection for reliable replenishment due to operations of the automobile itself. The invention provides condensate from the engine exhaust gas by cooling a region of the exhaust system using cooling fluid from the engine coolant system. The cooling fluid is circulated during a period following the engine cold start event when the heat load on the engine coolant system is low.
摘要翻译：本发明提供了一种用于向电解器供应液体水的汽车上的自补充液体水源，例如可用于抑制不期望的排放物的板上氢气发生器。虽然汽车通常具有由人员补充的储水器，但是由于汽车本身的操作，本发明提供了一种被动的水收集装置，用于可靠的补给。本发明通过使用来自发动机冷却剂系统的冷却流体冷却排气系统的区域来提供来自发动机废气的冷凝物。当发动机冷启动事件发动机冷却系统的热负荷低时，冷却液循环。

6. 发明申请

US20090071838A1 ELECTROCHEMICAL APPARATUS WITH RETRACTABLE ELECTRODE 审中-公开
标题翻译：具有可回收电极的电化学设备
公开(公告)号：US20090071838A1
公开(公告)日：2009-03-19
申请号：US12250641
申请日：2008-10-14
申请人： Oliver J. Murphy , Craig C. Andrews
发明人： Oliver J. Murphy , Craig C. Andrews
IPC分类号： C25B1/13 , C25D17/10 , C25B15/02
CPC分类号： A61L2/186 , A61L2/183 , A61L2/202 , A61L2202/11 , C01B13/10 , C02F1/28 , C02F1/281 , C02F1/283 , C02F1/32 , C02F1/42 , C02F1/46104 , C02F1/46109 , C02F1/4672 , C02F1/78 , C02F9/00 , C02F2001/427 , C02F2001/46123 , C02F2001/46133 , C02F2001/46142 , C02F2001/46166 , C02F2001/46185 , C02F2101/20 , C02F2201/46115 , C02F2201/46195 , C02F2201/78 , C02F2201/782 , C02F2201/784 , C02F2209/006 , C02F2303/04 , C25B1/13 , C25B9/00 , C25B9/12 , C25B15/00
摘要： Electrochemical apparatus and methods that support periodic, non-steady state, or discontinuous operation without suffering degradation of materials or loss of efficiency. The invention provides a means for positioning one or more electrodes into contact with electrolyte and means for retracting the one or more electrodes out of contact with the electrolyte. The means for positioning and means for retracting may be the same device or different devices. The means for positioning and means for retracting may be designed to provide automatic, passive, or fail-safe retraction of the electrode upon a given shutdown condition, such as a voltage of less than one Volt being applied between the first and second electrodes, expiration of a time period, an ozone concentration greater than a setpoint ozone concentration, contact pressure of less than 5 psig, and combinations thereof.
摘要翻译：支持周期性，非稳态或不连续运行的电化学装置和方法，而不会降低材料或效率损失。本发明提供了一种用于将一个或多个电极定位成与电解质接触的装置，以及用于缩回与电解质接触的一个或多个电极的装置。用于定位的装置和用于缩回的装置可以是相同的装置或不同的装置。用于定位的装置和用于缩回的装置可以被设计成在给定的关闭条件下提供电极的自动，被动或故障安全的回缩，例如施加在第一和第二电极之间的小于一伏的电压，期满一个时间段，臭氧浓度大于设定点臭氧浓度，接触压力小于5psig，以及它们的组合。

7. 再颁专利

USRE39720E1 Catalytic reduction of emissions from internal combustion engines 失效
标题翻译：催化还原内燃机的排放
公开(公告)号：USRE39720E1
公开(公告)日：2007-07-10
申请号：US10206157
申请日：2001-04-03
申请人： Oliver J. Murphy , Craig C. Andrews
发明人： Oliver J. Murphy , Craig C. Andrews
IPC分类号： F01N3/00
CPC分类号： F01N3/2046 , F01N3/2006 , F01N3/206 , F01N3/32 , F01N13/009 , F01N2610/04 , F01N2610/08 , F02M25/12 , Y02T10/121 , Y02T10/22 , Y02T10/26 , Y10S123/12
摘要： An apparatus for treating an exhaust gas stream from cold startup through continuous operating conditions of an internal combustion engine includes an oxidizing catalyst bed disposed in an exhaust pipe and a reducing catalyst bed disposed in the exhaust pipe downstream from the oxidizing catalyst bed. The oxidizing catalyst bed as one or more oxidizing catalysts and the reducing catalyst bed has one or more reducing catalysts. A method is provided for treating an exhaust gas stream both during cold start and during continuous operating conditions of an internal combustion engine by passing the stream through an oxidizing catalyst bed having one or more oxidizing catalysts at a light off temperature; a reducing catalyst bed having one or more reducing catalysts and providing hydrogen into the reducing catalyst bed to condition the reducing catalyst; and introducing hydrogen into the internal combustion engine during cold startup.
摘要翻译：一种用于处理来自冷起动的内燃机的连续运行状态的废气流的装置，包括设置在排气管中的氧化催化剂床和设置在氧化催化剂床下游的排气管内的还原催化剂床。作为一种或多种氧化催化剂和还原催化剂床的氧化催化剂床具有一种或多种还原催化剂。提供了一种用于在冷启动期间和在内燃机的连续运行条件下处理排气流的方法，该方法是使流经过具有一种或多种氧化催化剂的氧化催化剂床在轻度关闭温度下; 还原催化剂床，其具有一种或多种还原催化剂并向还原催化剂床提供氢以调节还原催化剂; 并在冷起动期间将氢气引入内燃机。

8. 发明授权

US06551490B2 Generation and delivery device for ozone gas and ozone dissolved in water 失效
公开(公告)号：US06551490B2
公开(公告)日：2003-04-22
申请号：US09951094
申请日：2001-09-13
申请人： Craig C. Andrews , Oliver J. Murphy
发明人： Craig C. Andrews , Oliver J. Murphy
IPC分类号： C25B102
CPC分类号： C25B9/10 , C01B13/10 , C02F1/46104 , C02F1/46109 , C02F1/4672 , C02F1/78 , C02F2001/46128 , C02F2001/46142 , C02F2001/46157 , C02F2201/46115 , C02F2201/4612 , C02F2201/46155 , C02F2201/4616 , C02F2201/4617 , C02F2303/18 , C25B1/13 , Y02W10/37
摘要： The present invention provides an ozone generation and delivery system that lends itself to small scale applications and requires very low maintenance. The system includes an anode reservoir and a cathode phase separator each having a hydrophobic membrane to allow phase separation of produced gases from water. The system may be configured to operate passively with no moving parts or in a self-pressurizing manner with the inclusion of a pressure controlling device or valve in the gas outlet of the anode reservoir. The hydrogen gas, ozone gas and water containing ozone may be delivered under pressure.

9. 发明授权

US06461487B1 Generation and delivery device for ozone gas 失效
标题翻译：臭氧气体生成和输送装置
公开(公告)号：US06461487B1
公开(公告)日：2002-10-08
申请号：US09431424
申请日：1999-11-01
申请人： Craig C. Andrews , Oliver J. Murphy
发明人： Craig C. Andrews , Oliver J. Murphy
IPC分类号： C25B900
CPC分类号： C25B9/10 , C01B13/10 , C02F1/46104 , C02F1/46109 , C02F1/4672 , C02F1/78 , C02F2001/46128 , C02F2001/46142 , C02F2001/46157 , C02F2201/46115 , C02F2201/4612 , C02F2201/46155 , C02F2201/4616 , C02F2201/4617 , C02F2303/18 , C25B1/13
摘要： The present invention provides an ozone generation and delivery system that lends itself to small scale applications and requires very low maintenance. The system preferably includes an anode reservoir and a cathode phase separator each having a hydrophobic membrane to allow phase separation of produced gases from water. The hydrogen gas, ozone gas and water containing ozone may be delivered under pressure.
摘要翻译：本发明提供一种适用于小规模应用的臭氧产生和输送系统，并且需要非常低的维护。该系统优选地包括阳极储存器和阴极相分离器，其各自具有疏水膜，以允许产生的气体与水相分离。氢气，臭氧气体和含臭氧的水可以在压力下输送。

10. 发明授权

US06427639B1 Method and apparatus for warming intake air to an internal combustion engine 失效
标题翻译：将内燃机的进气升温的方法和装置
公开(公告)号：US06427639B1
公开(公告)日：2002-08-06
申请号：US09206828
申请日：1998-12-07
申请人： Craig C. Andrews , Oliver J. Murphy
发明人： Craig C. Andrews , Oliver J. Murphy
IPC分类号： F02M2700
CPC分类号： B01D53/9454 , B60H1/00271 , B60H1/18 , B60H1/2203 , C25B1/10 , C25B9/20 , F01N3/2006 , F01N3/206 , F01N3/2889 , F01N3/32 , F01N3/34 , F01N5/02 , F01N2240/02 , F01N2610/04 , F01N2610/08 , F01P2060/00 , F01P2060/18 , F02B43/10 , F02B2043/106 , Y02A50/2324 , Y02A50/2325 , Y02E60/366 , Y02T10/16 , Y02T10/22 , Y02T10/24 , Y02T10/26 , Y02T10/32 , Y10S123/12
摘要： The present invention provides a method and apparatus for chemically heating one or more components of, or intake air flowing to, an internal combustion engine by feeding hydrogen to a catalyst. In accordance with the invention, condensation of fuels on cold engine cylinder walls during and after cold start-ups is prevented, thereby reducing wear on the engine. The invention also provides a method and apparatus for reducing pollutants commonly occurring during cold start-up of combustion engines by heating components of, or intake air flowing to, a combustion engine, in order to quickly warm the engine and its catalytic converter to operating temperatures.
摘要翻译：本发明提供一种用于通过将氢气输送到催化剂来化学加热流入内燃机的一个或多个组分或进气的方法和装置。根据本发明，防止在冷启动期间和之后在冷发动机气缸壁上的燃料冷凝，从而减少发动机的磨损。本发明还提供一种方法和装置，用于通过加热燃烧发动机的内燃部件或进气来减少内燃机的冷启动期间通常发生的污染物，以便将发动机及其催化转化器快速升温至工作温度。

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