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31. 发明授权

US09279085B2 Method for the production of monofunctionalized dialkylphosphinic acids, esters and salts, and use thereof 有权
标题翻译：用于制备单官能二烷基次膦酸，酯和盐的方法及其用途
公开(公告)号：US09279085B2
公开(公告)日：2016-03-08
申请号：US13140555
申请日：2009-10-06
申请人： Michael Hill , Harald Bauer , Werner Krause , Martin Sicken
发明人： Michael Hill , Harald Bauer , Werner Krause , Martin Sicken
IPC分类号： C07F9/02 , C07F9/22 , C07F9/28 , C08K5/53 , C09K21/12 , C07F9/30 , C07F9/32 , C08K5/5313
CPC分类号： C09K21/12 , C07F9/301 , C07F9/3211 , C08K5/5313
摘要： The invention relates to a method for producing monofunctionalized dialkylphosphinic acids, esters, and salts, characterized in that a phosphinic acid source (I) is reacted with olefins (IV) in the presence of a catalyst A to obtain an alkylphosphonous acid, the salt or ester thereof, whereupon said alkylphosphonous acid, the salt or ester (II) thereof is reacted with compounds containing C═C, C═O, or C═N double bonds to obtain compounds of type (III), wherein R1, R2, R3, R4, R5, R6 are identical or different from each other and independently represent, inter alia, H, C1-C18-alkyl, C6-C18-aryl, C6-C18-aralkyl, X represents, inter alia, H, C1-C18-alkyl, C6-C18-aryl, and/or Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Cu, Ni, Li, Na, K, H, and wherein A represents OH, NH2, NHR, NR2, or O—CO—R8, and W represents a mineral acid, carboxylic acid, Lewis acid, or organic acid, wherein n is a whole or a fractional number from 0 to 4, and catalyst A represents transition metals and/or transition metal compounds and/or catalyst systems composed of a transition metal and/or a transition metal compound and at least one ligand. The use of said dialkylphosphonic acids, esters, and salts is also disclosed.
摘要翻译：本发明涉及一种制备单官能化二烷基次膦酸，酯和盐的方法，其特征在于，在催化剂A存在下，次膦酸源（I）与烯烃（Ⅳ）反应得到烷基亚磷酸，其盐或酯，因此所述烷基亚膦酸，其盐或酯（II）与含有C = C，C = O或C = N双键的化合物反应，得到式（III）化合物，其中R1，R2，R3 ，R 4，R 5，R 6彼此相同或不同，并且独立地代表H，C 1 -C 18 - 烷基，C 6 -C 18 - 芳基，C 6 -C 18 - 芳烷基，X尤其表示H， C18烷基，C6-C18-芳基和/或Mg，Ca，Al，Sb，Sn，Ge，Ti，Fe，Zr，Zn，Ce，Bi，Sr，Mn，Cu，Ni，Li，Na，K ，H，其中A表示OH，NH2，NHR，NR2或O-CO-R8，W表示无机酸，羧酸，路易斯酸或有机酸，其中n为0或分数至4，催化剂A代表转化我 tals和/或过渡金属化合物和/或由过渡金属和/或过渡金属化合物和至少一种配体组成的催化剂体系。还公开了所述二烷基膦酸，酯和盐的用途。

32. 发明申请

US20150005421A1 Mixtures Of Diphosphinic Acids And Dialkylphosphinic Acids, A Process For The Preparation Thereof And The Use Thereof 审中-公开
标题翻译：二膦酸和二烷基次膦酸的混合物，其制备方法及其用途
公开(公告)号：US20150005421A1
公开(公告)日：2015-01-01
申请号：US14364851
申请日：2012-12-08
申请人： Fabian Schneider , Frank Osterod , Harald Bauer , Martin Sicken
发明人： Fabian Schneider , Frank Osterod , Harald Bauer , Martin Sicken
IPC分类号： C09K21/12 , C08K5/5313
CPC分类号： C09K21/12 , C07F9/301 , C07F9/305 , C08K5/5313 , C08K2201/014
摘要： The invention relates to mixtures of at least one diphosphinic acid of the formula (I) in which R1, R2 are the same or different and are each independently H, C1-C18-alkyl, C2-C18-alkenyl, C6-C18-aryl, C7-C18-alkylaryl, R5 is C1-C18-alkylene, C2-C18-alkenylene, C6-C18-arylene, C7-C18-alkylarylene with at least one dialkylphosphinic acid of the formula (II) in which R3, R4 are the same or different and are each independently C1-C18-alkyl, C2-C18-alkenyl, C6-C18-aryl and/or C7-C18-alkylaryl. The invention also relates to a process for preparing these mixtures and to the use thereof.
摘要翻译：本发明涉及式（I）的至少一种二次膦酸的混合物，其中R 1，R 2相同或不同，各自独立地为H，C 1 -C 18烷基，C 2 -C 18 - 烯基，C 6 -C 18 - 芳基，C 7 -C 18烷基芳基，R 5是C 1 -C 18亚烷基，C 2 -C 18亚烯基，C 6 -C 18亚芳基，具有式（II）的至少一种二烷基次膦酸的C 7 -C 18烷基亚芳基，其中R 3，R 4是 C 1 -C 18 - 烷基，C 2 -C 18 - 烯基，C 6 -C 18 - 芳基和/或C 7 -C 18 - 烷基芳基各自相同或不同。本发明还涉及制备这些混合物的方法及其用途。

33. 发明授权

US08592505B2 Hydrophosphorylation of phosphonous acid derivatives for flame retardants 有权
标题翻译：用于阻燃剂的膦酸衍生物的氢磷酸化
公开(公告)号：US08592505B2
公开(公告)日：2013-11-26
申请号：US13140563
申请日：2009-10-06
申请人： Michael Hill , Harald Bauer , Werner Krause , Martin Sicken
发明人： Michael Hill , Harald Bauer , Werner Krause , Martin Sicken
IPC分类号： C08K5/00 , C08K5/53 , C07F5/02 , C07F9/28
CPC分类号： C09K21/12 , A01N57/20 , A01N57/22 , B27K3/15 , B27K2240/30 , C07F9/4006 , C07F9/4093 , C07F9/505 , C07F9/5072 , C08K5/5393 , C08L77/00 , C08L97/02 , C09D5/086 , C09D5/185
摘要： Addition compounds of a) alkylphosphonous acid derivatives of the formula A-P(═O)(OX)—H (I) and b) diester-forming olefins of formula (II) Methods for the production of the addition compounds and the use thereof are also disclosed.
摘要翻译： a）a）式AP（= O）（OX）-H（I）的烷基亚膦酸衍生物和b）式（II）的二酯形成烯烃的加成化合物加成化合物的制备方法及其用途也披露

34. 发明申请

US20130190432A1 Flame Retardant-Stabilizer Combination For Thermoplastic Polymers 审中-公开
标题翻译：阻燃稳定剂组合热塑性聚合物
公开(公告)号：US20130190432A1
公开(公告)日：2013-07-25
申请号：US13878145
申请日：2011-09-30
申请人： Werner Krause , Harald Bauer , Martin Sicken , Sebastian Hoerold , Wolfgang Wanzke , Elke Schlosser
发明人： Werner Krause , Harald Bauer , Martin Sicken , Sebastian Hoerold , Wolfgang Wanzke , Elke Schlosser
IPC分类号： C08K5/5313 , C08K5/3492 , C08K5/10 , C08K3/22 , C08K5/5317 , C08K5/56 , C08K5/52 , C08K3/38
CPC分类号： C08K5/5313 , C08K3/22 , C08K3/38 , C08K5/0008 , C08K5/10 , C08K5/34922 , C08K5/34924 , C08K5/52 , C08K5/5317 , C08K5/56
摘要： A novel flame retardant-stabilizer combination for thermoplastic polymers, comprising as component A 20 to 99% by weight of a dialkylphosphinic salt of the formula (I) and/or of a diphosphinic salt of the formula (II) and/or polymers thereof in which R1, R2 are the same or different and are each C1-C6-alkyl, linear or branched; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, C7-C20-alkylarylene or C7-C20-arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m is 1 to 4; n is 1 to 4; x is 1 to 4, as component B 1 to 80% by weight of a salt of the phosphorous acid with the general formula (III) [HP(═O)O2]2−Mm+ (III) in which M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na and/or K and m is 1 to 4, as component C 0 to 30% by weight of a nitrogen-containing synergist and/or of a phosphorus/nitrogen flame retardant, as component D 0 to 10% by weight of a zinc salt and/or of a basic or amphoteric oxide, hydroxide, carbonate, silicate, borate, stannate, mixed oxide hydroxide, oxide hydroxide carbonate, hydroxide silicate and/or hydroxide borate and/or mixtures of these substances, as component E 0 to 3% by weight of a phosphonite and/or of a mixture of a phosphonite and a phosphite, and as component F 0 to 3% by weight of an ester and/or salt of long-chain aliphatic carboxylic acids (fatty acids) which typically have chain lengths of C14 to C40, where the sum of the components is always 100% by weight.
摘要翻译：一种热塑性聚合物的新型阻燃稳定剂组合物，其包含作为组分A 20至99重量％的式（I）的二烷基次膦酸盐和/或式（II）的二膦酸盐和/或其聚合物其中R 1，R 2相同或不同，并且各自为直链或支链的C 1 -C 6烷基; R3是C1-C10-亚烷基，直链或支链的C6-C10亚芳基，C7-C20-烷基亚芳基或C7-C20-芳基亚烷基; M是Mg，Ca，Al，Sb，Sn，Ge，Ti，Zn，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na，K和/或质子化氮碱; m为1〜4; n为1〜4; x为1〜4，作为成分B，通式（III）的亚磷酸盐为1〜80重量％[HP（= O）O 2] 2 -Mm +（III），其中M为Mg，Ca ，Al，Sb，Sn，Ge，Ti，Zn，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na和/或K和m为1〜4，作为组分C 0〜30重量％含氮增效剂和/或磷/氮阻燃剂，作为组分D 0至10重量％的锌盐和/或碱性或两性氧化物，氢氧化物，碳酸盐，硅酸盐，硼酸盐，锡酸盐，混合氧化物氢氧化物，氢氧化物碳酸盐，氢氧化硅酸盐和/或氢氧化物硼酸盐和/或这些物质的混合物，作为组分E 0至3重量％的亚膦酸盐和/或亚磷酸盐和亚磷酸盐的混合物，并且作为组分F 0至3重量％的通常具有C14至C40链长度的长链脂族羧酸（脂肪酸）的酯和/或盐，其中组分的总量总是为100重量％。

35. 发明授权

US08293938B2 Alkylphosphonous acids, salts and esters, methods for the production thereof, and use of the same 有权
标题翻译：烷基亚磷酸，盐和酯，其制备方法及其用途
公开(公告)号：US08293938B2
公开(公告)日：2012-10-23
申请号：US12668814
申请日：2008-07-02
申请人： Michael Hill , Harald Bauer , Werner Krause
发明人： Michael Hill , Harald Bauer , Werner Krause
IPC分类号： C07F9/28
CPC分类号： C07F9/4866 , C07F9/4816 , C07F9/485 , C08K5/5393
摘要： The invention relates to alkylphosphonous acids, salts and esters of formula (I) A-P(═O)(OX)—H (I) wherein A is C2-C20alkyl, C2-C20alkylene, and C8-C20 alkaryl are optionally substituted, and X is H, alkyl, aryl, alkylaryl, alkenyl, substituted alkyl, aryl, alkaryl, alkenyl, ammonium, primary, secondary, tertiary, quaternary alkyl and/or aryl ammonium, an alkali metal, an alkaline earth metal, a metal of the third and fourth main group and the second, fourth and eight sub-group or a metal of the lanthanoid group. The invention also relates to methods for producing same and to the uses of said compounds.
摘要翻译：本发明涉及烷基亚磷酸，其中A是C 2 -C 20烷基，C 2 -C 20亚烷基和C 8 -C 20烷芳基的式（I）AP（= O）（OX）-H（I）的烷基亚磷酸，盐和酯，是烷基，芳基，烷基芳基，烯基，取代的烷基，芳基，烷芳基，烯基，铵，伯，仲，叔，季烷基和/或芳基铵，碱金属，碱土金属，第三和第四主要组和第二，第四和第八子组或镧系元素的金属。本发明还涉及其生产方法和所述化合物的用途。

36. 发明申请

US20120214059A1 Collection structure in batteries 有权
标题翻译：电池收集结构
公开(公告)号：US20120214059A1
公开(公告)日：2012-08-23
申请号：US13199081
申请日：2011-08-17
申请人： Harald Bauer
发明人： Harald Bauer
IPC分类号： H01M4/64 , H01M4/72 , H01M4/66 , H01M6/00
CPC分类号： H01M4/70 , H01M4/661 , H01M4/667 , H01M4/72 , H01M10/052 , H01M10/0585 , Y02E60/122 , Y02P70/54 , Y02T10/7011 , Y10T29/49115
摘要： An electrode in a battery, e.g., a lithium-ion battery, has an electrically conductive carrier foil including (i) a terminal region for connection to an electrical circuit and (ii) at least one electrically conductive structure element configured to reduce the electrical resistance between the terminal region and a point on the carrier foil in order to improve electrical collection via the terminal region.
摘要翻译：电池中的电极（例如锂离子电池）具有导电载体箔，其包括（i）用于连接到电路的端子区域和（ii）被配置为降低电阻的至少一个导电结构元件在端子区域和载体箔片上的点之间，以便通过端子区域改善电收集。

37. 发明授权

US08097753B2 Mixtures composed or monocarboxy-functionalized dialkylphosphinic acids, their use and a process for their preparation 有权
标题翻译：混合物或单羧基官能化二烷基次膦酸，其用途及其制备方法
公开(公告)号：US08097753B2
公开(公告)日：2012-01-17
申请号：US11714482
申请日：2007-03-06
申请人： Wiebke Maas , Werner Krause , Harald Bauer
发明人： Wiebke Maas , Werner Krause , Harald Bauer
IPC分类号： C07F9/22
CPC分类号： C08K5/5313 , C07F9/301 , C07F9/306 , C08K2201/014
摘要： The invention relates to mixtures composed of monocarboxy-functionalized dialkylphosphinic acids and of further components, which comprise A) from 98 to 100% by weight of monocarboxy-functionalized dialkylphosphinic acids of the formula (I) in which R1, R2, R3, R4, R5, R6, and R7 are identical or different and, independently of one another, are H, methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, tert-butyl, and/or phenyl, X and Y are identical or different and, independently of one another, are H, Li, Na, K, or NH4, and B) from 0 to 2% by weight of halogens, where the entirety of the components always amounts to 100% by weight.
摘要翻译：本发明涉及由单羧基官能化的二烷基次膦酸和其它组分组成的混合物，其包含A）98至100重量％的式（I）的单羧基官能化二烷基次膦酸，其中R 1，R 2，R 3，R 4， R 5，R 6和R 7是相同或不同的，彼此独立地是H，甲基，乙基，正丙基，异丙基，正丁基，异丁基，叔丁基和/或苯基，X和Y是相同的或者不同，并且彼此独立地是H，Li，Na，K或NH 4，和B）0-2重量％的卤素，其中整个组分总计为100重量％。

38. 发明申请

US20110021676A1 Method for the Production of a Flame-retardant, Non-corrosive, and Easily flowable Polyamide and Polyester Molding Compounds 审中-公开
标题翻译：阻燃，无腐蚀，易流动的聚酰胺和聚酯成型化合物的制备方法
公开(公告)号：US20110021676A1
公开(公告)日：2011-01-27
申请号：US12919792
申请日：2009-02-25
申请人： Sebastian Hoerold , Ottmar Schacker , Harald Bauer , Werner Krause , Daniela Eisenhauer
发明人： Sebastian Hoerold , Ottmar Schacker , Harald Bauer , Werner Krause , Daniela Eisenhauer
IPC分类号： C08K5/3492 , C08K5/5313 , C09K21/12
CPC分类号： C09K21/12 , C08K5/0066 , C08K5/5313 , C08L77/00 , C08L67/02
摘要： The invention relates to a process for producing flame-retardant, non-corrosive, highly flawable polyamides and polyesters, which comprises using a flame retardant mixture made of a phosphinic salt of the formula (I), where M═Al, Mg, Ca, Ti, or Na (component A) in which R1 and R2 are identical or different and are C1-C6-alkyl, linear or branched, and/or aryl; n is from 1 to 3, and, as component B, a metal salt of an organic acid, and/or an inorganic zinc, calcium, magnesium, potassium, sodium, aluminum, titanium, tin, antimony, bismuth, or barium compound, where the amount of component A present in the flame retardant mixture is from 70 to 99.5% by weight and the amount of component B present in the flame retardant mixture is from 0.5 to 30% by weight.
摘要翻译：本发明涉及一种制造阻燃，非腐蚀性，高度可破坏的聚酰胺和聚酯的方法，其包括使用由式（I）的次膦酸盐制成的阻燃混合物，其中M = Al，Mg，Ca， Ti或Na（组分A），其中R 1和R 2相同或不同，为直链或支链的C 1 -C 6 - 烷基和/或芳基; n为1〜3，作为成分B的有机酸金属盐和/或无机锌，钙，镁，钾，钠，铝，钛，锡，锑，铋或钡化合物，其中存在于阻燃剂混合物中的组分A的量为70至99.5重量％，并且阻燃混合物中存在的组分B的量为0.5至30重量％。

39. 发明授权

US07635785B2 Process for preparation of dialkylphosphinic salts 有权
标题翻译：制备二烷基次膦酸盐的方法
公开(公告)号：US07635785B2
公开(公告)日：2009-12-22
申请号：US11016663
申请日：2004-12-17
申请人： Harald Bauer , Werner Krause , Martin Sicken , Norbert Weferling
发明人： Harald Bauer , Werner Krause , Martin Sicken , Norbert Weferling
IPC分类号： C07F9/30
CPC分类号： C07F9/30 , C08K5/5313
摘要： The invention relates to a process for preparation of salts of dialkylphosphinic acids, which comprises a) reacting hypophosphorous acid and/or its salts with olefins in the presence of a free-radical initiator to give dialkylphosphinic acids and/or their alkali metal salts, in a solvent system, and b) reacting the dialkylphosphinic acids and/or alkali metal dialkylphosphinates obtained in a) with compounds of the metals Mg, Ca, Al, Zn, Ti, Sn, Zr, and/or Fe to give the dialkylphosphinic salts of these metals. The invention also relates to the use of the metal dialkylphosphinic salts obtained by the inventive process, in particular for preparation of flame retardants.
摘要翻译：本发明涉及二烷基次膦酸的盐的制备方法，该方法包括：a）在自由基引发剂存在下使次亚磷酸和/或其盐与烯烃反应，得到二烷基次膦酸和/或其碱金属盐，溶剂体系，b）使a）中得到的二烷基次膦酸和/或碱金属二烷基次膦酸盐与金属Mg，Ca，Al，Zn，Ti，Sn，Zr和/或Fe的化合物反应，得到这些金属。本发明还涉及通过本发明方法获得的二烷基次膦酸金属盐的用途，特别是制备阻燃剂。

40. 发明申请

US20090137707A1 Mixed salts of diorganylphosphinic acids and carboxylic acids 有权
标题翻译：二有机基次膦酸和羧酸的混合盐
公开(公告)号：US20090137707A1
公开(公告)日：2009-05-28
申请号：US12313523
申请日：2008-11-21
申请人： Harald Bauer , Werner Krause , Wolfgang Wanzke
发明人： Harald Bauer , Werner Krause , Wolfgang Wanzke
IPC分类号： C09K21/12 , C07F19/00
CPC分类号： C07F9/301 , C07C63/28 , C08K5/0066 , C08K5/5313 , C08L21/00
摘要： The invention relates to mixtures of diorganylphosphinic acids and carboxylic acids of the formula [cationn+(phosphinate−)x(carboxylic acid anionz−1/z)y] where n=from 1 to 4 x=from 0.01 to n−0.01 y=n−x z=from 1 to 4, where “cation” means an element of the second main and/or transition group, an element of the third main and/or transition group, an element of the fourth main and/or transition group, an element of the fifth main and/or transition group, an element of the sixth transition group, an element of the seventh transition group, and/or an element of the eighth transition group, “phosphinate” means the anion of diorganylphosphinic acids of the formula where R1 and R2 are identical or different and, independently of one another, are H, C1-C6-alkyl, linear or branched, and/or aryl, and/or hydroxyalkyl, and “carboxylic acid anion” means C1-C18 carboxylic acid anions. The invention also relates to processes for their production, and to their use.
摘要翻译：本发明涉及二有机基次膦酸和羧酸的混合物，其结构式为：α-in-line-formula description =“In-line Formulas”end =“lead”→[cationn +（phosphinate-）x（carboxylic acid anionz-1 / z）y] <？in-line-formula description =“In-line Formulas”end =“tail”？>其中n = 1至4 x =从0.01到n-0.01 y = nx z =从1到4 其中“阳离子”是指第二主和/或转移基团的元素，第三主和/或过渡基团的元素，第四主和/或过渡基团的元素，第五主元素和/或过渡基团的元素和/ 或过渡组，第六过渡组的元素，第七过渡组的元素和/或第八过渡组的元素，“次膦酸酯”是指下式的二有机基次膦酸的阴离子，其中R 1和R 2相同或不同且彼此独立地为H，C 1 -C 6 - 烷基，直链或支链和/或芳基和/或羟烷基，“羧酸阴离子”是指C 1 -C 18羧酸a 国王本发明还涉及其生产方法及其用途。

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