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31. 发明授权

US4960874A Isothiazolylazo dyes having aminophenyl and aminonaphthyl components 失效
标题翻译：具有氨基苯基和氨基萘基组分的异噻唑基偶氮染料
公开(公告)号：US4960874A
公开(公告)日：1990-10-02
申请号：US214502
申请日：1988-07-01
申请人： Udo Bergmann , Johannes D. Dix , Guenter Hansen , Ernst Schefczik , Guenther Seybold
发明人： Udo Bergmann , Johannes D. Dix , Guenter Hansen , Ernst Schefczik , Guenther Seybold
IPC分类号： C09B29/039 , C09B29/00 , C09B29/06 , C09B29/08 , C09B29/095
CPC分类号： C09B29/0847 , C09B29/0081 , C09B29/06 , C09B29/0813 , C09B29/083 , C09B29/095 , Y10S534/02
摘要： Compounds of the general formula I ##STR1## where R is alkyl or unsubstituted or substituted aryl and K is a radical of the formula ##STR2## B is C.sub.1 -C.sub.4 -alkyl or substituted amino, R.sup.1 is hydrogen, methyl, methoxy or ethoxy, R.sup.2 and R.sup.3 independently of one another are each unsubstituted or substituted alkyl, R.sup.3 may furthermore be hydrogen, R.sup.4 is a radical of the formula --A--OCO--Y--R, Z is hydrogen or methyl, X is hydrogen, methyl, methoxy, chlorine or acylamino, A is C.sub.2 - or C.sub.3 -alkylene and Y is --O-- or --NH--, are very useful for dyeing cellulose esters and synthetic polyesters.

32. 发明授权

US4908437A Thien-2-one compounds with an alkylidene or imino group in the 5-position of the ring 失效
标题翻译：噻吩-2-酮在环的5位具有亚烷基或亚氨基
公开(公告)号：US4908437A
公开(公告)日：1990-03-13
申请号：US195668
申请日：1988-05-17
申请人： Guenter Hansen , Johannes P. Dix , Helmut Reichelt , Masahiro Hayashi
发明人： Guenter Hansen , Johannes P. Dix , Helmut Reichelt , Masahiro Hayashi
IPC分类号： C09B56/00 , C07D333/38 , C07D409/06 , C07D417/06 , C07D417/14 , C09B23/00 , C09B23/10 , C09B23/14 , C09B23/16 , C09B29/36 , C09B55/00 , C09B57/00 , C09B57/04 , D06P1/642 , D06P1/651
CPC分类号： C07D409/06 , C07D333/38 , C07D417/06 , C07D417/14 , C09B23/105 , C09B23/145 , C09B23/164 , C09B29/3682 , C09B29/3691 , C09B55/009 , D06P1/6426 , D06P1/65168
摘要： The invention relates to novel thienone compounds useful in dyeing fibers, of the formula: ##STR1## where R.sup.1 is cyano, C.sub.1 -C.sub.4 -alkoxycarbonyl, carbamoyl or C.sub.1 -C.sub.4 -monoalkylcarbamoyl or -dialkylcarbamoyl,R.sup.2 is hydrogen, C.sub.1 -C.sub.8 -alkyl, substituted or unsubstituted phenyl, furyl, thienyl or halogen,X is nitrogen or CR.sup.4 where R.sup.4 is hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxycarbonyl, cyano or substituted or unsubstituted phenyl, andR.sup.3 is an aniline, thiazole, indole, styrol or isoindole radical, with the proviso that if R.sup.1 is cyano, X is CH and R.sup.3 is 4-dimethylaminophenyl or styryl, then R.sup.2 is not methyl or phenyl and that if R.sup.1 is cyano, X is CH and R.sup.3 is phenyl or 4-methoxyphenyl, then R.sup.2 is not phenyl.
摘要翻译：本发明涉及用于染色纤维的新型噻吩酮化合物，其结构式如下：其中R 1是氰基，C 1 -C 4烷氧基羰基，氨基甲酰基或C 1 -C 4单烷基氨基甲酰基或二烷基氨基甲酰基，R 2是氢，C 1 -C 8 - 烷基取代或未取代的苯基，呋喃基，噻吩基或卤素，X为氮或CR4，其中R4为氢，C1-C4-烷基，C1-C4-烷氧基羰基，氰基或取代或未取代的苯基，R3为苯胺，噻唑，吲哚，苯乙烯或异吲哚基，条件是如果R1是氰基，X是CH，R3是4-二甲基氨基苯基或苯乙烯基，则R2不是甲基或苯基，如果R1是氰基，则X是CH，R3是苯基或4 - 甲氧基苯基，则R2不是苯基。

33. 发明授权

US4496480A Isothiazolazo dyes having coupling components which are free from unsaturated aliphatic radicals 失效
标题翻译：具有不饱和脂族基团的偶合组分的异噻唑偶氮染料
公开(公告)号：US4496480A
公开(公告)日：1985-01-29
申请号：US463001
申请日：1983-02-01
申请人： Udo Bergmann , Johannes P. Dix , Guenter Hansen , Ernst Schefczik
发明人： Udo Bergmann , Johannes P. Dix , Guenter Hansen , Ernst Schefczik
IPC分类号： C09B29/039 , C09B29/00 , C09B29/06 , C09B29/09 , C09B29/36 , C09B29/48 , C09B29/08 , C09B29/095
CPC分类号： C09B29/06 , C09B29/0081 , C09B29/36
摘要： Compounds of the general formula I ##STR1## where R is substituted alkyl and K is the radical of a coupling component free from unsaturated aliphatic radicals, are very useful for dyeing cellulose esters and synthetic polyesters.
摘要翻译：通式I的化合物，其中R是取代的烷基，K是不含不饱和脂族基团的偶联组分的基团，对染色纤维素酯和合成聚酯是非常有用的。

34. 发明授权

US5283326A Dyes containing thiophene radicals 失效
标题翻译：染料含有噻吩基
公开(公告)号：US5283326A
公开(公告)日：1994-02-01
申请号：US884472
申请日：1992-05-13
申请人： Guenter Hansen , Ernst Schefczik , Karl-Heinz Etzbach , Helmut Reichelt , Hermann Loeffler
发明人： Guenter Hansen , Ernst Schefczik , Karl-Heinz Etzbach , Helmut Reichelt , Hermann Loeffler
IPC分类号： C09B29/00 , C09B29/033 , C09B29/06 , C09B29/36 , D06P1/18
CPC分类号： C09B29/0059
摘要： The compounds of the general formula ##STR1## where X is fluorine, chlorine, bromine, SO.sub.2 E or unsubstituted or substituted hydroxyl or mercapto, E is alkyl, alkenyl, cycloalkyl, aralkyl, aryl, chlorine or unsubstituted or substituted hydroxyl or amino, Y is cyano, nitro, alkanoyl, aroyl, alkylsulfonyl, arylsulfonyl, carboxyl, a carboxylic ester group or unsubstituted or substituted carbamyl, T is hydrogen, C.sub.1 -C.sub.4 -alkyl, a radical which can be introduced by electrophilic substitution or a radical of the formula --CH.dbd.B, in which B is a radical of a methylene-active compound or of an amine, and K is a radical of a coupling component, are very useful for dyeing synthetic fibers or plastics.
摘要翻译：其中X为氟，氯，溴，SO 2 E或未取代或取代的羟基或巯基的通式为“IMAGE”的化合物，E为烷基，烯基，环烷基，芳烷基，芳基，氯或未取代或取代的羟基或氨基，Y为氰基，硝基，烷酰基，芳酰基，烷基磺酰基，芳基磺酰基，羧基，羧酸酯基或未取代或取代的氨基甲酰基，T是氢，C 1 -C 4烷基，可以通过亲电取代引入的基团或式 - CH = B，其中B是亚甲基活性化合物或胺的基团，K是偶合组分的基团，对于合成纤维或塑料的染色非常有用。

35. 发明授权

US5066791A Pyridoneazo dyes with an M-aminobenzoic ester as the diazo component 失效
标题翻译：具有作为DIAZO组分的M-氨基苯甲酸酯的吡哆醛染料
公开(公告)号：US5066791A
公开(公告)日：1991-11-19
申请号：US480359
申请日：1990-02-14
申请人： Guenter Hansen , Gunther Lamm , Hermann Loeffler
发明人： Guenter Hansen , Gunther Lamm , Hermann Loeffler
IPC分类号： C09B29/01 , C09B29/42
CPC分类号： C09B29/363 , C09B29/0003 , Y10S534/01
摘要： Pyridoneazo dyes of the formula ##STR1## where L is C.sub.2 - or C.sub.3 -alkylene, R is C.sub.1 -C.sub.3 -alkyl and n is 1, 2 or 3, are useful for dyeing polyester fabrics.
摘要翻译：其中L为C 2 - 或C 3 - 亚烷基，R为C 1 -C 3 - 烷基，n为1,2或3，可以用于染色涤纶织物的式“IMAGE”的吡咯酮偶氮染料。

36. 发明授权

US4837269A 2-aminothiophene radical substituted by an electron withdrawing group 失效
标题翻译：由吸电子基团取代的2-氨基噻吩基团
公开(公告)号：US4837269A
公开(公告)日：1989-06-06
申请号：US68168
申请日：1987-06-30
申请人： Karl-Heinz Etzbach , Guenter Hansen , Ernst Schefczik , Helmut Reichelt
发明人： Karl-Heinz Etzbach , Guenter Hansen , Ernst Schefczik , Helmut Reichelt
IPC分类号： C09B31/02 , C09B31/04 , C09B31/14
CPC分类号： C09B31/04 , C09B31/14
摘要： Disazothiphene dyes of the formula ##STR1## where X is an electron withdrawing group, Z is an electron withdrawing group, D is the radical of a diazo component and K is the radical of a coupling component, are highly suitable for dyeing synthetic fibers, in particular polyesters.
摘要翻译：其中X是吸电子基团，Z是吸电子基团，D是重氮组分的基团，K是偶合组分的基团，非常适合于染色合成纤维，其中X是吸电子基团，特定的聚酯。

37. 发明授权

US4486198A Navy dye mixtures 失效
标题翻译：海军染料混合物
公开(公告)号：US4486198A
公开(公告)日：1984-12-04
申请号：US570455
申请日：1984-01-13
申请人： Ernst Becker , Udo Bergmann , Helmut Degen , Guenter Hansen , Reinhold Krallmann
发明人： Ernst Becker , Udo Bergmann , Helmut Degen , Guenter Hansen , Reinhold Krallmann
IPC分类号： C09B29/08 , C09B67/22
CPC分类号： C09B67/0051 , C09B29/0813 , C09B29/0816 , C09B29/0825 , Y10S534/02 , Y10S8/922
摘要： Navy dye mixtures essentially contain dyes of the formula I ##STR1## where X is hydrogen, chlorine or bromine, the radicals R.sup.1 independently of one another are each methyl or ethyl and R is a radical of the formula ##STR2## where A is ##STR3## B is unsubstituted or substituted C.sub.1 -C.sub.4 -alkyl, phenyl-C.sub.1 -C.sub.4 -alkyl, phenoxy-C.sub.2 - or -C.sub.3 -alkyl or cyclohexyl and R.sup.2 is C.sub.1 -C.sub.4 -alkyl, the mixtures containing from 20 to 80 parts of dyes in which R is NH-A-COOB and from 80 to 20 parts of dyes in which R is ##STR4## The novel mixtures are very useful for dyeing synthetic polyesters, and give dyeings which have, in particular, very good heatfastness.
摘要翻译：海军染料混合物基本上含有式I的染料，其中X为氢，氯或溴，基团R 1彼此独立地为甲基或乙基，R为下式基团，其中A为< B是未取代的或取代的C 1 -C 4 - 烷基，苯基-C 1 -C 4 - 烷基，苯氧基-C 2 - 或-C 3-烷基或环己基，R 2是C 1 -C 4 - 烷基，所述混合物含有20至80份其中R是NH-A-COOB的染料和其中R为80至20份的染料。新颖的混合物对于染色合成聚酯是非常有用的，并且给出特别是非常好的耐热性的染色。

38. 发明授权

US4465628A Azo dyes comprising a heterocyclic diazo component 失效
标题翻译：包含杂环重氮组分的偶氮染料
公开(公告)号：US4465628A
公开(公告)日：1984-08-14
申请号：US92182
申请日：1979-11-07
申请人： Norbert Grund , Guenter Hansen , Wolf-Dieter Kermer
发明人： Norbert Grund , Guenter Hansen , Wolf-Dieter Kermer
IPC分类号： C09B29/09 , C09B29/00 , C09B29/08 , C09B29/039 , C09B29/045 , D06P3/54
CPC分类号： C09B29/0081 , C09B29/0813
摘要： An azo dye comprising a heterocyclic diazo component, of the general formula ##STR1## where D is a radical of the formula ##STR2## Y is nitro, chlorine or bromine, Z is hydrogen, chlorine, bromine, cyano or nitro,R.sup.1 is C.sub.1 -C.sub.4 -alkyl which is unsubstituted or substituted by hydroxyl, C.sub.1 -C.sub.4 -alkoxy, cyano, C.sub.1 -C.sub.4 -alkanoyloxy, C.sub.1 -C.sub.4 -alkoxycarbonyl, C.sub.1 -C.sub.4 -alkanoylamino, C.sub.1 -C.sub.4 -alkylaminocarbonyloxy, C.sub.1 -C.sub.4 -alkoxycarbonyloxy, chlorine, phenyl and/or phenoxy, or is cyclohexyl, propargyl or C.sub.3 -C.sub.5 -alkenyl, or is a radical of the formula(A-O).sub.n -R.sup.2,R.sup.2 is C.sub.1 -C.sub.4 -alkyl, phenyl or, if n>1, may also be hydrogen,R.sup.3 is C.sub.1 -C.sub.8 -alkyl, which may be substituted by phenyl or phenoxy,R.sup.4 is hydrogen, methyl, ethyl, methoxy, ethoxy or phenoxy,X is oxygen or a direct bond,A is --CH.sub.2 CH.sub.2 --, --CH.sub.2 CH.sub.2 CH.sub.2 --, ##STR3## and n is 1, 2 or 3.The dyes of the formula I are very suitable for dyeing synthetic textile materials, especially polyesters.
摘要翻译：包含通式为I的杂环重氮组分的偶氮染料，其中D是下式的基团Y是硝基，氯或溴，Z是氢，氯，溴，氰基或硝基，R 1是未取代或被羟基，C 1 -C 4 - 烷氧基，氰基，C 1 -C 4 - 烷酰氧基，C 1 -C 4 - 烷氧基羰基，C 1 -C 4 - 烷酰基氨基，C 1 -C 4烷基氨基羰基氧基，C 1 -C 4 - 烷氧基羰基氧基，或苯基和/或苯氧基，或为环己基，炔丙基或C3-C5-烯基，或为式（AO）n-R2，R2为C1-C4-烷基，苯基或（如果n≥1）可以是氢，R 3是可被苯基或苯氧基取代的C 1 -C 8 - 烷基，R 4是氢，甲基，乙基，甲氧基，乙氧基或苯氧基，X是氧或直接键，A是-CH 2 CH 2 - ，-CH 2 CH 2 CH 2 - ，和n是1,2或3.式I的染料非常适合于染色合成纺织品材料，特别是聚酯。

39. 发明授权

US4389216A Navy dye mixtures 失效
标题翻译：海军染料混合物
公开(公告)号：US4389216A
公开(公告)日：1983-06-21
申请号：US355309
申请日：1982-03-05
申请人： Udo Bergmann , Helmut Degen , Guenter Hansen , Reinhold Krallmann , Wolf-Dieter Kermer
发明人： Udo Bergmann , Helmut Degen , Guenter Hansen , Reinhold Krallmann , Wolf-Dieter Kermer
IPC分类号： C09B67/20 , C09B29/08 , C09B67/22 , D06P3/52
CPC分类号： C09B67/0051 , C09B29/081 , C09B29/0813 , C09B29/0825 , Y10S534/01 , Y10S8/922
摘要： Navy dye mixtures which contain, as essential components, compounds of the general formula I ##STR1## in the following amounts, based on the total weight of the mixture:______________________________________ X = Br R.sup.1 = C.sub.2 H.sub.4 CN R.sup.2 = CH.sub.2 CHCH.sub.2 39-49%, X = Br R.sup.1 = C.sub.2 H.sub.4 CN R.sup.2 = H 1-10%, X = Br R.sup.1 = H R.sup.2 = CH.sub.2 CHCH.sub.2 4-16%, X = Cl R.sup.1 = C.sub.2 H.sub.4 CN R.sup.2 = H 15-25%, X = Cl R.sup.1 = C.sub.2 H.sub.4 CN R.sup.2 = CH.sub.2 CHCH.sub.2 4-9%, and X = Cl ##STR2## R.sup.2 = H 4-10%. ______________________________________ The novel mixtures are very useful for dyeing synthetic polyesters.
摘要翻译：基于混合物的总重量含有以下量的通式I的化合物作为必要成分的海军染料混合物：-X = Br R1 = C2H4CN R2 = CH2CHCH2 39-49％， - X = Br R1 = C2H4CN R2 = H 1-10％，-X = Br R1 = H R2 = CH2CHCH2 4-16％，-X = C1 R1 = C2H4CN R2 = H 15-25％，-X = Cl R1 = C 2 H 4 CN R 2 = CH 2 CHCH 2 4-9％， - 和 - -X = Cl

40. 发明授权

US4386934A Navy dye mixtures 失效
标题翻译：海军染料混合物
公开(公告)号：US4386934A
公开(公告)日：1983-06-07
申请号：US370904
申请日：1982-04-22
申请人： Udo Bergmann , Helmut Degen , Guenter Hansen , Reinhold Krallmann , Wolf-Dieter Kermer
发明人： Udo Bergmann , Helmut Degen , Guenter Hansen , Reinhold Krallmann , Wolf-Dieter Kermer
IPC分类号： C09B29/08 , C09B67/22 , D06P1/18 , D06P3/54 , C09B29/00
CPC分类号： C09B67/0051 , C09B29/0813 , C09B29/0825 , D06P1/18 , Y10S534/01 , Y10S8/922
摘要： Navy dye mixtures which contain, as essential components, compounds of the general formula I ##STR1## where X is chlorine or bromine, Y is methoxy or ethoxy, and R is ##STR2## NHC.sub.2 H.sub.4 CN, NHCH.sub.2 CH.dbd.CH.sub.2 or N(C.sub.2 H.sub.4 OCOCH.sub.3).sub.2, and wherein the dye of the above formula where X is Br, Y is OCH.sub.3 or OC.sub.2 H.sub.5 and R is N(C.sub.2 H.sub.4 OCOCH.sub.3).sub.2 is present in an amount of 25-45%, based on the total weight of the mixture, are very useful for dyeing synthetic polyesters.
摘要翻译：含有作为必要组分的通式I的化合物的海军染料混合物，其中X是氯或溴，Y是甲氧基或乙氧基，R是NHC2H4CN，NHCH2CH = CH2或N（C2H4OCOCH3）2 并且其中X为Br，Y为OCH 3或OC 2 H 5且R为N（C 2 H 4 OCOCH 3）2的上式的染料的含量相对于混合物的总重量为25-45％，非常有用用于染色合成聚酯。

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