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    • 1. 发明授权
    • Reactive dyes with two or three nitrogen-containing haloheterocycles as
reactive system
    • 具有两种或三种含有硝酸的氢化物作为反应体系的反应性染料
    • US5149789A
    • 1992-09-22
    • US490710
    • 1990-03-08
    • Joerg L. JessenKlaus PandlHermann LoefflerBernd SiegelManfred Patsch
    • Joerg L. JessenKlaus PandlHermann LoefflerBernd SiegelManfred Patsch
    • C09B50/00C09B62/04C09B62/08D06P3/10D06P3/66
    • C09B62/043
    • Reactive dyes of the formula ##STR1## where 1 is 0 or 1,n is 0 or 1,E is nitrogen or C--Cl,A is the radical of an azo dye attached to the triazine ring via an imino or C.sub.1 -C.sub.4 -alkylimino group,B--if E is nitrogen--is the radical of an azo dye or of a formazan dye which in either case is bonded to the triazine ring via an imino or C.sub.1 -C.sub.4 -alkylimino group or else--if n is 0--is fluorine, chlorine or unsubstituted or substituted amino, or --if E is C--C1--is fluorine, chlorine or methyl,X.sup.1 and X.sup.2 are independently of the other fluorine or chlorine,X.sup.3 is fluorine or chlorine or else--if E is C--Cl--methylsulfonyl andZ.sup.1 and Z.sup.2 are independently of the other a radical of the formula ##STR2## where L.sup.3 and L.sup.4 are independently of the other hydrogen or unsubstituted or substituted C.sub.1 -C.sub.4 -alkyl,with the proviso that l and n are not simultaneously 0 and that, if E is C--Cl or if n is 0 and Z.sup.1 is the radical of the formula ##STR3## where L.sup.3 and L.sup.4 are each as defined above, A may also be the radical of a formazan dye which is bonded to the triazine ring via an imino or C.sub.1 -C.sub.4 -alkylimino group, are useful for dyeing or printing hydroxyl- or nitrogen-containing substrates.
    • 式1的反应性染料,其中1为0或1,n为0或1,E为氮或C-Cl,A为通过亚氨基或C 1 -C 4烷基连接到三嗪环上的偶氮染料的基团, 烷基亚氨基,B-如果E是氮 - 是偶氮染料或甲an染料的基团,其在任一情况下通过亚氨基或C 1 -C 4 - 烷基亚氨基键合到三嗪环,否则 - 如果n是0- 是氟,氯或未取代或取代的氨基,或 - 如果E是C-C1 - 是氟,氯或甲基,则X1和X2独立于其他氟或氯,X3是氟或氯,或者 - 如果E是C -Cl-甲基磺酰基,Z 1和Z 2独立地为下式的基团:其中L 3和L 4独立于另一个氢或未取代或取代的C 1 -C 4 - 烷基,其中 条件是l和n不同时为0,并且如果E是C-Cl或如果n是0,并且Z1是式“IMAGE”的基团,其中L3和L4各自如上所定义,A也可以是t 通过亚氨基或C 1 -C 4烷基亚胺基与三嗪环结合的甲an染料的基团可用于染色或印刷含羟基或含氮基底。
    • 5. 发明授权
    • Diaminopyridine azo dyes having acyloxy radicals substituted on the
diaminopyridine
    • 具有在二氨基吡啶上取代的酰氧基的二氨基吡啶偶氮染料
    • US4855412A
    • 1989-08-08
    • US42243
    • 1987-04-24
    • Johannes DehnertGunther LammHermann Loeffler
    • Johannes DehnertGunther LammHermann Loeffler
    • C09B29/00C09B29/42
    • C09B29/0085C09B29/0059C09B29/0081C09B29/3639Y10S534/02
    • Compounds of the general formula ##STR1## where D is a radical of the formula ##STR2## and one of the two radicals L.sup.1 and L.sup.2 is unsubstituted amino and the other the radical ##STR3## where R.sup.1 is hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy-C.sub.2 -C.sub.4 -alkyl or C.sub.1 -C.sub.8 -acyloxy-C.sub.2 -C.sub.4 -alkyl,R.sup.2 is C.sub.2 -C.sub.10 -alkylene or C.sub.2 -C.sub.10 -alkylene is interrupted by oxygen,T is C.sub.1 -C.sub.8 -alkanoyl which is unsubstituted or is substituted by chlorine or methoxy,B.sup.1 is C.sub.1 -C.sub.4 -alkyl or benzyl or phenyl, which are each unsubstituted or are each substituted by methyl, methoxy or chlorine,B.sup.2 is B.sup.1, hydrogen, halogen, cyano or C.sub.1 -C.sub.5 -alkoxycarbonyl,X.sup.1 is hydrogen, nitro, cyano, C.sub.1 -C.sub.9 -alkoxycarbonyl, C.sub.1 -C.sub.9 -mono- or -dialkylaminocarbonyl, trifluoromethyl, methylsulfonyl or ethylsulfonyl,X.sup.2 is nitro or C.sub.1 -C.sub.5 -alkoxycarbonyl,X.sup.3 is X.sup.2, cyano or formyl,Y is hydrogen, chlorine, bromine, methyl, methoxy or ethoxy andZ is hydrogen, chlorine, bromine, cyano or C.sub.1 -C.sub.9 -alkoxycarbonyl which is unsubstituted or is substituted by C.sub.1 -C.sub.4 -alkoxy, and one or more of the substituents X.sup.1, Y and Z is different from hydrogen, are disclosed.The dyes of the present invention may be used in dyeing synthetic polyester.
    • 其中D是下式的基团的化合物,其中D是式的基团,其中一个基团L 1和L 2是未取代的氨基,另一个是R 1是氢的基团,其中R 1是氢,C 1 C 1-4 - 烷基,C 1 -C 4 - 烷氧基-C 2 -C 4 - 烷基或C 1 -C 8 - 酰氧基-C 2 - C 4 - 烷基,R 2是C 2 -C 10亚烷基或C 2 -C 10亚烷基被氧中断,T是C1 未取代或被氯或甲氧基取代的C 1-8 - 烷酰基,B 1为C 1 -C 4 - 烷基或苄基或苯基,各自未被取代或各自被甲基,甲氧基或氯取代,B2为B1,氢,卤素, 氰基或C 1 -C 5 - 烷氧基羰基,X 1为氢,硝基,氰基,C 1 -C 9 - 烷氧基羰基,C 1 -C 9 - 单 - 或 - 二烷基氨基羰基,三氟甲基,甲基磺酰基或乙基磺酰基,X 2为硝基或C 1 -C 5烷氧基羰基, X 2,氰基或甲酰基,Y是氢,氯,溴,甲基,甲氧基或乙氧基,Z是氢,氯,溴,氰基或未被取代或被C 1 -C 4 - 烷氧基,并且一个或多个取代基X 1,Y和Z不同于氢。 本发明的染料可用于染色合成聚酯。
    • 6. 发明授权
    • Diazo dyes having a coupler component attached to a
sulfaphenyl-azo-phenyl-azo-radical
    • 重氮染料具有连接在磺基苯偶氮 - 苯偶氮基上的成色剂组分
    • US4419290A
    • 1983-12-06
    • US159474
    • 1980-06-16
    • Johannes DehnertHermann Loeffler
    • Johannes DehnertHermann Loeffler
    • C09B31/02C09B31/043C09B31/062C09B31/068C09B31/14
    • C09B31/025
    • A dye which in free acid form corresponds to the formula: ##STR1## wherein n is 1 or 2,Hal is chlorine or bromine,R.sup.1 is hydrogen, chlorine, bromine, methyl, ethyl, methoxy or ethoxy,R.sup.2 is hydrogen, chlorine, bromine, methyl or methoxy,R.sup.1 and R.sup.2 are a fused unsubstituted benzene ring or a fused benzene ring substituted by hydroxysulfonyl,K is ##STR2## B is hydrogen, C.sub.1 to C.sub.4 alkyl or .beta.-hydroxy-.gamma.-chloropropyl,B.sup.1 is hydrogen, C.sub.1 to C.sub.4 alkyl, C.sub.2 or C.sub.3 hydroxyalkyl, allyl,C.sub.2 or C.sub.3 alkyl substituted by C.sub.1 to C.sub.4 alkoxy or C.sub.1 to C.sub.4 alkanoyloxy, .beta.-chlorethyl, .beta.-cyanoethyl, or .beta.-hydroxy-.gamma.-chloropropyl,B.sup.2 is the same as B.sup.1 or is cyclohexyl, benzyl, sulfobenzyl, phenylethyl, sulfophenylethyl, phenyl or sulfophenyl,B.sup.3 is hydrogen, chloro, methyl or C.sub.1 to C.sub.4 alkanoylamino,B.sup.5 is hydrogen, allyl, methyl, .beta.-cyanoethyl, .beta.-carbamoylethyl or .gamma.-carboxyethyl,B.sup.6 is methyl or phenyl,B.sup.7 is hydrogen or C.sub.1 to C.sub.3 alkyl,B.sup.8 is hydrogen, C.sub.1 to C.sub.8 alkyl, C.sub.1 to C.sub.8 alkyl substituted by hydroxy, C.sub.1 to C.sub.8 alkoxy, phenoxy, phenyl, sulfophenoxy, sulfophenyl, carboxyl, or hydroxysulfonyloxy, cyclohexyl, norbornyl, phenyl, phenyl substituted by chlorine, methyl, methoxy or hydroxysulfonyl, CH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.2 OH or (CH.sub.2).sub.3 (OC.sub.2 H.sub.4).sub.q OB.sup.9,B.sup.9 is hydrogen, C.sub.1 to C.sub.4 alkyl, cyclohexyl, benzyl, phenylethyl, phenyl, sulfobenzyl, sulfophenylethyl or sulfophenyl,p is 0 of 1,q is 1 or 2 andX is cyano or carbamoyl.The dyes are exceptionally suitable for dyeing nitrogen-containing fibers, and give dyeings with excellent fastness properties, amongst which the fastness to light and to wet treatments are outstanding.
    • 游离酸形式的染料对应于下式:其中n为1或2,Hal为氯或溴,R1为氢,氯,溴,甲基,乙基,甲氧基或乙氧基,R2为氢,氯, 溴,甲基或甲氧基,R 1和R 2是稠合的未取代的苯环或被羟基磺酰基取代的稠合苯环,K是氢,C 1至C 4烷基或β-羟基-γ-氯丙基 ,C1为氢,C1至C4烷基,C2或C3羟基烷基,烯丙基,C1至C4烷氧基或C1至C4烷酰氧基取代的C2或C3烷基,β-氯乙基,β-氰基乙基或β-羟基-γ-氯丙基, B2与B1相同或为环己基,苄基,磺基苄基,苯基乙基,磺基苯乙基,苯基或磺基苯基,B3为氢,氯,甲基或C1至C4烷酰基氨基,B5为氢,烯丙基,甲基,β-氰基乙基, 或γ-羧乙基,B6为甲基或苯基,B7为氢或C1至C3烷基,B8为氢,C1至C8烷基, 被羟基取代的C1至C8烷基,C1至C8烷氧基,苯氧基,苯基,磺基苯氧基,磺基苯基,羧基或羟基磺酰氧基,环己基,降冰片基,苯基,被氯,甲基,甲氧基或羟基磺酰基取代的苯基,CH2CH2OCH2CH2OH或(CH2) OC2H4)qOB9,B9是氢,C1至C4烷基,环己基,苄基,苯基乙基,苯基,磺基苄基,磺基苯基乙基或磺基苯基,p为0,q为1或2,X为氰基或氨基甲酰基。 这些染料特别适用于含氮纤维的染色,并且具有优异的耐牢度性能的染色,其中耐光牢度和湿处理性能优异。
    • 8. 发明授权
    • Dyes containing 3,4-disubstituted-2-diaza-thiophene radicals
    • 含有3,4-取代-2-二氮杂-苯并呋喃的染料
    • US4952681A
    • 1990-08-28
    • US205359
    • 1988-07-27
    • Guenter HansenErnst SchefczikKarl-Heinz EtzbachHelmut ReicheltHermann Loeffler
    • Guenter HansenErnst SchefczikKarl-Heinz EtzbachHelmut ReicheltHermann Loeffler
    • C09B29/00C09B62/35C09B29/033C09B29/33C09B29/36
    • C09B29/0059
    • Compounds of the formula I ##STR1## where X is fluorine, chlorine, bromine, SO.sub.2 E or unsubstituted or substituted hydroxyl or mercapto, E is alkyl, alkenyl, cycloalkyl, aralkyl, aryl, chlorine or unsubstituted or substituted hydroxyl or amino, Y is cyano, nitro, alkanoyl, aroyl, alkylsulfonyl, arylsulfonyl, carboxyl, a carboxylic ester group or unsubstituted or substituted carbamyl, T is hydrogen, C.sub.1 -C.sub.4 -alkyl, a radical which can be introduced by electrophilic substitution or a radical of the formula --CH.dbd.B, in which B is a radical of a methylene-active compound or of an amine, and K is a radical of a coupling component, are disclosed. They are useful for dyeing synthetic fibers or plastics.
    • 1.式I的化合物参见图示:EP0201896,P71,F3,其中X是氟,氯,溴,SO2E,OH,OCH3,OC2H5,OC3H7,OC4H9,OCH2 C6H5,OC6H11,OC6H5 ,OC 6 H 4 CH 3,OC 6 H 4 Cl,SH,SCH 3,SC 2 H 5,SC 3 H 7,SC 4 H 9,SCH 2 C 6 H 5,SC 2 H 4 OH,SCH 2 COOCH 3,SCH 2 COOC 2 H 5,SC 6 H 11,SC 6 H 5或SC 6 H 4 CH 2,E是烷基 ,链烯基,环烷基,芳烷基,芳基,氯,OH,CH3O,C2H5O,C3H7O,C4H9O,C6H5 -CH2O,C6H5 -CH2 -CH2O,C6H5O,CIC6H4O, CH 3 C 4 H 4 O,NH 2,NHCH 3,N(CH 3)2,NHC 2 H 5,N(C 2 H 5)2,NCH 4 H 9,N(C 4 H 9)2,NHC 6 H 5,NHC 6 H 4 -CH 3,NHC 6 H 4 Cl或NCH 3 C 6 H 5 ,Y是氰基,硝基,烷酰基,芳酰基,烷基磺酰基,芳基磺酰基,羧基,羧酸酯基或未取代或取代的氨基甲酰基,T是氢,C 1 -C 4烷基,NO,NO 2,SO 3 H,CHO,CN, ,C 2 H 5 CO,C 6 H 5 CO,CH 3 SO 2,C 2 H 5 SO 2,C 6 H 5 SO 2或式-CH = B的基团,其中B是亚甲基活性化合物或胺的基团,K是 激进或 耦合部件。