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    • 35. 发明申请
    • PROCESS FOR PREPARING POROUS POLYMER PARTICLES
    • 制备多孔聚合物颗粒的方法
    • US20130165541A1
    • 2013-06-27
    • US13334199
    • 2011-12-22
    • Xiqiang YangJames R. Bennett
    • Xiqiang YangJames R. Bennett
    • C08J9/00C08L67/00C08L25/08
    • C08J9/0066C08J9/28C08J2201/0482C08J2325/14C08J2367/00
    • A process for forming polymer particles with aligned pores and controlled narrow particle size distribution, including: a) forming an oil phase by dissolving a polymeric binder in a solvent; b) dispersing the oil phase into a water phase containing a controlled amount of particulate stabilizer and forming an oil-in-water emulsion of controlled narrow dispersed oil phase droplet size distribution; c) freezing the emulsion to freeze solvent in the oil droplets to form frozen solvent domains within the polymeric binder, and also the water in the continuous water phase; and d) removing the frozen solvent from the polymeric binder and the frozen water in the continuous water phase, thereby forming porous polymer particles of controlled narrow particle size distribution and containing directional aligned non-spherical pore structures. Optionally, the porous particles may contain encapsulated functional ingredients.
    • 一种用于形成具有排列孔和受控的窄粒度分布的聚合物颗粒的方法,包括:a)通过将聚合物粘合剂溶解在溶剂中形成油相; b)将油相分散到含有受控量的颗粒稳定剂的水相中并形成受控窄分散油相液滴尺寸分布的水包油乳液; c)冷冻乳液以在油滴中冷冻溶剂,以在聚合物粘合剂内形成冷冻溶剂结构域,以及连续水相中的水; 以及d)从连续水相中的聚合物粘合剂和冷冻水中除去冷冻的溶剂,从而形成受控窄粒度分布的多孔聚合物颗粒并且包含定向排列的非球形孔结构。 任选地,多孔颗粒可以含有包封的功能性成分。
    • 37. 发明申请
    • POROUS PARTICLES WITH IMPROVED FILTERING PERFORMANCE
    • 具有改进过滤性能的多孔颗粒
    • US20120136080A1
    • 2012-05-31
    • US12956022
    • 2010-11-30
    • Xiqiang YangJames R. Bennett
    • Xiqiang YangJames R. Bennett
    • C08J9/28C08B15/00C08B37/02C08B3/00
    • C08J9/28C08B11/12C08J2201/05C08L1/284C08L1/286C08L5/02C08L33/26
    • A method of manufacturing porous polymer particles with improved filterability is described. One or more first water phases are formed comprising an anionic hydrocolloid with a mass-per-charge value of less than 600 and a relatively minor amount, compared to the anionic hydrocolloid, of at least one of a nonionic, cationic, zwitterionic, or weakly anionic water soluble or dispersible polymer, where the weakly anionic water soluble or dispersible polymer has a mass-per-charge value of larger than 600. A water-in-oil emulsion is formed by dispersing the one or more first water phases into an organic phase comprising at least one of either (i) preformed polymer dissolved in an organic solvent or (ii) polymerizable monomers, and homogenizing. A water-in-oil-in-water multiple emulsion is formed by dispersing the water-in-oil emulsion into a second water phase containing a stabilizing agent and homogenizing. The organic solvent is removed to precipitate the preformed polymer, or the polymerizable monomers are polymerized, to obtain a dispersion of porous polymer particles in an external aqueous phase, wherein individual porous particles each comprise a continuous polymer phase and internal pores containing an internal aqueous phase. The dispersion of porous polymer particles is filtered to remove the external aqueous phase. The method enables increased filtration rates of porous polymer particle dispersions containing water in the pores.
    • 描述了制造具有改进的过滤性的多孔聚合物颗粒的方法。 形成一个或多个第一水相,其包含阴离子水胶体,每批电荷值小于600,并且与阴离子水胶体相比,非离子,阳离子,两性离子或弱的至少一种 阴离子水溶性或可分散的聚合物,其中弱阴离子水溶性或可分散聚合物的每次电荷值大于600.通过将一个或多个第一水相分散到有机物中形成油包水乳液 包含(i)预先形成的聚合物溶解在有机溶剂中的至少一种或(ii)可聚合单体,并均化。 通过将油包水乳液分散到含有稳定剂的第二水相中并均化来形成水包油包水多重乳液。 去除有机溶剂以沉淀预制的聚合物,或聚合单体,得到多孔聚合物颗粒在外部水相中的分散体,其中各个多孔颗粒各自包含连续聚合物相和含有内部水相的内孔 。 过滤多孔聚合物颗粒的分散体以除去外部水相。 该方法能够增加在孔中含有水的多孔聚合物颗粒分散体的过滤速率。
    • 39. 发明申请
    • METHOD OF MANUFACTURING WAX-CONTAINING POLYMER PARTICLES
    • 制造含WAX的聚合物颗粒的方法
    • US20120003581A1
    • 2012-01-05
    • US12826832
    • 2010-06-30
    • Xiqiang YangJames R. Bennett
    • Xiqiang YangJames R. Bennett
    • G03G9/087
    • G03G9/08755G03G9/0804G03G9/08782G03G9/08795G03G9/08797
    • The present invention is directed towards methods of manufacturing wax-containing polymer particles by limited coalescence processes employing aqueous wax dispersions. In one embodiment, an aqueous wax dispersion or emulsion is dispersed in an oil phase comprising a water-immiscible solvent and a polymer to form a transient water-in-oil (W/O) emulsion, and a further aqueous phase containing a particulate stabilizer is then added to the W/O emulsion to induce phase inversion, and the mixture homogenized to form an oil-in-water (O/W) emulsion. The solvent is then removed from the emulsion to form particles containing wax domains inside. In another embodiment, the aqueous wax dispersion is first mixed with the aqueous phase containing the particulate stabilizer, and homogenization is made with the oil phase to form an O/W emulsion, from which wax-containing particles are obtained after solvent removal. In still further embodiments, the aqueous wax dispersion is used in the second water phase of a double emulsion (W1/O/W2) process to form porous polymer particles containing the wax.
    • 本发明涉及通过使用含水蜡分散体的有限聚结方法制造含蜡聚合物颗粒的方法。 在一个实施方案中,水性蜡分散体或乳液分散在包含水不混溶溶剂和聚合物的油相中以形成瞬时油包水(W / O)乳液,以及含有颗粒稳定剂 然后加入到W / O乳液中以诱导相转化,并将混合物均质化以形成水包油(O / W)乳液。 然后将溶剂从乳液中除去以形成含有内部蜡区域的颗粒。 在另一个实施方案中,首先将含水蜡分散体与含有颗粒稳定剂的水相混合,并用油相进行均化以形成O / W乳液,在除去溶剂后从其中获得含蜡颗粒。 在另外的实施方案中,水性蜡分散体用于双乳液(W1 / O / W2)方法的第二水相中以形成含有蜡的多孔聚合物颗粒。