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31. 发明授权

US07670476B2 Process to prepare a gas oil 失效
标题翻译：制备瓦斯油的工艺
公开(公告)号：US07670476B2
公开(公告)日：2010-03-02
申请号：US11667912
申请日：2005-11-18
申请人： Jan Lodewijk Maria Dierickx , Arend Hoek , Lip Piang Kueh
发明人： Jan Lodewijk Maria Dierickx , Arend Hoek , Lip Piang Kueh
IPC分类号： C10G65/16
CPC分类号： C10G65/16
摘要： Process to optimize the yield of gas oils from a Fischer-Tropsch derived feed by performing the following steps: (a) performing a hydroconversion/hydroisomerisation step on part of the Fischer-Tropsch derived feed; (b) performing a hydroconversion/hydroisomerisation step on another part of the Fischer-Tropsch feed at a conversion greater than the conversion in step (a); and (c) isolating by means of distillation a gas oil fraction from the two reaction products obtained in steps (a) and (b).
摘要翻译：通过执行以下步骤来优化来自费 - 托衍生的原料的瓦斯油的产率的方法：（a）对部分费 - 托衍生的进料进行加氢转化/加氢异构化步骤; （b）以大于步骤（a）中的转化率的转化率对费 - 托进料的另一部分进行加氢转化/加氢异构化步骤; 和（c）通过蒸馏分离来自步骤（a）和（b）中获得的两种反应产物的粗柴油馏分。

32. 发明申请

US20090124711A1 Fischer-tropsch process and reactor assembly 有权
标题翻译：费 - 托法和反应器组装
公开(公告)号：US20090124711A1
公开(公告)日：2009-05-14
申请号：US11988970
申请日：2006-07-14
申请人： Arend Hoek , Hans Michiel Huisman
发明人： Arend Hoek , Hans Michiel Huisman
IPC分类号： C10G2/00 , B01J19/00
CPC分类号： C10G2/32 , B01J8/0278 , B01J8/065 , B01J8/067 , B01J8/22 , B01J2219/00038 , B01J2219/00202 , B01J2219/00211 , B01J2219/00231 , B01J2219/00238 , C10G2/34 , C10G2400/02 , C10G2400/06 , C10G2400/08 , C10G2400/10 , C10G2400/18
摘要： A method of accommodating a reduction in production capacity of one or more reactors in a multi-reactor assembly adapted for the production of hydrocarbon products from syngas, the syngas being provided by a syngas manufacturing facility and provided to an entry stream system providing syngas to each of the reactors, and having an exit stream system taking at least hydrocarbon products from the reactors, wherein the method comprises the steps of: redistributing the syngas from the one or more said reactors to one or more other reactors, and increasing the temperature in the said one or more other reactors to at least partially take over the reduction in production capacity of the one or more reactors.
摘要翻译：一种在适合从合成气生产碳氢化合物产品的多反应器组合中容纳一个或多个反应器的生产能力降低的方法，合成气由合成气制造设施提供并提供给进入流系统，其将合成气提供给每个的反应器，并且具有至少从反应器中取出烃产物的出口流系统，其中所述方法包括以下步骤：将来自所述一个或多个所述反应器的合成气重新分配到一个或多个其它反应器，并且增加所述反应器中的温度所述一个或多个其它反应器至少部分地承担一个或多个反应器的生产能力的降低。

33. 发明申请

US20080051477A1 Process to Prepare a Gas Oil 失效
标题翻译：制备瓦斯油的工艺
公开(公告)号：US20080051477A1
公开(公告)日：2008-02-28
申请号：US11667912
申请日：2005-11-18
申请人： Jan Lodewijk Dierickx , Arend Hoek , Lip Kueh
发明人： Jan Lodewijk Dierickx , Arend Hoek , Lip Kueh
IPC分类号： C10G65/16
CPC分类号： C10G65/16
摘要： Process to optimize the yield of gas oils from a Fischer-Tropsch derived feed by performing the following steps: (a) performing a hydroconversion/hydroisomerisation step on part of the Fischer-Tropsch derived feed; (b) performing a hydroconversion/hydroisomerisation step on another part of the Fischer-Tropsch feed at a conversion greater than the conversion in step (a); and (c) isolating by means of distillation a gas oil fraction from the two reaction products obtained in steps (a) and (b).
摘要翻译：通过执行以下步骤来优化来自费 - 托衍生的原料的瓦斯油的产率的方法：（a）对部分费 - 托衍生的进料进行加氢转化/加氢异构化步骤; （b）以大于步骤（a）中的转化率的转化率对费 - 托进料的另一部分进行加氢转化/加氢异构化步骤; 和（c）通过蒸馏分离来自步骤（a）和（b）中获得的两种反应产物的粗柴油馏分。

34. 发明申请

US20050130837A1 Shaped catalyst particles for hydrocarbon synthesis 失效
标题翻译：用于烃合成的成型催化剂颗粒
公开(公告)号：US20050130837A1
公开(公告)日：2005-06-16
申请号：US10517098
申请日：2003-06-06
申请人： Arend Hoek , Hans Huisman , Carolus Matthias Mester
发明人： Arend Hoek , Hans Huisman , Carolus Matthias Mester
IPC分类号： B01J23/74 , B01J23/75 , B01J23/889 , B01J35/02 , B01J37/00 , C10G2/00 , C10G49/00 , B01J23/00
CPC分类号： C10G2/332 , B01J23/75 , B01J23/8892 , B01J35/026 , B01J37/0009 , C10G2/33 , C10G49/00
摘要： The invention relates to a shaped catalyst or catalyst precursor containing a catalytically active component or a precursor therefore, the component selected from elements of Group VIII of the Periodic Table of the Elements, supported on a carrier, which catalyst or catalyst precursor is an elongated shaped particle having three protrusions each extending from and attached to a central position, wherein the central position is aligned along the longitudinal axis of the particle, the cross-section of the particle occupying the space encompassed by the outer edges of six circles around a central circle, each of the six circles touching two neighboring circles while three alternating circles are equidistant to the central circle and may be attached to the central circle, minus the space occupied by the three remaining outer circles and including the six interstitial regions. The invention further relates to a process to prepare the catalyst or catalyst precursor from a shapeable dough, to the die-plate used for the preparation of an extruded catalyst or catalyst precursor, to the use of the catalysts, as well as to hydrocarbons prepared by using the catalyst. The invention further relates to a process to obtain fuels and optionally base oils, by hydrogenation, hydroisomerisation and/or hydrocracking of the hydrocarbons prepared by using the catalyst.
摘要翻译：本发明涉及含有催化活性组分或前体的成型催化剂或催化剂前体，所述催化剂或催化剂前体包含负载在载体上的选自元素周期表第Ⅷ族元素的组分，该催化剂或催化剂前体是细长形状具有从中心位置延伸并连接到中心位置的三个突起的颗粒，其中中心位置沿着颗粒的纵向轴线对准，颗粒的横截面占据由围绕中心圆的六个圆的外边缘包围的空间，六个圆中的每一个接触两个相邻的圆，而三个交替的圆与中心圆相等，并且可以附接到中心圆，减去三个剩余外圆所占据的空间并且包括六个间隙区。本发明还涉及一种从可成型面团制备催化剂或催化剂前体的方法，用于制备挤出的催化剂或催化剂前体的模板，使用催化剂以及由使用催化剂。本发明还涉及通过使用催化剂制备的烃的氢化，加氢异构化和/或加氢裂化来获得燃料和任选的基础油的方法。

35. 发明授权

US06858127B2 Process for the preparation of middle distillates 有权
标题翻译：中间馏分油的制备工艺
公开(公告)号：US06858127B2
公开(公告)日：2005-02-22
申请号：US10469843
申请日：2002-03-01
申请人： Arend Hoek , Matthijs Maria Gerardus Senden
发明人： Arend Hoek , Matthijs Maria Gerardus Senden
IPC分类号： C10G67/02 , C10G20060101 , C10G2/00 , C10G45/58 , C10G45/64 , C10G47/20 , C10G65/04 , C10G65/10 , C10M101/02 , C10M107/02 , C10M169/04 , C10M171/02 , C10G65/00 , C07C27/00 , C10G35/00 , C10G47/00
CPC分类号： C10M171/02 , C10G2/32 , C10G65/043 , C10G65/10 , C10G2400/04 , C10G2400/06 , C10G2400/08 , C10M101/02 , C10M107/02 , C10M169/04 , C10M2205/173 , C10N2230/02 , C10N2230/04 , C10N2230/12 , C10N2240/10 , C10N2240/102
摘要： A process for the preparation of one or more hydrocarbon fuel products boiling in the kero/diesel range from a stream of hydrocarbons produced in a Fischer-Tropsch process, in which process synthesis gas is converted into liquid hydrocarbons, at least a part of the hydrocarbons boiling above the kero/diesel range, having the following steps: (1) hydrocracking/hydroisomerizing at least a part of the Fischer-Tropsch hydrocarbons stream at a conversion per pass of at most 80 wt % of the material boiling above 370° C. into material boiling below 370° C.; (2) separating the product stream obtained in step (1) into one or more light fractions boiling below the kero/diesel boiling range, one or more fractions boiling in the kero/diesel boiling range and a heavy fraction boiling above the kero/diesel boiling range; (3) hydrocracking/hydroisomerizing the major part of the heavy fraction obtained in step (2) at a conversion per pass of at most 80 wt % of the material boiling above 370° C. into material boiling below 370° C.; (4) separating the product stream obtained in step (3) into one or more light fractions boiling below the kero/diesel boiling range, one or more fractions boiling in the kero/diesel boiling range and a heavy fraction boiling above the kero/diesel boiling range; and, (5) hydrocracking/hydroisomerizing the major part of the heavy fraction obtained in step (4) in the hydrocracking/hydroisomerizing process described in step (1) and/or step (3), in which process the Fischer-Tropsch hydrocarbons stream comprises at least 35 wt % C30+ (based on total amount of hydrocarbons in the Fischer-Tropsch hydrocarbons stream) and in which stream the weight ratio C60+/C30+ is at least 0.2.
摘要翻译：一种用于制备一种或多种在kero /柴油范围内沸腾的烃类燃料产物的方法，该烃类燃料产物是从费 - 托法生产的烃流中制备的，其中工艺合成气被转化为液态烃，至少一部分烃沸点高于kero /柴油范围，具有以下步骤：（1）以至少一半沸点高于370℃的材料的80重量％的转化率将费 - 托烃流的至少一部分加氢裂化/加氢异构化。沸腾到低于370℃的材料;（2）将步骤（1）中获得的产物流分离成一个或多个沸点低于kero /柴油沸程的轻馏分，一个或多个沸点为kero /柴油沸程的馏分和沸点高于kero /柴油沸点范围的重馏分;（3）在步骤（2）中获得的重馏分的主要部分加氢裂化/加氢异构化，转化率最高为沸点高于370℃的材料的80重量％进入m （4）将步骤（3）中获得的产物流分离成沸点低于kero /柴油沸程的一种或多种轻馏分，一种或多种沸点为kero /柴油沸程的馏分和重馏分沸腾超过kero /柴油沸程; 和（5）在步骤（1）和/或步骤（3）中描述的加氢裂化/加氢异构化方法中，将步骤（4）中获得的重馏分的主要部分加氢裂化/加氢异构化，其中费 - 托烃流包含至少35重量％的C30 +（基于费 - 托烃流中的烃的总量），其中重量比C60 + / C30 +为至少0.2。

36. 发明授权

US5958985A Process for the preparation of hydrocarbons 失效
标题翻译：烃类制备方法
公开(公告)号：US5958985A
公开(公告)日：1999-09-28
申请号：US989430
申请日：1997-12-12
申请人： Jacobus Johannes Cornelis Geerlings , Arend Hoek , Hans Michiel Huisman , Peter William Lednor
发明人： Jacobus Johannes Cornelis Geerlings , Arend Hoek , Hans Michiel Huisman , Peter William Lednor
IPC分类号： B01J23/889 , C07C1/04 , C10G2/00 , C07C27/00 , B01J23/00 , B01J23/32
CPC分类号： C10G2/332 , B01J23/8892 , C07C1/0435 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2523/34 , C07C2523/75 , C07C2523/889
摘要： A process for the preparation of hydrocarbons by catalytic reaction of carbon monoxide with hydrogen in which reaction a feed comprising hydrogen and carbon monoxide is contacted at elevated temperature and pressure with a catalyst comprising cobalt and manganese in which catalyst the cobalt/manganese molar ratio is between 14:1 and 7:1 and the GHSV is at least 1600 N1/1/h. Preferably the cobalt/manganese molar ratio is between 13:1 and 9:1 and the GHSV is between 2700 and 25,000 N1/1/h. The reaction is especially carried out in a slurry phase regime.
摘要翻译：通过一氧化碳与氢的催化反应制备烃的方法，其中使包含氢和一氧化碳的进料在高温和高压下与包含钴和锰的催化剂接触，其中催化剂的钴/锰摩尔比介于 14：1和7：1，GHSV至少为1600N1 / 1 / h。优选钴/锰的摩尔比为13:1至9:1，GHSV为2700至25,000N1 / 1 / h。反应特别是在淤浆相状态下进行。

37. 发明授权

US07674940B2 Process for the preparation of detergent compounds 有权
标题翻译：洗涤剂化合物的制备方法
公开(公告)号：US07674940B2
公开(公告)日：2010-03-09
申请号：US10546281
申请日：2004-02-19
申请人： Henk Dirkzwager , Robert Martijn Van Hardeveld , Arend Hoek , Peter William Lednor , Joannes Ignatius Geijsel
发明人： Henk Dirkzwager , Robert Martijn Van Hardeveld , Arend Hoek , Peter William Lednor , Joannes Ignatius Geijsel
IPC分类号： C07C2/00 , C07C4/00 , C07C6/00 , C11D17/00
CPC分类号： C10G67/02 , C07C1/0485 , C10G2/00 , C10G65/04 , C10G69/123 , C10G2300/1022 , C10G2300/301
摘要： A process for the preparation of detergents containing a relatively low amount of isoparaffins, involving separating a hydrocarbonaceous product stream from a Fischer-Tropsch process using a cobalt based catalyst and producing normally liquid and normally solid hydrocarbons into a light fraction boiling below an intermediate fraction having detergent hydrocarbons, an intermediate boiling fraction having detergent hydrocarbons and a heavy fraction boiling above the intermediate boiling fraction having detergent hydrocarbons, followed by conversion of the detergent hydrocarbons present in the intermediate boiling fraction into detergents, the Fischer-Tropsch process being carried out at a relatively high pressure.
摘要翻译：一种用于制备含有相对低量的异链烷烃的洗涤剂的方法，包括使用钴基催化剂从费 - 托法中分离烃产物流，并将通常为液态的和通常为固体的烃生产成沸点低于具有洗涤剂烃，具有洗涤剂烃的中间沸点馏分和在具有洗涤剂烃的中间沸点馏分以上沸腾的重馏分，随后将存在于中间沸点馏分中的洗涤剂烃转化为洗涤剂，费 - 托方法在比较高的压力。

38. 发明申请

US20090200203A1 PROCESS FOR HYDROCRACKING AND HYDRO-ISOMERISATION OF A PARAFFINIC FEEDSTOCK 有权
标题翻译：水力收割过程和水分收稿日期：
公开(公告)号：US20090200203A1
公开(公告)日：2009-08-13
申请号：US12208160
申请日：2008-09-10
申请人： Focco Kornelis Bijlsma , Jan Lodewijk Maria Dierickx , Arend Hoek
发明人： Focco Kornelis Bijlsma , Jan Lodewijk Maria Dierickx , Arend Hoek
IPC分类号： C10G47/12
CPC分类号： C10G45/62 , C10G2300/1022 , C10G2300/301 , C10G2400/06 , C10G2400/10 , Y10S208/95
摘要： A process for hydrocracking and hydro-isomerisation of a paraffinic feedstock obtained by Fischer-Tropsch hydrocarbon synthesis comprising at least 50 wt % of components boiling above 370° C. to obtain a hydro-isomerised feedstock, the process comprising contacting the feedstock, in the presence of hydrogen, at elevated temperature and pressure with a catalyst comprising a hydrogenating compound supported on a carrier comprising amorphous silica-alumina, the carrier having a pore volume of at least 0.8 ml/g, wherein at most 40% of the pore volume comes from pores having a pore diameter above 35 nm and wherein at most 20% of the pore volume comes from pores having a pore diameter below 50 Å and above 37 Å, the carrier having a median pore diameter of at least 85 Å, wherein the product of (surface area per pore volume) and (median pore diameter as measured by mercury intrusion porosimetry) of the carrier is at least 34,000 Å·m2/ml.
摘要翻译：通过费 - 托烃合成获得的石蜡原料的加氢裂化和加氢异构化的方法，其包含至少50重量％沸点高于370℃的组分以获得加氢异构化原料，该方法包括使原料在在升高的温度和压力下，使用包含负载在包含无定形二氧化硅 - 氧化铝的载体上的氢化化合物的催化剂存在氢，所述载体具有至少0.8ml / g的孔体积，其中至多40％的孔体积来从孔径大于35nm的孔和其中至多20％的孔体积来自孔径低于和高于37埃的孔，载体的中值孔径至少为85，其中产物（孔体积的表面积）和（通过水银压入孔隙率测定的中值孔径）为至少34,000埃/ 2毫升。

39. 发明申请

US20070265359A1 Process to Prepare Lower Olefins from a Carbon Containing Feedstock 有权
标题翻译：从含碳原料制备低烯烃的方法
公开(公告)号：US20070265359A1
公开(公告)日：2007-11-15
申请号：US11664657
申请日：2005-10-06
申请人： Emil Cruijsberg , Jan Dierickx , Arend Hoek , Johannes Van Schijndel , Jeroen Van Westrenen
发明人： Emil Cruijsberg , Jan Dierickx , Arend Hoek , Johannes Van Schijndel , Jeroen Van Westrenen
IPC分类号： C10G9/00
CPC分类号： C10G9/00 , C10G2/30
摘要： Process to make ethylene and/or propylene from a carbonaceous feedstock by performing the following steps, (aa) preparing a mixture of carbon monoxide and hydrogen from said feedstock, (bb) performing a Fischer-Tropsch synthesis step using the gaseous mixture obtained in step (aa) to obtain a Fischer-Tropsch product, in admixture with the unconverted carbon monoxide and hydrogen, (cc) performing a thermal cracking step on the Fischer-Tropsch product in admixture with the unconverted carbon monoxide and hydrogen of step (bb).
摘要翻译：（aa）从所述原料制备一氧化碳和氢气的混合物的方法，（bb）使用步骤（a）中获得的气态混合物进行费 - 托合成步骤，（bb）从碳原料制备乙烯和/ （aa），以与未转化的一氧化碳和氢气混合获得费 - 托产物，（cc）与步骤（bb）的未转化的一氧化碳和氢气混合，在费 - 托产物上进行热裂解步骤。

40. 发明申请

US20070193923A1 Process to prepare a fischer-tropsch product 有权
标题翻译：制备费 - 托产品的方法
公开(公告)号：US20070193923A1
公开(公告)日：2007-08-23
申请号：US10561477
申请日：2004-07-02
申请人： Jan Dierickx , Arend Hoek , Lip Piang Kueh
发明人： Jan Dierickx , Arend Hoek , Lip Piang Kueh
IPC分类号： C10G73/02 , C10G73/38
CPC分类号： C10G2/32 , C10G45/00 , C10G45/02 , C10G2400/10
摘要： A process to prepare a waxy Raffinate product by performing the following steps: (a) subjecting a Fischer-Tropsch derived product having a weight ratio of compounds boiling above 540° C. and compounds boiling between 370 and 540° C. of greater than 2 to a hydroconversion step and (b) fractionating the effluent of step (a) to obtain products boiling in the fuels range and a waxy raffinate product boiling between 350 and 600° C.
摘要翻译：一种通过进行以下步骤制备蜡状提余液产物的方法：（a）使沸点高于540℃的化合物的重量比的费 - 托衍生产物和在370和540℃之间沸腾的化合物大于2 加氢转化步骤和（b）将步骤（a）的流出物分馏以获得在燃料范围内沸腾的产物和沸点在350和600℃之间的蜡状提余物产物。

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