专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

31. 发明授权

US6090895A Crosslinked ion conductive membranes 失效
标题翻译：交联离子导电膜
公开(公告)号：US6090895A
公开(公告)日：2000-07-18
申请号：US84073
申请日：1998-05-22
申请人： Shane S. Mao , Steven J. Hamrock , David A. Ylitalo
发明人： Shane S. Mao , Steven J. Hamrock , David A. Ylitalo
IPC分类号： B01D67/00 , B01D71/52 , B01D71/68 , B01D71/82 , C08G65/48 , C08J3/24 , C08J5/22 , H01B1/06 , H01B13/00 , H01M8/02 , H01M8/10 , C08F8/32
CPC分类号： B01D67/0093 , B01D71/52 , B01D71/68 , B01D71/82 , C08G65/48 , C08J5/2256 , H01M8/1025 , H01M8/1027 , H01M8/1032 , H01M8/1072 , B01D2323/30 , C08J2371/12 , Y02P70/56
摘要： A method is provided for making crosslinked acidic polymers useful as ion conductive membranes, such as crosslinked sulfonated polyether ketones, sulfonated polysulfones, sulfonated polystyrenes, and other acidic polymers, by crosslinking with a species which generates an acidic functionality. The crosslinker preferably binds to acid functions by conversion of acid groups to imide functionality, which, due to the acidity of the N-H bonds therein, compensate for the acidity lost by the occupation of the acid groups and thus preserve membrane conductivity while contributing to membrane strength and resistance to swelling.
摘要翻译：通过与产生酸性官能团的物质交联，提供了用于制备交联的酸性聚合物作为离子导电膜，例如交联磺化聚醚酮，磺化聚砜，磺化聚苯乙烯和其它酸性聚合物的方法。交联剂优选通过将酸基团转化为酰亚胺官能团而结合酸官能团，其由于其中NH键的酸性而补偿由于占据酸基而损失的酸度，从而保持膜导电性，同时有助于膜强度和抗肿胀。

32. 发明授权

US5514493A Perfluoroalkylsulfonates, sulfonimides, and sulfonyl methides, and electrolytes containing them 失效
标题翻译：全氟烷基磺酸盐，磺酰亚胺和磺酰基甲基化物，以及含有它们的电解质
公开(公告)号：US5514493A
公开(公告)日：1996-05-07
申请号：US398859
申请日：1995-03-06
申请人： Jennifer E. Waddell , William M. Lamanna , Larry J. Krause , George G. I. Moore , Steven J. Hamrock
发明人： Jennifer E. Waddell , William M. Lamanna , Larry J. Krause , George G. I. Moore , Steven J. Hamrock
IPC分类号： C07D295/08 , C07C303/38 , C07C309/14 , C07C311/48 , C07C317/28 , C07D241/04 , H01M6/04 , H01M6/16 , H01M10/40
CPC分类号： H01M6/166 , C07C303/38 , H01M6/04
摘要： An electrolyte composition that includes a salt disposed in a matrix in which the salt has a formula selected from the group consisting of ##STR1## in which X.sup.- is --O.sup.-, --N.sup.- SO.sub.2 R.sub.f.sup.3, or ##STR2## Z is --CF.sub.2 --, --O--, --NR.sub.f.sup.8 --, or --SF.sub.4 --; R.sub.f.sup.1 and R.sub.f.sup.2, independently, are --CF.sub.3, --C.sub.m F.sub.2m+1, or --(CF.sub.2).sub.q --SO.sub.2 --X.sup.- M.sup.+ ; R.sub.f.sup.3, R.sub.f.sup.4, and R.sub.f.sup.5, independently, are --CF.sub.3, --C.sub.mf.sub.2m+1, --(CF.sub.2).sub.q --X.sup.- M.sup.+, ##STR3## R.sub.f.sup.8 is --CF.sub.3, --C.sub.m F.sub.2m+1, or --(CF.sub.2).sub.q --SO.sub.2 --X.sup.- M.sup.+ ; R.sub.f.sup.6 and R.sub.f.sup.7, independently, are perfluoroalkylene moieties having the formula --C.sub.r F.sub.2r ; n is 1-4; r is 1-4; m is 1-12; q is 1-4; and M.sup.+ is a counterion.
摘要翻译：一种电解质组合物，其包括设置在基质中的盐，其中所述盐具有选自由下列组成的组的式：-CF 2 - ， - O - ， - NR f 8 - 或-SF 4 - ; Rf1和Rf2独立地是-CF3，-CmF2m + 1或 - （CF2）q-SO2-X-M +; Rf3，Rf4和Rf5独立地是-CF3，-Cmf2m + 1， - （CF2）qX-M +，图像Rf8是-CF3，-CmF2m + 1或 - （CF2）q-SO2 -X-M +; Rf6和Rf7独立地是具有式-CrF 2r的全氟亚烷基部分; n为1-4; r为1-4; m为1-12; q为1-4; 而M +是一个反离子。

33. 发明授权

US08137828B2 Durable fuel cell membrane electrode assembly with combined additives 有权
标题翻译：耐用的燃料电池膜电极组件与组合添加剂
公开(公告)号：US08137828B2
公开(公告)日：2012-03-20
申请号：US12342370
申请日：2008-12-23
申请人： Daniel M. Pierpont , Steven J. Hamrock , Matthew H. Frey
发明人： Daniel M. Pierpont , Steven J. Hamrock , Matthew H. Frey
IPC分类号： H01M8/10
CPC分类号： H01M8/1004 , H01M4/9016 , H01M8/1025 , H01M8/1039 , H01M8/1046 , H01M8/1051 , H01M2008/1095 , H01M2300/0082 , H01M2300/0091 , Y02E60/521
摘要： A fuel cell membrane electrode assembly is provided comprising a polymer electrolyte membrane comprising a first polymer electrolyte and at least one manganese compound; and one or more electrode layers comprising a catalyst and at least one cerium compound. The membrane electrode assembly demonstrates an unexpected combination of durability and performance.
摘要翻译：提供一种燃料电池膜电极组件，其包括包含第一聚合物电解质和至少一种锰化合物的聚合物电解质膜; 以及包含催化剂和至少一种铈化合物的一个或多个电极层。膜电极组件表现出耐久性和性能的意想不到的组合。

34. 发明授权

US08110320B2 Method of making durable polymer electrolyte membranes 有权
标题翻译：制造耐用聚合物电解质膜的方法
公开(公告)号：US08110320B2
公开(公告)日：2012-02-07
申请号：US11962971
申请日：2007-12-21
申请人： Steven J. Hamrock
发明人： Steven J. Hamrock
IPC分类号： H01M8/10 , B05D1/02 , B05D1/16
CPC分类号： H01M8/1004 , H01M8/1048 , H01M8/1088 , H01M2300/0082 , H01M2300/0094 , Y02P70/56
摘要： A method of making a durable fuel cell polymer electrolyte membrane is provided comprising the steps of: a) providing a polymer electrolyte membrane; b) providing a solution of a salt selected from the group consisting of manganese salts and cerium salts or a suspension of particles of a compound selected from the group consisting of manganese oxides and cerium oxides; and c) applying the solution or suspension to the polymer electrolyte membrane by a method selected from the group consisting of brushing, spraying and use of a slot die. Some embodiments comprise metered application of the solution to the polymer electrolyte membrane.
摘要翻译：提供一种制造耐久性燃料电池聚合物电解质膜的方法，包括以下步骤：a）提供聚合物电解质膜; b）提供选自锰盐和铈盐的盐或者选自氧化锰和氧化铈的化合物的颗粒的悬浮液; 和c）通过选自刷涂，喷涂和使用槽模的组中的方法将溶液或悬浮液施加到聚合物电解质膜上。一些实施方案包括将溶液计量施加到聚合物电解质膜。

35. 发明授权

US07179847B2 Polymer electrolytes crosslinked by e-beam 有权
标题翻译：通过电子束交联的聚合物电解质
公开(公告)号：US07179847B2
公开(公告)日：2007-02-20
申请号：US10712361
申请日：2003-11-13
申请人： Michael A. Yandrasits , Steven J. Hamrock , Naiyong Jing
发明人： Michael A. Yandrasits , Steven J. Hamrock , Naiyong Jing
IPC分类号： C08F2/46
CPC分类号： C08J5/2293 , C08J2327/18 , H01M8/1004 , H01M8/1023 , H01M8/1039 , H01M8/1072 , Y02P70/56
摘要： A method of making a crosslinked polymer is provided as well as the polymer so made, the method comprising the steps of: providing a highly fluorinated fluoropolymer, typically a perfluorinated fluoropolymer, comprising pendent groups which include a group according to the formula —SO2X, where X is F, Cl, Br, OH, or —O−M+, where M+ is a monovalent cation, and exposing said fluoropolymer to electron beam radiation so as to result in the formation of crosslinks. Typically, the method according to the present invention additionally comprises the step of: forming said fluoropolymer into a membrane, typically having a thickness of 90 microns or less, more typically 60 microns or less, and most typically 30 microns or less.
摘要翻译：提供制备交联聚合物的方法以及如此制备的聚合物，该方法包括以下步骤：提供高度氟化的含氟聚合物，通常为全氟化含氟聚合物，其包含侧基，其包括根据式-SO _{2 X，其中X是F，Cl，Br，OH或-O - ，其中M + 是单价阳离子，并将所述含氟聚合物暴露于电子束辐射，从而导致交联的形成。通常，根据本发明的方法另外包括以下步骤：将所述含氟聚合物形成膜，通常具有90微米或更小，更典型地为60微米或更小，最通常为30微米或更小的厚度。}

36. 发明授权

US07074841B2 Polymer electrolyte membranes crosslinked by nitrile trimerization 失效
标题翻译：通过腈三聚交联的聚合物电解质膜
公开(公告)号：US07074841B2
公开(公告)日：2006-07-11
申请号：US10712589
申请日：2003-11-13
申请人： Michael A. Yandrasits , Steven J. Hamrock , Werner M. Grootaert , Miguel A. Guerra , Naiyong Jing
发明人： Michael A. Yandrasits , Steven J. Hamrock , Werner M. Grootaert , Miguel A. Guerra , Naiyong Jing
IPC分类号： C08J3/28 , C08J3/00 , C08J5/22 , C08J5/20
CPC分类号： C08J5/225 , C08J2327/12
摘要： A method is provided for making a crosslinked polymer electrolyte, typically in the form of a membrane for use as a polymer electrolyte membrane in an electrolytic cell such as a fuel cell, by trimerization of nitrile groups contained on groups pendant from the polymer. The resulting polymer electrolyte membrane comprises a highly fluorinated polymer comprising: a perfluorinated backbone, first pendent groups which comprise sulfonic acid groups, and crosslinks comprising trivalent groups according to the formula: The first pendent groups are typically according to the formula: —R1—SO3H, where R1 is a branched or unbranched perfluoroalkyl or perfluoroether group comprising 1–15 carbon atoms and 0–4 oxygen atoms, most typically —O—CF2—CF2—CF2—CF2—SO3H or —O—CF2—CF(CF3)—O—CF2—CF2—SO3H.
摘要翻译：提供了一种制备交联聚合物电解质的方法，通常是通过聚合物悬浮在基团上的腈基的三聚作用，在电解池如燃料电池中用作聚合物电解质膜的膜形式。所得聚合物电解质膜包括高度氟化的聚合物，其包含：全氟化骨架，包含磺酸基团的第一侧基和包含根据下式的三价基团的交联：第一侧基通常根据下式：-R

37. 发明授权

US07071271B2 Aqueous emulsion polymerization of functionalized fluoromonomers 有权
标题翻译：官能化含氟单体的水乳液聚合
公开(公告)号：US07071271B2
公开(公告)日：2006-07-04
申请号：US10697768
申请日：2003-10-30
申请人： Arne Thaler , Klaus Hintzer , Kai H. Lochhaas , Franz Maerz , Steven J. Hamrock
发明人： Arne Thaler , Klaus Hintzer , Kai H. Lochhaas , Franz Maerz , Steven J. Hamrock
IPC分类号： C08F114/18
CPC分类号： C08F214/18 , C08F214/184
摘要： A method is provided for aqueous emulsion co-polymerization of two or more fluoromonomers comprising the steps of: 1) forming an aqueous pre-emulsion by mixing a fluoromonomer according to formula I: F2C═CF—R1—SO2X (I) wherein R1 is a branched or unbranched perfluoroalkyl, perfluoroalkoxy or perfluoroether group comprising 1–15 carbon atoms and 0–4 oxygen atoms and wherein X is F, Cl or Br, together with 0.001–0.9 molar equivalents of a base, in the absence of added emulsifier; and 2) reacting the pre-emulsion with one or more perfluorinated comonomers in the absence of added emulsifier so as to form a fluoropolymer latex comprising a fluoropolymer wherein more than 1 mol % of monomer units are derived from the fluoromonomer according to formula I. In another aspect, the present invention provides a fluoropolymer derived from the fluoropolymer latex made according to the method of the present invention which is free of added emulsifier. In another aspect, the present invention provides a polymer electrolyte membrane comprising the fluoropolymer made according to the method of the present invention which is free of added emulsifier.
摘要翻译：提供了一种用于两种或更多种含氟单体的水乳液共聚的方法，包括以下步骤：1）通过混合式I的含氟单体形成水性预乳液：<？in-line-formula description =“In-line 公式“end =”lead“？> F 2 C-CF-R 1 -SO 2 X（I）<βin-line -formulae description =“In-line Formulas”end =“tail”？>其中R 1是支链或非支链全氟烷基，包含1-15个碳原子和0-4个氧原子的全氟烷氧基或全氟醚基团在不加入乳化剂的情况下，X是F，Cl或Br，以及0.001-0.9摩尔当量的碱; 和2）在不存在加入的乳化剂的情况下使预乳液与一种或多种全氟化共聚单体反应，以便形成含氟聚合物的含氟聚合物胶乳，其中大于1mol％的单体单元衍生自根据式I的含氟单体。另一方面，本发明提供了衍生自根据本发明的方法制备的含氟聚合物胶乳的氟聚合物，其不含添加的乳化剂。另一方面，本发明提供了一种聚合物电解质膜，其包含根据本发明的方法制备的含氟聚合物，其不含添加的乳化剂。

38. 发明授权

US07060756B2 Polymer electrolyte with aromatic sulfone crosslinking 失效
标题翻译：聚合物电解质与芳香砜交联
公开(公告)号：US07060756B2
公开(公告)日：2006-06-13
申请号：US10720906
申请日：2003-11-24
申请人： Naiyong Jing , Michael A. Yandrasits , Steven J. Hamrock
发明人： Naiyong Jing , Michael A. Yandrasits , Steven J. Hamrock
IPC分类号： C08G75/00 , C08F136/00 , C08F114/00 , C08F114/06 , C08F283/00
CPC分类号： B01D67/0093 , B01D69/141 , B01D71/32 , B01D2323/30 , C08F214/18 , C08F214/26 , C08J5/2237 , C08J2327/18 , H01M8/1023 , H01M8/1039 , H01M8/106 , H01M8/1081 , H01M8/1088 , Y02P70/56
摘要： A method is provided for obtaining crosslinked polymers having pendent sulfonic acid groups by crosslinking through the sulfonic acid groups or their precursors with aromatic crosslinkers or aromatic pendent crosslinking groups to form aromatic sulfones. Such crosslinked polymers may be used to make polymer electrolyte membranes (PEM's) that may be used in electrolytic cells such as fuel cells.
摘要翻译：提供了一种通过使用芳族交联剂或芳族侧链交联基团通过磺酸基团或其前体进行交联以形成芳族砜来获得具有侧链磺酸基团的交联聚合物的方法。这种交联聚合物可用于制备可用于诸如燃料电池的电解池中的聚合物电解质膜（PEM's）。

39. 发明授权

US07060738B2 Polymer electrolytes crosslinked by ultraviolet radiation 失效
标题翻译：通过紫外线辐射交联的聚合物电解质
公开(公告)号：US07060738B2
公开(公告)日：2006-06-13
申请号：US10733211
申请日：2003-12-11
申请人： Naiyong Jing , Steven J. Hamrock , Michael A. Yandrasits
发明人： Naiyong Jing , Steven J. Hamrock , Michael A. Yandrasits
IPC分类号： C08F2/46
CPC分类号： C08J3/28 , C08F14/18 , C08J5/225 , C08J2327/12
摘要： A method is provided for making a crosslinked polymer electrolyte, typically in the form of a membrane for use as a polymer electrolyte membrane in an electrolytic cell such as a fuel cell, as well as the polymer so made, the method comprising application of ultraviolet radiation to a highly fluorinated fluoropolymer comprising: a backbone derived in part from tetrafluoro-ethylene monomer, first pendent groups which include a group according to the formula —SO2X, where X is F, Cl, Br, OH or —O−M+, where M+ is a monovalent cation, and second pendent groups which include Br, Cl or I. Typically, the membrane has a thickness of 90 microns or less, more typically 60 or less, and most typically 30 microns or less.
摘要翻译：提供了一种制造交联聚合物电解质的方法，该电解质通常是在诸如燃料电池的电解槽中用作聚合物电解质膜的膜形式，以及如此制备的聚合物，该方法包括施加紫外线辐射涉及一种高度氟化的含氟聚合物，其包含：部分由四氟乙烯单体衍生的主链，第一侧基，其包括根据式-SO 2 X的基团，其中X为F，Cl，Br， OH或-O - ，其中M + +是一价阳离子，第二侧基包括Br，Cl或I.通常，膜的厚度为90微米或更小，更通常为60或更小，最通常为30微米或更小。

40. 发明授权

US06833412B2 Acid functional fluoropolymer membranes and method of manufacture 有权
标题翻译：酸官能含氟聚合物膜及其制造方法
公开(公告)号：US06833412B2
公开(公告)日：2004-12-21
申请号：US10195221
申请日：2002-07-15
申请人： Steven J. Hamrock , Naiyong Jing , Shane S. Mao , L. Charles Hardy
发明人： Steven J. Hamrock , Naiyong Jing , Shane S. Mao , L. Charles Hardy
IPC分类号： C08F834
CPC分类号： C08L27/22 , C08F8/26 , C08J5/225 , C08L27/16 , C08L2205/02 , H01M8/1023 , H01M8/1039 , H01M8/1072 , Y02P70/56 , C08F14/18 , C08L2666/04
摘要： Methods are provided to make acid functional fluoropolymers by: a) dehydrofluorinating a starting fluoropolymer with a dehydrofluorinating agent to form an unsaturated fluoropolymer; b) adding an acidifiable nucleophilic functionalizing agent to a double bond of the unsaturated fluoropolymer; and c) acidifying the added acidifiable function. Acid functional fluoropolymers and ion conducting membranes thereof are also provided, including acid functional fluoropolymer having pendent groups according to the formula: —X—Ar—An, wherein X is selected from O, S or NR, where R is selected from H and C1-C30 alkyl or aryl, which are optionally substituted, wherein Ar is a C6-C30 aromatic group, which is optionally substituted, wherein A is an acidic function or salt thereof, wherein a can be independently chosen to be 1, 2 or 3.
摘要翻译：提供通过以下方式制备酸官能含氟聚合物的方法：a）用脱氟化氢剂使起始含氟聚合物脱氟化氢以形成不饱和含氟聚合物; b）将可酸化的亲核官能化剂加入到不饱和含氟聚合物的双键中; 和c）酸化所添加的酸化功能。还提供了酸官能含氟聚合物及其离子传导膜，包括具有根据下式的侧基的酸官能含氟聚合物：-X-Ar-An，其中X选自O，S或NR，其中R选自H和C1 -C30烷基或芳基，其任选被取代，其中Ar是任选取代的C 6 -C 30芳族基团，其中A是酸性官能团或其盐，其中A可以独立地选择为1,2或3。

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式