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    • 9. 发明授权
    • Sulfonated perfluorocyclobutane ion-conducting membranes
    • 磺化全氟环丁烷离子导电膜
    • US06559237B1
    • 2003-05-06
    • US09587522
    • 2000-06-05
    • Shane S. MaoKrzysztof A. LewinskiDavid A. Ylitalo
    • Shane S. MaoKrzysztof A. LewinskiDavid A. Ylitalo
    • C08F838
    • C08F8/36C08F2800/20C08J5/18C08F116/14C08F216/1408C08F216/125
    • Disclosed are sulfonated aromatic perfluorocyclobutane polymers meeting a condition selected from: a) the equivalent weight of the polymer is 5000 or less, and b) the proton conductivity of the polymer at 25° C. is 0.01 Siemens per centimeter (S/cm) or higher, and methods of making same, especially sulfonated aromatic perfluorocyclobutane polymers which comprise units according to the formula: wherein —B— is 1,2-perfluorocyclobutylene (C4F6); each —X— is independently selected from the group consisting of: a bond, —O—, —S—, —SO—, —SO2—, —CO—, —NH—, —NR1—, and —R2—, wherein R1 is C1-C25 substituted or unsubstituted, saturated or unsaturated alkyl or aryl and R2 is C1-C25 substituted or unsubstituted, saturated or unsaturated alkylene or arylene; —Ar— is a substituted or unsubstituted C1-C30 at least divalent aromatic hydrocarbon group; n is a non-negative integer chosen independently for each of said repeating units such that the average for the polymer is greater than 0. They are particularly useful in ion conducting membranes for use in electrochemical cells.
    • 公开了满足以下条件的磺化芳族全氟环丁烷聚合物:a)聚合物的当量为5000或更小,以及b)聚合物在25℃下的质子传导率为0.01西门子/厘米(S / cm)或 特别是含有下式的单元的磺化芳族全氟环丁烷聚合物:其中-B-是1,2-全氟环丁烯(C 4 F 6); 每个-X-独立地选自:-O - , - S - , - SO - , - SO 2 - , - CO - , - NH - , - NR 1 - 和-R 2 - ,其中 R1是C1-C25取代或未取代的饱和或不饱和的烷基或芳基,R2是C1-C25取代或未取代的饱和或不饱和的亚烷基或亚芳基; -Ar-是取代或未取代的C1-C30至少二价芳族烃基; n是对于每个所述重复单元独立地选择的非负整数,使得聚合物的平均值大于0.它们在用于电化学电池的离子导电膜中特别有用。