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    • 22. 发明授权
    • Process for preparing ceramic-metal composite bodies
    • 制备陶瓷 - 金属复合体的方法
    • US5214011A
    • 1993-05-25
    • US752824
    • 1991-08-30
    • Michael C. Breslin
    • Michael C. Breslin
    • C04B35/65
    • C04B35/652
    • A process is presented for the fabrication of a metal/ceramic composite by a non-vapor phase oxidation of a molten metal by contacting said molten metal at an elevated temperature with a sacrificial ceramic preform. The shape of the preform is retained but the ceramic preform is reduced, oxidizing the molten metal. A preferred sacrificial ceramic preform is silica, but can also be, for example, mullite, titania or zirconia, and the preferred molten metal is aluminum or an aluminum alloy. Thus, for example, is produced from immersing a silica preform into molten aluminum alloy, an Al/Al.sub.2 O.sub.3 composite metal/ceramic article which does not contain silica or silicon and which is extremely tough.
    • 提出了一种通过熔融金属非气相氧化制造金属/陶瓷复合材料的方法,该方法是通过使熔融金属在升高的温度下与牺牲陶瓷预制件接触。 保留预成型体的形状,但是陶瓷预制件被还原,氧化熔融金属。 优选的牺牲陶瓷预制件是二氧化硅,但也可以是例如莫来石,二氧化钛或氧化锆,优选的熔融金属是铝或铝合金。 因此,例如,通过将二氧化硅预制体浸入熔融铝合金中制造,Al / Al 2 O 3复合金属/陶瓷制品,其不含二氧化硅或硅并且非常坚韧。
    • 26. 发明授权
    • Ceramic materials
    • 陶瓷材料
    • US5118647A
    • 1992-06-02
    • US631229
    • 1990-12-21
    • Marc S. NewkirkSteven F. Dizio
    • Marc S. NewkirkSteven F. Dizio
    • C04B35/10C04B35/65C22C29/12
    • C04B35/10C04B35/652C22C29/12
    • Novel self-supporting ceramic structures are produced by the oxidation reaction of a molten metal precursor with a vapor-phase oxidant to form an oxidation reaction product. Molten metal is drawn through the oxidation reaction product towards the oxidant to cause continued growth of the product at the interface between oxidant and previously formed product. This reaction or growth is continued to form a thick, self-supporting ceramic body. The resulting ceramic material of the polycrystalline growth product consists essentially of an oxidation reaction product and, optionally, one or more non-oxidized constituents of the metal precursor.
    • 通过熔融金属前体与气相氧化剂的氧化反应生成新的自支撑陶瓷结构体以形成氧化反应产物。 熔融金属通过氧化反应产物被吸入氧化剂,以使产物在氧化剂和先前形成的产物之间的界面处持续生长。 该反应或生长继续形成厚的自支撑陶瓷体。 所得到的多晶生长产物的陶瓷材料基本上由金属前体的氧化反应产物和任选的一种或多种非氧化成分构成。
    • 29. 发明授权
    • Inverse shape replication method of making ceramic composite articles
and articles obtained thereby
    • 制造陶瓷复合制品的反型复制方法及由此得到的制品
    • US5051382A
    • 1991-09-24
    • US329794
    • 1989-03-28
    • Marc S. NewkirkAndrew W. UrquhartH. Daniel Lesher
    • Marc S. NewkirkAndrew W. UrquhartH. Daniel Lesher
    • C04B35/622C04B35/117C04B35/65
    • C04B35/117C04B35/652C04B2235/3217C04B2235/3418C04B2235/3826C04B2235/401C04B2235/402C04B2235/428C04B2235/6028C04B2235/80Y10T428/249987
    • A method of producing a self-supporting ceramic composite body having therein at least one cavity which inversely replicates the geometry of a positive mold of parent metal. The method includes embedding the mold of parent metal within a conformable bed of filler to provide therein a cavity shaped and filled by the mold. The assembly is heated to melt the parent metal mold, e.g., an aluminum parent metal mold, and contacted with an oxidant to oxidize the molten parent metal to form a polycrystalline material which grows through the surrounding bed of filler, the molten metal being drawn through the growing polycrystalline material to be oxidized at the interface between the oxidant and previously formed oxidation reaction product whereby the cavity formerly filled by the mold of parent metal is eventually evacuated of the metal. There remains behind a cavity whose shape inversely replicates the original shape of the mold. The method provides ceramic composite articles having therein at least one cavity inversely replicating the shape of the mold which supplied the parent metal for oxidation.
    • 一种自支撑陶瓷复合体的制造方法,其中具有至少一个反向复制母体金属正模的几何形状的空腔。 该方法包括将母体金属模具嵌入到适形的填料床中,以在其中提供由模具成型并填充的空腔。 将组件加热以熔化母体金属模具,例如铝母体金属模具,并与氧化剂接触以氧化熔融母体金属,以形成通过周围的填料层生长的多晶材料,熔融金属被吸入 在氧化剂和预先形成的氧化反应产物之间的界面处被氧化的生长中的多晶材料,由此母体金属的模具以前被填充的空腔最终被排出金属。 在其后面仍然存在一个模腔,其形状相反地复制了模具的原始形状。 该方法提供了在其中具有至少一个空腔的陶瓷复合制品,其反向复制了供给母体金属进行氧化的模具的形状。
    • 30. 发明授权
    • Assembly for making ceramic composite structures and method of using the
same
    • 陶瓷复合结构的组装及其使用方法
    • US5047269A
    • 1991-09-10
    • US298647
    • 1989-01-18
    • Marc S. NewkirkH. Daniel Lesher
    • Marc S. NewkirkH. Daniel Lesher
    • B22F3/12C04B35/65
    • C04B35/652B22F3/1208Y10T428/131Y10T428/24744Y10T428/24926
    • An assembly for the preparation of ceramic composite structures includes a segmented container within which a permeable filler is retained and a parent metal body is contacted with the bed of permeable filler. The segmented container is comprised of one or more segments made of a material, such as an inconnel alloy, which has a coefficient of thermal expansion which is significantly greater than that of the filler. The segments are arranged to defined between or among them one or more expansion joints which are effective to accommodate circumferential thermal expansion of the segments to thereby inhibit or prevent volumetric expansion of the container. A method of forming ceramic composite structures includes heating the resulting assembly in the presence of an oxidant to melt and oxidize the parent metal, e.g., aluminum, to form a polycrystalline material comprising an oxidation reaction product which grows through the mass of filler to embed it and thus form the composite structure.
    • 用于制备陶瓷复合结构的组件包括分段容器,在其中保持可渗透填料并使母体金属体与可渗透填料床接触。 分段容器由一个或多个由诸如非合金合金的材料制成的段组成,其具有明显大于填料的热膨胀系数。 这些段被布置成在它们之间或之间限定一个或多个膨胀接头,其有效地适应段的周向热膨胀,从而抑制或防止容器的体积膨胀。 形成陶瓷复合结构的方法包括在存在氧化剂的情况下加热所得的组合物以熔化和氧化母体金属(例如铝),以形成多晶材料,该多晶材料包含通过填料填充物生长的氧化反应产物 从而形成复合结构。