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    • 1. 发明授权
    • Composite ceramic articles
    • 复合陶瓷制品
    • US5187130A
    • 1993-02-16
    • US659473
    • 1991-02-25
    • Marc S. NewkirkAndrew W. UrquhartHarry R. ZwickerH. Daniel Lesher
    • Marc S. NewkirkAndrew W. UrquhartHarry R. ZwickerH. Daniel Lesher
    • C04B35/65C04B35/76C04B35/80C04B41/50C04B41/87
    • C04B41/87C04B35/652C04B35/76C04B35/80C04B41/5025
    • Self supporting ceramic composite structures having filler embedded therein produced by a method which includes infiltrating a permeable mass of filler with polycrystalline material comprising an oxidation reaction product obtained by oxidation of a parent metal such as aluminum and optionally containing therein non-oxidized constituents of the parent metal. The structure is formed by placing a parent metal adjacent to a permeable filler and heating the assembly to melt the parent metal and provide a molten body of parent metal which is contacted with a suitable vapor-phase oxidant. Within a certain temperature region and optionally aided by one or more dopants in or on the parent metal, molten parent metal will migrate through previously formed oxidation reaction product into contact with the oxidant, causing the oxidation reaction product to grow so as to embed the adjacent filler and provide the composite structure.
    • 具有嵌入其中的填料的自支撑陶瓷复合结构体通过包括通过氧化母体金属如铝并且任选地含有母体的非氧化成分而获得的氧化反应产物的多晶材料渗透渗透性的方法制备的填料 金属。 通过将母体金属放置在可渗透填料附近并加热该组件以熔化母体金属并提供与合适的气相氧化剂接触的母体金属的熔融体来形成结构。 在一定温度范围内,并且任选地由母体金属中或母体金属上的一种或多种掺杂剂辅助,熔融母体金属将迁移通过预先形成的氧化反应产物与氧化剂接触,导致氧化反应产物生长以便嵌入相邻 填料并提供复合结构。
    • 3. 发明授权
    • Inverse shape replication method of making ceramic composite articles
and articles obtained thereby
    • 制造陶瓷复合制品的反型复制方法及由此得到的制品
    • US5275987A
    • 1994-01-04
    • US983191
    • 1992-11-30
    • Marc S. NewkirkAndrew W. UrquhartH. Daniel Lesher
    • Marc S. NewkirkAndrew W. UrquhartH. Daniel Lesher
    • C04B35/622C04B35/117C04B35/65C04B35/10
    • C04B35/117C04B35/652C04B2235/3217C04B2235/3418C04B2235/3826C04B2235/401C04B2235/402C04B2235/428C04B2235/6028C04B2235/80Y10T428/249987
    • A method of producing a self-supporting ceramic composite body having therein at least one cavity which inversely replicates the geometry of a positive mold of parent metal. The method includes embedding the mold of parent metal within a conformable bed of filler to provide therein a cavity shaped and filled by the mold. The assembly is heated to melt the parent metal mold, e.g., an aluminum parent metal mold, and contacted with an oxidant to oxidize the molten parent metal to form a polycrystalline material which grows through the surrounding bed of filler, the molten metal being drawn through the growing polycrystalline material to be oxidized at the interface between the oxidant and previously formed oxidation reaction product whereby the cavity formerly filled by the mold of parent metal is eventually evacuated of the metal. There remains behind a cavity whose shape inversely replicates the original shape of the mold. The method provides ceramic composite articles having therein at least one cavity inversely replicating the shape of the mold which supplied the parent metal for oxidation.
    • 一种自支撑陶瓷复合体的制造方法,其中具有至少一个反向复制母体金属正模的几何形状的空腔。 该方法包括将母体金属模具嵌入到适形的填料床中,以在其中提供由模具成型并填充的空腔。 将组件加热以熔化母体金属模具,例如铝母体金属模具,并与氧化剂接触以氧化熔融母体金属,以形成通过周围的填料床生长的多晶材料,熔融金属被吸入 在氧化剂和预先形成的氧化反应产物之间的界面处被氧化的生长中的多晶材料,由此母体金属的模具以前被填充的空腔最终被排出金属。 在其后面仍然存在一个模腔,其形状相反地复制了模具的原始形状。 该方法提供了陶瓷复合材料制品,其中具有至少一个空腔,其相反地复制了供应母体金属进行氧化的模具的形状。
    • 5. 发明授权
    • Inverse shape replication method of making ceramic composite articles
    • 制造陶瓷复合制品的逆形复制方法
    • US4828785A
    • 1989-05-09
    • US823542
    • 1986-01-27
    • Marc S. NewkirkAndrew W. UrquhartH. Daniel Lesher
    • Marc S. NewkirkAndrew W. UrquhartH. Daniel Lesher
    • C04B35/622C04B35/117C04B35/65
    • C04B35/117C04B35/652C04B2235/3217C04B2235/3418C04B2235/3826C04B2235/401C04B2235/402C04B2235/428C04B2235/6028C04B2235/80Y10T428/249987
    • A method of producing a self-supporting ceramic composite body having therein at least one cavity which inversely replicates the geometry of a positive mold of parent metal. The method, includes embedding the mold of parent metal within a conformable bed of filler to provide there in a cavity shaped and filled by the mold. The assembly is heated to melt the parent metal mold, e.g., an aluminum parent metal mold, and contacted with an oxidant to oxidize the molten parent metal to form a polycrystalline material which grows through the surrounding bed of filler, the molten metal being drawn through the growing polycrystalline material to be oxidized at the interface between the oxidant and previously formed oxidation reaction product whereby the cavity formerly filled by the mold of parent metal is eventually evacuated of the metal. There remains behind a cavity whose shape inversely replicates the original shape of the mold. The method provides ceramic composite articles having therein at least one cavity inversely replicating the shape of the mold which supplied the parent metal for oxidation.
    • 一种自支撑陶瓷复合体的制造方法,其中具有至少一个反向复制母体金属正模的几何形状的空腔。 该方法包括将母体金属模具嵌入适形的填料床中,以在模具中形成并填充的空腔中。 将组件加热以熔化母体金属模具,例如铝母体金属模具,并与氧化剂接触以氧化熔融母体金属,以形成通过周围的填料床生长的多晶材料,熔融金属被吸入 在氧化剂和预先形成的氧化反应产物之间的界面处被氧化的生长中的多晶材料,由此母体金属的模具以前被填充的空腔最终被排出金属。 在其后面仍然存在一个模腔,其形状相反地复制了模具的原始形状。 该方法提供了在其中具有至少一个空腔的陶瓷复合制品,其反向复制了供给母体金属进行氧化的模具的形状。
    • 6. 发明授权
    • Reservoir feed method of making ceramic composite structures and
structures made thereby
    • 由此制作陶瓷复合结构和结构的储层进料方法
    • US4996176A
    • 1991-02-26
    • US414195
    • 1989-09-28
    • Marc S. NewkirkH. Daniel LesherRatnesh K. DwivediRobert C. Kantner
    • Marc S. NewkirkH. Daniel LesherRatnesh K. DwivediRobert C. Kantner
    • B28B7/34C04B35/65
    • B28B7/344B28B7/342C04B35/652
    • A method for producing a self-supporting ceramic composite structure which includes a ceramic matrix embedding a filler, includes oxidizing a parent metal to form a polycrystalline material comprising the oxidation reaction product of the parent metal with an oxidant and, optionally, one or more metallic constituents, and the filler embedded by the matrix. The method includes heating a first source of molten parent metal and a source of molten parent metal and contacting the first source of molten parent metal with a permeable bedding of filler. The first source of molten parent metal is reacted with the oxidant to form the oxidation reaction product and is replenished from the reservoir as the reacting continues for a time sufficient to grow the oxidation reaction product to a desired extent and thereby embed at least a portion of the bedding of filler within the oxidation reaction product to form the ceramic composite structure. The bedding of filler may have any suitable shape, including that of a hollow body, the interior of which is contacted by the first source of molten parent metal to grow the oxidation reaction product through the shaped, hollow body of filler.
    • 一种包括填充填料的陶瓷基体的自支撑陶瓷复合结构体的制造方法,包括使母体金属氧化以形成多晶材料,所述多晶材料包含母体金属与氧化剂的氧化反应产物和任选的一种或多种金属 成分,以及由基质嵌入的填料。 该方法包括加热熔融母体金属的第一源和熔融母体金属源,并使熔融母体金属的第一源与填充物的可渗透层接触。 熔融母体金属的第一来源与氧化剂反应以形成氧化反应产物,并且随着反应继续进行足以将氧化反应产物生长至期望的程度并从而将至少一部分 氧化反应产物中填料的床垫形成陶瓷复合结构。 填料的床垫可以具有任何合适的形状,包括中空体的形状,其内部与熔融母体金属的第一源接触,以通过成型的中空填料体生长氧化反应产物。
    • 8. 发明授权
    • Ceramic composite structures having intrinsically fitted encasement
members thereon & methods of making the same
    • 具有本体安装的包装件的陶瓷复合结构及其制造方法
    • US4822759A
    • 1989-04-18
    • US212071
    • 1988-06-24
    • Marc S. NewkirkH. Daniel Lesher
    • Marc S. NewkirkH. Daniel Lesher
    • C04B35/65C04B37/02F41A21/02C04B35/58
    • C04B35/652F41A21/02Y10S264/25Y10S264/36
    • A method is provided of producing a self-supporting ceramic composite structure having one or more encasement members, such as an encasing steel sleeve, joined to it by growth of the ceramic material to engagement surface(s) of the encasement member(s). A parent metal is contacted with a body of filler which is encased by the encasement member(s). The resulting assembly is heated to melt and oxidize the parent metal, e.g., aluminum, to form a polycrystalline material comprising an oxidation reaction product which grows through the doby of filler and stops at the engagement surface(s) of the encasement member(s) which thereby determines the surface geometry of the grown ceramic matrix. Upon cooling, the encasement member(s) is shrink-fitted about the ceramic composite body. The invention also provides the resultant articles, for example, a ceramic composite body having a stainless steel member affixed thereto.
    • 提供了一种制造自支撑陶瓷复合结构的方法,该自支撑陶瓷复合结构具有一个或多个外壳构件,例如通过将陶瓷材料生长成包裹构件的接合表面而与其相连的外壳钢套筒。 母体金属与被封装构件封装的填料体接触。 将所得的组件加热熔化并氧化母体金属例如铝,以形成多晶材料,该多晶材料包含氧化反应产物,该氧化反应产物通过多个填料生长,并在包裹部件的接合表面处停止, 从而确定生长的陶瓷基体的表面几何形状。 在冷却时,包裹件在陶瓷复合体周围收缩。 本发明还提供了所得制品,例如具有固定在其上的不锈钢构件的陶瓷复合体。
    • 9. 发明授权
    • Inverse shape replication method of making ceramic composite articles
    • 制造陶瓷复合制品的逆形复制方法
    • US5494868A
    • 1996-02-27
    • US176058
    • 1994-01-03
    • Marc S. NewkirkAndrew W. UrquhartH. Daniel Lesher
    • Marc S. NewkirkAndrew W. UrquhartH. Daniel Lesher
    • C04B35/622C04B35/117C04B35/65
    • C04B35/117C04B35/652C04B2235/3217C04B2235/3418C04B2235/3826C04B2235/401C04B2235/402C04B2235/428C04B2235/6028C04B2235/80Y10T428/249987
    • A method of producing a self-supporting ceramic composite body having therein at least one cavity which inversely replicates the geometry of a positive mold of parent metal. The method includes embedding the mold of parent metal within a conformable bed of filler to provide therein a cavity shaped and filled by the mold. The assembly is heated to melt the parent metal mold, e.g., an aluminum parent metal mold, and contacted with an oxidant to oxidize the molten parent metal to form a polycrystalline material which grows through the surrounding bed of filler, the molten metal being drawn through the growing polycrystalline material to be oxidized at the interface between the oxidant and previously formed oxidation reaction product whereby the cavity formerly filled by the mold of parent metal is eventually evacuated of the metal. There remains behind a cavity whose shape inversely replicates the original shape of the mold. The method provides ceramic composite articles having therein at least one cavity inversely replicating the shape of the mold which supplied the parent metal for oxidation.
    • 一种自支撑陶瓷复合体的制造方法,其中具有至少一个反向复制母体金属正模的几何形状的空腔。 该方法包括将母体金属模具嵌入到适形的填料床中,以在其中提供由模具成型并填充的空腔。 将组件加热以熔化母体金属模具,例如铝母体金属模具,并与氧化剂接触以氧化熔融母体金属,以形成通过周围的填料床生长的多晶材料,熔融金属被吸入 在氧化剂和预先形成的氧化反应产物之间的界面处被氧化的生长中的多晶材料,由此母体金属的模具以前被填充的空腔最终被排出金属。 在其后面仍然存在一个模腔,其形状相反地复制了模具的原始形状。 该方法提供了在其中具有至少一个空腔的陶瓷复合制品,其反向复制了供给母体金属进行氧化的模具的形状。
    • 10. 发明授权
    • Ceramic composite articles obtained by inverse shape replication
    • 通过反形状复制获得的陶瓷复合制品
    • US5168081A
    • 1992-12-01
    • US763681
    • 1991-09-23
    • Marc S. NewkirkAndrew W. UrquhartH. Daniel Lesher
    • Marc S. NewkirkAndrew W. UrquhartH. Daniel Lesher
    • C04B35/65
    • C04B35/652
    • A method of producing a self-supporting ceramic composite body having therein at least one cavity which inversely replicates the geometry of a positive mold of parent metal. The method includes embedding the mold of parent metal within a conformable bed of filler to provide therein a cavity shaped and filled by the mold. The assembly is heated to melt the parent metal mold, e.g., an aluminum parent metal mold, and contacted with an oxidant to oxidize the molten parent metal to form a polycrystalline material which grows through the surrounding bed of filler, the molten metal being drawn through the growing polycrystalline material to be oxidized at the interface between the oxidant and previously formed oxidation reaction product whereby the cavity formerly filled by the mold of parent metal is eventually evacuated of the metal. There remains behind a cavity whose shape inversely replicates the original shape of the mold. The method provides ceramic composite articles having therein at least one cavity inversely replicating the shape of the mold which supplied the parent metal for oxidation.
    • 一种自支撑陶瓷复合体的制造方法,其中具有至少一个反向复制母体金属正模的几何形状的空腔。 该方法包括将母体金属模具嵌入到适形的填料床中,以在其中提供由模具成型并填充的空腔。 将组件加热以熔化母体金属模具,例如铝母体金属模具,并与氧化剂接触以氧化熔融母体金属,以形成通过周围的填料床生长的多晶材料,熔融金属被吸入 在氧化剂和预先形成的氧化反应产物之间的界面处被氧化的生长中的多晶材料,由此母体金属的模具以前被填充的空腔最终被排出金属。 在其后面仍然存在一个模腔,其形状相反地复制了模具的原始形状。 该方法提供了陶瓷复合材料制品,其中具有至少一个空腔,其相反地复制了供应母体金属进行氧化的模具的形状。