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    • 23. 发明授权
    • Composition containing a polymer or copolymer of a 3,4-dialkoxythiophene and non-aqueous solvent
    • 含有3,4-二烷氧基噻吩和非水溶剂的聚合物或共聚物的组合物
    • US07223357B2
    • 2007-05-29
    • US11180051
    • 2005-07-12
    • Jean-Pierre TahonRoger Van den BogaertBert GroenendaalFrank Louwet
    • Jean-Pierre TahonRoger Van den BogaertBert GroenendaalFrank Louwet
    • H01B1/12
    • H01B1/128C08J3/09C08J2365/00C08L65/00C09D5/24C09D11/033C09D11/36C09D11/52C09D165/00Y10T428/2809
    • A method for preparing a composition containing between 0.08 and 3.0% by weight of polymer or copolymer of a 3,4-dialkoxythiophene in which the two alkoxy groups may be the same or different or together represent an optionally substituted oxy-alkylene-oxy bridge, a polyanion and at least one non-aqueous solvent from a dispersion of the polymer or copolymer of (3,4-dialkoxythiophene) and the polyanion in water which is prepared in the substantial absence of oxygen, comprising in the following order the steps of: i) mixing at least one of the non-aqueous solvents with the aqueous dispersion of the polymer or copolymer of (3,4-dialkoxythiophene) and the polyanion; and ii) evaporating water from the mixture prepared in step i) until the content of water therein is reduced by at least 65% by weight; a printing ink, printing paste or coating composition, capable of yielding layers with enhanced conductivity at a given transparency, prepared according to the above-described method; a coating process with the coating composition thereby producing a layer with enhanced conductivity at a given transparency; and a printing process with the printing ink or paste thereby producing a layer with enhanced conductivity at a given transparency.
    • 一种制备含有0.08至3.0重量%的3,4-二烷氧基噻吩的聚合物或共聚物的组合物的方法,其中两个烷氧基可以相同或不同,或一起代表任选取代的氧 - 亚烷基 - 氧桥, 聚阴离子和至少一种非水溶剂,其由(3,4-二烷氧基噻吩)的聚合物或共聚物和聚阴离子在水中的分散体组成,其在基本上不存在氧的情况下制备,包括以下步骤: i)将至少一种非水溶剂与(3,4-二烷氧基噻吩)和聚阴离子的聚合物或共聚物的水分散体混合; 和ii)从步骤i)中制备的混合物蒸发水,直到其中的水含量降低至少65重量%; 印刷油墨,印刷浆料或涂料组合物,其能够产生根据上述方法制备的在给定透明度下具有增强的导电性的层; 所述涂料组合物由此在给定的透明度下产生具有增强的导电性的层; 以及具有印刷油墨或糊料的印刷方法,从而在给定的透明度下产生具有增强的导电性的层。
    • 24. 发明授权
    • Layer configuration with improved stability to sunlight exposure
    • 层状结构具有改善的阳光照射的稳定性
    • US07147936B2
    • 2006-12-12
    • US10642933
    • 2003-08-18
    • Frank LouwetGeert Van DyckJohan LoccufierBert GroenendaalHieronymus Andriessen
    • Frank LouwetGeert Van DyckJohan LoccufierBert GroenendaalHieronymus Andriessen
    • C07D211/021H01L51/50
    • C08G61/126C08L25/08C08L2666/06C09J165/00H01G11/48H01G11/56Y02E60/13Y10S428/917
    • A layer configuration on a support, the layer configuration comprising a layer containing a polymer containing optionally substituted 3,4-alkylenedioxythiophene structural units, in which the two alkoxy groups may be the same or different or together represent an optionally substituted oxy-alkylene-oxy bridge, and a compound selected from the group consisting of polyphosphoric acids, polyphosphoric acid salts, thia-alkanedicarboxylic acids, cyclohexadiene compounds and polyhydroxy-compounds selected from the group consisting of tetronic acid derivatives; ortho-dihydroxybenzene compounds with at least one sulpho group, compounds according to formula (I): HO—CH2—CH(OH)—(CH2)m—S—CH2—C(R1)(R2)—CH2—S—(CH2)n—CH(OH)—CH2—OH  (I) wherein R1 and R2 are independently H, —OH or alkyl, and n and m are independently 1, 2 or 3; compounds according to formula (II): HO—(CH2)p—S—CH2—S—(CH2)q—OH  (II) wherein p and q are independently 2, 3 or 4; compounds hydrolyzable to tetronic acid derivatives; compounds hydrolyzable to compounds according to formula (I); and sulpho-substituted 2-thia-alkyl-benzimidazole compounds.
    • 在支撑体上的层构型,该层构型包括含有含有任选取代的3,4-亚烷基二氧噻吩结构单元的聚合物的层,其中两个烷氧基可以相同或不同,或一起代表任选取代的氧基 - 桥,以及选自多磷酸,多磷酸盐,硫杂烷二羧酸,环己二烯化合物和选自由以下组成的组的多羟基化合物的化合物:四氢酸衍生物; 具有至少一个磺酸基的邻二羟基苯化合物,根据式(I)的化合物:<?in-line-formula description =“In-line formula”end =“lead”?> HO-CH 2 -CH(OH) - (CH 2 CH 2)m -S- CH 2 -C(R 1) (R 2) - CH 2 -S-(CH 2)n - (CH 2)n - (CH 2) -CH 2 -O-OH(I)<β在线公式描述=“在线式”末端=“尾”→其中R 1和R 2, SUP> 2独立地是H,-OH或烷基,n和m独立地是1,2或3; 根据式(II)的化合物:<?in-line-formula description =“In-line Formulas”end =“lead”?> HO-(CH 2) > -S-CH 2 -S-(CH 2)2 -O-OH(II)<β在线配方说明书=“ 其中p和q独立地为2,3或4; 可水解成四氢酸衍生物的化合物; 可水解成根据式(I)的化合物的化合物的化合物; 和磺基取代的2-硫代 - 烷基 - 苯并咪唑化合物。
    • 27. 发明申请
    • New 3,4-alkylenedioxy-thiophene copolymers
    • 新的3,4-亚烷基二氧基 - 噻吩共聚物
    • US20050009986A1
    • 2005-01-13
    • US10844551
    • 2004-05-12
    • Bert GroenendaalFrank Louwet
    • Bert GroenendaalFrank Louwet
    • C08G61/12C09D165/00C08F20/58
    • C08G61/126C09D165/00H01G11/48H01G11/56Y02E60/13
    • An aqueous dispersion of a copolymer of at least one 3,4-alkylenedioxythiophene compound with a solubility in water at 25° C. of less than 2.2 g/L with at least one 3,4-alkylenedioxythiophene compound with a solubility in water at 25° C. of at least 2.2 g/L and a polyanion; a preparation process therefor; its use for coating; a printing ink containing the aqueous dispersion; an electro-conductive layer containing a copolymer of at least one 3,4-alkylenedioxythiophene compound with a solubility in water at 25° C. of less than 2.2 g/L with at least one 3,4-alkylenedioxythiophene compound with a solubility in water at 25° C. of at least 2.2 g/L and a polyanion derived from an aqueous dispersion thereof; and an antistatic layer containing a copolymer of at least one 3,4-alkylenedioxy-thiophene compound with a solubility in water at 25° C. of less than 2.2 g/L with at least one 3,4-alkylenedioxythiophene compound with a solubility in water at 25° C. of at least 2.2 g/L and a polyanion derived from an aqueous dispersion thereof.
    • 至少一种3,4-二亚烷基二氧噻吩化合物在25℃下在水中的溶解度小于2.2g / L的共聚物的水分散体与至少一种在水中溶解度为25的3,4-亚烷基二氧噻吩化合物 至少2.2g / L的聚阴离子; 其准备过程; 其用于涂料; 含有水分散体的印刷油墨; 含有至少一种在25℃下在水中的溶解度低于2.2g / L的3,4-亚烷基二氧噻吩化合物与至少一种在水中溶解度的3,4-亚烷基二氧噻吩化合物的共聚物的导电层 在25℃下为至少2.2g / L,衍生自其水分散体的聚阴离子; 以及含有至少一种在25℃下在水中溶解度小于2.2g / L的3,4-亚烷基二氧基 - 噻吩化合物与至少一种具有溶解度的3,4-亚烷基二氧噻吩化合物的共聚物的抗静电层 25℃下的水至少为2.2g / L,衍生自其水分散体的聚阴离子。
    • 28. 发明授权
    • Redispersable latex comprising a polythiophene
    • 包含聚噻吩的可再分散胶乳
    • US06632472B2
    • 2003-10-14
    • US09892011
    • 2001-06-26
    • Frank LouwetRaf Samijn
    • Frank LouwetRaf Samijn
    • C09D1102
    • C09D11/52C08G61/126C09D11/106C09D165/00
    • A redispersible or soluble product, optionally having a solids content higher than 10% by weight, obtainable by freeze drying an aqueous dispersion of a latex comprising a polyanion and a polymer or copolymer of a substituted or unsubstituted thiophene; a printing ink comprising the above product; a coating dispersion or solution comprising the above product; and a method for making an antistatic or electroconductive layer comprising the steps of redispersing or diluting the above product by adding water or an organic solvent so as to obtain a dispersion or solution, optionally adding other ingredients to the coating solution or dispersion and applying the dispersion or solution to an object.
    • 通过将包含聚阴离子和取代或未取代的噻吩的聚合物或共聚物的胶乳的水分散体冷冻干燥,可再分散或可溶性产品,任选地具有高于10重量%的固体含量; 包含上述产品的印刷油墨; 包含上述产品的涂料分散体或溶液; 以及制造抗静电或导电层的方法,包括以下步骤:通过加入水或有机溶剂对上述产物进行再分散或稀释,以获得分散体或溶液,任选地向涂布溶液或分散体中加入其它成分并施加该分散体 或解决方案。