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21. 发明授权

US06913674B2 Process for fractionating water-containing crude amine mixtures from amine synthesis 有权
$Process for fractionating water-containing crude amine mixtures from amine synthesis$
标题翻译：从胺合成分馏含水粗胺混合物的方法
公开(公告)号：US06913674B2
公开(公告)日：2005-07-05
申请号：US10888839
申请日：2004-07-12
申请人： Andreas Wölfert , Heinz Rütter , Stefan Rittinger , Mark Wehinger , Aurelie Alemany , Willi Schmidt
发明人： Andreas Wölfert , Heinz Rütter , Stefan Rittinger , Mark Wehinger , Aurelie Alemany , Willi Schmidt
IPC分类号： C07D211/12 , C07C209/16 , C07C209/84 , C07C211/08 , C07D207/04 , C07D207/06 , C07D211/04 , C07D211/14 , C07D265/30 , C07D295/02 , C07D295/027 , C07D295/03 , B01D3/14
CPC分类号： C07D295/027 , C07D207/04 , C07D211/04 , C07D295/03 , Y10S203/20
摘要： A mixture containing one or more amines, water, low-boilers and high-boilers, is fractioned in a process wherein (i) low-boilers are separated from the mixture by distillation, (ii) high-boilers are separated from the mixture by distillation, (iii) the mixture is extracted with a sodium hydroxide solution to form an aqueous, sodium-hydroxide-containing first phase and an aqueous-organic, amine-containing second phase, and (iv) the aqueous-organic second phase is distilled to form an amine/water azeotrop and an essentially anhydrous amine, and the amine/water azeotrop is recycled to the extraction step (iii).
摘要翻译：含有一种或多种胺，水，低沸点锅炉和高锅炉的混合物在其中（i）通过蒸馏从混合物中分离低沸点的方法进行分馏，（ii）将高锅炉与混合物分离，通过蒸馏，（iii）混合物用氢氧化钠溶液萃取以形成含氢氧化钠的含水氢氧化物的第一相和含水有机胺的第二相，和（iv）蒸馏出含水有机相第二相以形成胺/水共沸物和基本上无水的胺，并将胺/水共沸物再循环至提取步骤（iii）。

22. 发明授权

US06821396B2 Process for fractionating water-containing crude amine mixtures from amine synthesis 失效
$Process for fractionating water-containing crude amine mixtures from amine synthesis$
标题翻译：从胺合成分馏含水粗胺混合物的方法
公开(公告)号：US06821396B2
公开(公告)日：2004-11-23
申请号：US10272012
申请日：2002-10-17
申请人： Andreas Wolfert , Heinz Rütter , Stefan Rittinger , Mark Wehinger , Aurelie Alemany , Willi Schmidt
发明人： Andreas Wolfert , Heinz Rütter , Stefan Rittinger , Mark Wehinger , Aurelie Alemany , Willi Schmidt
IPC分类号： B01D314
CPC分类号： C07D295/027 , C07D207/04 , C07D211/04 , C07D295/03 , Y10S203/20
摘要： A mixture containing mixture one or more amines, water, low-boilers and high-boilers, is fractioned in a process wherein (i) low-boilers are separated from the mixture by distillation, (ii) high-boilers are separated from the mixture by distillation, (iii) the mixture is extracted with a sodium hydroxide solution to form an aqueous, sodium-hydroxide-containing first phase and an aqueous-organic, amine-containing second phase, and (iv) the aqueous-organic second phase is distilled to form an amine/water azeotrope and an essentially anhydrous amine, and the amine/water azeotrope is recycled to the extraction step (iii).
摘要翻译：将混合物中含有一种或多种胺，水，低锅炉和高锅炉的混合物在一个方法中进行分馏，其中（i）通过蒸馏将低沸点物与混合物分离，（ii）从混合物中分离出高锅炉通过蒸馏，（iii）混合物用氢氧化钠溶液萃取以形成含氢氧化钠的第一相和含水有机胺的第二相，和（iv）含水有机相第二相为蒸馏以形成胺/水共沸物和基本上无水的胺，并将胺/水共沸物再循环至提取步骤（iii）。

23. 发明授权

US06198002B1 Preparation of secondary and tertiary 2-methyl-1, 5-pentanediamines 失效
标题翻译：二级和叔级2-甲基-1,5-戊二胺的制备
公开(公告)号：US06198002B1
公开(公告)日：2001-03-06
申请号：US09324715
申请日：1999-06-03
申请人： Karsten Eller , Bernd Fiege , Stefan Rittinger , Eberhard Fuchs
发明人： Karsten Eller , Bernd Fiege , Stefan Rittinger , Eberhard Fuchs
IPC分类号： C07C20948
CPC分类号： C07C211/09 , C07C209/48
摘要： A process for preparing a secondary or tertiary 2-methyl-1,5-pen-tanediamine of the formula I where R1 and R2 are H, C1-C20-alkyl, C3-C8-cycloalkyl, aryl, C7-C20-arylalkyl, where the radicals R1 and R2 may bear substituents selected from the group consisting of C1-C20-alkyl, C1-C20-alkoxy, C6-C20-aryloxy and hydroxy, and R1 and R2 are not simultaneously hydrogen, or R1 and R2 are together an unsubstituted or C1-C20-alkyl- and/or C1-C20-alkoxy-substituted C3-C7-alkylene chain which may, if desired, be interrupted by one or two O or NR3 groups, where R3 is H or C1-C20-alkyl comprises reacting 2-methylglutarodinitrile with a primary or secondary amine of the formula R1R2NH and hydrogen at from 50 to 250° C. and pressures of from 0.5 to 35 MPa in the presence of an oxidic supported catalyst comprising one or more noble metals which has been treated with hydrogen at from 50 to 300° C. for at least 0.5 hour before use. The compound 1,5-bis(dimethylamino)-2-methylpentane is also claimed.
摘要翻译：制备式I其中R 1和R 2的仲或叔2-甲基-1,5-辛烷二胺的方法是H，C 1 -C 20 - 烷基，C 3 -C 8 - 环烷基，芳基，C 7 -C 20 - 芳烷基，其中基团R 1和R 2可以具有选自C 1 -C 20 - 烷基，C 1 -C 20 - 烷氧基，C 6 -C 20 - 芳氧基和羟基的取代基，并且R 1和R 2不同时为氢，或者R 1和R 2一起为未取代或未取代的 C 1 -C 20烷基 - 和/或C 1 -C 20 - 烷氧基取代的C 3 -C 7 - 亚烷基链，如果需要，可以被一个或两个O或NR 3基团中断，其中R 3是H或C 1 -C 20烷基， - 甲基戊二腈与式R1R2NH的伯胺或仲胺和50-250℃的氢气和0.5-35MPa的压力在包含一种或多种已经用氢处理过的贵金属的氧化载体催化剂存在下在使用前至少0.5小时，从50至300℃。还要求化合物1,5-双（二甲基氨基）-2-甲基戊烷。

24. 发明授权

US5972064A Use of low-volatility pyrazole derivatives having hydrophilic groups as nitrification inhibitors 失效
标题翻译：使用具有亲水基团的低挥发性吡唑衍生物作为硝化抑制剂
公开(公告)号：US5972064A
公开(公告)日：1999-10-26
申请号：US875755
申请日：1997-08-06
申请人： Stefan Rittinger , Norbert Rieber , Randall Evan Gold , Jurgen Dressel
发明人： Stefan Rittinger , Norbert Rieber , Randall Evan Gold , Jurgen Dressel
IPC分类号： C05G3/08 , C07D231/12 , C07D231/16 , C09K17/14 , C09K101/00 , C07C11/08 , C07D231/20 , C07D231/22
CPC分类号： C07D231/12 , C05G3/08 , C07D231/16 , Y02P60/218
摘要： The present invention provides pyrazole compounds which are useful as nitrification inhibitors.
摘要翻译： PCT No.PCT / EP96 / 00319 Sec。 371日期：1997年8月6日 102（e）日期1997年8月6日PCT 1996年1月26日PCT公布。出版物WO96 / 24566 日期：1996年8月15日本发明提供可用作硝化抑制剂的吡唑化合物。

25. 发明授权

US5420365A Preparation of 2,4-hexadiyne-1,6-diol 失效
标题翻译： 2,4-己二炔-1,6-二醇的制备
公开(公告)号：US5420365A
公开(公告)日：1995-05-30
申请号：US176825
申请日：1994-01-03
申请人： Stefan Rittinger , Norbert Rieber
发明人： Stefan Rittinger , Norbert Rieber
IPC分类号： C07C29/42 , C07C31/18
CPC分类号： C07C29/42
摘要： Process for the preparation of 2,4-hexadiyne-1,6-diol of the formula IHO-CH.sub.2 -CH.sub.2 -C.ident.C-.ident.C-CH.sub.2 -OH (I)by the reaction of diacetylene of the formula IIH-C.ident.C-C.ident.C-H (II)with formaldehyde of the formula IIIH.sub.2 C=O (III),in the presence of a silver catalysts, in which the reaction is carried out in the presence of a polar organic solvent at temperatures ranging from 0.degree. to 150.degree. C. and under pressures ranging from 0.01 to 10 bar.
摘要翻译：式II HO-CH2-CH2-C = C-C-C-CH2-OH（Ⅰ）的2,4-己二炔-1,6-二醇通过式II的二乙炔的反应制备方法HC = 在银催化剂存在下，CC = CH（II）与式IIIH 2 C = O（III）的甲醛反应，其中反应在极性有机溶剂存在下，在0℃至150℃的温度范围内进行在0.01至10巴的压力下进行。

26. 发明授权

US08884076B2 Method for preparing polymethylols 有权
标题翻译：多羟甲基纤维素的制备方法
公开(公告)号：US08884076B2
公开(公告)日：2014-11-11
申请号：US13133861
申请日：2009-12-07
申请人： Tilman Sirch , Michael Steiniger , Steffen Maas , Stefan Rittinger , Stephan Schlitter
发明人： Tilman Sirch , Michael Steiniger , Steffen Maas , Stefan Rittinger , Stephan Schlitter
IPC分类号： C07C27/04 , C08G63/16 , C08G18/56 , C07C29/80 , C07C29/141 , C08L67/00 , C08L75/04
CPC分类号： C07C29/141 , C07C29/80 , C08G18/56 , C08G63/16 , C08L67/00 , C08L75/04 , C07C31/245 , C07C31/20 , C07C31/22
摘要： The present invention relates to a process for distilling an aqueous polymethylol mixture which comprises a polymethylol of the formula (I) (HOCH2)2—C—R2 (I) in which each R is independently a further methylol group or an alkyl group having 1 to 22 carbon atoms or an aryl or aralkyl group having 6 to 22 carbon atoms, a tertiary amine, water and the adduct of tertiary amine and formic acid (amine formate), which comprises performing the distillation in a distillation column which is connected at the bottom to an evaporator, the bottom temperature being above the evaporation temperature of the monoester of formic acid and polymethylol (polymethylol formate) which forms during distillation. The present invention further relates to a composition comprising polymethylol and 1 to 10 000 ppm by weight of polymethylol formate, and to the use thereof.
摘要翻译：本发明涉及一种蒸馏水性多羟甲基混合物的方法，该方法包括式（I）的多羟甲基（HOCH 2）2 -C-R 2（I），其中每个R独立地是另外的羟甲基或具有1 至22个碳原子或具有6至22个碳原子的芳基或芳烷基，叔胺，水和叔胺和甲酸（甲酸胺）的加合物，其包括在蒸馏塔中进行蒸馏，所述蒸馏塔在底部到蒸发器，底部温度高于在蒸馏期间形成的甲酸和多羟甲基（多羟甲基甲酸酯）的单酯的蒸发温度。本发明还涉及一种包含多羟甲基和1-10万重量ppm的多羟甲基甲酸酯的组合物及其用途。

27. 发明申请

US20100113836A1 METHOD FOR PRODUCING HYDROXY PIVALIN ALDEHYDE AND NEOPENTYL GLYCOL 有权
标题翻译：用于生产羟脯氨酸醛酸和甘氨酸的方法
公开(公告)号：US20100113836A1
公开(公告)日：2010-05-06
申请号：US12529197
申请日：2008-02-25
申请人： Tilman Sirch , Michael Steiniger , Steffen Maas , Stefan Rittinger , Stephan Schlitter
发明人： Tilman Sirch , Michael Steiniger , Steffen Maas , Stefan Rittinger , Stephan Schlitter
IPC分类号： C07C45/45 , C07C31/20
CPC分类号： C07C45/75 , C07C29/141 , C07C45/82 , C07C47/19 , C07C31/20
摘要： The preparation of hydroxypivalaldehyde is effected by aldolizing isobutyraldehyde with formaldehyde and subsequently working up the resulting reaction effluent by distillation, wherein the reaction effluent is fed to a distillation column which is operated at a top pressure in the range from 0.5 to 1.5 bar and in which a two-stage condensation is provided in the top region, in which the vapors are first conducted into a partial condenser operated at a temperature in the range from 50 to 80° C., whose condensate is recycled at least partly into the distillation column, and in which the vapors uncondensed in the partial condenser are fed to a downstream condenser operated at a temperature in the range from −40 to +30° C., whose condensate is at least partly discharged.
摘要翻译：羟基新戊醛的制备通过用甲醛醛化异丁醛和随后通过蒸馏处理所得反应流出物来实现，其中将反应流出物进料到蒸馏塔中，该蒸馏塔在0.5-1.5巴的最高压力下操作，其中在顶部区域中提供两级冷凝，其中蒸气首先被导入到在50-80℃的温度下操作的部分冷凝器，其冷凝物至少部分地再循环到蒸馏塔中，并且其中在部分冷凝器中未冷凝的蒸气被供给到在-40至+ 30℃的温度范围内操作的下游冷凝器，其冷凝物至少部分地排出。

28. 发明授权

US07405327B2 Method for the continuous production of an amine 失效
标题翻译：连续生产胺的方法
公开(公告)号：US07405327B2
公开(公告)日：2008-07-29
申请号：US11596292
申请日：2005-05-04
申请人： Frank Haese , Arnd Bottcher , Bernd Stein , Wolfgang Reif , Johann-Peter Melder , Karl-Heinz Roβ , Heinz Rutter , Shelue Liang , Stefan Rittinger
发明人： Frank Haese , Arnd Bottcher , Bernd Stein , Wolfgang Reif , Johann-Peter Melder , Karl-Heinz Roβ , Heinz Rutter , Shelue Liang , Stefan Rittinger
IPC分类号： C07C209/26
CPC分类号： C07C209/26 , C07C209/16 , C07C213/02 , C07D295/027 , C07D295/03 , C07D295/088 , C08G59/50 , Y02P20/582 , C07C211/06 , C07C211/08 , C07C211/35 , C07C217/08
摘要： Process for the continuous preparation of an amine by reaction of a primary or secondary alcohol, aldehyde and/or ketone with hydrogen and a nitrogen compound selected from the group consisting of ammonia, primary and secondary amines at a temperature in the range from 60 to 300° C. in the presence of a copper-containing catalyst, wherein the catalytically active composition of the catalyst prior to reduction with hydrogen comprises from 20 to 85% by weight of aluminum oxide (Al2O3), zirconium dioxide (ZrO2), titanium dioxide (TiO2) and/or silicon dioxide (SiO2), from 1 to 70% by weight of oxygen-containing compounds of copper, calculated as CuO, from 0 to 50% by weight of oxygen-containing compounds of magnesium, calculated as MgO, oxygen-containing compounds of chromium, calculated as Cr2O3, oxygen-containing compounds of zinc, calculated as ZnO, oxygen-containing compounds of barium, calculated as BaO, and/or oxygen-containing compounds of calcium, calculated as CaO, and less than 30% by weight of oxygen-containing compounds of nickel, calculated as NiO, based on the oxygen-containing compounds of copper, calculated as CuO, and the reaction is carried out isothermally in the gas phase in a tube reactor.
摘要翻译：通过伯醇或仲醇，醛和/或酮与氢和选自氨，伯胺和仲胺的氮化合物在60至300℃的温度下反应来连续制备胺的方法在含铜催化剂存在下，其中催化剂在用氢还原之前的催化活性组合物包含20至85重量％的氧化铝（Al 2 O 3 > 3），二氧化锆（ZrO 2），二氧化钛（TiO 2）和/或二氧化硅（SiO 2）），1至70重量％的以CuO计的铜的含氧化合物，0至50重量％的以MgO计的含氧化合物的镁，含氧化合物的铬，其计算为Cr 以ZnO计算的含氧化合物锌，以BaO表示的含氧化合物的钡，以BaO计算， /或以CaO计的钙的含氧化合物，以NiO计，以CuO计的含铜化合物计，小于30重量％的含氧化合物的镍，反应为在管式反应器中在气相中等温进行。

29. 发明授权

US06488734B1 Nitrification inhibitors, and the use of polyacids which contain a nitrification inhibitor for the treatment of inorganic fertilizers 有权
标题翻译：硝化抑制剂，以及使用含有硝化抑制剂的多酸用于无机肥料的处理
公开(公告)号：US06488734B1
公开(公告)日：2002-12-03
申请号：US09680195
申请日：2000-10-06
申请人： Thomas Barth , Norbert Rieber , Randall Evan Gold , Jürgen Dressel , Klaus Erhardt , Klaus Horchler von Locquengh , Edgar Leibold , Stefan Rittinger
发明人： Thomas Barth , Norbert Rieber , Randall Evan Gold , Jürgen Dressel , Klaus Erhardt , Klaus Horchler von Locquengh , Edgar Leibold , Stefan Rittinger
IPC分类号： C05C900
CPC分类号： C07D231/12 , C05F3/00 , C05G3/08 , C07D231/16 , C07D233/56 , C07D249/08 , Y02A40/205 , Y02P20/145 , Y02P60/218 , Y10S71/902
摘要： The use of inorganic or organic polyacids for the treatment of inorganic fertilizers, in particular the use of the polyacids as a mixture with at least one nitrification inhibitor for the treatment of inorganic fertilizers; the use of selected pyrazole derivatives as nitrification inhibitor in inorganic fertilizers and also as stabilizers of liquid manure or liquid fertilizer formulations, as well as the corresponding treated inorganic fertilizers per se; and novel pyrazole derivatives which can be used as nitrification inhibitors in inorganic fertilizers and also as stabilizers of liquid manure or liquid fertilizer formulations are described.
摘要翻译：使用无机或有机多酸来处理无机肥料，特别是使用多酸作为与至少一种硝化抑制剂的混合物用于无机肥料的处理; 在无机肥料中使用选择的吡唑衍生物作为硝化抑制剂，还用作液体肥料或液体肥料配方的稳定剂，以及相应的经处理的无机肥料本身; 并且描述了可用作无机肥料中的硝化抑制剂以及作为液体肥料或液体肥料制剂的稳定剂的新型吡唑衍生物。

30. 发明授权

US5484941A Preparation of 3(5)-methylpyrazoles 失效
标题翻译：制备3（5） - 甲基吡唑
公开(公告)号：US5484941A
公开(公告)日：1996-01-16
申请号：US232291
申请日：1994-05-06
申请人： Ralf Kaestner , Stefan Rittinger , Peter Paessler , Norbert Rieber
发明人： Ralf Kaestner , Stefan Rittinger , Peter Paessler , Norbert Rieber
IPC分类号： C07D237/12 , C07D231/12
CPC分类号： C07D231/12
摘要： Process for the preparation of methylpyrazoles from diacetylene and hydrazines in which the diacetylene is removed from cracked gas by absorption and is then reacted with hydrazines.
摘要翻译： PCT No.PCT / EP92 / 02514 Sec。 371日期：1994年5月6日 102（e）日期1994年5月6日PCT提交1992年11月3日PCT公布。 WO93 / 10098 PCT出版物日期：1993年5月27日。从乙炔和肼制备甲基吡唑的方法，其中通过吸收将二乙炔从裂化气体中除去，然后与肼反应。

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