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    • 21. 发明授权
    • Color photographic developing solution composition and method for
processing a silver halide color photographic material
    • 彩色照相显影液组合物和卤化银彩色照相材料的加工方法
    • US4833068A
    • 1989-05-23
    • US76430
    • 1987-07-21
    • Nobutaka OhkiKazuto AndohHiroshi Fujimoto
    • Nobutaka OhkiKazuto AndohHiroshi Fujimoto
    • G03C7/30G03C7/407G03C7/413
    • G03C7/413
    • A developing solution composition for a silver halide color photographic material is described, comprising an aromatic primary amine color developing agent and a compound represented by formula (I) ##STR1## wherein R.sup.1 and R.sup.2, which may be the same or different each represents a hydrogen atom or a substituted or unsubstituted alkyl group; R.sup.3 represents a substituted or unsubstituted alkylene group; and the total number of carbon atoms contained in R.sup.1, R.sup.2 and R.sup.3 is at least 3.The color developer composition has improved stability and color forming properties and remarkably limits fog formation during continuous processing.A method for processing a silver halide color photographic material including the step of developing a silver halide color photographic material comprising a support having thereon at least one silver halide emulsion layer with a developing solution comprising an aromatic primary amine color developing agent and a compound represented by formula (I) described above, and substantially no benzyl alcohol content, is also disclosed.
    • 描述了一种用于卤化银彩色照相材料的显影溶液组合物,其包含芳族伯胺显色剂和由式(I)表示的化合物。其中R1和R2各自可以相同或不同 表示氢原子或取代或未取代的烷基; R3表示取代或未取代的亚烷基; 并且R1,R2和R3中所含的碳原子总数至少为3.彩色显影剂组合物具有改进的稳定性和成色性,并且显着地限制了连续加工期间的雾形成。 一种用于处理卤化银彩色照相材料的方法,其包括显影卤化银彩色照相材料的步骤,该材料包括其上具有至少一个卤化银乳剂层的载体,所述显影溶液包含芳族伯胺显色剂和由 式(I),基本上不含苄醇含量。
    • 22. 发明授权
    • Color reversal photographic light-sensitive materials
    • 彩色反转照相感光材料
    • US4614707A
    • 1986-09-30
    • US702564
    • 1985-02-19
    • Munehisa FujitaYasuhiro HayashiTakashi OzawaNobutaka Ohki
    • Munehisa FujitaYasuhiro HayashiTakashi OzawaNobutaka Ohki
    • G03C5/50G03C7/20G03C7/26G03C7/392G03C1/02G03C1/46
    • G03C7/39216
    • A color reversal photographic light-sensitive materials comprising a base having thereon (a) at least one light-sensitive silver halide emulsion layer containing a dye forming coupler and (b) a silver halide emulsion layer substantially without light-sensitivity provided adjacent to said light-sensitive layer, or (a) at least one light-sensitive silver halide emulsion layer containing a dye forming coupler, (b) a silver halide emulsion layer substantially without light-sensitivity to light, and (c) an intermediate layer therebetween, wherein said intermediate layer or said silver halide emulsion layer substantially without light-sensitivity, or both said intermediate layer and said silver halide emulsion layer substantially without light-sensitivity contain at least one compound represented by the following formula (I): ##STR1## wherein R.sup.1 and R.sup.2, which may be the same or different, each represents a hydrogen atom or a group having 1 to 10 carbon atoms capable of being hydrolyzed with alkali, R.sup.3, R.sup.4 and R.sup.5 each represents a hydrogen atom, a sulfo group, a carboxyl group, a sulfoalkyl group having 1 to 6 carbon atoms, a carboxyalkyl group having 1 to 6 carbon atoms or an alkyl group having 1 to 22 carbon atoms, provided that at least one of R.sup.3, R.sup.4 and R.sup.5 is a group selected from a sulfo group, a carboxyl group, a sulfoalkyl group and a carboxyalkyl group, and at least one of R.sup.3, R.sup.4 and R.sup.5 is an alkyl group.
    • 一种彩色反转照相感光材料,其包含其上具有(a)至少一种含有染料形成成色剂的感光卤化银乳剂层的基材和(b)基本上不含光敏感性的卤化银乳剂层,其邻近于所述光 敏感层,或(a)至少一种含有染料形成成色剂的感光卤化银乳剂层,(b)基本上对光没有光敏感性的卤化银乳剂层,和(c)它们之间的中间层,其中 所述中间层或所述卤化银乳剂层基本上不具有光敏性,或基本上没有光敏性的所述中间层和所述卤化银乳剂层都包含至少一种由下式(I)表示的化合物: )其中可以相同或不同的R 1和R 2各自表示氢原子或能够水解的具有1至10个碳原子的基团 碱,R3,R4和R5各自表示氢原子,磺基,羧基,具有1至6个碳原子的磺基烷基,具有1至6个碳原子的羧基烷基或具有1至22个碳原子的烷基 原子,条件是R3,R4和R5中的至少一个是选自磺基,羧基,磺基烷基和羧基烷基的基团,并且R 3,R 4和R 5中的至少一个是烷基。
    • 24. 发明授权
    • Silver halide color photographic light-sensitive material
    • 卤化银彩色摄影感光材料
    • US5380631A
    • 1995-01-10
    • US2465
    • 1993-01-08
    • Yasushi NozawaNobuo SetoNobutaka OhkiMasayoshi Toyoda
    • Yasushi NozawaNobuo SetoNobutaka OhkiMasayoshi Toyoda
    • G03C1/035G03C1/18G03C1/34G03C7/305G03C7/333G03C7/392G03C1/46
    • G03C7/3335G03C7/305G03C7/39216Y10S430/158
    • A silver halide color photographic light-sensitive material having at least one negative silver halide emulsion layer on a support, wherein the silver halide color photographic light-sensitive material contains at least one type of a compound which reacts with the oxidized form of a developing agent to release a development inhibitor or a precursor of a development inhibitor and/or at least one type of a compound which cleaves after reacting with the oxidized form of a color developing agent, the cleaved compound of which in turn reacts with another molecule of the oxidized form of a color developing agent to cleave a development inhibitor, and contains at least one type of a compound selected from Formulas (A) and (B) below. In Formulas (A) and (B), each of R.sub.a1 to R.sub.a5 and R.sub.b1 to R.sub.b5 represents a hydrogen atom, an alkyl group or other groups. R.sub.a1 to R.sub.a5 are not simultaneously hydrogen atoms, and one or two of R.sub.b2 to R.sub.b5 are hydroxyl groups. ##STR1##
    • 一种卤化银彩色照相感光材料,其在载体上具有至少一个负卤化银乳剂层,其中所述卤化银彩色照相感光材料含有至少一种与氧化形式的显影剂反应的化合物 释放开发抑制剂或显影抑制剂的前体和/或至少一种类型的化合物,其与氧化形式的显色剂反应后裂解,其中切割的化合物又与另一分子的氧化的 形成显色剂以切割显影抑制剂,并含有至少一种选自下式(A)和(B)的化合物。 在式(A)和(B)中,Ra1〜Ra5和Rb1〜Rb5各自表示氢原子,烷基或其它基团。 Ra1〜Ra5不同时为氢原子,Rb2〜Rb5中的一个或两个为羟基。 公式(A)公式(B)
    • 25. 发明授权
    • Method for processing silver halide color photographic materials
    • 卤化银彩色照相材料的处理方法
    • US5176987A
    • 1993-01-05
    • US776851
    • 1991-10-16
    • Koichi NakamuraNobutaka Ohki
    • Koichi NakamuraNobutaka Ohki
    • G03C7/413
    • G03C7/4136Y10S430/164
    • A method for processing an imagewise exposed color photographic material using fast developing time while maintaining stable processing conditions, reduced developer replenishing, and light fastness of developed color images. The method comprises developing a color photographic material containing silver halide grains comprising (i) substantially no silver iodide and (ii) at least about 80 mol % silver chloride with a developer comprising (i) substantially no benzyl alcohol and (ii) a p-phenylenediamine derivative represented by the formula (I): ##STR1## wherein R.sup.1 and R.sup.2 each represents an alkyl group having from 1 to 4 carbon atoms and R.sup.2 represents a straight chain or branched alkylene group having 3 or 4 carbon atoms and wherein the developing is for a period of time of less than 30 seconds.
    • 使用快速显影时间处理成像曝光的彩色照相材料的方法,同时保持显影的彩色图像的稳定的处理条件,减少的显影剂补充和耐光性。 该方法包括显影含有卤化银颗粒的彩色照相材料,其包含(i)基本上不含碘化银和(ii)至少约80mol%氯化银,显影剂包含(i)基本上不含苄醇和(ii) (I)表示的苯二胺衍生物:其中R 1和R 2各自表示具有1至4个碳原子的烷基,R 2表示具有3或4个碳原子的直链或支链亚烷基,并且其中 开发时间短于30秒。
    • 26. 发明授权
    • Silver halide color photographic materials
    • 卤化银彩色照相材料
    • US5041365A
    • 1991-08-20
    • US555676
    • 1990-07-19
    • Osamu TakahashiHideaki NaruseMasakazu MorigakiNobutaka OhkiNobuo Furutachi
    • Osamu TakahashiHideaki NaruseMasakazu MorigakiNobutaka OhkiNobuo Furutachi
    • G03C7/26G03C7/38G03C7/392
    • G03C7/3805G03C7/39252
    • The present invention provides silver halide color photographic materials having a layer which contains at least one magenta color image-forming oleophilic coupler of the following formulae (I) and/or (II) and at least one of the following formula (III): ##STR1## in which Ar represents a phenyl group which is substituted by at least one substituent selected from the group consisting of a halogen atom, an alkyl group, an alkoxy group, an alkoxycarbonyl group and a cyano group; Y represents an acylamino group or an anilino group; and Z.sub.1 represents a group capable of being removed by coupling, ##STR2## in which X represents a hydrogen atom or a substituent; Z.sub.2 represents a hydrogen atom or a group capable of being removed by coupling;W represents a hydrogen atom, an acyl group or an aliphatic or aromatic sulfonyl group;Za and Zb each represent a methine group, a substituted methine group or --N.dbd.; andX, Z.sub.2 or the substituted methine of Za or Zb may form a dimer or higher polymer, ##STR3## in which A represents an alkyl group, an aryl group, a heterocyclic group, an acyl group, an alkoxy group, an aryloxy group, a heterocyclic oxy group, an alkylthio group, an arylthio group or an amino group, which may be substituted or unsubstituted; R.sub.1 and R.sub.2 each independently represents a hydrogen atom or a substituted or unsubstituted alkyl group; R.sub.3a and R.sub.3b each represents a hydrogen atom, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, an alkylthio group or an arylthio group; R.sub.4 represents an alkyl group, an aryl group or a heterocyclic group; and D represents an oxygen atom or a sulfur atom.The use of the combination of the magenta couplers(s) of the formulae (I) and/or (II) and the stain-inhibitory additive(s) of the formula (III) provides photographic light-sensitive materials that are almost free from stains when such materials are preserved for a long period of time after having been exposed, developed and then photographically processed.
    • 28. 发明授权
    • Silver-halide photographic light-sensitive material
    • 卤化银感光材料
    • US4439519A
    • 1984-03-27
    • US491829
    • 1983-05-05
    • Nobutaka OhkiKen KawataIsamu Itoh
    • Nobutaka OhkiKen KawataIsamu Itoh
    • G03C5/29C07C67/00C07C227/00C07C227/02C07C227/18C07C259/10C07D213/82G03C1/42G03C7/30G03C7/392
    • C07D213/82C07C255/00G03C1/42G03C7/39236Y10S430/156Y10S430/16
    • A silver halide photographic light-sensitive material containing a diffusion resistant coupler, a light-sensitive silver halide and at least one compound represented by the following general formula (I) in the same layer or different layers on a support. ##STR1## wherein R.sup.1 and R.sup.2 independently represent an alkyl group having from 1 to 5 carbon atoms, a hydroxyalkyl group having from 1 to 5 carbon atoms, an alkoxyalkyl group having from 2 to 10 carbon atoms or an alkylsulfonamidoalkyl group having from 2 to 10 carbon atoms; R.sup.3 represents a hydrogen atom, an alkyl group having from 1 to 5 carbon atoms or an alkoxy group having from 1 to 5 carbon atoms; X represents a hydrogen atom or a group capable of being removed with alkali; Y represents ##STR2## and Z represents an alkyl group, an alkenyl group, an aryl group or a heterocyclic group.The compound represented by the general formula (I) is a novel precursor of a color developing agent which provides a sufficiently high color density on development and causes less desensitization as well as less fog or stain formation during storage of any photographic light-sensitive material containing it. A method of forming a color photographic image using the silver photographic light-sensitive material is also disclosed.
    • 一种含有扩散阻抗成色剂,感光卤化银和至少一种由下述通式(I)表示的化合物的卤化银照相感光材料,在载体上的相同层或不同层中。 (I)其中R 1和R 2独立地表示具有1至5个碳原子的烷基,具有1至5个碳原子的羟基烷基,具有2至10个碳原子的烷氧基烷基或具有2至10个碳原子的烷基磺酰氨基烷基 2至10个碳原子; R3表示氢原子,具有1至5个碳原子的烷基或具有1至5个碳原子的烷氧基; X表示氢原子或能够被碱除去的基团; Y表示,Z表示烷基,烯基,芳基或杂环基。 由通式(I)表示的化合物是彩色显影剂的新型前体,其在显影时提供足够高的色密度,并且在储存任何摄影感光材料的过程中引起较少的脱敏以及较少的雾或污点形成 它。 还公开了使用银摄影感光材料形成彩色摄影图像的方法。