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21. 发明授权

US5565501A Active-energy-ray-curable coating composition 失效
标题翻译：活性能量射线固化涂料组合物
公开(公告)号：US5565501A
公开(公告)日：1996-10-15
申请号：US422947
申请日：1995-04-17
申请人： Noritaka Hosokawa , Kazuhide Hayama
发明人： Noritaka Hosokawa , Kazuhide Hayama
IPC分类号： C09D4/02 , C08F2/46 , C08J7/04 , C09D4/00
CPC分类号： C08J7/047 , C09D4/00 , C08J2433/00
摘要： The present invention provides a composition comprising (a) a carboxyl-group containing multifunctional acrylate; (b) a multifunctional acrylate having three or more acryloyl groups in the molecule; (c) an organic solvent; and optionally, (d) a photopolymerization initiator, (e) a colloidal metal oxide and (f) an acrylic resin is provided. This composition is applied to a plastic substrate and then irradiated with active energy rays, thereby forming a hard-coating layer having good adhesiveness to the substrate, transparency and hardwearing properties.
摘要翻译：本发明提供了包含（a）含羧基的多官能丙烯酸酯的组合物; （b）分子中具有3个以上丙烯酰基的多官能丙烯酸酯; （c）有机溶剂; 和（d）光聚合引发剂，（e）胶态金属氧化物和（f）丙烯酸树脂。将该组合物施加到塑料基材上，然后用活性能量射线照射，从而形成对基材具有良好粘附性的硬涂层，透明性和耐磨性。

22. 发明授权

US5409965A Abrasion resistant coating composition comprising a caboxylate-containing polyfunctional acrylate and silica sol 失效
标题翻译：包含含有含草酰氧基的多官能丙烯酸酯和二氧化硅溶胶的耐磨涂料组合物
公开(公告)号：US5409965A
公开(公告)日：1995-04-25
申请号：US279890
申请日：1994-07-26
申请人： Noritaka Hosokawa , Kazuhide Hayama
发明人： Noritaka Hosokawa , Kazuhide Hayama
IPC分类号： C08F2/50 , C08L23/16 , C09D4/00 , C09D5/00 , C09D131/06 , C08F267/02 , C08K3/36
CPC分类号： C09D4/00
摘要： An active energy ray-curing abrasion resistant coating composition is provided by incorporating following components: (a) a carboxylate-containing polyfunctional acrylate obtained by reacting a tetracarboxylic dianhydride and a hydroxyl group-containing polyfunctional acrylate having hydroxyl group(s) and at least three acryloyl groups and then neutralizing the reaction product; (b) a polyfunctional acrylate having at least three acryloyl groups; (c) an organic solvent; and (d) a photopolymerization initiator. The composition may comprise in addition to the components (e) a silica sol in an organic solvent as a dispersion medium. The composition may further comprise in addition to the components (f) an acrylic resin. Such composition is an active energy ray-curing abrasion-resistant coating composition which forms a film having excellent adhesion to a plastic sustrate, transparency, abrasion resistance and antistatic properties.
摘要翻译：通过掺入以下组分提供活性能量射线固化耐磨涂料组合物：（a）通过使四羧酸二酐和含羟基的含羟基的多官能丙烯酸酯与至少三个羟基反应得到的含羧酸酯的多官能丙烯酸酯丙烯酰基，然后中和反应产物; （b）具有至少三个丙烯酰基的多官能丙烯酸酯; （c）有机溶剂; 和（d）光聚合引发剂。组合物除了组分（e）之外还可以包含作为分散介质的有机溶剂中的硅溶胶。除了组分（f）之外，组合物还可以包含丙烯酸树脂。这种组合物是一种活性能量射线固化耐磨涂料组合物，其形成对塑料底片具有优异粘合性，透明性，耐磨性和抗静电性能的膜。

23. 发明授权

US5180766A Resin composition for primer use and primer composition employing the same 失效
标题翻译：用于初始使用的树脂组合物和使用该组合物的组合物
公开(公告)号：US5180766A
公开(公告)日：1993-01-19
申请号：US687517
申请日：1991-04-19
申请人： Kazuhide Hayama , Kazuyuki Hata , Katsuhiko Yamada , Keizo Abe , Takahiro Ozu
发明人： Kazuhide Hayama , Kazuyuki Hata , Katsuhiko Yamada , Keizo Abe , Takahiro Ozu
IPC分类号： C08F255/00 , C08F290/12 , C08F299/00 , C08J7/04 , C09D5/00 , C09D5/08 , C09J5/00
CPC分类号： C08F299/00 , C08F255/00 , C08F290/122 , C08J7/047 , C08J2323/02 , C08J2433/12
摘要： A resin composition for primer use is described, which contains a copolymer of (I) a radical-polymerizable olefin resin and (c) a monomer copolymerizable with said olefin resin (I) and containing an alkyl (meth)acrylate and/or a fluorine-containing unsaturated monomer as essential ingredients, said radical-polymerizable olefin resin (I) being a product of the reaction of (a) an olefin resin having at least one functional group per molecule with (b) a radical-polymerizable monomer having a functional group reactive to the functional group contained in said olefin resin (a).A primer composition is also described.

24. 发明授权

US5049629A Color developer for pressure-sensitive copying paper 失效
标题翻译：压敏复印纸的彩色显影剂
公开(公告)号：US5049629A
公开(公告)日：1991-09-17
申请号：US431232
申请日：1989-11-03
申请人： Kazuhide Hayama , Yukio Saitoh
发明人： Kazuhide Hayama , Yukio Saitoh
IPC分类号： B41M5/155 , C08G8/12 , C08G8/28 , C08G8/30
CPC分类号： C08G8/12 , C08G8/28 , C08G8/30
摘要： A color developer for pressure-sensitive copying paper is disclosed, containing a polyvalent metal-modification product of a p-substituted phenolformaldehyde condensate substantially terminated with an o-substituted phenol nucleus, with a content of a condensate component in which each of both terminal phenol nuclei thereof has a hydrogen atom at the o-position being not more than 20% by weight based on the total condensate. The color developer exhibits excellent color developability, undergoes no yellowing, and provides a color image having excellent water resistance.
摘要翻译：公开了一种用于压敏复印纸的彩色显影剂，其包含基本上用O-取代的酚核末端终止的对取代的苯酚甲醛缩合物的多价金属改性产物，其中两个末端苯酚其核在O位上的氢原子不超过基于总冷凝物的20重量％。彩色显影剂显示出优异的显色性，不发黄，并提供具有优异耐水性的彩色图像。

25. 发明授权

US4906526A Thermoplastic resin film having improved printability 失效
标题翻译：具有改善的印刷性的热塑性树脂膜
公开(公告)号：US4906526A
公开(公告)日：1990-03-06
申请号：US278244
申请日：1988-11-30
申请人： Masayuki Inoue , Akira Okamoto , Koichi Asami , Kazuhide Hayama , Kanji Narazaki
发明人： Masayuki Inoue , Akira Okamoto , Koichi Asami , Kazuhide Hayama , Kanji Narazaki
IPC分类号： B32B27/08 , B05D5/04 , B05D7/04 , B32B27/32 , B32B27/42 , C08J7/04 , C09D179/02
CPC分类号： B05D5/04 , B05D7/04 , Y10T428/31721 , Y10T428/3175 , Y10T428/31913 , Y10T428/31938
摘要： A thermoplastic resin film having improved printability is described, which is formed by coating a polyolefin film with an aqueous solution containing a modified polyethylene-imine represented by the following general formula: ##STR1## where A is ##STR2## or a polyamine-polyamide residue; R.sub.1 -R.sup.4 are each independently H, an alkyl or alkenyl group having 1-24 carbon atoms, an alicyclic hydrocarbon group or a benzyl group, provided that at least one of R.sup.1 -R.sup.4 is a group other than H; m is 0-300; and n, p and q are each a number of 1-300, and drying the coated solution to form a surface coating.
摘要翻译：描述了具有改进的可印刷性的热塑性树脂膜，其通过用含有由以下通式表示的改性聚乙烯 - 亚胺的水溶液涂布聚烯烃膜而形成：其中A为或多胺 - 聚酰胺残基 ; R1-R4各自独立地为H，具有1-24个碳原子的烷基或烯基，脂环族烃基或苄基，条件是R 1 -R 4中的至少一个是除H以外的基团; m为0-300; n，p和q各自为1-300，并干燥涂布的溶液以形成表面涂层。

26. 发明授权

US4741969A Aqueous ink recording sheet 失效
标题翻译：水墨记录纸
公开(公告)号：US4741969A
公开(公告)日：1988-05-03
申请号：US917682
申请日：1986-10-10
申请人： Kazuhide Hayama , Akira Yamashita
发明人： Kazuhide Hayama , Akira Yamashita
IPC分类号： B41M5/00 , B41M5/52 , C09D11/00 , C09D11/30 , C09D151/00 , B32B23/08 , B05D3/06 , B32B27/10
CPC分类号： C09D151/003 , B41M5/5254 , Y10T428/31895 , Y10T428/31906
摘要： An aqueous ink recording sheet is described which is prepared by coating on the surface of a substrate sheet a resin composition containing as the chief ingredient a mixture comprising (A) 10 to 90 wt % of photo polymerizable, double bonded anionic synthetic resin, and (B) 90 to 0 wt % of partially or completely saponified polyvinyl alcohol, or partially or completely saponified polymer resin composed of 20 to 100 wt % of vinyl acetate and 80 to 0 wt % of other polymerizable monomer or derivatives thereof, and/or (C) 90 to 0 wt % of homopolymer resin of N-vinylpyrrolidone or copolymer resin of other polymerizable monomer therewith, with the weight ratio of (A)/[(B)+(C)] being 90/10 to 10/90, drying the coated resin composition, and then curing the resin composition by the irradiation with actinic rays so as to form a resin coating layer on the substrate.The aqueous ink recording sheet of the present invention is not only capable of recording distinctly and sharply the multicolor full color copy that is an advantageous point in ink jet process but also excellent in both the adsorbency and the dryness against the ink.
摘要翻译：描述了一种水性油墨记录纸，其通过在基材表面上涂布树脂组合物制备，所述树脂组合物含有（A）10-90重量％的光聚合性双键阴离子合成树脂和（A） B）90〜0重量％的部分或完全皂化的聚乙烯醇，或部分或完全皂化的聚合物树脂，其由20-100重量％的乙酸乙烯酯和80至0重量％的其它可聚合单体或其衍生物组成，和/或（ C）90〜0重量％的N-乙烯基吡咯烷酮的均聚物树脂或其它可聚合单体的共聚物树脂，（A）/ [（B）+（C）]的重量比为90/10〜10/90，干燥涂布的树脂组合物，然后通过用光化射线照射固化树脂组合物，以在基材上形成树脂涂层。本发明的水性墨水记录纸不仅能够清楚地且清楚地记录喷墨工艺中有利点的多色全色复印件，而且对于油墨的吸附性和干燥性均优异。

27. 发明授权

US4698395A Process of purifying maleic anhydride-modified polyolefin 失效
标题翻译：纯化马来酸酐改性聚烯烃的方法
公开(公告)号：US4698395A
公开(公告)日：1987-10-06
申请号：US863191
申请日：1986-05-14
申请人： Takayuki Inoue , Masafumi Hattori , Kazuhide Hayama , Riichiro Maruta
发明人： Takayuki Inoue , Masafumi Hattori , Kazuhide Hayama , Riichiro Maruta
IPC分类号： C08F6/06 , C08F8/44 , C08F8/46 , C08F255/00 , C08F8/42
CPC分类号： C08F8/46 , C08F255/00 , C08F6/06 , C08F8/44
摘要： A process of purifying maleic anhydride graft polyolefin comprising the steps of adding an aqueous solution of alkali initial hydroxide to a solution of maleic anhydride graft polyolefin containing unreacted maleic anhydride which is dissolved in an organic solvent at a temperature from 80.degree. C. to 160.degree. C., thereby precipitating maleic anhydride graft polyolefin particles to make a W/O emulsion; stirring the W/O emulsion while maintaining the temperature at a same temperature as above for less than 2 hours, thereby selectively forming the alkali metal salt of unreacted maleic anhydride; adding the aqueous solution of alkali metal hydroxide to the W/O emulsion to convert the W/O emulsion into an O/W emulsion; separating the maleic anhydride draft polyolefin particles, and washing the maleic anhydride graft polyolefin particles with water.
摘要翻译：一种纯化马来酸酐接枝聚烯烃的方法，包括以下步骤：将碱初始氢氧化物水溶液加入到含有未反应的马来酸酐的马来酸酐接枝聚烯烃溶液中，所述马来酸酐接枝聚烯烃在80℃至160℃的温度下溶解在有机溶剂中从而沉淀马来酸酐接枝聚烯烃颗粒以制备W / O乳液; 搅拌W / O乳液同时将温度保持在与上述相同的温度下少于2小时，从而选择性地形成未反应的马来酸酐的碱金属盐; 将碱金属氢氧化物水溶液加入到W / O乳液中以将W / O乳液转化为O / W乳液; 分离马来酸酐卷曲聚烯烃颗粒，并用水洗涤马来酸酐接枝聚烯烃颗粒。

28. 发明授权

US06921576B2 Active energy ray-curable antistatic coating composition 有权
标题翻译：活性能量射线固化型抗静电涂料组合物
公开(公告)号：US06921576B2
公开(公告)日：2005-07-26
申请号：US10266735
申请日：2002-10-09
申请人： Makoto Terauchi , Noritaka Hosokawa , Kazuhide Hayama
发明人： Makoto Terauchi , Noritaka Hosokawa , Kazuhide Hayama
IPC分类号： C08G18/28 , C08G18/38 , C08G18/62 , C08G18/71 , C08J7/04 , C09D5/24 , C09D7/12 , B32B5/16
CPC分类号： C08J7/047 , C08G18/283 , C08G18/284 , C08G18/289 , C08G18/3821 , C08G18/6283 , C08G18/6295 , C08G18/718 , C08J2367/02 , C08J2475/00 , C08K3/22 , C08K3/36 , C08K9/06 , C09D5/24 , C09D7/62 , Y10T428/2991 , Y10T428/2993 , Y10T428/2995 , Y10T428/2998 , Y10T428/31663
摘要： An active energy ray-curable antistatic coating composition contains (A) inorganic oxide fine particles having a side chain having a molecular weight of at least 300 and having a functional group and (B) an antistatic agent containing at least a quaternary ammonium salt group-containing polymer, a quaternary ammonium salt group-containing silane coupling agent and/or a hydrolysis condensate of the silane coupling agent, and optionally contains (C) a polyfunctional (meth)acrylate having at least 3 (meth)acryloyl groups in a molecule.
摘要翻译：活性能量射线固化型抗静电涂料组合物含有（A）分子量至少为300的具有官能团的侧链的无机氧化物细粒子，（B）至少含有季铵盐基团的抗静电剂，含有季铵盐基团的硅烷偶联剂和/或硅烷偶联剂的水解缩合物，并且任选地含有（C）分子中具有至少3个（甲基）丙烯酰基的多官能（甲基）丙烯酸酯。

29. 发明授权

US06586106B2 Thermoplastic resin film satisfactory in printability 有权
标题翻译：热塑性树脂膜的印刷性良好
公开(公告)号：US06586106B2
公开(公告)日：2003-07-01
申请号：US09921747
申请日：2001-08-06
申请人： Nobuhiro Shibuya , Kazuhisa Kitamura , Ayako Shibata , Yasuo Kitani , Kazuhide Hayama
发明人： Nobuhiro Shibuya , Kazuhisa Kitamura , Ayako Shibata , Yasuo Kitani , Kazuhide Hayama
IPC分类号： B32B2700
CPC分类号： C08J7/047 , B41M1/305 , C08J2479/00 , Y10T428/249991 , Y10T428/31504 , Y10T428/31507 , Y10T428/31725 , Y10T428/31775 , Y10T428/31786 , Y10T428/31909 , Y10T428/31913
摘要： Described is a thermoplastic resin film having on a surface thereof a hydroxy-modified imine polymer containing repeating units represented by the following general formula (I) in an amount of 5 mol % or more based on the total of repeating units. This thermoplastic resin film has ink transfer, adhesion and aging stability, and excellent printability of generating no back ghost when offset printing using oxidation polymerization type ink is performed on both faces
摘要翻译：描述了一种热塑性树脂膜，其表面上含有基于重复单元总数为5摩尔％以上的含有下述通式（I）所示的重复单元的羟基改性亚胺系聚合物。该热塑性树脂膜具有油墨转移，粘合和老化稳定性，以及在两面上进行使用氧化聚合型油墨的胶版印刷时不产生反向重影的优异的可印刷性

30. 发明授权

US06403731B1 Process for preparing polymer solution 有权
标题翻译：制备聚合物溶液的方法
公开(公告)号：US06403731B1
公开(公告)日：2002-06-11
申请号：US09544113
申请日：2000-04-06
申请人： Yukio Saitou , Shigeoki Kawaguchi , Kouhei Sawa , Tadahiko Kondou , Kazuhide Hayama
发明人： Yukio Saitou , Shigeoki Kawaguchi , Kouhei Sawa , Tadahiko Kondou , Kazuhide Hayama
IPC分类号： C08F206
CPC分类号： C08F2/06 , C08F2220/1825 , C08F2220/1858 , C08F220/06
摘要： Disclosed is a process for preparing a polymer solution having a reduced unreacted unsaturated monomer content, comprising radically polymerizing at least one unsaturated monomer in a solvent in the presence of a radical polymerization initiator, the at least one unsaturated monomer having a lower boiling point than that of the solvent, wherein the weight ratio of the total amount of the unsaturated monomers to the solvent is from 1/9 to 7/3, the polymerization is carried out until the conversion of the unsaturated monomer having the lowest conversion of all the other unsaturated monomers whose boiling point is lower than that of the solvent reaches at least 85%, and, after completion of the polymerization, the reaction mixture is rectified to remove the unreacted unsaturated monomer or monomers.
摘要翻译：公开了一种制备具有降低的未反应不饱和单体含量的聚合物溶液的方法，该方法包括在自由基聚合引发剂存在下在溶剂中自由基聚合至少一种不饱和单体，所述至少一种不饱和单体的沸点低于沸点。的溶剂，其中不饱和单体与溶剂的总量的重量比为1/9至7/3，进行聚合直至转化所有其它不饱和单体的转化率最低的不饱和单体沸点低于溶剂的单体达到至少85％，聚合完成后，将反应混合物精馏除去未反应的不饱和单体。

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