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    • 29. 发明授权
    • Non-aqueous electrolyte secondary cell
    • 非水电解质二次电池
    • US07704640B2
    • 2010-04-27
    • US11362225
    • 2006-02-27
    • Keisuke OogaMasato IwanagaHideyuki InomataRyuji Ohshita
    • Keisuke OogaMasato IwanagaHideyuki InomataRyuji Ohshita
    • H01M4/58
    • H01M10/4235H01M4/1391H01M10/0567H01M2004/021H01M2004/028
    • A non-aqueous electrolyte secondary cell excellent in cycle characteristics is provided. This purpose is achieved by the following structure. A non-aqueous electrolyte secondary cell has a positive electrode having a positive electrode active material, a negative electrode having a negative electrode active material, and a non-aqueous electrolyte having a non-aqueous solvent and an electrolytic salt. The positive electrode active material has a lithium-cobalt compound oxide having added therein at least zirconium. The non-aqueous electrolyte has LiBF4 at from 0.05 to 1.0 mass % of a total mass of the non-aqueous electrolyte and unsaturated cyclic carbonate at from 1.0 to 4.0 mass %. The true density ratio of the positive electrode is 0.72 or greater, the true density ratio being represented by formula 1 shown below: (Formula 1) True density ratio=active material apparent density of electrode active material layer÷true density of active material.
    • 提供循环特性优异的非水电解质二次电池。 该目的通过以下结构实现。 非水电解质二次电池具有具有正极活性物质的正极,具有负极活性物质的负极和具有非水溶剂和电解质盐的非水电解质。 正极活性物质具有至少添加有锆的锂 - 钴复合氧化物。 非水电解质的LiBF 4的含量为0.05〜1.0质量%,非水电解质和不饱和环状碳酸酯的总质量为1.0〜4.0质量%。 正极的真密度比为0.72以上,真密度比由下式1表示:(式1)真密度比=活性物质活性物质表观密度÷活性物质的真密度。