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    • 22. 发明授权
    • Apparatus for manufacturing photographic emulsions
    • 用于制造照相乳剂的装置
    • US06443611B1
    • 2002-09-03
    • US09738734
    • 2000-12-15
    • Dirk J. HasbergRajesh V. MehtaMichael BryanRamesh Jagannathan
    • Dirk J. HasbergRajesh V. MehtaMichael BryanRamesh Jagannathan
    • B01F1502
    • B01F7/00758B01F3/0807B01F7/1665B01F2215/0093G03C1/015G03C1/49845G03C2200/09
    • An apparatus and method for mixing at least two reactants is taught wherein a first reactant is delivered to a reaction zone through a first annular flow path and a second reactant is delivered to the reaction zone through a second annular flow path. The first and second annular flow paths are concentric with one another and the two reactants intermix with one another in the reaction zone. There is a rotating disc having a surface, defining one boundary of the reaction zone. The flow of the first and second reactants across the rotating disc and through the reaction zone is generally radial and has a residence time in the reaction zone of not more than about 100 msec, and preferably not more than about 50 msec. The reaction zone resides in a main reactor vessel and there is a driven agitator residing in the main reactor vessel to stir the contents thereof.
    • 教导了用于混合至少两种反应物的装置和方法,其中第一反应物通过第一环形流动路径被输送到反应区,并且第二反应物通过第二环形流动路径输送到反应区。 第一和第二环形流动路径彼此同心,两个反应物在反应区中相互混合。 存在具有限定反应区的一个边界的表面的旋转盘。 第一反应物和第二反应物跨过旋转盘并通过反应区的流动通常是径向的,并且在反应区中的停留时间不超过约100毫秒,优选不超过约50毫秒。 反应区位于主反应器容器中,并且存在位于主反应器容器中以驱动其内容物的驱动搅拌器。
    • 23. 发明申请
    • MEMS PRINTHEAD BASED COMPRESSED FLUID PRINTING SYSTEM
    • 基于MEMS PRINTHEAD的压缩流体打印系统
    • US20090079783A1
    • 2009-03-26
    • US11860820
    • 2007-09-25
    • Rajesh V. MehtaMichael A. MarcusRuizheng WangGilbert A. Hawkins
    • Rajesh V. MehtaMichael A. MarcusRuizheng WangGilbert A. Hawkins
    • B41J2/015
    • B41J2/015B41J2/04
    • A method and apparatus for delivering a mixture of compressed fluid and marking material and depositing the marking material in a pattern onto a substrate, includes a high pressure source of a mixture of compressed fluid and marking material. A micro-machined manifold includes a plurality of micro-nozzles, a fluid chamber, and an entrance port with portions of a first surface of the micro-machined manifold defining the entrance port with the entrance port being connected in fluid communication with the fluid chamber. Each of the micro-nozzles having an inlet and an outlet with the inlet being connected in fluid communication with the fluid chamber and the outlet being located on the second surface of the micro-machined manifold. Each micro-nozzle is shaped to produce a directed beam of the mixture of compressed fluid and marking material beyond the outlet of the micro-nozzle. A housing is connected in fluid communication with the high pressure source and the entrance port of the micro-machined manifold with the connection being a sealed connection. Optionally, a device operable to capture marking material that does not adhere to the substrate can be included.
    • 用于输送压缩流体和标记材料的混合物并将标记材料以图案沉积到基底上的方法和装置包括压缩流体和标记材料的混合物的高压源。 微加工歧管包括多个微喷嘴,流体室和入口,其中微加工歧管的第一表面的部分限定入口,入口与流体室流体连通地连接 。 每个微喷嘴具有入口和出口,入口与流体室流体连通并且出口位于微加工歧管的第二表面上。 每个微型喷嘴被成形为产生压缩流体和标记材料的混合物的定向束超过微喷嘴的出口。 壳体与微加工歧管的高压源和入口端口流体连通,连接是密封连接的。 可选地,可以包括可操作以捕获不粘附到基底的标记材料的装置。
    • 24. 发明授权
    • Process for formation and collection of particles using cryogenic material
    • 使用低温材料形成和收集颗粒的方法
    • US07931834B2
    • 2011-04-26
    • US11674291
    • 2007-02-13
    • Rajesh V. MehtaRobert LinkMichael A. Marcus
    • Rajesh V. MehtaRobert LinkMichael A. Marcus
    • B29B9/00B22F9/00B22F9/02B22F9/06
    • B22F9/02
    • A process for the formation of particles of a target material is disclosed, comprising: (i) introducing the target material into a particle formation vessel, and forming a continuous liquid surface of the target material in the particle formation vessel, and an interface between said liquid surface of the target material and additional gaseous contents of said particle formation vessel; (ii) introducing a stream of cryogenic material including solid particles of cryogenic material into the particle formation vessel and into contact with the target material in a liquid state below the continuous liquid surface; (iii) allowing rapid volumetric expansion of the cryogenic material into a gaseous state while in contact with the target material in a liquid state, and release of the expanded gaseous cryogenic material through the continuous liquid surface, and forming liquid droplet particles of the target material; and (iv) collecting the formed particles of the target material.
    • 公开了一种用于形成目标材料颗粒的方法,包括:(i)将目标材料引入颗粒形成容器中,并且在颗粒形成容器中形成目标材料的连续液体表面,以及在所述颗粒形成容器之间的界面 所述目标材料的液体表面和所述颗粒形成容器的附加气体含量; (ii)将包括低温材料的固体颗粒的低温材料流引入颗粒形成容器中并在连续液体表面下方以液态与目标材料接触; (iii)允许低温材料在液体状态下与目标材料接触时快速体积膨胀到气态,并且通过连续液体表面释放膨胀的气态低温材料,以及形成目标材料的液滴颗粒 ; 和(iv)收集所形成的目标材料的颗粒。
    • 25. 发明授权
    • MEMS printhead based compressed fluid printing system
    • 基于MEMS打印头的压缩流体打印系统
    • US07762647B2
    • 2010-07-27
    • US11860820
    • 2007-09-25
    • Rajesh V. MehtaMichael A. MarcusRuizheng WangGilbert A. Hawkins
    • Rajesh V. MehtaMichael A. MarcusRuizheng WangGilbert A. Hawkins
    • B41J2/015
    • B41J2/015B41J2/04
    • A method and apparatus for delivering a mixture of compressed fluid and marking material and depositing the marking material in a pattern onto a substrate, includes a high pressure source of a mixture of compressed fluid and marking material. A micro-machined manifold includes a plurality of micro-nozzles, a fluid chamber, and an entrance port with portions of a first surface of the micro-machined manifold defining the entrance port with the entrance port being connected in fluid communication with the fluid chamber. Each of the micro-nozzles having an inlet and an outlet with the inlet being connected in fluid communication with the fluid chamber and the outlet being located on the second surface of the micro-machined manifold. Each micro-nozzle is shaped to produce a directed beam of the mixture of compressed fluid and marking material beyond the outlet of the micro-nozzle. A housing is connected in fluid communication with the high pressure source and the entrance port of the micro-machined manifold with the connection being a sealed connection. Optionally, a device operable to capture marking material that does not adhere to the substrate can be included.
    • 用于输送压缩流体和标记材料的混合物并将标记材料以图案沉积到基底上的方法和装置包括压缩流体和标记材料的混合物的高压源。 微加工歧管包括多个微喷嘴,流体室和入口,其中微加工歧管的第一表面的部分限定入口,入口与流体室流体连通地连接 。 每个微喷嘴具有入口和出口,入口与流体室流体连通并且出口位于微加工歧管的第二表面上。 每个微型喷嘴被成形为产生压缩流体和标记材料的混合物的定向束超过微喷嘴的出口。 壳体与微加工歧管的高压源和入口端口流体连通,连接是密封连接的。 可选地,可以包括可操作以捕获不粘附到基底的标记材料的装置。
    • 26. 发明授权
    • Process for the preparation of high bromide cubic grain emulsions
    • 制备高溴化物立方颗粒乳剂的方法
    • US06753134B2
    • 2004-06-22
    • US10202314
    • 2002-07-24
    • Dirk J. HasbergRajesh V. MehtaRalph W. Jones, Jr
    • Dirk J. HasbergRajesh V. MehtaRalph W. Jones, Jr
    • G03C1035
    • G03C1/035G03C1/015G03C2001/03511G03C2001/03535G03C2001/03541
    • A process for the preparation of a radiation-sensitive silver halide emulsion comprised of high bromide cubical silver halide grains is described, the process comprising: (a) providing in a stirred reaction vessel a dispersing medium and high bromide silver halide seed grains, the seed grains comprising at least 5 mole % of the final emulsion silver, and (b) precipitating a silver halide shell which comprises at least 5 mole % of the final emulsion silver onto the seed grains by introducing at least a silver salt solution into the dispersing medium at a rate such that the normalized shell molar addition rate, Rs, is above 1.0×10−3 min−2, Rs satisfying the formula: R s = M s M t ⁢ t s 2 where Ms is the number of moles of silver halides added to the reaction vessel during the formation of the shell, ts is the run time, in minutes, of the silver salt solution for the formation of the shell, and Mt is total moles of silver halide in the reaction vessel at the end of the precipitation of the shell; wherein the concentration of silver halide grains in the reaction vessel at the end of the precipitation of the shell is at least 0.5 mole/L. The invention provides an improved manufacturing process for the preparation of high bromide silver halide cubical grain emulsion enabling concentrated emulsion batches to be prepared with desired photographic properties. In certain embodiments of the invention, further advantages are enabled in accordance with the discovery that when the exterior portion of high bromide silver halide cubic grains are grown under specific conditions of high molar addition rates, emulsions of enhanced sensitivity, improved contrast and radiographic curve shape may be produced while controlling the minimum fog level.
    • 描述了制备由高溴化物立方卤化银颗粒组成的辐射敏感卤化银乳剂的方法,该方法包括:(a)在搅拌的反应容器中提供分散介质和高溴化物卤化银种子颗粒,种子 包含至少5摩尔%的最终乳液银的颗粒,和(b)通过将至少一种银盐溶液引入到分散介质中,将包含至少5摩尔%的最终乳液银的卤化银壳沉淀到种子晶粒上 使得归一化的壳摩尔加成速率Rs大于1.0×10 -3 min 2,Rs满足下式:其中Ms是在反应容器中加入的卤化银的摩尔数 壳的形成,ts是用于形成壳的银盐溶液的运行时间(分钟),Mt是壳体沉淀结束时反应容器中卤化银的总摩尔数; 其中壳体沉淀结束时反应容器中卤化银颗粒的浓度为至少0.5mol / L。 本发明提供了一种用于制备高溴化银卤化银立方颗粒乳液的改进的制备方法,使得能够制备具有所需照相性能的浓缩乳液批料。 在本发明的某些实施方案中,根据以下发现可以实现进一步的优点:当高溴化银卤化银立方晶粒的外部部分在高摩尔添加速率的特定条件下生长时,增强灵敏度,改善的对比度和放射线形状曲线形状的乳剂 可以在控制最小雾水平的同时产生。
    • 27. 发明授权
    • High chloride emulsions doped with iridium complexes
    • 掺有铱络合物的高氯化物乳液
    • US06242172B1
    • 2001-06-05
    • US09475841
    • 1999-12-30
    • Jerzy A. BudzEric L. BellRajesh V. Mehta
    • Jerzy A. BudzEric L. BellRajesh V. Mehta
    • G03C108
    • G03C5/04G03C1/035G03C1/09G03C2001/03535G03C2001/03541G03C2001/093G03C2200/39
    • A radiation-sensitive emulsion is disclosed comprised of cubical silver halide grains containing from 0.05 to 3 mole percent iodide, based on total silver, and an iridium coordination complex dopant, wherein (i) the iodide is incorporated in the grains in a controlled, non-uniform distribution forming a core containing at least 50 percent of total silver, an iodide free surface shell having a thickness of greater than 50 Å, and a sub-surface shell that contains a maximum iodide concentration, and (ii) the iridium coordination complex dopant is incorporated into the sub-surface shell or into a region of the core extending up to 60% of the total silver into the grain from the sub-surface shell. Speed and reciprocity of iodochloride emulsions can be improved by localized addition of known in the art reciprocity-controlling iridium dopants in relation to high iodide region of the grain. By carefully incorporating reciprocity-controlling dopant within a well defined band within a grain the difficulties of the prior art can be overcome.
    • 公开了一种辐射敏感性乳剂,其包含基于总银含有0.05至3摩尔%碘化物的立方体卤化银颗粒和铱配位络合物掺杂剂,其中(i)碘化物以受控的非 - - 均匀分布,形成含有至少50%的总银,不含碘离子的表面壳,厚度大于的核心,以及含有最大碘化物浓度的亚表面壳,和(ⅱ)铱配位络合物 掺杂剂结合到子表面壳体中或引入芯部的区域中,该区域从底表面壳体延伸到总银的60%到晶粒内。 通过本领域已知的互易控制铱掺杂剂相对于颗粒的高碘化物区域的局部添加可以提高碘氯化物乳剂的速度和互惠。 通过将互易控制掺杂剂小心地结合在晶粒内的良好限定的带内,可以克服现有技术的困难。