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21. 发明申请

US20090214447A1 Preparation of cationic nanoparticles and personal care compositions comprising said nanoparticles 失效
标题翻译：包含所述纳米颗粒的阳离子纳米颗粒和个人护理组合物的制备
公开(公告)号：US20090214447A1
公开(公告)日：2009-08-27
申请号：US12378567
申请日：2009-02-17
申请人： John Jennings , Dietmar Haglin , Jianwen Mao , Andreas Muhlebach
发明人： John Jennings , Dietmar Haglin , Jianwen Mao , Andreas Muhlebach
IPC分类号： A61K8/02 , A61Q19/00 , A61Q5/00 , A61Q11/00 , A61Q15/00 , A61Q9/02 , A61Q5/02 , A61Q5/04 , A61Q5/10 , A61Q5/08 , A61Q3/02 , A61Q1/06 , A61Q1/10 , A61Q17/04 , A01N25/00 , A01P1/00
CPC分类号： A61K8/8117 , A61K8/11 , A61K8/8129 , A61K2800/413 , A61Q5/02 , A61Q5/12 , A61Q17/005 , A61Q17/04 , A61Q19/04
摘要： The present invention is directed to cationic nanoparticles, methods to make them, and the use of compositions containing said nanoparticles in personal care compositions or formulations. The nanoparticles are useful in personal care applications and impart antimicrobial properties to home and personal care products containing them. These cationic nanoparticles also contribute useful conditioning properties to hair-care and skin-care products.
摘要翻译：本发明涉及阳离子纳米颗粒，制备它们的方法，以及在个人护理组合物或制剂中使用含有所述纳米颗粒的组合物。纳米颗粒可用于个人护理应用，并将抗微生物特性赋予含有它们的家庭和个人护理产品。这些阳离子纳米颗粒还为护发和护肤产品提供有用的调理性能。

22. 发明申请

US20090099282A1 Functionalized nanoparticles 审中-公开
标题翻译：官能化纳米粒子
公开(公告)号：US20090099282A1
公开(公告)日：2009-04-16
申请号：US11920295
申请日：2006-05-17
申请人： Martin Muller , Andreas Muhlebach , Thomas Giesenberg , Didier Bauer , Thomas Ruch , Francois Rime , Leonhard Feiler , Roman Lenz , Laurent Michau
发明人： Martin Muller , Andreas Muhlebach , Thomas Giesenberg , Didier Bauer , Thomas Ruch , Francois Rime , Leonhard Feiler , Roman Lenz , Laurent Michau
IPC分类号： C08K5/5419 , C04B16/00 , C08K5/00
CPC分类号： C09B69/103 , C09B67/0097 , C09B68/20 , C09B68/443 , C09B69/10
摘要： The present invention discloses functionalized nanoparticles comprising on the surface a covalently bound radical of formula (1), wherein the nanoparticles are SiO2, Al2O3 or mixed SiO2 and Al2O3 nanoparticles, R1 and R2 are independently of each other hydrogen, nanoparticle surface-O—, or a substituent, n is 1, 2, 3, 4, 5, 6, 7 or 8, and Y is a radical of formula —B1-D1 (2a), wherein B1 is the direct bond or a bridge member, and D1 is a radical of a cationic dye, a radical of a phthalocyanine dye which carries no water-solubilizing group, or a radical of a fluorescent dye selected from the group consisting of coumarins, benzocoumarins, xanthenes, benzo[a]xanthenes, benzo[b]xanthenes, benzo[c]xanthenes, phenoxazines, benzo[a]phenoxazines, benzo[b]phenoxazines, benzo[c]phenoxazines, napthalimides, naphtholactams, azlactones, methines, oxazines, thiazines, diketopyrrolopyrroles, quinacridones, benzoxanthenes, thio-epindolines, lactamimides, diphenylmaleimides, acetoacetamides, imidazothiazines, benzanthrones, phthalimides, benzotriazoles, pyrimidines, pyrazines and triazines, or Y is a radical of formula —B2D2 (2b), wherein B2 is an organic radical comprising at least one group having a negative charge, and D2 is a cationic dye selected from the group consisting of monoazo, disazo, polyazo, methine, azamethine, diphenylmethane, triphenylmethane, triaminotriaryl methane, azine, oxazine, cyanine and anthraquinone dyes.
摘要翻译：本发明公开了在表面上包含式（1）的共价结合基团的官能化纳米颗粒，其中纳米颗粒是SiO 2，Al 2 O 3或混合的SiO 2和Al 2 O 3纳米颗粒，R 1和R 2彼此独立地是氢，纳米颗粒表面-O-，或取代基，n为1,2,3,4,5,6,7或8，并且Y为式-B1-D1（2a）的基团，其中B1为直接键或桥式构件，D1为是阳离子染料的自由基，不含水溶性基团的酞菁染料的基团，或选自香豆素，苯并香豆素，呫吨，苯并[a]呫吨，苯并[b 苯并[c]呫吨酮，苯并[c]呫吨酮，吩恶嗪，苯并[a]吩恶嗪，苯并[b]吩恶嗪，苯并[c]吩恶嗪，萘酰亚胺，萘并内酰胺，吖内酯，次甲基，恶嗪，噻嗪，二酮吡咯并吡咯，喹吖啶酮，苯并恶庚烯，硫代 - ，内酰胺，二苯基马来酰亚胺，乙酰乙酰胺，咪唑硫基吖嗪，苯并呋喃，邻苯二甲酰亚胺，苯并三唑，嘧啶，吡嗪和三嗪，或Y是式-B2D2（2b）的基团，其中B2是包含至少一个具有负电荷的基团的有机基团，并且D2是选择的阳离子染料来自由单偶氮，双偶氮，多偶氮，次甲基，氮杂酮，二苯基甲烷，三苯甲烷，三氨基三芳基甲烷，吖嗪，恶嗪，花青和蒽醌染料组成的组。

23. 发明申请

US20070093576A1 Reinforced coatings with improved scratch resistance 审中-公开
标题翻译：具有改善耐刮擦性的增强涂层
公开(公告)号：US20070093576A1
公开(公告)日：2007-04-26
申请号：US10574766
申请日：2004-10-06
申请人： Martin Albrecht , Tunja Jung , Andreas Muhlebach
发明人： Martin Albrecht , Tunja Jung , Andreas Muhlebach
IPC分类号： B60C1/00
CPC分类号： C08K3/01 , C08K3/36 , C09D7/60 , C09D7/61 , C09D7/67 , C09D7/68
摘要： The instant invention discloses a coating composition comprising a) an organic film-forming binder, and b) an inorganic additive of small particle size dispersed in an aqueous or alcoholic solvent prepared by a process which comprises the hydrolysis of a metal alcoholate or a compound of the formula (I) in which R1 is C1-C8alkyl, C5-C8cycloalkyl, phenyl or C1-C4alkyl substituted phenyl; R2 is C1-C8salkyl, and n is 0, 1, 2 or 3; with a base. These coatings for protecting surfaces are reinforced and show improved scratch resistance.
摘要翻译：本发明公开了一种涂料组合物，其包含a）有机成膜粘合剂，和b）分散在水溶液或醇溶剂中的小粒径的无机添加剂，该无机添加剂通过包括水解金属醇化物或其中R 1是C 1 -C 8烷基，C 5 -C 6烷基的式（I）苯基或C 1 -C 4烷基取代的苯基; C 1 -C 4烷基取代的苯基; R 2是C 1 -C 8烷基，n是0,1,2或3; 与一个基地。这些用于保护表面的涂层被加强并显示出改善的耐划伤性。

24. 发明申请

US20050004317A1 Pigment compositions with modified atrp copolymer dispersants 审中-公开
标题翻译：具有改性的atrp共聚物分散剂的颜料组合物
公开(公告)号：US20050004317A1
公开(公告)日：2005-01-06
申请号：US10495519
申请日：2002-11-21
申请人： Clemens Auschra , Ernst Eckstein , Marie-Odile Zink , Andreas Muhlebach
发明人： Clemens Auschra , Ernst Eckstein , Marie-Odile Zink , Andreas Muhlebach
IPC分类号： C08F2/38 , C08F4/40 , C08F293/00 , C08K3/00 , C08K5/00 , C08L53/00 , C09D7/12 , C09D11/02 , C09D17/00 , C09D153/00 , C09J11/00
CPC分类号： C08F293/005 , C08F293/00 , C08F2438/01 , C08K5/0041 , C08L53/00 , C09D11/03 , C09D153/00
摘要： The present invention relates to a composition containing modified block copolymer dispersants and dispersible inorganic or organic pigment. The block copolymers are prepared by atom transfer radical polymerization (ATRP) and modified with a salt forming group. The pigment composition is useful for preparing coating compositions, prints, images, inks or lacquers and other disperse systems.
摘要翻译：本发明涉及含有改性嵌段共聚物分散剂和可分散无机或有机颜料的组合物。嵌段共聚物通过原子转移自由基聚合（ATRP）制备并用成盐基团改性。颜料组合物可用于制备涂料组合物，印刷品，图像，油墨或漆和其它分散体系。

25. 发明授权

US5849841A Crosslinked polymers containing ester or amide groups 失效
标题翻译：含有酯或酰胺基团的交联聚合物
公开(公告)号：US5849841A
公开(公告)日：1998-12-15
申请号：US875340
申请日：1997-07-30
申请人： Andreas Muhlebach , Beat Muller
发明人： Andreas Muhlebach , Beat Muller
IPC分类号： G02C7/04 , B29D11/00 , C08F2/48 , C08F8/00 , C08F8/30 , C08F18/04 , C08F26/02 , C08F299/00 , C08G73/02 , C08J3/24 , G02B1/04
CPC分类号： G02B1/043 , C08F8/30
摘要： The invention relates to a novel process for the production of mouldings, in particular contact lenses, in which a water-soluble, crosslinkable polymer is crosslinked in solution, and to mouldings, in particular contact lenses, obtainable by this process. The present invention likewise relates to novel water-soluble, crosslinkable polymers, in particular those comprising units of formula (III or IIIa), in which R.sub.1 and R.sub.2, independently of one another, are hydrogen, a C.sub.1 -C.sub.8 alkyl group, an aryl group or a cyclohexyl group, where these groups can be monosubstituted or polysubstituted, R.sub.3 is hydrogen or a C.sub.1 -C.sub.4 alkyl group, and R.sub.4 is an --OH-- or --NH-- bridge; and to crosslinked polymers made from these novel water-soluble, crosslinkable polymers, to a process for the preparation of the novel water-soluble, crosslinkable polymers and the homopolymers and copolymers obtainable therefrom, to mouldings made from said homopolymers or copolymers, in particular contact lenses made from these homopolymers or copolymers, and to a process for the production of contact lenses using said homopolymers or copolymers. ##STR1##
摘要翻译： PCT No.PCT / EP96 / 00246 Sec。 371日期1997年7月30日 102（e）日期1997年7月30日PCT 1996年1月22日PCT PCT。出版物WO96 / 24075 日期1996年8月8日本发明涉及一种用于制造模制品，特别是其中水溶性可交联聚合物在溶液中交联的模制品，以及可通过该方法获得的模制品，特别是隐形眼镜的新型制备方法。本发明同样涉及新的水溶性可交联聚合物，特别是包含式（III或IIIa）单元的那些，其中R 1和R 2彼此独立地是氢，C 1 -C 8烷基，芳基或环己基，其中这些基团可以被单取代或多取代，R3是氢或C1-C4烷基，R4是-OH-或-NH-桥; 以及由这些新型水溶性可交联聚合物制成的交联聚合物，用于制备新型水溶性可交联聚合物的方法和由其获得的均聚物和共聚物，由所述均聚物或共聚物制成的模制品，特别是接触由这些均聚物或共聚物制成的透镜，以及使用所述均聚物或共聚物制备隐形眼镜的方法。（III）（IIIa）

26. 发明申请

US20080280070A1 Coating Compositions Containing Levelling Agents Prepared by Nitroxyl Mediated Polymerisation 有权
标题翻译：包含由硝酸酯介导的聚合制备的流平剂的涂料组合物
公开(公告)号：US20080280070A1
公开(公告)日：2008-11-13
申请号：US10581137
申请日：2004-12-01
申请人： Ralf Knischka , Clemens Auschra , Andreas Muhlebach , Sevgi Zeren
发明人： Ralf Knischka , Clemens Auschra , Andreas Muhlebach , Sevgi Zeren
IPC分类号： C09D133/10 , B05D3/00 , C09D133/24 , C09D133/02
CPC分类号： C09D5/033 , C08L57/12 , C08L2201/00 , C09D7/47
摘要： The present invention relates to coating compositions containing a polymeric or copolymeric levelling agent, which has been prepared by nitroxyl-mediated polymerisation. Further aspects are a process for the preparation of smooth surface coatings and the use of said polymer or copolymer as levelling agent in coating compositions. Yet another aspect are specific ethylenically unsaturated monomer compositions from which copolymers can be obtained by atom transfer radical polymerisation or nitroxyl mediated polymerisation, which copolymers are useful as levelling agents in coating compositions. Still another aspect is the use of poly-tert.-butyl acrylate or poly-tert.butylmethacrylate as a levelling agent in powder coating compositions.
摘要翻译：本发明涉及包含通过硝酰基介导的聚合制备的聚合物或共聚物流平剂的涂料组合物。另外的方面是制备光滑表面涂层的方法以及所述聚合物或共聚物作为涂料组合物中的流平剂的用途。另一方面是特定的烯键式不饱和单体组合物，其可通过原子转移自由基聚合或硝酰基介导的聚合获得共聚物，该共聚物可用作涂料组合物中的流平剂。另一方面是在粉末涂料组合物中使用聚丙烯酸叔丁酯或聚 - 叔丁基甲基丙烯酸酯作为流平剂。

27. 发明申请

US20060160940A1 Process for intercalating natural or szynthetic clays with block or comb copolymers 审中-公开
标题翻译：使用嵌段或梳状共聚物插入天然或合成粘土的方法
公开(公告)号：US20060160940A1
公开(公告)日：2006-07-20
申请号：US10547265
申请日：2004-02-23
申请人： Andreas Muhlebach , Francois Rime
发明人： Andreas Muhlebach , Francois Rime
IPC分类号： C08K3/34 , C08L53/00 , B32B27/00
CPC分类号： C09J151/003 , C08F4/00 , C08F291/00 , C08F293/005 , C08K9/08 , C08L51/003 , C08L53/00 , C08L2666/02 , C09D151/003 , C09D153/00 , C09J153/00
摘要： The instant invention relates to a process for manufacturing nanoparticles by intercalating and/or exfoliating natural or synthetic clays using block or comb copolymers having one cationic block and at least one non polar block, which are prepared by controlled free radical polymerization (CFRP). The invention also relates to improved nanocomposite compositions containing nanoparticles produced by this process and to the use of these nanocomposite compositions as, for example in, coatings, sealants, caulks, adhesives and as plastic additives.
摘要翻译：本发明涉及通过使用通过控制自由基聚合（CFRP）制备的具有一个阳离子嵌段和至少一个非极性嵌段的嵌段或梳状共聚物来嵌入和/或剥离天然或合成粘土来制造纳米颗粒的方法。本发明还涉及包含通过该方法生产的纳米颗粒的改进的纳米复合材料组合物以及这些纳米复合材料组合物在例如涂料，密封剂，填缝剂，粘合剂和塑料添加剂中的应用。

28. 发明申请

US20050272617A1 Polymers produced by atom transfer radical polymerisation technique with structurally modified terminal groups 失效
标题翻译：通过原子转移自由基聚合技术制备的结构改性末端基团的聚合物
公开(公告)号：US20050272617A1
公开(公告)日：2005-12-08
申请号：US10513837
申请日：2003-04-29
申请人： Hugo Camenzind , Paul Dubs , Peter Hanggi , Roger Martin , Andreas Muhlebach , Francois Rime
发明人： Hugo Camenzind , Paul Dubs , Peter Hanggi , Roger Martin , Andreas Muhlebach , Francois Rime
IPC分类号： C08F2/38 , C08F8/00 , C08F293/00 , C08K5/00 , C10M145/14
CPC分类号： C08F293/005 , C08F8/26 , C08F8/30 , C08F8/34 , C08F8/40 , C08F2438/01 , C08K5/005 , C08F120/18
摘要： The present invention relates to a block copolymer prepared by ATRP, wherein the polymer chain terminal group is structurally modified with the functionally effective group of a lubricant or polymer additive selected from the group consisting of antioxidants, metal deactivators, antiwear and extreme pressure additives and corrosion inhibitors. The invention also relates to a composition comprising the structurally modified block copolymer and a composition of matter subject to oxidative, thermal or light induced degradation, such as lubricants or polymers.
摘要翻译：本发明涉及通过ATRP制备的嵌段共聚物，其中聚合物链端基在结构上用功能有效的润滑剂或聚合物添加剂基团进行改性，所述润滑剂或聚合物添加剂选自抗氧化剂，金属钝化剂，抗磨和极压添加剂和腐蚀抑制剂。本发明还涉及包含结构改性的嵌段共聚物和经受氧化，热或光诱导降解的物质组合物如润滑剂或聚合物的组合物。

29. 发明申请

US20050096406A1 Reactive diluents and alkyd resin coating compositions 审中-公开
标题翻译：活性稀释剂和醇酸树脂涂料组合物
公开(公告)号：US20050096406A1
公开(公告)日：2005-05-05
申请号：US10504239
申请日：2003-02-25
申请人： Roger Pretot , Andreas Muhlebach , Wolfgang Peter , Kurt Dietliker , Tunja Jung , Clemens Auschra , Hans Kirner , Paul Van Der Schaaf
发明人： Roger Pretot , Andreas Muhlebach , Wolfgang Peter , Kurt Dietliker , Tunja Jung , Clemens Auschra , Hans Kirner , Paul Van Der Schaaf
IPC分类号： C07C13/28 , C07C13/44 , C07C33/12 , C07C43/162 , C07C69/007 , C07C69/54 , C07C69/60 , C07C69/80 , C09D4/00 , C09D5/00 , C09D7/00 , C09D7/12 , C09D11/02 , C09D11/10 , C09D167/08 , C08G2/00
CPC分类号： C09D11/101 , C07C13/28 , C07C13/44 , C07C33/12 , C07C43/162 , C07C69/007 , C07C69/54 , C07C69/60 , C07C69/80 , C07C2601/08 , C07C2602/22 , C09D167/08
摘要： The invention relates to new reactive diluents of the formulae (Ia, Ib, Ic, Id, Ie) and to an alkyd coating composition comprising them. In a preferred embodiment R1 and R2 are hydrogen; R3 is (meth)acryloyloxy-methyl or phenyl para substituted by vinyl, R4 is phenyl or phenyl para substituted by vinyl or (meth)acryloyloxy; or a substituted phenyl residue of the formula —C6H4CH2—W, wherein W is (meth)acryloyloxy, or an aliphatic residue of the formula —CH2—Y-A, wherein Y is a bond, O—C1-C12alkylene, wherein the alkylene linker is linear or branched and may be interrupted once or more than once by oxygen, A is hydroxy, C1-C6alkoxy, acetoxy, (meth)acryloyloxy, or a phthalate- or maleate-residue; R5 is hydrogen; n is 1; X is —(CH2)—. The invention further relates to a solvent-based or water-based alkyd coating composition comprising 0.3 to 10 wt. % of a mono-, bis- or trisacylphosphinoxide photoinitiator, especially Irgacure 819.
摘要翻译：本发明涉及式（Ia，Ib，Ic，Id，Ie）的新型反应性稀释剂和包含它们的醇酸树脂涂料组合物。在优选的实施方案中，R 1和R 2是氢; R 3是（甲基）丙烯酰氧基 - 甲基或被乙烯基取代的对苯基，R 4是苯基或被乙烯基或（甲基）丙烯酰氧基取代的对苯基; 或式-C 6 H 2 CH 2 -W的取代的苯基，其中W是（甲基）丙烯酰氧基或脂族基式-CH 2 -YA的残基，其中Y是一个键，OC 1 -C 12亚烷基，其中亚烷基接头是直链的或分支，并且可以被氧中断一次或多于一次，A是羟基，C 1 -C 6烷氧基，乙酰氧基，（甲基）丙烯酰氧基或邻苯二甲酸酯 - 或马来酸盐残基; R 5是氢; n为1; X是 - （CH 2） - 。本发明还涉及一种溶剂型或水性醇酸涂料组合物，其包含0.3至10wt。％的单，双或三酰基次膦酰基光引发剂，特别是Irgacure 819。

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