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1. 发明授权

US08568834B2 Superhydrophilic coating compositions and their preparation 失效
标题翻译：超亲水性涂料组合物及其制备方法
公开(公告)号：US08568834B2
公开(公告)日：2013-10-29
申请号：US12321542
申请日：2009-01-22
申请人： Valentina Mitina , Michael Chin , Keqing Fa , Thomas Giesenberg
发明人： Valentina Mitina , Michael Chin , Keqing Fa , Thomas Giesenberg
IPC分类号： B05D5/00
CPC分类号： B05D5/00 , C03C17/23 , C03C17/3417 , C03C2217/212 , C03C2217/213 , C03C2217/216 , C03C2217/23 , C03C2217/71 , C03C2217/75 , C03C2218/111 , C04B41/009 , C04B41/5089 , C04B41/85 , C04B2111/20 , C04B2111/2069 , C08K3/22 , C09D7/61 , C09D7/67 , Y10T428/31504 , Y10T428/31678 , C04B33/00
摘要： A method is provided for preparing on the surface of a substrate a superhydrophilic layer containing at least one metal oxide which method comprises calcining at elevated temperatures a cross-linked precursor film in which film the metal oxide is evenly distributed and immobilized. The precursor film is prepared by sequentially applying to the surface of the substrate a polyamine or other cationic polymer, a suspension of metal oxide and then a suitable cross linking agent. The superhydrophilic layer can be applied as a coating to a variety of substrates including metal, glass and ceramic and provides excellent dirt resistance, scratch resistance and antifogging effect. Multi-layer systems are also available using the inventive process.
摘要翻译：提供了一种在基材表面上制备含有至少一种金属氧化物的超亲水层的方法，该方法包括在升高的温度下煅烧金属氧化物均匀分布和固定的交联前体膜。通过将多胺或其它阳离子聚合物，金属氧化物的悬浮液和合适的交联剂依次施加到基材的表面来制备前体膜。超亲水层可以作为涂层施加到包括金属，玻璃和陶瓷的各种基材上，并提供优异的抗污性，耐擦伤性和防雾效果。使用本发明的方法也可以使用多层系统。

2. 发明申请

US20090246536A1 Superhydrophil Coating Compositions and their Preparation 失效
标题翻译：超亲水涂料组合物及其制备方法
公开(公告)号：US20090246536A1
公开(公告)日：2009-10-01
申请号：US12321542
申请日：2009-01-22
申请人： Valentina Mitina , Michael Chin , Keqing Fa , Thomas Giesenberg
发明人： Valentina Mitina , Michael Chin , Keqing Fa , Thomas Giesenberg
IPC分类号： B05D3/10 , B32B17/06 , B32B15/04 , B32B9/04
CPC分类号： B05D5/00 , C03C17/23 , C03C17/3417 , C03C2217/212 , C03C2217/213 , C03C2217/216 , C03C2217/23 , C03C2217/71 , C03C2217/75 , C03C2218/111 , C04B41/009 , C04B41/5089 , C04B41/85 , C04B2111/20 , C04B2111/2069 , C08K3/22 , C09D7/61 , C09D7/67 , Y10T428/31504 , Y10T428/31678 , C04B33/00
摘要： A method is provided for preparing on the surface of a substrate a superhydrophilic layer containing at least one metal oxide which method comprises calcining at elevated temperatures a cross-linked precursor film in which film the metal oxide is evenly distributed and immobilized. The precursor film is prepared by sequentially applying to the surface of the substrate a polyamine or other cationic polymer, a suspension of metal oxide and then a suitable cross linking agent. The superhydrophilic layer can be applied as a coating to a variety of substrates including metal, glass and ceramic and provides excellent dirt resistance, scratch resistance and antifogging effect. Multi-layer systems are also available using the inventive process.
摘要翻译：提供了一种在基材表面上制备含有至少一种金属氧化物的超亲水层的方法，该方法包括在升高的温度下煅烧金属氧化物均匀分布和固定的交联前体膜。通过将多胺或其它阳离子聚合物，金属氧化物的悬浮液和合适的交联剂依次施加到基材的表面来制备前体膜。超亲水层可以作为涂层施加到包括金属，玻璃和陶瓷的各种基材上，并提供优异的抗污性，耐擦伤性和防雾效果。使用本发明的方法也可以使用多层系统。

3. 发明申请

US20090076198A1 Functionalized nanoparticles 审中-公开
标题翻译：官能化纳米粒子
公开(公告)号：US20090076198A1
公开(公告)日：2009-03-19
申请号：US11665627
申请日：2005-10-17
申请人： Thomas Giesenberg , Andreas Muhlebach , Tunja Jung , Francois Rime , Laurent Michau , Martin Muller , Didier Bauer
发明人： Thomas Giesenberg , Andreas Muhlebach , Tunja Jung , Francois Rime , Laurent Michau , Martin Muller , Didier Bauer
IPC分类号： B32B5/16 , C08K5/00 , C08K5/34 , C08K5/45 , C08K5/15 , C08K5/51 , C08K5/53 , B05D3/02
CPC分类号： C09D7/63 , C01P2002/84 , C01P2002/88 , C01P2004/64 , C08K9/06 , C09C1/3081 , C09C1/40 , C09C1/407 , C09D7/48 , Y10T428/2982
摘要： The present invention discloses functionalized nanoparticles comprising on the surface a covalently bound radical of the formula (I) wherein the nanoparticles are SiO2, Al2O3 or mixed SiO2 and Al2O3 nanoparticles, and wherein the general symbols are as defined in claim 1. These functionalized nanoparticles are for example useful as stabilizers and/or compatibilizers in organic materials, or as photoinitiators in pre-polymeric or pre-crosslinking formulations, or as reinforcer of coatings and improver of scratch resistance in coating compositions for surfaces.
摘要翻译：本发明公开了在表面上包含共价结合的式（I）基团的官能化纳米颗粒，其中纳米颗粒是SiO 2，Al 2 O 3或混合SiO 2和Al 2 O 3纳米颗粒，其中通式符号如权利要求1中所定义。这些官能化纳米颗粒是例如在有机材料中用作稳定剂和/或增容剂，或作为预聚物或预交联制剂中的光引发剂，或用作表面涂料组合物中涂料的增强剂和耐划伤性改进剂。

4. 发明申请

US20100178512A1 CHANGING SURFACE PROPERTIES BY FUNCTIONALIZED NANOPARTICLES 审中-公开
标题翻译：通过功能化纳米粒子改变表面特性
公开(公告)号：US20100178512A1
公开(公告)日：2010-07-15
申请号：US12516890
申请日：2007-11-26
申请人： Thomas Giesenberg , Pascal Hayoz , Thomas Vogel , Andreas Muhlebach , Markus Frey , Stephan Ilg , Rachel Kohli Steck , Laurent Michau , Francois Rime
发明人： Thomas Giesenberg , Pascal Hayoz , Thomas Vogel , Andreas Muhlebach , Markus Frey , Stephan Ilg , Rachel Kohli Steck , Laurent Michau , Francois Rime
IPC分类号： B32B5/16 , B05D3/00 , B05D3/06 , C08G79/00 , C08G79/10 , C08F20/06 , C08F14/06 , C08F12/08
CPC分类号： C08F2/44 , B05D3/065 , B05D3/142 , B05D5/00 , B05D7/04 , B05D2401/32 , B29C70/64 , B82Y30/00 , C01P2004/03 , C01P2004/64 , C08F2/48 , C08F291/00 , C08F292/00 , C08J7/123 , C08J2323/06 , C08J2323/12 , C08K3/18 , C08K9/08 , C08L51/003 , C08L51/10 , C09C1/3081 , C09C3/063 , C09D5/1618 , C09D7/62 , Y10T428/2995 , Y10T428/31663 , Y10T428/31678 , Y10T428/31855 , C08L2666/02
摘要： A process for modifying the surface of an inorganic or organic substrate with strongly adherent nanoparticles is described, providing to the surface modified substrate durable effects like hydrophobicity, hydrophilicity, electrical conductivity, magnetic properties, flame retardance, color, adhesion, roughness, scratch resistance, UV-absorbance, antimicrobial properties, antifouling properties, antiprotein properties, antistatic properties, antifog properties, release properties. In this process, an optional first step a) a low-temperature plasma, ozonization, high energy irradiation, corona discharge or a flame is caused to act on the inorganic or organic substrate, and in a second step b) one or more defined nanoparticles or mixtures of defined nanoparticles with monomers, containing at least one ethylenically unsaturated group, or solutions, suspensions or emulsions of the afore-mentioned substances, are applied, preferably at normal pressure, to the inorganic or organic substrate. In a third step c) suitable methods are applied to dry or cure those afore-mentioned substances and, optionally, in a fourth step d) a further coating is applied on the substrate so pretreated.
摘要翻译：描述了一种用强粘附纳米颗粒改性无机或有机基材的表面的方法，为表面改性的基材提供耐久效果，如疏水性，亲水性，导电性，磁性，阻燃性，颜色，粘合性，粗糙度，耐擦伤性，紫外线吸收，抗菌性，防污性，抗蛋白性，抗静电性，防雾性，脱模性。在该过程中，引入可选的第一步骤a）低温等离子体，臭氧化，高能辐射，电晕放电或火焰作用于无机或有机衬底，并且在第二步骤中b）一个或多个限定的纳米颗粒或含有至少一个烯属不饱和基团的限定的纳米颗粒与单体的混合物，或上述物质的溶液，悬浮液或乳液，优选常压下施用于无机或有机基材。在第三步骤中，c）应用合适的方法来干燥或固化上述物质，并且任选地在第四步骤中d）将另外的涂层施加在基材上以进行预处理。

5. 发明申请

US20090280326A1 Process for the Treatment of Metal Coated Particles 审中-公开
标题翻译：金属涂层颗粒的处理方法
公开(公告)号：US20090280326A1
公开(公告)日：2009-11-12
申请号：US12226114
申请日：2007-04-02
申请人： Thomas Giesenberg , Peter Hänggi , Patrice Bujard
发明人： Thomas Giesenberg , Peter Hänggi , Patrice Bujard
IPC分类号： B32B19/00 , B32B15/02 , B05D3/00 , H01B1/02 , C09D11/02
CPC分类号： C23C8/36 , B22F1/0085 , B22F2999/00 , Y10T428/2991 , B22F1/025 , B22F2207/01 , B22F2202/13
摘要： The present invention relates to a process for the thermal treatment of metal coated particles, to the particles obtainable by the process and to their use for the manufacture of printable electronics, or for EMI shielding.
摘要翻译：本发明涉及一种用于热处理金属涂覆颗粒的方法，涉及通过该方法可获得的颗粒及其用于制造可印刷电子器件或用于EMI屏蔽的方法。

6. 发明申请

US20090099282A1 Functionalized nanoparticles 审中-公开
标题翻译：官能化纳米粒子
公开(公告)号：US20090099282A1
公开(公告)日：2009-04-16
申请号：US11920295
申请日：2006-05-17
申请人： Martin Muller , Andreas Muhlebach , Thomas Giesenberg , Didier Bauer , Thomas Ruch , Francois Rime , Leonhard Feiler , Roman Lenz , Laurent Michau
发明人： Martin Muller , Andreas Muhlebach , Thomas Giesenberg , Didier Bauer , Thomas Ruch , Francois Rime , Leonhard Feiler , Roman Lenz , Laurent Michau
IPC分类号： C08K5/5419 , C04B16/00 , C08K5/00
CPC分类号： C09B69/103 , C09B67/0097 , C09B68/20 , C09B68/443 , C09B69/10
摘要： The present invention discloses functionalized nanoparticles comprising on the surface a covalently bound radical of formula (1), wherein the nanoparticles are SiO2, Al2O3 or mixed SiO2 and Al2O3 nanoparticles, R1 and R2 are independently of each other hydrogen, nanoparticle surface-O—, or a substituent, n is 1, 2, 3, 4, 5, 6, 7 or 8, and Y is a radical of formula —B1-D1 (2a), wherein B1 is the direct bond or a bridge member, and D1 is a radical of a cationic dye, a radical of a phthalocyanine dye which carries no water-solubilizing group, or a radical of a fluorescent dye selected from the group consisting of coumarins, benzocoumarins, xanthenes, benzo[a]xanthenes, benzo[b]xanthenes, benzo[c]xanthenes, phenoxazines, benzo[a]phenoxazines, benzo[b]phenoxazines, benzo[c]phenoxazines, napthalimides, naphtholactams, azlactones, methines, oxazines, thiazines, diketopyrrolopyrroles, quinacridones, benzoxanthenes, thio-epindolines, lactamimides, diphenylmaleimides, acetoacetamides, imidazothiazines, benzanthrones, phthalimides, benzotriazoles, pyrimidines, pyrazines and triazines, or Y is a radical of formula —B2D2 (2b), wherein B2 is an organic radical comprising at least one group having a negative charge, and D2 is a cationic dye selected from the group consisting of monoazo, disazo, polyazo, methine, azamethine, diphenylmethane, triphenylmethane, triaminotriaryl methane, azine, oxazine, cyanine and anthraquinone dyes.
摘要翻译：本发明公开了在表面上包含式（1）的共价结合基团的官能化纳米颗粒，其中纳米颗粒是SiO 2，Al 2 O 3或混合的SiO 2和Al 2 O 3纳米颗粒，R 1和R 2彼此独立地是氢，纳米颗粒表面-O-，或取代基，n为1,2,3,4,5,6,7或8，并且Y为式-B1-D1（2a）的基团，其中B1为直接键或桥式构件，D1为是阳离子染料的自由基，不含水溶性基团的酞菁染料的基团，或选自香豆素，苯并香豆素，呫吨，苯并[a]呫吨，苯并[b 苯并[c]呫吨酮，苯并[c]呫吨酮，吩恶嗪，苯并[a]吩恶嗪，苯并[b]吩恶嗪，苯并[c]吩恶嗪，萘酰亚胺，萘并内酰胺，吖内酯，次甲基，恶嗪，噻嗪，二酮吡咯并吡咯，喹吖啶酮，苯并恶庚烯，硫代 - ，内酰胺，二苯基马来酰亚胺，乙酰乙酰胺，咪唑硫基吖嗪，苯并呋喃，邻苯二甲酰亚胺，苯并三唑，嘧啶，吡嗪和三嗪，或Y是式-B2D2（2b）的基团，其中B2是包含至少一个具有负电荷的基团的有机基团，并且D2是选择的阳离子染料来自由单偶氮，双偶氮，多偶氮，次甲基，氮杂酮，二苯基甲烷，三苯甲烷，三氨基三芳基甲烷，吖嗪，恶嗪，花青和蒽醌染料组成的组。

7. 发明授权

US08456733B2 Coloured particles for electrophoretic displays 有权
标题翻译：用于电泳显示器的彩色颗粒
公开(公告)号：US08456733B2
公开(公告)日：2013-06-04
申请号：US12083884
申请日：2006-10-16
申请人： Margherita Fontana , Gabriele Baisch , Thomas Giesenberg , Laurent Michau , Reinhold Öhrlein , Andreas Mühlebach
发明人： Margherita Fontana , Gabriele Baisch , Thomas Giesenberg , Laurent Michau , Reinhold Öhrlein , Andreas Mühlebach
IPC分类号： G02B26/00
CPC分类号： G02F1/167 , B82Y30/00 , C01P2002/88 , C01P2004/62 , C01P2004/64 , C09C1/3081 , C09C1/407 , C09C3/12
摘要： The present invention discloses the use of functionalized particles as electrophoretic displaying particles, wherein the functionalized particles are SiO2, Al2O3 or mixed SiO2 and Al2O3 particles comprising, covalently bound to an oxygen atom on the surface, a radical of formula (1), wherein R1 and R2 are independently of each other hydrogen, particle surface-O—, or a substituent, n is 1, 2, 3, 4, 5, 6, 7 or 8, B is the direct bond or a bridge member, and D is the residue of an organic chromophore.
摘要翻译：本发明公开了使用官能化颗粒作为电泳显示颗粒，其中官能化颗粒是SiO 2，Al 2 O 3或混合SiO 2和Al 2 O 3颗粒，其包含与表面上的氧原子共价结合的式（1）基团，其中R 1 和R2彼此独立地为氢，颗粒表面-O-或取代基，n为1,2,3,4,5,6,7或8，B为直接键或桥构件，D为有机发色团的残留物。

8. 发明申请

US20090217465A1 Process for Hair Dyeing Comprising Application of Composite Pigment 审中-公开
标题翻译：包含复合颜料应用的染发工艺
公开(公告)号：US20090217465A1
公开(公告)日：2009-09-03
申请号：US12084023
申请日：2006-10-16
申请人： Christian Cremer , Andreas Mühlebach , Olof Wallquist , Thomas Giesenberg , Beate Fröhling , Richard Lewis Riggs
发明人： Christian Cremer , Andreas Mühlebach , Olof Wallquist , Thomas Giesenberg , Beate Fröhling , Richard Lewis Riggs
IPC分类号： A61K8/58 , A61K8/02
CPC分类号： C09C1/407 , A61K8/25 , A61K8/355 , A61Q5/065 , A61Q5/10 , B82Y30/00 , C01P2002/88 , C01P2004/62 , C01P2004/64 , C09C1/3063 , C09C1/3081 , C09C1/309 , C09C3/12
摘要： Disclosed is a process for dyeing of keratin-containing fibers comprising treating the fibers with at least one functionalized particle comprising on the surface an organic chromophore which is bound via a bridge member, wherein the particles are based on SiO2, Al2O3 or mixtures thereof, and the functionalized particles carry a positive charge.
摘要翻译：公开了一种用于染色含角蛋白纤维的方法，包括用至少一种官能化颗粒处理纤维，所述官能化颗粒在表面上包含通过桥构件结合的有机发色团，其中所述颗粒基于SiO 2，Al 2 O 3或其混合物，以及官能化颗粒携带正电荷。

9. 发明申请

US20090296195A1 Coloured Particles for Electrophoretic Displays 有权
标题翻译：用于电泳显示器的彩色颗粒
公开(公告)号：US20090296195A1
公开(公告)日：2009-12-03
申请号：US12083884
申请日：2006-10-16
申请人： Margherita Fontana , Gabriele Baisch , Thomas Giesenberg , Laurent Michau , Reinhold Öhrlein , Andreas Mühlebach
发明人： Margherita Fontana , Gabriele Baisch , Thomas Giesenberg , Laurent Michau , Reinhold Öhrlein , Andreas Mühlebach
IPC分类号： G02F1/167 , C07K1/26
CPC分类号： G02F1/167 , B82Y30/00 , C01P2002/88 , C01P2004/62 , C01P2004/64 , C09C1/3081 , C09C1/407 , C09C3/12
摘要： The present invention discloses the use of functionalized particles as electrophoretic displaying particles, wherein the functionalized particles are SiO2, Al2O3 or mixed SiO2 and Al2O3 particles comprising, covalently bound to an oxygen atom on the surface, a radical of formula (1), wherein R1 and R2 are independently of each other hydrogen, particle surface-O—, or a substituent, n is 1, 2, 3, 4, 5, 6, 7 or 8, B is the direct bond or a bridge member, and D is the residue of an organic chromophore.
摘要翻译：本发明公开了使用官能化颗粒作为电泳显示颗粒，其中官能化颗粒是SiO 2，Al 2 O 3或混合SiO 2和Al 2 O 3颗粒，其包含与表面上的氧原子共价结合的式（1）基团，其中R 1 和R2彼此独立地为氢，颗粒表面-O-或取代基，n为1,2,3,4,5,6,7或8，B为直接键或桥构件，D为有机发色团的残留物。

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